CN106835855A - 一种耐腐蚀防水墙纸及其制备方法 - Google Patents
一种耐腐蚀防水墙纸及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种耐腐蚀防水墙纸,包括基材层、防水层和耐腐蚀层,基材层的外周涂覆有防水层,所述防水层远离基材层的外周涂覆有耐腐蚀层,其中:耐腐蚀层的原料包括聚氨酯丙烯酸酯、有机硅丙烯酸酯、丙烯酸乳液、硅溶胶、偶联剂、乳化剂、烷基丁二酸酯磺酸钠、甲基丙烯酸甲酯、丙烯酸丁酯、钛白粉、改性助剂、云母、硅灰石粉、高岭土、滑石粉、羟乙基纤维素、分散剂、消泡剂、增稠剂和水。本发明还提出上述一种耐腐蚀防水墙纸的制备方法。本发明制备得到的墙纸具有优异的耐腐蚀防水性能。
Description
技术领域
本发明涉及墙纸领域,尤其涉及一种耐腐蚀防水墙纸及其制备方法。
背景技术
墙纸,也称为壁纸,是一种用于裱糊墙面的室内装修材料,广泛用于住宅、办公室、宾馆、酒店的室内装修等。材质不局限于纸,也包含其他材料。因为具有色彩多样、图案丰富、豪华气派、安全环保、施工方便、价格适宜等多种其它室内装饰材料所无法比拟的特点,故在欧美、日本等发达国家和地区得到相当程度的普及。壁纸分为很多类,如覆膜壁纸、涂布壁纸、压花壁纸等。通常用漂白化学木浆生产原纸,再经不同工序的加工处理,如涂布、印刷、压纹或表面覆塑,最后经裁切、包装后出厂。具有一定的强度、韧度、美观的外表和良好的抗水性能。
现有技术中墙纸的耐腐蚀和防水性能无法满足实际使用时的需求,因此亟需设计一种耐腐蚀防水墙纸来解决现有技术中的问题。
发明内容
为解决背景技术中存在的技术问题,本发明提出一种耐腐蚀防水墙纸及其制备方法,制备得到的墙纸具有优异的耐腐蚀防水性能。
本发明提出的一种耐腐蚀防水墙纸,包括基材层、防水层和耐腐蚀层,基材层的外周涂覆有防水层,所述防水层远离基材层的外周涂覆有耐腐蚀层,其中:
基材层为木浆纸、无纺纸、布中的任意一种;
防水层的原料按重量份包括:改性石蜡15-25份、乳化剂AEO-03 1-5份、乳化剂TX-10 3-9份、油酸三乙醇胺2-5份、聚乙烯醇1-4份、羧乙基纤维素钠3-5份、氨基硅油1-4份、三羟乙基甲基季铵硫酸甲酯2-5份、三硬脂酸甘油酯3-5份、十二烷基苯磺酸钠1-4份、N-甲基吡咯烷酮3-6份、润湿剂2-5份、研磨剂1-5份;
耐腐蚀层的原料按重量份包括:聚氨酯丙烯酸酯80-120份、有机硅丙烯酸酯15-35份、丙烯酸乳液40-80份、硅溶胶20-60份、偶联剂10-30份、乳化剂5-15份、烷基丁二酸酯磺酸钠2-8份、甲基丙烯酸甲酯3-9份、丙烯酸丁酯4-12份、钛白粉3-6份、改性助剂2-12份、云母4-12份、硅灰石粉6-18份、高岭土4-9份、滑石粉3-9份、羟乙基纤维素1-6份、分散剂2-8份、消泡剂3-8份、增稠剂1-5份、水12-24份。
优选地,防水层的原料中,改性石蜡按如下工艺进行制备:将石蜡于水浴中加热至80-90℃使其融化,然后加入疏水纳米二氧化硅溶液和甲苯混合均匀,于9000-12000r/min分散20-40min,冷却至室温得到改性石蜡。
优选地,防水层的原料中,改性石蜡的制备工艺中,疏水纳米二氧化硅溶液的质量分数为2.5-4.5%。
优选地,防水层的原料中,改性石蜡的制备工艺中,石蜡、疏水纳米二氧化硅溶液和甲苯的重量比为1-3:3-6:4-8。
优选地,耐腐蚀层的原料中,改性助剂的原料按重量份包括:硅灰石4-8份、纳米碳酸钙3-6份、硬脂酸锌3-8份、纳米二氧化锌3-5份、纳米氮化铝2-6份、纳米二氧化硅2-5份、硬脂酸稀土2-5份、轻质活性钙4-8份、纳米陶瓷粉3-5份、羟丙基甲基纤维素3-9份、甲基丙烯酸酯2-5份、硅烷偶联剂KH-5703-6份、润滑剂4-8份。
优选地,耐腐蚀层的原料中,改性助剂按如下工艺进行制备:将硅灰石研磨成20-30目粉末状物料a,然后放入95-105℃的烘箱中烘干,然后加入纳米碳酸钙和硬脂酸锌混合均匀,在50-60℃温度下密封低速搅拌10-25min,然后与纳米二氧化锌、纳米氮化铝、纳米二氧化硅、硬脂酸稀土、轻质活性钙和纳米陶瓷粉混合均匀,45-55℃密封低速搅拌5-10min,再加入羟丙基甲基纤维素、甲基丙烯酸酯、硅烷偶联剂KH-570和润滑剂,升温至135-140℃,低速搅拌10-20min,出料,冷却至室温得到改性助剂。
本发明的一种耐腐蚀防水墙纸的制备方法,包括如下步骤:
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层,制得墙纸半成品;
S2、在墙纸半成品的正面通过圆网套印工艺印制防水层;
S3、将耐腐蚀层的原料组合物采用圆网套印工艺印制在防水层的层上,形成耐腐蚀层,印刷完成后置于烘箱内干燥,冷却至室温得到耐腐蚀防水墙纸。
优选地,S3中,圆网套印工艺参数具体为:印刷速度为5-15m/min;烘箱温度为先用100-120℃烘干,再用160-180℃成膜形成附着效果;圆网上形成有六角网孔,六角网孔的开孔率为30-45%;成品圆网的网厚度为0.1-0.3mm。
优选地,S3中,干燥的温度为70-90℃,干燥的时间为4-6h。
本发明的一种耐腐蚀防水墙纸,包括基材层、防水层和耐腐蚀层,基材层的外周涂覆有防水层,所述防水层远离基材层的外周涂覆有耐腐蚀层,其中:防水层的原料包括改性石蜡、乳化剂AEO-03、乳化剂TX-10、油酸三乙醇胺、聚乙烯醇、羧乙基纤维素钠、氨基硅油、三羟乙基甲基季铵硫酸甲酯、三硬脂酸甘油酯、十二烷基苯磺酸钠、N-甲基吡咯烷酮、润湿剂和研磨剂;以改性石蜡为主料,添加乳化剂AEO-03、乳化剂TX-10、油酸三乙醇胺、聚乙烯醇、羧乙基纤维素钠、氨基硅油、三羟乙基甲基季铵硫酸甲酯、三硬脂酸甘油酯、十二烷基苯磺酸钠、N-甲基吡咯烷酮、润湿剂和研磨剂作为助剂,得到的防水层具有优异的附着性能,且具有优异的防水性能。其中改性石蜡通过将石蜡于水浴中加热使其融化,然后加入疏水纳米二氧化硅溶液和甲苯混合均匀,分散后冷却至室温得到改性石蜡,运用到防水层的制备,能够有效提高防水层的疏水性能。耐腐蚀层的原料包括聚氨酯丙烯酸酯、有机硅丙烯酸酯、丙烯酸乳液、硅溶胶、偶联剂、乳化剂、烷基丁二酸酯磺酸钠、甲基丙烯酸甲酯、丙烯酸丁酯、钛白粉、改性助剂、云母、硅灰石粉、高岭土、滑石粉、羟乙基纤维素、分散剂、消泡剂、增稠剂和水。以聚氨酯丙烯酸酯、有机硅丙烯酸酯、丙烯酸乳液和硅溶胶为主料,以偶联剂、乳化剂、烷基丁二酸酯磺酸钠、甲基丙烯酸甲酯、丙烯酸丁酯、羟乙基纤维素、分散剂、消泡剂、增稠剂和水为助剂,以钛白粉、改性助剂、云母、硅灰石粉、高岭土和滑石粉为填料,经过主料、助剂和填料的配合,合理控制配比,得到的耐腐蚀层具有优异的耐腐蚀性能。其中改性助剂通过将硅灰石研磨成粉末状物料a,然后放入烘箱中烘干,然后加入纳米碳酸钙和硬脂酸锌混合均匀,密封低速搅拌,然后与纳米二氧化锌、纳米氮化铝、纳米二氧化硅、硬脂酸稀土、轻质活性钙和纳米陶瓷粉混合均匀,密封低速搅拌,再加入羟丙基甲基纤维素、甲基丙烯酸酯、硅烷偶联剂KH-570和润滑剂,升温后低速搅拌,出料,冷却至室温得到改性助剂,运用到耐腐蚀层的制备中,有效提高了耐腐蚀层的耐腐蚀性能。
附图说明
图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
具体实施方式
下面结合具体实施例对本发明做出详细说明,应当了解,实施例只用于说明本发明,而不是用于对本发明进行限定,任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
实施例1
如图1所示,图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
参照图1,本发明的一种耐腐蚀防水墙纸,包括基材层1、防水层2和耐腐蚀层3,基材层1的外周涂覆有防水层2,所述防水层2远离基材层1的外周涂覆有耐腐蚀层3,其中:
基材层1为木浆纸;
防水层2的原料按重量份包括:改性石蜡20份、乳化剂AEO-03 3份、乳化剂TX-10 6份、油酸三乙醇胺3.5份、聚乙烯醇2.5份、羧乙基纤维素钠4份、氨基硅油2.5份、三羟乙基甲基季铵硫酸甲酯3.5份、三硬脂酸甘油酯4份、十二烷基苯磺酸钠2.5份、N-甲基吡咯烷酮4.5份、润湿剂3.5份、研磨剂3份;
耐腐蚀层3的原料按重量份包括:聚氨酯丙烯酸酯100份、有机硅丙烯酸酯25份、丙烯酸乳液60份、硅溶胶40份、偶联剂20份、乳化剂10份、烷基丁二酸酯磺酸钠5份、甲基丙烯酸甲酯6份、丙烯酸丁酯8份、钛白粉4.5份、改性助剂7份、云母8份、硅灰石粉12份、高岭土6.5份、滑石粉6份、羟乙基纤维素3.5份、分散剂5份、消泡剂5.5份、增稠剂3份、水18份。
实施例2
如图1所示,图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
参照图1,本发明的一种耐腐蚀防水墙纸,包括基材层1、防水层2和耐腐蚀层3,基材层1的外周涂覆有防水层2,所述防水层2远离基材层1的外周涂覆有耐腐蚀层3,其中:
基材层1为无纺纸;
防水层2的原料按重量份包括:改性石蜡15份、乳化剂AEO-03 5份、乳化剂TX-10 3份、油酸三乙醇胺5份、聚乙烯醇1份、羧乙基纤维素钠5份、氨基硅油1份、三羟乙基甲基季铵硫酸甲酯5份、三硬脂酸甘油酯3份、十二烷基苯磺酸钠4份、N-甲基吡咯烷酮3份、润湿剂5份、研磨剂1份;
耐腐蚀层3的原料按重量份包括:聚氨酯丙烯酸酯80份、有机硅丙烯酸酯35份、丙烯酸乳液40份、硅溶胶60份、偶联剂10份、乳化剂15份、烷基丁二酸酯磺酸钠2份、甲基丙烯酸甲酯9份、丙烯酸丁酯4份、钛白粉6份、改性助剂2份、云母12份、硅灰石粉6份、高岭土9份、滑石粉3份、羟乙基纤维素6份、分散剂2份、消泡剂8份、增稠剂1份、水24份。
防水层2的原料中,改性石蜡按如下工艺进行制备:按重量份将1份石蜡于水浴中加热至90℃使其融化,然后加入3份质量分数为4.5%的疏水纳米二氧化硅溶液和4份甲苯混合均匀,于12000r/min分散20min,冷却至室温得到改性石蜡。
耐腐蚀层3的原料中,改性助剂按如下工艺进行制备:按重量份将4份硅灰石研磨成30目粉末状物料a,然后放入95℃的烘箱中烘干,然后加入6份纳米碳酸钙和3份硬脂酸锌混合均匀,在60℃温度下密封低速搅拌10min,然后与5份纳米二氧化锌、2份纳米氮化铝、5份纳米二氧化硅、2份硬脂酸稀土、8份轻质活性钙和3份纳米陶瓷粉混合均匀,55℃密封低速搅拌5min,再加入9份羟丙基甲基纤维素、2份甲基丙烯酸酯、6份硅烷偶联剂KH-570和4份润滑剂,升温至140℃,低速搅拌10min,出料,冷却至室温得到改性助剂。
实施例3
如图1所示,图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
参照图1,本发明的一种耐腐蚀防水墙纸,包括基材层1、防水层2和耐腐蚀层3,基材层1的外周涂覆有防水层2,所述防水层2远离基材层1的外周涂覆有耐腐蚀层3,其中:
基材层1为布;
防水层2的原料按重量份包括:改性石蜡25份、乳化剂AEO-03 1份、乳化剂TX-10 9份、油酸三乙醇胺2份、聚乙烯醇4份、羧乙基纤维素钠3份、氨基硅油4份、三羟乙基甲基季铵硫酸甲酯2份、三硬脂酸甘油酯5份、十二烷基苯磺酸钠1份、N-甲基吡咯烷酮6份、润湿剂2份、研磨剂5份;
耐腐蚀层3的原料按重量份包括:聚氨酯丙烯酸酯120份、有机硅丙烯酸酯15份、丙烯酸乳液80份、硅溶胶20份、偶联剂30份、乳化剂5份、烷基丁二酸酯磺酸钠8份、甲基丙烯酸甲酯3份、丙烯酸丁酯12份、钛白粉3份、改性助剂12份、云母4份、硅灰石粉18份、高岭土4份、滑石粉9份、羟乙基纤维素1份、分散剂8份、消泡剂3份、增稠剂5份、水12份。
本发明的一种耐腐蚀防水墙纸的制备方法,包括如下步骤:
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层,制得墙纸半成品;
S2、在墙纸半成品的正面通过圆网套印工艺印制防水层;
S3、将耐腐蚀层的原料组合物采用圆网套印工艺印制在防水层的层上,形成耐腐蚀层,印刷完成后置于烘箱内干燥,干燥的温度为90℃,干燥的时间为4h,冷却至室温得到耐腐蚀防水墙纸,其中圆网套印工艺参数具体为:印刷速度为15m/min;烘箱温度为先用100℃烘干,再用180℃成膜形成附着效果;圆网上形成有六角网孔,六角网孔的开孔率为30%;成品圆网的网厚度为0.3mm。
实施例4
如图1所示,图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
参照图1,本发明的一种耐腐蚀防水墙纸,包括基材层1、防水层2和耐腐蚀层3,基材层1的外周涂覆有防水层2,所述防水层2远离基材层1的外周涂覆有耐腐蚀层3,其中:
基材层1为无纺纸;
防水层2的原料按重量份包括:改性石蜡18份、乳化剂AEO-03 4份、乳化剂TX-10 4份、油酸三乙醇胺4份、聚乙烯醇2份、羧乙基纤维素钠4.5份、氨基硅油2份、三羟乙基甲基季铵硫酸甲酯4份、三硬脂酸甘油酯3.5份、十二烷基苯磺酸钠3份、N-甲基吡咯烷酮4份、润湿剂4份、研磨剂2份;
耐腐蚀层3的原料按重量份包括:聚氨酯丙烯酸酯85份、有机硅丙烯酸酯32份、丙烯酸乳液45份、硅溶胶55份、偶联剂15份、乳化剂12份、烷基丁二酸酯磺酸钠3份、甲基丙烯酸甲酯8份、丙烯酸丁酯5份、钛白粉5份、改性助剂4份、云母11份、硅灰石粉8份、高岭土8份、滑石粉4份、羟乙基纤维素5份、分散剂3份、消泡剂7份、增稠剂2份、水22份。
防水层2的原料中,改性石蜡按如下工艺进行制备:按重量份将1.5份石蜡于水浴中加热至55℃使其融化,然后加入4份质量分数为4.2%的疏水纳米二氧化硅溶液和5份甲苯混合均匀,于11000r/min分散25min,冷却至室温得到改性石蜡。
耐腐蚀层3的原料中,改性助剂按如下工艺进行制备:按重量份将5份硅灰石研磨成28目粉末状物料a,然后放入95℃的烘箱中烘干,然后加入5份纳米碳酸钙和4份硬脂酸锌混合均匀,在58℃温度下密封低速搅拌15min,然后与4.5份纳米二氧化锌、3份纳米氮化铝、4份纳米二氧化硅、3份硬脂酸稀土、7份轻质活性钙和3.5份纳米陶瓷粉混合均匀,52℃密封低速搅拌6min,再加入8份羟丙基甲基纤维素、3份甲基丙烯酸酯、5份硅烷偶联剂KH-570和5份润滑剂,升温至139℃,低速搅拌12min,出料,冷却至室温得到改性助剂。
本发明的一种耐腐蚀防水墙纸的制备方法,包括如下步骤:
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层,制得墙纸半成品;
S2、在墙纸半成品的正面通过圆网套印工艺印制防水层;
S3、将耐腐蚀层的原料组合物采用圆网套印工艺印制在防水层的层上,形成耐腐蚀层,印刷完成后置于烘箱内干燥,干燥的温度为75℃,干燥的时间为5.5h,冷却至室温得到耐腐蚀防水墙纸,其中圆网套印工艺参数具体为:印刷速度为8m/min;烘箱温度为先用115℃烘干,再用165℃成膜形成附着效果;圆网上形成有六角网孔,六角网孔的开孔率为40%;成品圆网的网厚度为0.15mm。
实施例5
如图1所示,图1为本发明提出的一种耐腐蚀防水墙纸的结构示意图。
参照图1,本发明的一种耐腐蚀防水墙纸,包括基材层1、防水层2和耐腐蚀层3,基材层1的外周涂覆有防水层2,所述防水层2远离基材层1的外周涂覆有耐腐蚀层3,其中:
基材层1为木浆纸;
防水层2的原料按重量份包括:改性石蜡22份、乳化剂AEO-03 2份、乳化剂TX-10 8份、油酸三乙醇胺3份、聚乙烯醇3份、羧乙基纤维素钠3.5份、氨基硅油3份、三羟乙基甲基季铵硫酸甲酯3份、三硬脂酸甘油酯4.5份、十二烷基苯磺酸钠2份、N-甲基吡咯烷酮5份、润湿剂3份、研磨剂4份;
耐腐蚀层3的原料按重量份包括:聚氨酯丙烯酸酯115份、有机硅丙烯酸酯18份、丙烯酸乳液75份、硅溶胶25份、偶联剂25份、乳化剂8份、烷基丁二酸酯磺酸钠7份、甲基丙烯酸甲酯4份、丙烯酸丁酯11份、钛白粉4份、改性助剂10份、云母5份、硅灰石粉16份、高岭土5份、滑石粉8份、羟乙基纤维素2份、分散剂7份、消泡剂4份、增稠剂4份、水14份。
防水层2的原料中,改性石蜡按如下工艺进行制备:按重量份将2.5份石蜡于水浴中加热至82℃使其融化,然后加入5份质量分数为2.8%的疏水纳米二氧化硅溶液和7份甲苯混合均匀,于10000r/min分散35min,冷却至室温得到改性石蜡。
耐腐蚀层3的原料中,改性助剂按如下工艺进行制备:按重量份将7份硅灰石研磨成23目粉末状物料a,然后放入102℃的烘箱中烘干,然后加入4份纳米碳酸钙和7份硬脂酸锌混合均匀,在52℃温度下密封低速搅拌20min,然后与3.5份纳米二氧化锌、5份纳米氮化铝、3份纳米二氧化硅、4份硬脂酸稀土、5份轻质活性钙和4.5份纳米陶瓷粉混合均匀,48℃密封低速搅拌9min,再加入4份羟丙基甲基纤维素、4份甲基丙烯酸酯、4份硅烷偶联剂KH-570和7份润滑剂,升温至136℃,低速搅拌18min,出料,冷却至室温得到改性助剂。
本发明的一种耐腐蚀防水墙纸的制备方法,包括如下步骤:
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层,制得墙纸半成品;
S2、在墙纸半成品的正面通过圆网套印工艺印制防水层;
S3、将耐腐蚀层的原料组合物采用圆网套印工艺印制在防水层的层上,形成耐腐蚀层,印刷完成后置于烘箱内干燥,干燥的温度为85℃,干燥的时间为4.5h,冷却至室温得到耐腐蚀防水墙纸,其中圆网套印工艺参数具体为:印刷速度为12m/min;烘箱温度为先用105℃烘干,再用175℃成膜形成附着效果;圆网上形成有六角网孔,六角网孔的开孔率为35%;成品圆网的网厚度为0.25mm。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (9)
1.一种耐腐蚀防水墙纸,包括基材层(1)、防水层(2)和耐腐蚀层(3),基材层(1)的外周涂覆有防水层(2),所述防水层(2)远离基材层(1)的外周涂覆有耐腐蚀层(3),其特征在于,其中:
基材层(1)为木浆纸、无纺纸、布中的任意一种;
防水层(2)的原料按重量份包括:改性石蜡15-25份、乳化剂AEO-03 1-5份、乳化剂TX-10 3-9份、油酸三乙醇胺2-5份、聚乙烯醇1-4份、羧乙基纤维素钠3-5份、氨基硅油1-4份、三羟乙基甲基季铵硫酸甲酯2-5份、三硬脂酸甘油酯3-5份、十二烷基苯磺酸钠1-4份、N-甲基吡咯烷酮3-6份、润湿剂2-5份、研磨剂1-5份;
耐腐蚀层(3)的原料按重量份包括:聚氨酯丙烯酸酯80-120份、有机硅丙烯酸酯15-35份、丙烯酸乳液40-80份、硅溶胶20-60份、偶联剂10-30份、乳化剂5-15份、烷基丁二酸酯磺酸钠2-8份、甲基丙烯酸甲酯3-9份、丙烯酸丁酯4-12份、钛白粉3-6份、改性助剂2-12份、云母4-12份、硅灰石粉6-18份、高岭土4-9份、滑石粉3-9份、羟乙基纤维素1-6份、分散剂2-8份、消泡剂3-8份、增稠剂1-5份、水12-24份。
2.根据权利要求1所述的耐腐蚀防水墙纸,其特征在于,防水层(2)的原料中,改性石蜡按如下工艺进行制备:将石蜡于水浴中加热至80-90℃使其融化,然后加入疏水纳米二氧化硅溶液和甲苯混合均匀,于9000-12000r/min分散20-40min,冷却至室温得到改性石蜡。
3.根据权利要求1或2所述的耐腐蚀防水墙纸,其特征在于,防水层(2)的原料中,改性石蜡的制备工艺中,疏水纳米二氧化硅溶液的质量分数为2.5-4.5%。
4.根据权利要求1-3任一项所述的耐腐蚀防水墙纸,其特征在于,防水层(2)的原料中,改性石蜡的制备工艺中,石蜡、疏水纳米二氧化硅溶液和甲苯的重量比为1-3:3-6:4-8。
5.根据权利要求1-4任一项所述的耐腐蚀防水墙纸,其特征在于,耐腐蚀层(3)的原料中,改性助剂的原料按重量份包括:硅灰石4-8份、纳米碳酸钙3-6份、硬脂酸锌3-8份、纳米二氧化锌3-5份、纳米氮化铝2-6份、纳米二氧化硅2-5份、硬脂酸稀土2-5份、轻质活性钙4-8份、纳米陶瓷粉3-5份、羟丙基甲基纤维素3-9份、甲基丙烯酸酯2-5份、硅烷偶联剂KH-5703-6份、润滑剂4-8份。
6.根据权利要求1-5任一项所述的耐腐蚀防水墙纸,其特征在于,耐腐蚀层(3)的原料中,改性助剂按如下工艺进行制备:将硅灰石研磨成20-30目粉末状物料a,然后放入95-105℃的烘箱中烘干,然后加入纳米碳酸钙和硬脂酸锌混合均匀,在50-60℃温度下密封低速搅拌10-25min,然后与纳米二氧化锌、纳米氮化铝、纳米二氧化硅、硬脂酸稀土、轻质活性钙和纳米陶瓷粉混合均匀,45-55℃密封低速搅拌5-10min,再加入羟丙基甲基纤维素、甲基丙烯酸酯、硅烷偶联剂KH-570和润滑剂,升温至135-140℃,低速搅拌10-20min,出料,冷却至室温得到改性助剂。
7.一种根据权利要求1-6任一项所述的耐腐蚀防水墙纸的制备方法,其特征在于,包括如下步骤:
S1、在基材层表面通过印刷工艺在基材层上形成具有图案的印刷层,制得墙纸半成品;
S2、在墙纸半成品的正面通过圆网套印工艺印制防水层;
S3、将耐腐蚀层的原料组合物采用圆网套印工艺印制在防水层的层上,形成耐腐蚀层,印刷完成后置于烘箱内干燥,冷却至室温得到耐腐蚀防水墙纸。
8.根据权利要求7所述的耐腐蚀防水墙纸的制备方法,其特征在于,S3中,圆网套印工艺参数具体为:印刷速度为5-15m/min;烘箱温度为先用100-120℃烘干,再用160-180℃成膜形成附着效果;圆网上形成有六角网孔,六角网孔的开孔率为30-45%;成品圆网的网厚度为0.1-0.3mm。
9.根据权利要求7或8所述的耐腐蚀防水墙纸的制备方法,其特征在于,S3中,干燥的温度为70-90℃,干燥的时间为4-6h。
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