CN107236471A - Glass-cutting adhesive sheet and its manufacture method - Google Patents
Glass-cutting adhesive sheet and its manufacture method Download PDFInfo
- Publication number
- CN107236471A CN107236471A CN201710191565.6A CN201710191565A CN107236471A CN 107236471 A CN107236471 A CN 107236471A CN 201710191565 A CN201710191565 A CN 201710191565A CN 107236471 A CN107236471 A CN 107236471A
- Authority
- CN
- China
- Prior art keywords
- glass
- adhesive sheet
- agent layer
- cutting
- adhering agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
Abstract
Present invention offer is a kind of to be suppressed to collapse broken, effectively cutting glass plate glass-cutting adhesive sheet and its manufacture method.The glass-cutting that the present invention is provided possesses with adhesive sheet：Base material and be laminated in the base material at least one side adhering agent layer, wherein, the thickness of the base material is for 30 μm less than 130 μm, and storage modulus of the adhering agent layer at 100 DEG C is 6~50kPa.
Description
Technical field
Use viscous the present invention relates to a kind of glass-cutting for cutting glass plate, to obtain chip glass (glass chip)
Piece and its manufacture method.
Background technology
When manufacture is loaded into the camera module of mobile phone and smart mobile phone, it is necessary to trickle sheet glass.It is such
Sheet glass can be cut a glass sheets and obtained by using cutting sheet material.I.e., it is possible to by the way that glass plate is affixed on into cutting
After sheet material, the glass plate is cut using cutting blade, the glass (hereinafter sometimes referred to " chip glass ") of monolithic is obtained.Closely
Nian Lai, because of the development of the slimming of smart mobile phone etc., the camera module loaded is also minimized, as a result, needing to manufacture more
Thin small chip glass is (hereinafter sometimes referred to " small chip ".).
During the crisp material such as glass-cutting, easily produce and collapse broken (chipping).Here, so-called " collapsing broken ", refers to cutting
When chip glass end or cut the meaning of face defect.The thickness of glass plate is thinner, and more significantly generation is collapsed broken.
Patent Document 1 discloses a kind of glass substrate cutting adhesion that adhering agent layer is provided with base material film
Piece.At this, Patent Document 1 discloses the film that by using thickness be more than 130 μm and tensile modulus of elasticity is more than 1GPa
As base material film, the thickness for further making adhering agent layer is less than 9 μm, so as to reduce adhesive sheet because of the pressure of cutting blade
Deformation, can suppress generation and collapse broken and chip to disperse (0010 section of patent document 1).
Prior art literature
Patent document
Patent document 1：Japanese Patent No. 3838637
The content of the invention
The technical problem to be solved in the present invention
In recent years, the miniaturization of camera module is continued to develop, and the size of required chip glass also becomes very small.
Adhesive sheet disclosed in patent document 1, it is impossible to which the chip for fully suppressing such small chip disperses.
The present invention in view of above-mentioned actual conditions and complete, it is therefore intended that provide one kind can suppress to collapse broken and can effectively cut
Cut glass-cutting adhesive sheet and its manufacture method of glass plate.
Solve the technological means of technical problem
To achieve the above object, first, the present invention provides a kind of glass-cutting adhesive sheet, and it possesses：Base material and stacking
In the adhering agent layer of at least one side of the base material, it is characterised in that：The thickness of the base material is 30 μm less than 130 μ
M, storage modulus of the adhering agent layer at 100 DEG C is 6~50kPa (invention 1).
In foregoing invention (invention 1), by making base material that there is above-mentioned thickness, the operation of glass-cutting adhesive sheet can be made
Property is good.Moreover, by making adhering agent layer show the above-mentioned storage modulus at 100 DEG C, frictional heat when because of cutting makes
When the temperature of adhering agent layer is into about 100 DEG C of high temperature, it can fully suppress to produce vibration during cutting, even as a result, will be thin
Glass plate when cutting into small chip, can also suppress generation collapse it is broken.By the thickness and adhering agent layer that control base material as described above
Modulus of elasticity, small chip effectively can be obtained by thin glass plate.
In foregoing invention (invention 1), the thickness of the adhering agent layer, preferably 5~25 μm (invention 2).
In foregoing invention (invention 1,2), storage modulus of the adhering agent layer at 23 DEG C is preferably 30~100kPa
(invention 3).
In foregoing invention (invention 1~3), the face of the side opposite with the base material of the adhering agent layer is pasted onto alkali-free
On glass, after standing 20 minutes, the glass-cutting adhesive sheet is to the adhesion strength of the alkali-free glass, preferably 8000
~25000mN/25mm (invention 4).
In foregoing invention (invention 1~4), the adhering agent layer, pass through JIS Z0237：Method described in 1991
It is middle peeling rate is changed to the condition of 1mm/ minutes, the energy that is determined using probe sticky (probe tack) is preferably 0.01
~5mJ/5mm Φ (invention 5).
In foregoing invention (invention 1~5), the adhering agent layer preferably forms (hair by the sticker of energy ray-curable
It is bright 6).
In foregoing invention (invention 6), preferably described adhering agent layer is by sticker that adhesion agent composition is formed and shape
Into the adhesion agent composition contains (methyl) acrylate copolymer (A) (hair that side chain is imported with energy ray-curable group
It is bright 7).
In foregoing invention (invention 7), the adhesion agent composition preferably further contains except described (methyl) acrylic acid
Energy ray-curable compound (B) (invention 8) beyond ester copolymer (A).
In foregoing invention (invention 7,8), the adhesion agent composition is preferably further containing crosslinking agent (C) (invention 9).
In foregoing invention (invention 1~9), storage modulus of the base material at 23 DEG C is preferably 100~8000MPa
(invention 10).
Second, the present invention provides a kind of manufacture method of glass-cutting adhesive sheet, and it is used to manufacture the glass-cutting
The method of adhesive sheet (invention 7), it is characterised in that include：Make at least by (methyl) alkyl acrylate monomer (A1) and have
The acrylic copolymer (AP) of monomer (A2) copolymerization containing functional group of reactive functional groups, with can with it is described
The energy content line solidification of the functional group of the functional group reactionses of monomer (A2) containing functional group and the carbon-to-carbon double bond of energy ray-curable
Property group compound (A3) reaction, prepare and (methyl) acrylate copolymer of energy ray-curable group be imported with side chain
(A) process；And using containing the adhesion agent composition for being somebody's turn to do (methyl) acrylate copolymer (A), at least one side of base material
It is laminated the process (invention 11) of adhering agent layer.
In foregoing invention (invention 11), preferably make the acrylic copolymer (AP) and the energy content line curability
The reaction of the compound (A3) of group, selected from the organic compound containing zirconium, the organic compound of titaniferous and stanniferous is organising
Carried out in the presence of at least one of compound organo-metallic catalyst (D) (invention 12).
Invention effect
Glass-cutting according to manufactured by the glass-cutting of the present invention with the manufacture method of adhesive sheet and the utilization present invention is used
Adhesive sheet, can suppress to collapse it is broken, can effectively cutting glass plate.
Embodiment
Hereinafter, embodiments of the present invention are illustrated.
The glass-cutting of present embodiment is with adhesive sheet (hereinafter sometimes referred to simply as " adhesive sheet ".), possess base material and layer
It is laminated on the adhering agent layer of the one side of base material and is configured.
In the glass-cutting adhesive sheet of present embodiment, the thickness of base material is for 30 μm less than 130 μm.In addition,
Storage modulus of the adhering agent layer at 100 DEG C is 6~50kPa.
In the glass-cutting adhesive sheet of present embodiment, by making base material that there is above-mentioned thickness, glass-cutting can be made
Operability becomes good.In addition, by making storage modulus of the adhering agent layer at 100 DEG C in above range, even if during because of cutting
The frictional heat of generation, when making the temperature of adhering agent layer into the condition of high temperature, can also suppress the vibration of adhesive sheet.Thus glass can be suppressed
Collision or glass plate or chip glass between chip cut the accident collision of face and cutting blade, are collapsed so as to suppress generation
It is broken.As a result, small chip effectively can be obtained from thin glass plate.
1. base material
In the glass-cutting adhesive sheet of present embodiment, the thickness of base material for 30 μm less than 130 μm, preferably
For more than 50 μm and be less than 120 μm, particularly preferably more than 70 μm and for less than 110 μm.If the thickness of base material is less than 30 μm,
Then become the vibration of the easily generation adhesive sheet in cutting action, glass plate becomes easily to shift on adhesive sheet, as a result, becoming
Easily produce collapse it is broken, and easily produce chip skew (die shift).In addition, so-called " chip skew ", refers to glass during cutting
The meaning that glass plate is offset from the position of the script on adhesive sheet.If further being cut in the state of chip skew is produced,
Then glass plate can not be cut in target location, as a result, the chip glass with desired shape can not be obtained.In addition, base
When the thickness of material is less than 30 μm, then becomes when operating adhesive sheet or be easily broken off during expansion process.On the other hand, if base material
Thickness is more than 130 μm, then the overall flexibility of adhesive sheet can be reduced, and when being pasted on ring frame or cutting fixture, or
During cutting glass plate, adhesive sheet becomes easily to come off from ring frame or fixture.
In the glass-cutting adhesive sheet of present embodiment, storage modulus of the base material at 23 DEG C be preferably 100~
8000MPa, particularly preferably 1500~7000MPa, more preferably 2000~6000MPa.By making base material at 23 DEG C
Storage modulus be more than 100MPa, adhesive sheet can be lowered and produces vibration in cutting action, suppression glass plate is on adhesive sheet
Displacement, as a result, can effectively suppress generation collapse it is broken, and can also suppress chip skew.In addition, by making base material at 23 DEG C
Storage modulus in below 8000MPa, it can be ensured that the flexibility of base material, make the extensibility (dilatancy) of base material more excellent.Thus,
In expansion process, adhesive sheet shows more excellent dilatancy, the pickup of the chip glass after being cut well.This
Outside, storage modulus of the base material at 23 DEG C, determining device using the dynamic modulus of elasticity, (TA Instrument companies manufacture, commodity
Number " DMA Q800 "), determined with following condition.
0 DEG C of on-test Wen Du ︰
200 DEG C of off-test Wen Du ︰
Rise 3 DEG C/min of Wen Sudu ︰
Pin Shuai ︰ 11Hz
20 μm of Zhen Fu ︰
The base material of the glass-cutting adhesive sheet of present embodiment, as long as with above-mentioned thickness, its constituent material has no spy
Do not limit.Base material may include the film (resin film) using the material of resinae as main material.Preferred substrates are only by resin film structure
Into.As the specific example of resin film, vinyl-vinyl acetate copolymer film, ethene-(methyl) acrylic acid copolymer can be included
The ethene copolymer films such as thing film, ethene-(methyl) acrylate copolymer film；Polyethylene film, polypropylene screen, polybutene film,
The TPO films such as polybutadiene film, polymethylpentene film, ethylene-norbornene copolymer film, norbornene resin film；Polychlorostyrene
The polyvinyl chloride films such as vinyl film, vinyl chloride copolymer film；Polyethylene terephthalate film, polybutylene terephthalate
The polyesters film such as ester film；Polyurethane film；Polyimide film；Polystyrene film；Polycarbonate membrane；Fluororesin film etc..It is used as poly- second
The example of alkene film, can include low density polyethylene (LDPE) (LDPE) film, straight-chain low density polyethylene (LLDPE) film, high-density polyethylene
Alkene (HDPE) film etc..In addition, it is possible to use the Modified Membrane such as cross linking membrane, ionic polymer membranes of these films.Base material can be by upper
State a kind of constituted film in film or the two or more stacked films combined by above-mentioned film.Wherein, from easy
Reach from the viewpoint of described storage modulus, preferably use polyethylene terephthalate film.In addition, in this manual
" (methyl) acrylic acid ", refer to both acrylic acid and methacrylic acid.Other similar terms are also identical.
In the substrate, in above-mentioned film, also can containing pigment, dyestuff, fire retardant, plasticizer, antistatic additive, lubricant,
The various additives such as filler.As pigment, such as can include titanium dioxide, carbon black.In addition, as filler, can illustrate such as
Organic-based material, the mineral-type materials as aerosil as melmac and the gold as nickel particles
Belong to class material.As the content of these additives, though be not particularly limited, be preferably can play to the desired function of base material and
The scope of flatness and flexibility is not lost.
For make adhering agent layer solidification use ultraviolet as irradiation energy line when, preferred substrates are to ultraviolet with wearing
Permeability.In addition, during using electron beam as the energy line, preferred substrates have penetrability to electron beam.
The face of adhering agent layer side in base material, to improve the adaptation with adhering agent layer, can be imposed at bottom layer treatment, corona
Reason, corona treatment, roughened processing (cloudy surface processing) etc. are surface-treated.As roughened processing, for example, it can include pressure
Line processing method, sandblasting processing method etc..In addition, setting various paintings on the face of side opposite with adhering agent layer that also can be in the substrate
Film.
2. adhering agent layer
(1) the thickness transitivity of adhering agent layer
Storage modulus of the adhering agent layer at 100 DEG C be 6~50kPa, preferably 7~40kPa, particularly preferably 10~
30kPa.Typically in glass-cutting adhesive sheet, frictional heat can be produced during cutting, adhering agent layer can become about 100 DEG C of high temperature
State.Under the condition of high temperature so, when adhering agent layer shows the low storage modulus less than 6kPa, then adhesive sheet meeting in cutting
Produce vibration, and glass plate or chip glass are easily shifted on adhesive sheet, as a result, can produce collapse it is broken.If in addition, the energy storage
When modulus is higher than 50kPa, it is accompanied by this, the storage modulus at 23 DEG C (by energy ray-curable described later adhered by adhering agent layer
Dosage form into when, the storage modulus before irradiation energy line at 23 DEG C) also easily uprise, and be difficult to obtain good adherence.
As a result, being difficult to glass plate or chip glass being maintained on adhesive sheet well, it is impossible to which collapsing when fully suppressing cutting is broken.This
Outside, in this manual, when adhering agent layer is formed by the sticker of energy ray-curable described later, the storage modulus is in irradiation
The value determined before energy line.In addition, the measure side of storage modulus of the adhering agent layer before irradiation energy line at 100 DEG C
Method, shown in test example as be described hereinafter.
Storage modulus of the adhering agent layer at 23 DEG C is preferably 30~100kPa, particularly preferably 40~90kPa, further
Preferably 50~80kPa.By making the modulus of elasticity in above range, glass-cutting adhesive sheet can be made to play good adhesion
Chip glass, thus, can be maintained on adhesive sheet by power well, and collapsing when can effectively suppress cutting is broken, and can also press down
Combinations piece is offset and chip disperses.In addition, in this manual, adhering agent layer is by energy ray-curable sticker institute described later shape
Cheng Shi, the storage modulus is the value that is determined before irradiation energy line.In addition, adhering agent layer is before irradiation energy line,
The assay method of storage modulus at 23 DEG C, shown in test example as be described hereinafter.
In the glass-cutting adhesive sheet of present embodiment, the thickness of adhering agent layer is preferably 5~25 μm, more preferably
7~20 μm, particularly preferably 8~19 μm, more preferably 9~15 μm, be still more preferably 10~12 μm.By making to glue
The thickness for oxidant layer is more than 5 μm, is easily controlled adhesion strength, can effectively suppress to collapse it is broken, and can also suppress chip skew and
Chip disperses.In addition, being less than 25 μm by making the thickness of adhering agent layer, it can more reduce adhering agent layer and be produced in cutting and be shaken
It is dynamic, it can effectively suppress glass plate and be shifted on adhesive sheet, as a result, can effectively suppress to collapse broken, and may also suppress chip
Skew.
The energy that adhering agent layer is determined using probe viscosity (is also referred to as " viscosity value " in this specification.), it is preferably
0.01~5mJ/5mm Φ, particularly preferably 0.13~4mJ/5mm Φ, more preferably 0.18~3.5mJ/5mm Φ.Pass through
Make viscosity value in above range, chip glass can be maintained to glass-cutting adhesive sheet well, as a result, cutting can be suppressed
When produce chip disperse.In addition, in this manual, when adhering agent layer is formed by energy ray-curable sticker described later,
The viscosity value is by the value that is determined before irradiation energy line.In addition, in this manual, viscosity value is with JIS Z0237：2009 institutes
The method of record, the condition that peeling rate is changed into 1mm/ minutes is measured, shown in the test example of details as be described hereinafter.
When adhering agent layer is formed by the sticker of energy ray-curable described later, adhering agent layer after irradiation energy line,
Tensile modulus of elasticity at 23 DEG C is preferably 15~70MPa, particularly preferably 50~60MPa, more preferably 23~
50MPa.By making the tensile modulus of elasticity be more than 15MPa, picking up for the chip glass after energy line can be irradiated well
Take.In addition, by making the tensile modulus of elasticity be below 70MPa, the dilatancy of glass-cutting adhesive sheet can be made more excellent, and
It can be picked up well.In addition, adhering agent layer is before irradiation energy line, the measure side of the tensile modulus of elasticity at 23 DEG C
Shown in the test example of method as be described hereinafter.
The gel fraction of the sticker of composition adhering agent layer, preferably 12.5~100%, particularly preferably 37.5~
100%, more preferably 50~95%.The gel fraction of sticker within the above range when, then readily satisfy above-mentioned viscous
The physical property of oxidant layer.In addition, being more than 12.5% by making the gel fraction of sticker, the cohesiveness of sticker can be made good,
The durability of adhering agent layer is maintained.
(2) sticker of adhering agent layer is constituted
Constitute adhering agent layer sticker can be non-curable sticker, or curability sticker.In addition, solid
The sticker for the property changed can be the state after the state before solidification, or solidification.When adhering agent layer is made up of multilayer, also it can be combined
The sticker of non-curable and the sticker of curability.As the sticker of non-curable, for example, it can include acrylic compounds and glue
Agent, rubber-like sticker, silicone sticker, polyurethanes sticker, polyesters sticker, glymes sticker
Deng.As the sticker of curability, such as can include energy ray-curable sticker, Thermocurable sticker.
In the glass-cutting adhesive sheet of present embodiment, adhering agent layer is preferably by the adhesion dosage form of energy ray-curable
Into particularly preferably being formed by the acrylic compounds sticker of energy ray-curable.By making adhering agent layer by energy ray-curable
Sticker is formed, and can solidify sticker before pickup process to adhering agent layer irradiation energy line.Thus, can moderately it drop
Low adhesive sheet can be picked up well to the adhesion strength of chip glass.
Generally, as the acrylic compounds sticker of energy ray-curable, it there are：By being imported with energy containing side chain
(methyl) acrylate copolymer (A) of line curability group and without in addition to (methyl) acrylate copolymer (A)
The acrylic compounds sticker that the adhesion agent composition of energy ray-curable compound (B) is formed (below, is conveniently referred to as sometimes
" X-type ".)；By containing the acrylic polymer (N) without energy ray-curable and except above-mentioned (methyl) acrylic ester copolymer
The acrylic compounds sticker that the adhesion agent composition of energy ray-curable compound (B) beyond thing (A) is formed (below, has
When be conveniently referred to as " Y types ".)；And by being imported with (methyl) acrylate copolymer of energy ray-curable group containing side chain
(A) the adhesion agent composition institute shape of the energy ray-curable compound (B) and in addition to (methyl) acrylate copolymer (A)
Into acrylic compounds sticker (it is following, be conveniently referred to as sometimes " Z-type ".).
In the glass-cutting adhesive sheet of present embodiment, adhering agent layer can by any of the above-described type adhesion dosage form
Into.Particularly, the sticker of X-type is due to showing higher modulus of elasticity in the condition of high temperature, therefore, from cutting when effectively suppress
Collapse it is broken, further suppress chip skew from the viewpoint of, preferably use the sticker of X-type.In addition, the sticker of Y types is due to holding
It is easy to get to excellent viscosity, therefore particularly preferably uses the adhesion of Y types from the viewpoint of suppression chip disperses in cutting
Agent.In addition, using Z-type sticker when, because the modulus of elasticity of the adhering agent layer after irradiation energy line can become higher, because
This, from the viewpoint of good pickup is carried out, preferably uses the sticker of Z-type.
Above-mentioned is imported with (methyl) acrylate copolymer (A) of energy ray-curable group and without energy in side chain
The acrylic polymer (N) of line curability is measured, can be directly contained in adhering agent layer, can also enter with crosslinking agent described later (C)
Row cross-linking reaction and think the form of cross-linking agent and be contained in adhering agent layer.
(2-1) is imported with (methyl) acrylate copolymer (A) of energy ray-curable group in side chain
(methyl) acrylate copolymer (A) of energy ray-curable group is imported with side chain, preferably by making propylene
Acid copolymer (AP), obtain with the reaction of the compound (A3) of energy content line curability group.
Acrylic copolymer (AP), preferably by least making (methyl) alkyl acrylate monomer (A1), and with anti-
Monomer (A2) copolymerization containing functional group of answering property functional group and obtain.
As (methyl) alkyl acrylate monomer (A1), the preferably carbon number of alkyl is 1~18, particularly preferably carbon
Atomicity 1~4.As the specific example of (methyl) alkyl acrylate monomer (A1), can include (methyl) methyl acrylate,
(methyl) ethyl acrylate, (methyl) propyl acrylate, (methyl) n-butyl acrylate, (methyl) acrylic acid n-pentyl ester, (first
Base) the just own ester of acrylic acid, (methyl) 2-EHA, (methyl) Isooctyl acrylate monomer, the positive last of the ten Heavenly stems ester of (methyl) acrylic acid,
(methyl) lauryl acrylate, (methyl) myristyl ester, (methyl) acrylic acid palm ester, (methyl) stearyl acrylate acyl
Ester etc..These monomers can be used alone, and two or more use also can be combined.
The quality of structure division from above-mentioned (methyl) alkyl acrylate monomer (A1) accounts for acrylic copolymer
(AP) ratio of overall quality, particularly preferably preferably 50~98 mass %, 60~95 mass %, more preferably 70
~90 mass %.
As the monomer (A2) containing functional group, using with can be had with the compound (A3) of energy content line curability group
The monomer of the reactive functional groups of some functional group reactionses.The functional group having as the monomer (A2) containing functional group, for example
Hydroxyl, carboxyl, amino, substituted-amino, epoxy radicals etc. can be included, wherein preferably hydroxyl and carboxyl, particularly preferably hydroxyl.
In addition, during using crosslinking agent described later (C), the reactive functional groups that the monomer (A2) containing functional group has also can be with the crosslinking
Agent (C) is reacted.
During using the monomer (monomer of hydroxyl) with hydroxyl as monomer (A2) containing functional group, as its example,
(methyl) acrylic acid hydroxy alkyl ester can be included, as its specific example, can include (methyl) acrylic acid 2- hydroxy methacrylates,
(methyl) acrylic acid 2- hydroxy propyl esters, (methyl) acrylic acid 3- hydroxy propyl esters, (methyl) acrylic acid 2- hydroxybutyls, (methyl) third
Olefin(e) acid 3- hydroxybutyls, (methyl) acrylic acid 4- hydroxybutyls etc..Wherein, examined in terms of the reactivity and copolymerizable of hydroxyl
Consider, be preferably (methyl) acrylic acid 2- hydroxy methacrylates.These monomers can be used alone, and two or more use also can be combined.
During using the monomer (carboxylic monomer) with carboxyl as monomer (A2) containing functional group, as its example,
Ethene unsaturated carboxylic acid can be included, as its specific example, acrylic acid, methacrylic acid, crotonic acid, Malaysia can be included
Acid, itaconic acid, citraconic acid etc..Wherein, from the aspect of the reactivity and copolymerizable of carboxyl, preferred acrylic acid.These monomers can
To be used alone, two or more use also can be combined.
Different types of monomer (A2) containing functional group is used in addition, also can be combined.For example also can be by above-mentioned hydroxyl
Monomer used with carboxylic combination of monomers.
The quality for carrying out the structure division of the monomer (A2) of self-contained functional group accounts for the overall quality of acrylic copolymer (AP)
Ratio, preferably 5~40 mass %, particularly preferably 7~35 mass %, more preferably 10~30 mass %.Pass through
Make the ratio for carrying out the quality of the structure division of the monomer (A2) of self-contained functional group in above range, energy content line curability base can be made
The import volume of (methyl) acrylate copolymer (A) that the compound (A3) of group is imported with energy ray-curable group to side chain exists
Suitable scope.In addition, using crosslinking agent described later (C), can when making the monomer (A2) containing functional group with crosslinking agent (C) reaction
Make the crosslinking degree of the crosslinking agent (C), i.e. gel fraction in suitable scope, can control the physical property such as the cohesiveness of adhering agent layer.
On acrylic copolymer (AP), as its monomer is constituted, except above-mentioned (methyl) alkyl acrylate
Outside monomer (A1) and monomer (A2) containing functional group, it can also contain other monomers.
As other monomers, such as (methyl) methoxyethyl methyl esters, (methyl) acrylic acid methoxy can be included
(methyl) third containing alkoxyalkyl such as base ethyl ester, (methyl) ethioxy methyl esters, (methyl) ethoxyethyl acrylate
Olefin(e) acid ester；(methyl) cyclohexyl acrylate etc. has (methyl) acrylate of aliphatic ring；(methyl) phenyl acrylate etc. has
There is (methyl) acrylate of aromatic ring；The acrylamide of the non-crosslinked property such as acrylamide, Methacrylamide；(methyl) third
The tertiary amine groups with non-crosslinked property of olefin(e) acid N, N- dimethylamino ethyl ester, (methyl) acrylic acid N, N- dimethylamino propyl ester etc.
(methyl) acrylate；Vinyl acetate；Styrene etc..These monomers can be used alone, and two or more make also can be combined
With.
The polymerization methodses of acrylic copolymer (AP) can be random copolymer, or block copolymer.In addition, on
Polymerization, is not particularly limited, it is possible to use general polymerization is polymerize.
The compound (A3) of energy content line curability group, with functional group reactionses that can be with the monomer (A2) containing functional group
Functional group and energy ray-curable carbon-to-carbon double bond.
As functional group that can be with the functional group reactionses of the monomer (A2) containing functional group, for example, it can include isocyanates
Base, epoxy radicals etc., wherein, it is preferably the reactive high NCO with hydroxyl.
As the curability group (energy ray-curable group) of the carbon-to-carbon double bond with energy ray-curable, it is preferably
(methyl) acryloyl group etc..Furthermore it is preferred that there are 1 in the compound (A3) of energy content line curability group in 1 molecule
~5, particularly preferably there are 1~3 energy ray-curable carbon-to-carbon double bond.
As the example of the compound (A3) of energy content line curability group, 2- methylacryoyloxyethyls can be included different
Cyanate, adjacent isopropenyl-bis (alpha, alpha-dimethylbenzyl) based isocyanate, methacryloyl isocyanate, allyl iso cyanurate,
1,1- (double acryloyloxymethyls) ethyl isocyanate；Diisocyanate cpd or polyisocyanate compounds, with hydroxyl second
Acryloyl group monoisocyanate compound obtained from base (methyl) acrylate reactions；Diisocyanate cpd or poly- isocyanide
Ester compound, acryloyl group Dan Yi obtained from the reaction with polyol compound and hydroxyethyl (methyl) acrylate
Cyanate esters etc..Wherein, particularly preferred 2- methylacryoyloxyethyls isocyanates.In addition, energy content line curability base
The compound (A3) of group, can be used alone, and two or more use also can be combined.
It is imported with side chain in the preparation of (methyl) acrylate copolymer (A) of energy ray-curable group, acrylic acid
The preparation of analog copolymer (AP) and acrylic copolymer (AP) are anti-with the compound (A3) of energy content line curability group
Should, it can be carried out by conventional method.In the reaction process, the monomer containing functional group in acrylic copolymer (AP)
(A2) functional group reactionses in reactive functional groups, with the compound (A3) of energy content line curability group.Thus, obtain
Side chain is imported with (methyl) acrylate copolymer (A) of energy ray-curable group.In addition, as described later, acrylic compounds are common
Polymers (AP) and the reaction of the compound (A3) of energy content line curability group, the preferably presence in organo-metallic catalyst (D)
It is lower to carry out.
It is imported with side chain in (methyl) acrylate copolymer (A) of energy ray-curable group, the solidification of energy content line
The amount of reactive functional groups of the amount relative to the monomer (A2) containing functional group of the compound (A3) of property group, preferably 30~
100 moles of %, particularly preferably 40~95 moles %, more preferably 50~90 moles %.
The weight average molecular weight (Mw) of (methyl) acrylate copolymer (A) of energy ray-curable group is imported with side chain
Preferably 100,000~2,500,000, particularly preferably 150,000~2,000,000, more preferably 300,000~1,500,000.In addition, in this explanation
Weight average molecular weight in book is the value that the conversion determined using gel permeation chromatography (GPC) method claims polystyrene standard.By making
Side chain is imported with the weight average molecular weight (Mw) of (methyl) acrylate copolymer (A) of energy ray-curable group in above-mentioned model
Enclose, it is ensured that the coating of adhesion agent composition, and the coherency of adhering agent layer can be made good, therefore, can obtain being suitable to cut
The physical property cut.
(2-2) does not have the acrylic polymer (N) of energy ray-curable
As the acrylic polymer (N) without energy ray-curable, as long as without energy ray-curable, can make
With the polymer of known acrylic compounds.The acrylic polymer, can be formed by a kind of acrylic monomer
Homopolymer or the copolymer that is formed by multiple acrylic acid monomers or by one or more acrylic acid
The copolymer that class monomer is formed with the monomer in addition to acrylic monomer.
The specific species of compound as acrylic monomer, is not particularly limited, as specific example, can include
(methyl) acrylic acid, (methyl) acrylate, its derivative (acrylonitrile, itaconic acid etc.).As more specifically example, it can enumerate
Go out above-mentioned alkyl acrylate monomer (A1) and the monomer (A2) containing functional group, in addition, (methyl) acrylic acid first can be included
Epoxide methyl esters, (methyl) methoxyethyl acrylate, (methyl) ethioxy methyl esters, (methyl) ethoxyethyl acrylate
Deng (methyl) acrylate containing alkoxyalkyl；(methyl) cyclohexyl acrylate etc. has (methyl) acrylic acid of aliphatic ring
Ester；(methyl) phenyl acrylate etc. has (methyl) acrylate of aromatic ring；Acrylamide, Methacrylamide etc. are non-to be handed over
The acrylamide of connection property；(methyl) acrylic acid N, N- dimethylamino ethyl ester, (methyl) acrylic acid N, N- dimethylamino propyl ester
Deng (methyl) acrylate of the tertiary amine groups with non-crosslinked property；Vinyl acetate；Styrene etc..
The acrylic polymer (N) of non-energy line curability is in the reactivity with the monomer (A2) for coming self-contained functional group
During functional group, from the degree for making crosslinking from the viewpoint of good scope, carry out the structural portion of the monomer (A2) of self-contained functional group
The quality divided accounts for the ratio of the overall quality of acrylic polymer, preferably 1~20 mass % or so, more preferably 2~10
Quality %.
The weight average molecular weight (Mw) of acrylic polymer (N) without energy ray-curable is preferably 100,000~250
Ten thousand, particularly preferably 150,000~2,000,000, more preferably 200,000~1,500,000.By making third without energy ray-curable
The weight average molecular weight (Mw) of alkene acids polymers (N) is in above-mentioned scope, it is ensured that the coating of adhesion agent composition, and can
Make the coherency of adhering agent layer good, therefore, the physical property suitable for cutting can be obtained.
(2-3) energy ray-curable compound (B)
Energy ray-curable compound (B), polymerizing curable when referring to be irradiated by ultraviolet, electron beam Isoenergetical line
Compound.As the example of above-mentioned energy ray-curable compound (B), low point with energy line polymerizable group can be included
Son quantifies compound (mono-functional or multi-functional monomer and oligomer), specifically, and trimethylolpropane tris propylene can be used
Acid esters, tetramethylol methane tetraacrylate, pentaerythritol triacrylate, dipentaerythritol monohydroxypentaacryande, two
The acrylate such as the acrylate of pentaerythrite six, BDO diacrylate, 1,6- hexanediyl esters, two rings penta
The acrylate of the skeletons containing annular aliphatic such as diene dimethoxy diacrylate, iso-bornyl acrylate, polyethylene glycol
Diacrylate, oligoester acrylate, urethane acrylate oligomer, epoxy modification acrylate, polyether acrylate,
The acrylic ester compounds such as itaconic acid oligomer.Such compound has energy ray-curable double bond in intramolecular, generally
Molecular weight is 100~30000, preferably 300~10000 or so.
When adhering agent layer in the present embodiment is formed by above-mentioned Y type stickers, the energy in adhesion agent composition
The content of line curability compound (B), relative to the acrylic polymer without energy ray-curable of 100 mass parts
(N), preferably 20~200 mass parts, more preferably particularly preferably 40~160 mass parts, 40~150 mass parts.
When adhering agent layer in the present embodiment is formed by above-mentioned Z-type sticker, the energy in adhesion agent composition
The content of line curability compound (B), the side chain relative to 100 mass parts is imported with (methyl) third of energy ray-curable group
Olefin(e) acid ester copolymer (A), preferably 3~60 mass parts, particularly preferably 5~50 mass parts, more preferably 10~40 matter
Measure part.
(3) crosslinking agent (C)
The adhesion agent composition of adhering agent layer in the present embodiment is formed, preferably comprising can make side chain be imported with energy
(methyl) acrylate copolymer (A) of line curability group or the acrylic polymer (N) without energy ray-curable
The crosslinking agent (C) of crosslinking.Now, the sticker in present embodiment, containing by making (methyl) acrylate copolymer (A)
Or the acrylic polymer (N) and cross-linking agent obtained from the cross-linking reaction of crosslinking agent (C).By using the crosslinking agent (C),
The gel fraction adjustment of sticker of adhering agent layer can will easily be formed in suitable scope, the physical property suitable for cutting is obtained.
As crosslinking agent (C) species, such as epoxy compounds, Polyisocyanate esters compound, metal can be included
The polyimides such as chelates compound, aziridines compound (polyimine) class compound, melmac, ureaformaldehyde tree
Fat, twain-aldehyde compound, methylol polymer, metal alkoxide, metal salt etc..Wherein, it is excellent from the consideration of the reasons such as cross-linking reaction is easily controlled
Choosing uses epoxy compounds or Polyisocyanate esters compound, particularly preferably uses Polyisocyanate esters compound.
As epoxy compounds, can include double (N, the N'- diglycidyl amino methyl) hexamethylenes of such as 1,3-,
N, N, N', N'- four glycidyl group meta-xylylenediamine, ethylene glycol diglycidylether, 1,6-HD two shrink sweet
Oily ether, trimethylolpropane diglycidyl ether, 2-glycidyl aniline, 2-glycidyl amine etc..
Polyisocyanate esters compound is the compound for the NCO that every 1 molecule has more than 2.It can specifically enumerate
Go out, the aromatic poly-isocyanate such as toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate, XDI；
The aliphatic polymeric isocyanates such as hexamethylene diisocyanate；IPDI, hydrogenation diphenylmethane diisocyanates
Ester ring type PIC such as ester etc..Biuret body, the isocyanide urea of these Polyisocyanate esters compounds can further be included
Acid esters body, addition body etc..As addition body, it can include and ethylene glycol, propane diols, neopentyl glycol, trimethylolpropane, castor-oil plant
The reactant of the compound of the reactive hydrogens containing low molecule such as oil.
Crosslinking agent (C), can be used alone one kind, and two or more use also can be combined.
When sticker is X-type or Z-type, the content of the crosslinking agent (C) of the adhesion agent composition of adhering agent layer is formed, relative to
The side chain of 100 mass parts is imported with (methyl) acrylate copolymer (A) of energy ray-curable group, preferably 0.01~15
Mass parts, particularly preferably 0.05~10 mass parts, more preferably 0.1~2 mass parts.In addition, when sticker is Y types,
The content of the crosslinking agent (C) of the adhesion agent composition of adhering agent layer is formed, relative to the acrylic acid without energy ray-curable
Birds of the same feather flock together compound (N), more preferably preferably 3~20 mass parts, particularly preferably 5~17 mass parts, 7~14 mass parts.
(4) organo-metallic catalyst (D)
To obtain (methyl) acrylate copolymer (A) that energy ray-curable group is imported with side chain, make acrylic acid
When the compound (A3) of analog copolymer (AP) and energy content line curability group is reacted, the reaction is preferably in organo-metallic catalyst
(D) carried out in the presence of.As organo-metallic catalyst (D), particularly preferably using selected from the organic compound containing zirconium, titaniferous
At least one in organic compound and stanniferous organic compound.Pass through depositing at such organo-metallic catalyst (D)
In lower reaction, the resulting adhesion agent composition containing (methyl) acrylate copolymer (A) can be formed with more excellent viscous
The adhering agent layer of property, can effectively suppress chip and disperse.Organo-metallic catalyst (D), 3 kinds of above-mentioned organic compounds it
In, at least one of organic compound of organic compound and titaniferous preferably containing zirconium, particularly preferably containing the organic of zirconium
Compound.
As the example of the form of above-mentioned organic compound, alkoxide compound, chelate, acylate etc. can be included,
Wherein preferred chelate.
As organo-metallic catalyst (D) specific example, zirconium alkoxide, zirconium chelate, Titanium alkoxides, titanium chelating can be included
Thing, tin alkoxide, tin chelate etc..Wherein, preferably zirconium chelate.Organo-metallic catalyst (D) can be in these catalyst
One kind is constituted, and can be also made up of two or more in these catalyst.
In the reaction for obtaining being imported with (methyl) acrylate copolymer (A) of energy ray-curable group in side chain
Used in organo-metallic catalyst (D) usage amount, and be not limited.The usage amount should (first relative to 100 mass parts
Base) acrylate copolymer (A) solid constituent, it is especially excellent to be converted into metal gauge, preferably 0.001~10 mass parts
Elect 0.01~5 mass parts, more preferably 0.05~3 mass parts as.In addition, in the present invention, it is so-called " to be converted into metal
Amount ", refer in organo-metallic catalyst (D), remove equivalent to the structure being made up of organic matter molecular weight quality, only with
Addition or adding proportion that the Mass Calculation of metal goes out.
(5) other compositions
The adhesion agent composition of adhering agent layer in the present embodiment is formed, in addition to mentioned component, can also be contained
The various additions such as the coloured materials such as Photoepolymerizationinitiater initiater, crosslinking accelerator, dyestuff or pigment, fire retardant, filler, antistatic additive
Agent.
As Photoepolymerizationinitiater initiater, can include aroma compounds of resting in peace, acetophenone compound, acylphosphine oxide compound,
Sensitising agents such as the light triggers such as cyclopentadiene titanium compound, thioxanthone compounds, peroxide compound, amine or quinone etc..Specifically, can example
Show Alpha-hydroxy cyclohexyl benzophenone, styrax, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzyldiphenyl thioether,
Tetra methylthiuram list sulfide, azodiisobutyronitrile, bibenzyl, biacetyl, β-chloroanthraquinone, 2,4,6- trimethylbenzoyls two
Phenyl phosphine oxide etc..During using ultraviolet as energy line, by adding Photoepolymerizationinitiater initiater, irradiation time and irradiation can be reduced
Amount.
, also can be according to the friendship when adhesion agent composition of the adhering agent layer formed in present embodiment contains crosslinking agent (C)
Join species of agent (C) etc., contain appropriate crosslinking accelerator.
(6) irradiation of energy line
In the glass-cutting adhesive sheet of present embodiment, adhering agent layer is formed by the sticker of energy ray-curable
When, as the energy line for solidifying the sticker, free radiation, i.e. ultraviolet, electron beam, X-ray etc. can be included.
Wherein, preferably it is easier to import the ultraviolet of irradiation apparatus.
During using ultraviolet as free radiation, from the aspect of operational ease, it is 200 to preferably use comprising wavelength
The near ultraviolet ray of~380nm or so ultraviolet., can be according to energy ray-curable contained in adhesion agent composition as light quantity
The species of composition and the thickness of adhering agent layer and suitably select, usually 50~500mJ/cm2Left and right, preferably 100~
450mJ/cm2, more preferably 200~400mJ/cm2.In addition, ultraviolet illumination is usually 50~500mW/cm2Left and right, be preferably
100~450mW/cm2, more preferably 200~400mW/cm2.To ultraviolet source, there is no particular restriction, and such as high-pressure mercury can be used
Lamp, metal halide lamp, UV-LED etc..
During using electron beam as free radiation, on its accelerating potential, according to energy contained in adhesion agent composition
Measure the species of line curability composition and the thickness of adhering agent layer is suitably selected, usual accelerating potential is preferably 10~1000kV
Left and right.As long as in addition, illuminated line amount is set as the scope that sticker is properly cured, the generally model in 10~1000krad
Enclose selected.As electron beam source, there is no particular restriction, and such as cock Luo Fu-Wa Erdun (Cockcroft-Walton) can be used
Type, Fan get Ge pressgangs (Van de Graaff) type, resonance transformer type, insulated core transformer type, or linear pattern, that rice
(Dynamitron) the various electron-beam accelerators such as type, high-frequency type.
3. stripping film
In the glass-cutting adhesive sheet of present embodiment, during before pasting adherend, to protect adhering agent layer
In side opposite with base material face for the purpose of, also can the surface layer fold stripping film.The structure of stripping film is any, and can illustrate to mould
Expect that film carries out the structure of lift-off processing using remover etc..As the specific example of plastic foil, it can include poly- to benzene two
The polyester films such as formic acid glycol ester, polybutylene terephthalate (PBT), PEN and polypropylene or polyethylene
Deng polyolefin film.As remover, silicone remover, fluorine class remover, chain alkyl class remover etc. can be used.Wherein,
It is preferred that cheap and the silicone remover of stability can be obtained.The thickness of stripping film, there is no particular restriction, but usually 20~
250 μm or so.
4. the physical property of glass-cutting adhesive sheet
The face of the side opposite with base material of adhering agent layer is pasted onto on alkali-free glass, after standing 20 minutes, this reality
Adhesion strength of the glass-cutting adhesive sheet to the alkali-free glass of mode is applied, preferably 8000~25000mN/25mm is especially excellent
Elect 9000~22000mN/25mm, more preferably 10000~19000mN/25mm as.By making the adhesion strength in above-mentioned model
Enclose, chip glass can be maintained in cutting on adhesive sheet well.Thus, it can effectively suppress to exist due to chip glass
Collision and glass plate or chip glass caused by skew on adhesive sheet between chip glass cut face and cutting blade
Accident collision, effectively suppression is collapsed broken.In addition, glass plate can be maintained on adhesive sheet well in cutting, as a result, can
Suppress generation chip to disperse and chip skew.In addition, in this manual, being glued in adhering agent layer by above-mentioned energy ray-curable
When agent and being formed, above-mentioned adhesion strength is the value that is determined before irradiation energy line.
When adhering agent layer is formed by the sticker of above-mentioned energy ray-curable, by the side opposite with base material of adhering agent layer
Face is pasted onto on alkali-free glass, after to the adhering agent layer irradiation energy line, the glass-cutting adhesive sheet of present embodiment
To the adhesion strength of alkali-free glass, preferably 50~250mN/25mm, particularly preferably 60~160mN/25mm are more preferably
70~130mN/25mm.By making the adhesion strength after irradiation energy line in more than 50mN/25mm, it can suppress from adhesive sheet
Pick up the stage before chip glass, chip glass is unexpectedly peeled off or offset from adhesive sheet, can be picked up better.Separately
On the one hand, such as, can when picking up chip glass respectively by making the adhesion strength after irradiation energy line in below 250mN/25mm
Pickup chip glass is without breakage well, and can suppress to produce cull.
In addition, the adhesion strength in this specification, as using alkali-free glass as adherend, using according to JIS Z0237：
The adhesion strength (mN/25mm) that 2009 180 ° of stripping methods are determined, shown in the test example of the details of assay method as be described hereinafter.
5. the manufacture method of glass-cutting adhesive sheet
The manufacture method of glass-cutting adhesive sheet, as long as the adhering agent layer that will can be formed by the adhesion agent composition
The one side of base material is layered in, then is not particularly limited.
As an example of the manufacture method of glass-cutting adhesive sheet, first, prepare containing sticker combination
Thing and the solvent or the coating composition of decentralized medium further contained according to expectation.Then, by the coating composition,
In the one side of base material, applied using die coater, curtain coater, flush coater, slit coater, knife type coater etc.
Cloth, forms film.In addition, by making the dried coating film, adhering agent layer can be formed.Coating composition, as long as can be coated,
Its character is not particularly limited.Composition for forming adhering agent layer, can be included in coating composition as solute, or
Also it can be included in as dispersate in coating composition.
When coating composition contains crosslinking agent (C), in order to there is density formation cross-linked structure with desired, it can change
The condition (temperature, time etc.) of above-mentioned drying, or heating can be also set in addition., can in order to fully carry out cross-linking reaction
Be laminated by the above method on base material after adhering agent layer, by resulting glass-cutting adhesive sheet, for example 23 DEG C,
Relative humidity is in 50% environment, standing is cured for 1 week to 2 weeks or so.
As the other examples of the manufacture method of glass-cutting adhesive sheet, first, in the stripping of stripping film as described above
From coating composition is coated with process face, film is formed.Then, make the dried coating film, formed by adhering agent layer and stripping film
The layered product constituted.Further, the face of the side opposite with stripping film of the adhering agent layer of the layered product is pasted onto on base material.It is logical
The method for crossing the above, can obtain the layered product of glass-cutting adhesive sheet and stripping film.Stripping film in the layered product, can conduct
Engineering material is peeled off, also can be during being pasted on before adherend, for protecting adhering agent layer.
6. the application method of glass-cutting adhesive sheet
The glass-cutting of present embodiment can be used for the cutting of glass plate with adhesive sheet.In addition, the glass of present embodiment
Adhesive sheet for use in cutting, it can also be used to a series of process of cutting including glass plate and its follow-up pickup.
When being used in the series of processes including cutting and its follow-up pickup, originally, the glass of present embodiment is cut
Cut the face of side opposite with base material for the adhering agent layer for using adhesive sheet (hereinafter sometimes referred to " bonding plane ".) paste on a glass.
When bonding plane is laminated with stripping film, the stripping film is peeled off, glass plate is pasted to the bonding plane exposed.On the other hand, adhere
The peripheral part in face is pasted onto the fixture of the referred to as ring-type for being used to convey or fix device of ring frame.In addition, from paste glass
Glass plate preferably stands 10 minutes~120 minutes, particularly preferably stands 15 minutes to during implementing before cutting action then
~60 minutes, further preferably stand 20 minutes~40 minutes.By standing the period, the close of glass plate and adhesive sheet can be made
Conjunction property is abundant.
Then, cutting action is implemented.That is, the glass plate that will be pasted on glass-cutting adhesive sheet, uses cutting blade
Cut.Thus, obtain being pasted onto multiple chip glasses on glass-cutting adhesive sheet.Cut in the glass of present embodiment
Cut with adhesive sheet, it is thus good as the operability of adhesive sheet by making base material that there is the thickness.In addition, by making to glue
Storage modulus of the oxidant layer at 100 DEG C in the scope, frictional heat during because of cutting makes the temperature of adhering agent layer as about
During 100 DEG C of high temperature, it can fully control to produce vibration in cutting, even as a result, small thin glass plate is cut into
During chip, can also suppress generation collapse it is broken.As a result, by thin glass plate efficiency small chip can be obtained well.
When adhering agent layer is formed by the sticker of above-mentioned energy ray-curable, after end cutting action, to being pasted with
The adhesive sheet of multiple chip glasses, face or the face irradiation energy line of substrate side by chip glass side.Thus, (methyl) propylene is made
The energy ray-curable group that acid ester copolymer (A) has carries out polymerisation, reduces adherence, and easily carries out then
Pickup process.
Pickup process, can be carried out by the first-class universal means of vacuum clip.Now, to easily pick up, preferably by the glass of object
Glass chip is from the face of the side opposite with adhering agent layer of base material, using pushing pin (pin) or syringe needle (needle) etc. is elected.At this
In the glass-cutting adhesive sheet of embodiment, the thickness by making base material makes adhesive sheet have well soft in above range
It is soft.Thus, it can be picked up well.
Furthermore it is preferred that carrying out expansion process before pickup process.Now, glass-cutting adhesive sheet is made to in-plane
Elongation.Thus, expand the interval between chip glass, and become to easily pick up.The degree of elongation, as long as between considering preferably
Every the suitable setting such as, tensile strength of base material.In addition, expansion process, can also be carried out before irradiation energy line.
In addition, using the glass-cutting of present embodiment with adhesive sheet cutting glass plate when, resulting chip glass
The area of plane, preferably 1 × 10-6mm2~1mm2, more preferably 1 × 10-4mm2~0.25mm2, particularly preferably 2.5 × 10-3mm2~0.09mm2, more preferably 0.01mm2~0.03mm2.According to the glass-cutting adhesive sheet of present embodiment, lead to
Crossing makes storage modulus of the adhering agent layer at 100 DEG C in the scope, can suppress adhesive sheet and produce vibration in cutting, therefore,
Even the small chip glass of the area with above range, can also suppress generation collapse it is broken.
Using the glass-cutting of present embodiment with adhesive sheet come cutting glass plate when, be used as the thickness of the glass plate of workpiece
Degree, preferably 50~10000 μm, more preferably particularly preferably 100~5000 μm, 300~800 μm.In addition, in this theory
In bright book, so-called " workpiece " refers to the adherend of glass-cutting adhesive sheet for being pasted with present embodiment, or use the adhesion
The machined object of piece processing.According to the glass-cutting adhesive sheet of present embodiment, by making storage of the adhering agent layer at 100 DEG C
Energy modulus can suppress adhesive sheet and produce vibration in cutting in the scope, therefore, even thickness is 50 μm of thin glass
Plate, can also suppress generation and collapse broken and cut.
The implementation described above in order to be readily appreciated that the present invention and be described, be not intended to limit the present invention and by
Record.Therefore, each key element disclosed in above-mentioned embodiment, also to include the whole design changes for the technical scope for belonging to the present invention
Purport more or including equivalent.
For example, between the base material and adhering agent layer of glass-cutting adhesive sheet, can also intervene other layers.
Embodiment
Hereinafter, the present invention is further illustrated using embodiment etc., but the scope of the present invention is not limited to this
A little embodiments etc..In addition, the record of the mass parts in following, is described in the way of the value for being converted into solid constituent.
[embodiment 1]
(1) preparation of (methyl) acrylate copolymer (A)
Make the third of the 2-EHA of 75 mass parts and the methyl methacrylate of 10 mass parts and 15 mass parts
Olefin(e) acid 2- hydroxy methacrylate copolymerization, obtains acrylic copolymer (AP).Point of acrylic copolymer (AP) obtained by determining
The result of son amount, weight average molecular weight (Mw) is 700,000.In addition, the weight average molecular weight (Mw) in the present embodiment, to be oozed using gel
Saturating chromatogram (GPC) determines the weight average molecular weight for being converted into polystyrene standard of (GPC measure).
Then, resulting acrylic copolymer (AP) and the compound as energy content line curability group are made
(A3) 2- methylacryoyloxyethyls isocyanates (MOI), in the zirconium chelate catalyst as organo-metallic catalyst (D)
Reacted in the presence of (Matsumoto Fine Chemical companies manufacture, article number " ZC-700 ").Thus, obtain in side chain
It is imported with (methyl) acrylate copolymer (A) of energy ray-curable group (methylacryloyl).Now, acrylic compounds are made
Every 100 molar equivalent of acrylic acid 2- hydroxy methacrylate units of copolymer (AP), MOI turns into the mode of 60 moles (60 moles of %),
React the two.In addition, the addition of organo-metallic catalyst (D), relative to the acrylic copolymer (AP) of 100 mass parts
For 0.1 mass parts.
(2) preparation of adhesion agent composition
By (methyl) acrylate copolymer (A) obtained by the above-mentioned operation (1) of 100 mass parts, 3.0 mass parts
It is used as Alpha-hydroxy cyclohexyl benzophenone (BASF AG manufactures, article number " IRGACURE 184 ") and 0.2 matter of Photoepolymerizationinitiater initiater
Measure trimethylolpropane modified toluene diisocyanate (the TOSOH CORPORATION manufactures, business as crosslinking agent (C) of part
Article Number " CORONATE L ") mix in a solvent, obtain the coating solution of adhesion agent composition.In addition, by using the adhesion
Agent composition, obtains the sticker of X-type.
(3) making of glass-cutting adhesive sheet
By the coating solution of adhesion agent composition resulting in above-mentioned operation (2), in polyethylene terephthalate
The one side of film through silicone remover lift-off processing stripping film (LINTEC company systems, article number " SP-PET381031 ",
38 μm of Hou Du ︰) lift-off processing face on, be coated using die coater.Then, handled 1 minute with 100 DEG C, make film
Cross-linking reaction is carried out while drying.Thus, the layered product being made up of stripping film and thickness 10 μm of adhering agent layer is obtained.
In addition, the face of the adhering agent layer side to the layered product, pastes polyethylene terephthalate (PET) film as base material
(TOYOBO CO., LTD. manufactures, article number " A-4100 ", 100 μm of Hou Du ︰).Thus, obtain being sequentially laminated with base material, adhesion
The glass-cutting adhesive sheet of oxidant layer and stripping film.
[embodiment 2~12]
The material of base material, the thickness of base material, the 2- methylacryoyloxyethyls for forming adhering agent layer and using is different
The amount of cyanate (MOI), for the species of organo-metallic catalyst (D) that forms adhering agent layer and use and adhering agent layer
Beyond thickness is changed to shown in table 1, glass-cutting adhesive sheet is manufactured in the same manner as example 1.
[comparative example 1]
Beyond the thickness of base material is changed to shown in table 1, glass-cutting adhesion is manufactured in the same manner as example 1
Piece.
[comparative example 2]
(1) preparation of adhesion agent composition
Make the butyl acrylate of 90 mass parts, the acrylic acid copolymer with 10 mass parts, obtain not having energy ray-curable
Acrylic polymer (N).The result of polymer (N) molecular weight obtained by determining, weight average molecular weight (Mw) is 600,000.
By the acrylic polymer (N) without energy ray-curable obtained as described above of 100 mass parts, 127
The 3 degree of functionality urethane acrylate oligomer (Dainichiseika as energy ray-curable compound (B) of mass parts
Color＆Chemicals Mfg.Co., Ltd. manufacture, article number " EXL810TL ", Mw=5000), the conduct light of 4 mass parts gathers
The Alpha-hydroxy cyclohexyl benzophenone (BASF AG manufactures, article number " IRGACURE184 ") of initiator, the conduct of 11 mass parts is closed to hand over
Join the trimethylolpropane modified toluene diisocyanate (TOSOH CORPORATION systems, article number " CORONATE L ") of agent
Mix in a solvent, obtain the coating solution of adhesion agent composition.In addition, by using the adhesion agent composition, obtaining Y types
Sticker.
(2) making of glass-cutting adhesive sheet
In addition to using the coating solution of the adhesion agent composition obtained by above-mentioned operation (1), with the phase of embodiment 1
Same mode makes glass-cutting adhesive sheet.
[comparative example 3]
(1) preparation of adhesion agent composition
It is total to the acrylic acid of the 2-EHA, the methyl acrylate of 40 mass parts and 10 mass parts of 50 mass parts
It is poly-, obtain the acrylic polymer (N) without energy ray-curable.The knot of polymer (N) molecular weight obtained by determining
Really, weight average molecular weight (Mw) is 800,000.
By the resulting acrylic polymer (N) without energy ray-curable as described above of 100 mass parts, 40
10 degree of functionality urethane acrylate (the The Nippon as energy ray-curable compound (B) of mass parts
Synthetic Chemical Industry Co., Ltd.s manufacture, article number " UV-1700B ", Fen Liang ︰ 1700), 0.1 matter
The Alpha-hydroxy cyclohexyl benzophenone (BASF AG manufactures, article number " IRGACURE184 ") as Photoepolymerizationinitiater initiater of amount part, 10
(TOSOH CORPORATION are manufactured the trimethylolpropane modified toluene diisocyanate as crosslinking agent of mass parts, commodity
Number " CORONATE L ") mix in a solvent, obtain the coating solution of adhesion agent composition.In addition, by using the sticker
Composition, obtains the sticker of Y types.
(2) making of glass-cutting adhesive sheet
In addition to using the coating solution of the adhesion agent composition obtained by above-mentioned operation (1), with the phase of embodiment 1
Same mode makes glass-cutting adhesive sheet.
[comparative example 4 and 5]
In addition to being changed to the thickness of adhering agent layer shown in table 1, cut with manufacturing glass with the identical mode of comparative example 3
Cut and use adhesive sheet.
The detailed content of dummy suffix notation described in table 1 is as follows.
[material of base material]
PET (100 μm of thickness)：Polyethylene terephthalate film (TOYOBO CO., LTD. manufactures, article number " A-
4100”)
PET (50 μm of thickness)：Polyethylene terephthalate film (TOYOBO CO., LTD. manufactures, article number " A-
4100”)
PET (188 μm of thickness)：Polyethylene terephthalate film (TOYOBO CO., LTD. manufactures, article number " A-
4100”)
PO：Polyolefin film (Rikentechnos companies manufacture, article number " ADN09-100T-M8 ")
PP：Polypropylene screen (DiaPlus Film companies manufacture, article number " PL109 ")
PI：Polyimide film (MPRTECH companies manufacture, article number " MordoharPIF100 ")
[organo-metallic catalyst]
Zr ︰ zirconium chelates catalyst (Matsumoto Fine Chemical companies manufacture, article number " ZC-700 ")
Sn：The fourth tin catalyst of laurate two (TOYOCHEM companies manufacture, " BXX-3778 ")
[test example 1] (measure of the storage modulus of base material)
On the base material used in embodiment and comparative example, the energy storage mould at 23 DEG C is determined with following apparatus and condition
Amount.Show the result in table 1.
Determine dress and put ︰ dynamic moduluss of elasticity measure device, the manufacture of TA Instrument companies, article number " DMA Q800 "
0 DEG C of on-test Wen Du ︰
200 DEG C of off-test Wen Du ︰
Rise 3 DEG C/min of Wen Sudu ︰
Pin Shuai ︰ 11Hz
20 μm of Zhen Fu ︰
[test example 2] (measure of the storage modulus of the adhering agent layer before irradiation ultraviolet radiation)
By the coating solution of the adhesion agent composition used in embodiment and comparative example, be coated on thickness for 38 μm the
On the lift-off processing face of one stripping film (LINTEC companies manufacture, article number " SP-PET381031 ").By resulting film,
Kept for 1 minute at 100 DEG C, make dried coating film.Thus, the adhering agent layer that thickness is 40 μm is formed on the first stripping film.In addition,
By the face of the side opposite with the first stripping film of the adhering agent layer, the second stripping film (LINTEC companies that thickness is 38 μm are pasted on
Manufacture, article number " SP-PET381031 ") lift-off processing face, obtain being sequentially laminated with the first stripping film, be 40 μm with thickness
Adhering agent layer and the second stripping film layered product.The step of by by the above resulting adhering agent layer laminated multi-layer extremely
Thickness is 800 μm.A diameter of 10mm circle is gone out by the layered product that the thickness is 800 μm, the sample for measure is used as.It is logical
Determination of viscoelasticity device (TA Instrument companies manufacture, article number " ARES ") is crossed, frequency 1Hz deformation is assigned to sample,
The storage modulus of -50~150 DEG C of measure, obtains the value of the storage modulus at 23 DEG C and 100 DEG C.Show the result in table 1.This
Outside, during laminated multi-layer adhering agent layer, using after adhering agent layer is formed, placed 1 week in the environment of 23 DEG C of temperature, humidity 50%
Layered product be used as above-mentioned layered product.
[test example 3] (measure of the tensile modulus of elasticity of the adhering agent layer after ultraviolet irradiation)
With the step same with test example 2, laminated multi-layer adhering agent layer so that thickness is 200 μm.
Then, ultraviolet is carried out using ultraviolet lamp (LINTEC companies manufacture, article number " RAD-2000 ")
(UV) (illumination is irradiated：230mW/cm2, light quantity：190mJ/cm2), solidify adhering agent layer.Further, be cut into 15mm ×
140mm, obtains test film.
Stripping film is peeled off from resulting test film, on the adhering agent layer after solidification, according to JIS K7161：
1994 and JIS K7127：1999, determine the tensile modulus of elasticity at 23 DEG C.Specifically, cupping machine (Shimadzu is utilized
Make manufactured, and article number " Autograph AG-IS500N "), fixture spacing is set as after 100mm, with 200mm/ points
The speed of clock carries out tension test, determines tensile modulus of elasticity (Pa).Show the result in table 1.
[test example 4] (measure of viscosity value)
For the face of the adhering agent layer side of adhesive sheet manufactured in embodiment and comparative example, a diameter of 5mm (5mm are used
Probe Φ), viscosity value is determined using tack meter of popping one's head in (Rhesca companies manufacture, article number " RPT-100 ").Measure side
Method is, in JIS Z0237：In method described in 2009, peeling rate is changed to 1mm/ minutes, on the other hand, loading is
100gf/cm2, time of contact is 1 second, is measured according to described in above-mentioned JIS regulation.Obtain determined energy (ripple
Peak integrating value), it regard this as the mono- Wei ︰ mJ/5mm Φ of viscosity value ().Show the result in table 1.In addition, for said determination, using
After adhering agent layer is formed, in 23 DEG C of temperature, the environment of humidity 50% places the adhesive sheet of 1 week.
[test example 5] (measure of the adhesion strength after ultraviolet pre-irradiation)
At room temperature, from embodiment and comparative example it is manufactured, in the environment of 23 DEG C of temperature, humidity 50% place 1
The glass-cutting in week is with peeling off stripping film on adhesive sheet.By the one of the face for exposing adhering agent layer and 6 inches of alkali-free glass plate
Surface layer fold, by make 2kg roller make a round trip application loading and fit, place 20 minutes.Afterwards, according to JIS Z0237：2009
180 ° of stripping methods, from alkali-free glass plate, with peeling rate 300mm/ minutes, 180 ° of peel angle, peel off glass-cutting and use
Adhesive sheet, determines adhesion strength (mN/25mm).Adhesion strength before using the measured value as irradiation ultraviolet radiation.Show the result in table
1。
In addition, as described above, by the glass-cutting adhesive sheet manufactured by embodiment and comparative example and 6 inches of alkali-frees
Glass plate is bonded, and after placing 20 minutes, from the substrate side of glass-cutting adhesive sheet, uses ultraviolet lamp
(LINTEC companies manufacture, article number " RAD-2000 "), carries out ultraviolet (UV) irradiation (photograph degree ︰ 200mW/cm2, Guang Liang ︰
180mJ/cm2), solidify adhering agent layer.Afterwards, adhesion strength (mN/25mm) is determined in the same manner as described above.This is determined
Value is used as the adhesion strength after irradiation ultraviolet radiation.Show the result in table 1.
[test example 6] (evaluation for collapsing the skew of broken and chip)
Glass that is manufactured from embodiment and comparative example, being placed 1 week in the environment of 23 DEG C of temperature, humidity 50% is cut
Cut with adhesive sheet, stripping film is peeled off, (LINTEC companies manufacture, article number " Adwill RAD2500m/ using Belt sticking machine
12 "), in the exposed surface of adhering agent layer, 6 inches of alkali-free glass plates and cutting ring frame that thickness is 550 μm are pasted.Then,
With the external diameter of ring frame matchingly severing glass-cutting adhesive sheet.Further, using cutter device (DISCO companies manufacture,
Article number " DFD-651 "), the cutting cut off with following cutting condition from glass plate side, the glass for obtaining 0.6mm square is brilliant
Piece.
<Cutting condition>
Cutting dress puts ︰ DISCO companies manufacture DFD-651
Knife piece ︰ DISCO companies manufacture NBC-2H 2050 27HECC
0.025~0.030mm of Dao Pian Kuan ︰
0.640~0.760mm of Jin Dao Liang ︰
Dao piece Zhuan Su ︰ 30000rpm
Cut Su Du ︰ 80mm/sec
20 μm of base material incision Shen Du ︰
Cutting water Liang ︰ 1.0L/ minutes
20 DEG C of cutting water Wen ︰
Cutting ruler Cun ︰ 0.6mm square (the area 0.36mm of plane2)
After the completion of cutting, the central part and its neighbouring chip glass of glass-cutting adhesive sheet are pointed to, end is observed
There are N/D and shape.Specifically, using electron microscope, (KEYENCE companies manufacture, article number " VHZ-100 ", times rate ︰ 300
Times), the side of 50 chips of flow direction (MD direction) of the observation in the manufacture of base material and the direction (CD orthogonal with MD directions
Direction) 50 chips side.Then, it will be judged to collapsing broken, its quantity of number with 20 μm more than of width or the defect of depth.
By the result, on the basis of following, evaluation is collapsed broken.Evaluation result is shown in table 1.
◎：The quantity for collapsing broken chip is produced less than 5.
○：Produce and collapse the quantity of broken chip for 5 less than 50.
×：Produce and collapse the quantity of broken chip for more than 50.
[test example 7] (operability is evaluated)
Glass that is manufactured from embodiment and comparative example, being placed 1 week in the environment of 23 DEG C of temperature, humidity 50% is cut
Cut with adhesive sheet, stripping film is peeled off, using cutting Belt sticking machine (LINTEC companies manufacture, article number " RAD2500F/8 "),
In the exposed surface of adhering agent layer, it is 550 μm of 6 inches of alkali-free glass plates and cutting ring frame to paste thickness.The operation is repeated
50 times, on the basis of following, evaluate the operability of adhesive sheet.
○：The problem of not producing special, can continuously paste 50 times.
×：Mistake is produced in midway, makes job interruption, it is impossible to be continuous to paste 50 times.
[table 1]
As shown in Table 1, according to the adhesive sheet of embodiment, can suppress generation collapse it is broken.In addition, understand the adhesive sheet of embodiment
Operability is excellent.
Industrial applicibility
The glass-cutting adhesive sheet of the present invention, available for the cutting action of glass, especially can be applied to thin glass
Cutting action.
Claims (12)
1. a kind of glass-cutting adhesive sheet, it possesses：Base material and be laminated in the base material at least one side adhering agent layer,
It is characterized in that：
The thickness of the base material be 30 μm less than 130 μm, storage modulus of the adhering agent layer at 100 DEG C be 6~
50kPa。
2. glass-cutting adhesive sheet according to claim 1, it is characterised in that the thickness of the adhering agent layer is 5~
25μm。
3. glass-cutting adhesive sheet according to claim 1, it is characterised in that storage of the adhering agent layer at 23 DEG C
Energy modulus is 30~100kPa.
4. glass-cutting adhesive sheet according to claim 1, it is characterised in that by the adhering agent layer and the base
The face of the opposite side of material is pasted on alkali-free glass, and after standing 20 minutes, the glass-cutting adhesive sheet is to the alkali-free glass
The adhesion strength of glass is 8000~25000mN/25mm.
5. glass-cutting adhesive sheet according to claim 1, it is characterised in that the adhering agent layer, pass through JIS
Z0237：Peeling rate is changed to the condition of 1mm/ minutes, the energy using probe viscosity measure in method described in 1991
For 0.01~5mJ/5mm Φ.
6. glass-cutting adhesive sheet according to claim 1, it is characterised in that the adhering agent layer is by energy line curing
The sticker of property is formed.
7. glass-cutting adhesive sheet according to claim 6, it is characterised in that the adhering agent layer is combined by sticker
Sticker that thing is formed and formed, the adhesion agent composition contains (methyl) that side chain is imported with energy ray-curable group
Acrylate copolymer (A).
8. glass-cutting adhesive sheet according to claim 7, it is characterised in that the adhesion agent composition further contains
There is the energy ray-curable compound (B) in addition to described (methyl) acrylate copolymer (A).
9. glass-cutting adhesive sheet according to claim 7, it is characterised in that the adhesion agent composition further contains
Crosslinking dose (C).
10. glass-cutting adhesive sheet according to claim 1, it is characterised in that energy storage of the base material at 23 DEG C
Modulus is 100~8000MPa.
11. a kind of manufacture method of glass-cutting adhesive sheet, it is the glass-cutting adhesive sheet described in manufacturing claims 7
Method, it is characterised in that including：
Make the monomer (A2) containing functional group at least by (methyl) alkyl acrylate monomer (A1) and with reactive functional groups
The acrylic copolymer (AP) of copolymerization,
With with functional group that can be with the functional group reactionses of the monomer (A2) containing functional group and the carbon-to-carbon of energy ray-curable
Compound (A3) reaction of the energy content line curability group of double bond, preparation is imported with energy ray-curable group in side chain
The process of (methyl) acrylate copolymer (A)；And
Using the adhesion agent composition containing (methyl) acrylate copolymer (A), adhesion is laminated at least one side of base material
The process of oxidant layer.
12. the manufacture method of glass-cutting adhesive sheet according to claim 11, it is characterised in that selected from containing zirconium
At least one of organic compound, the organic compound of titaniferous and stanniferous organic compound organo-metallic catalyst (D)
In the presence of, carry out the acrylic copolymer (AP) and the reaction of the compound (A3) of the energy content line curability group.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-064928 | 2016-03-29 | ||
| JP2016064928A JP6623098B2 (en) | 2016-03-29 | 2016-03-29 | Adhesive sheet for glass dicing and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107236471A true CN107236471A (en) | 2017-10-10 |
Family
ID=59983390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710191565.6A Pending CN107236471A (en) | 2016-03-29 | 2017-03-28 | Glass-cutting adhesive sheet and its manufacture method |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6623098B2 (en) |
| KR (1) | KR102638359B1 (en) |
| CN (1) | CN107236471A (en) |
| TW (1) | TWI791424B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1656190A (en) * | 2002-05-28 | 2005-08-17 | 3M创新有限公司 | Segmented curable transfer tapes |
| CN101381587A (en) * | 2007-09-06 | 2009-03-11 | 日东电工株式会社 | Pressure-sensitive adhesive sheet for dicing and dicing method |
| JP4585164B2 (en) * | 2002-07-18 | 2010-11-24 | 日東電工株式会社 | UV curable adhesive sheet |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000044894A (en) * | 1998-07-31 | 2000-02-15 | Nippon Synthetic Chem Ind Co Ltd:The | Peelable tacky agent composition |
| JP3838637B2 (en) | 2002-06-10 | 2006-10-25 | 日東電工株式会社 | Glass substrate dicing adhesive sheet and glass substrate dicing method |
| JP4550680B2 (en) * | 2005-07-12 | 2010-09-22 | 古河電気工業株式会社 | Adhesive tape for fixing semiconductor wafers |
| JP4931519B2 (en) * | 2006-09-01 | 2012-05-16 | 日東電工株式会社 | Active surface-attached dicing adhesive tape or sheet and method of picking up a workpiece cut piece |
| CN102015937B (en) * | 2008-04-21 | 2014-11-12 | Lg化学株式会社 | Pressure-sensitive adhesive film and back-grinding method using the same |
| JP2011018669A (en) * | 2009-07-07 | 2011-01-27 | Nitto Denko Corp | Adhesive sheet for dicing semiconductor wafer, and method for dicing semiconductor wafer using the same |
| JP6081094B2 (en) * | 2012-07-13 | 2017-02-15 | リンテック株式会社 | Dicing sheet |
| JP5294366B1 (en) * | 2012-10-18 | 2013-09-18 | 古河電気工業株式会社 | Dicing tape |
| JP6232842B2 (en) * | 2013-08-26 | 2017-11-22 | 日立化成株式会社 | Wafer processing tape |
| WO2016017265A1 (en) * | 2014-07-31 | 2016-02-04 | リンテック株式会社 | Dicing sheet, method for manufacturing dicing sheet, and method for manufacturing molded chip |
-
2016
- 2016-03-29 JP JP2016064928A patent/JP6623098B2/en active Active
-
2017
- 2017-01-16 TW TW106101359A patent/TWI791424B/en active
- 2017-02-23 KR KR1020170024152A patent/KR102638359B1/en active IP Right Grant
- 2017-03-28 CN CN201710191565.6A patent/CN107236471A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1656190A (en) * | 2002-05-28 | 2005-08-17 | 3M创新有限公司 | Segmented curable transfer tapes |
| JP4585164B2 (en) * | 2002-07-18 | 2010-11-24 | 日東電工株式会社 | UV curable adhesive sheet |
| CN101381587A (en) * | 2007-09-06 | 2009-03-11 | 日东电工株式会社 | Pressure-sensitive adhesive sheet for dicing and dicing method |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20170113062A (en) | 2017-10-12 |
| KR102638359B1 (en) | 2024-02-19 |
| TW201802205A (en) | 2018-01-16 |
| JP6623098B2 (en) | 2019-12-18 |
| JP2017179028A (en) | 2017-10-05 |
| TWI791424B (en) | 2023-02-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101215105B1 (en) | An adhesive sheet for a stealth dicing and a production method of a semiconductor wafer device | |
| TWI683881B (en) | Method for manufacturing dicing sheet and semiconductor wafer | |
| CN103443229B (en) | The processing adherent zones such as semiconductor wafer | |
| KR20140035346A (en) | Pressure sensitive adhesive sheet | |
| KR102085533B1 (en) | Film, sheet substrate for processing workpiece, and sheet for processing workpiece | |
| CN107236472A (en) | Glass-cutting adhesive sheet and its manufacture method | |
| CN105793035A (en) | Laminate for resin film formation sheet | |
| KR20210023870A (en) | Adhesive tape for semiconductor processing and manufacturing method of semiconductor device | |
| CN107236473A (en) | Glass-cutting adhesion sheet material and its manufacture method | |
| JP5990910B2 (en) | Adhesive tape for processing semiconductor wafers | |
| CN109312199B (en) | Adhesive sheet for semiconductor processing | |
| CN107078038A (en) | The manufacture method of cutting sheet, the manufacture method of cutting sheet and die chip | |
| JP5303330B2 (en) | Dicing tape and semiconductor chip manufacturing method | |
| JP2006259324A (en) | Substrate for marking film and marking film using the same | |
| CN107236471A (en) | Glass-cutting adhesive sheet and its manufacture method | |
| CN107236474A (en) | Glass-cutting adhesion sheet material and its manufacture method | |
| JP6087122B2 (en) | Dicing sheet | |
| CN107236475A (en) | Glass-cutting adhesion sheet material and its manufacture method | |
| JP2006036834A (en) | Adhesive tape for processing semiconductor wafer | |
| TW202136447A (en) | Adhesive sheet | |
| WO2018101335A1 (en) | Double-sided adhesive sheet, and method for producing double-sided adhesive sheet | |
| CN114270494A (en) | Method for manufacturing semiconductor device with electromagnetic wave shielding film and terminal protection tape | |
| KR20220072733A (en) | Method for manufacturing laminate and laminate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171010 |