CN107216922A - Clean environmental-protective diesel emulsifying agent - Google Patents

Clean environmental-protective diesel emulsifying agent Download PDF

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Publication number
CN107216922A
CN107216922A CN201710644170.7A CN201710644170A CN107216922A CN 107216922 A CN107216922 A CN 107216922A CN 201710644170 A CN201710644170 A CN 201710644170A CN 107216922 A CN107216922 A CN 107216922A
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parts
emulsifying agent
diesel oil
monoethanolamine
ferrocene
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刘少君
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Weihai Ding Yang Clean Energy Research Institute Co Ltd
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Weihai Ding Yang Clean Energy Research Institute Co Ltd
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/106Liquid carbonaceous fuels containing additives mixtures of inorganic compounds with organic macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
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    • C10L1/1225Inorganic compounds halogen containing compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00Liquid carbonaceous fuels
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    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
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    • C10L1/232Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
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    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/14Function and purpose of a components of a fuel or the composition as a whole for improving storage or transport of the fuel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/026Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The invention discloses a kind of diesel oil emulsifier, it can more particularly to manufacture a kind of color and transparency and be as good as with pure diesel oil, and excellent, the easy to use clean environment firendly diesel oil emulsification of long shelf-life security and stability.Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:0.5 part -10 parts of 5 parts -40 parts of 0.4 part -12 parts of monoethanolamine, ethanol or methanol, isooctyl ester nitrate or amyl nitrate, 0.1 part -5 parts of ferrocene, 0.01 part -6 parts of toluene, 1 part -4 parts of BTA, 0.3 part -11 parts of cyclohexylamine, 1 part -8 parts of stannous chloride.Clean environmental-protective diesel emulsifying agent, the diesel oil emulsification produced with the emulsifying agent has long shelf-life, the diesel oil emulsification produced with the emulsifying agent has long shelf-life, up to not being demulsified within more than 12 years, can long term storage, oily intersolubility is good, water repellency is good, substantial amounts of water can be added, water content is high, cost is low, sulfur content is low, good environmental protection, the discharge of pernicious gas can be greatly lowered.

Description

Clean environmental-protective diesel emulsifying agent
Technical field
The present invention relates to a kind of diesel oil emulsifier, can more particularly to manufacture a kind of color and transparency and pure diesel oil without It is different, and excellent, the easy to use clean environment firendly diesel oil emulsification of long shelf-life security and stability.
Background technology
Diesel oil is extracted in oil, due to the shortage of current petroleum resources, generates many artificial synthesized diesel oils, Such as Patent No. ZL200410082835.2 Chinese patent is disclosed《A kind of condensed emulsified diesel, preparation method and its With》Technology, this patent is there is also stability is poor, complex manufacturing, the technical problem of difficult control, and its quality guarantee period also needs into one Step is improved.The Chinese patent of Patent No. 201210139070.6 is disclosed《A kind of condensed emulsified diesel and its preparation side Method》, the Chinese patent of Patent No. 201210072369.4 discloses《A kind of condensed emulsified diesel and preparation method thereof》, on State two patents and disclose the technology i.e. diesel oil emulsification technology that diesel oil is replaced with water, but they have the following disadvantages and can not pushed away Wide application:Current diesel oil emulsification shelf-life or relatively short, stability are poor, cost is high, sulfur content is high, the feature of environmental protection is compared with energy Difference, it is difficult to meet the requirement of commercialization, is subject to certain restrictions popularization and application;It is anti-easily chemistry to be produced with other commercial Dissel oils Should, security is poor.
The content of the invention
The present invention be exactly in order to solve the above-mentioned technical problem, and provide clean environmental-protective diesel emulsifying agent, use the emulsifying agent The diesel oil emulsification of production has long shelf-life, up to not being demulsified within more than 12 years, and oily intersolubility is good, and water repellency is good, cost is low, Sulfur content is low, good environmental protection, can be greatly lowered the discharge of pernicious gas, storage transportation safety, fire prevention.
In order to solve the above-mentioned technical problem, the present invention is achieved through the following technical solutions:
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:0.4 part -12 parts of monoethanolamine, Ethanol or 0.5 part -10 parts of 5 parts -40 parts of methanol, isooctyl ester nitrate or amyl nitrate, 0.1 part -5 parts of ferrocene, toluene 0.01 part -6 parts, 1 part -4 parts of BTA, 0.3 part -11 parts of cyclohexylamine, 1 part -8 parts of stannous chloride.
Above-mentioned cleaning diesel oil emulsifier, it is to be prepared from by following components by the parts by weight:Monoethanolamine 2 parts -5 Part, ethanol or 2 parts -5 parts of 15 parts -25 parts of methanol, isooctyl ester nitrate or amyl nitrate, 2 parts -3 parts of ferrocene, toluene 2 - 4 parts of part, 2 parts -3 parts of BTA, 4 parts -7 parts of cyclohexylamine, 3 parts -4 parts of stannous chloride.
Above-mentioned cleaning diesel oil emulsifier, it is to be prepared from by following components by the parts by weight:4 parts of monoethanolamine, second Alcohol or 3 parts of 20 parts of methanol, isooctyl ester nitrate or amyl nitrate, 2.5 parts of ferrocene, 2.5 parts of toluene, 2.5 parts of BTA, 5 parts of cyclohexylamine, 3.5 parts of stannous chloride.
Above-mentioned monoethanolamine is monoethanolamine, diethanol amine, any one in triethanolamine.
The preparation method of above-mentioned clean environmental-protective diesel emulsifying agent, step is as follows:Take the monoethanolamine for meeting the parts by weight, second Alcohol or methanol, isooctyl ester nitrate or amyl nitrate, ferrocene, toluene, BTA, cyclohexylamine, stannous chloride are added to In stirring container, it is sufficiently stirred for, produces.
Above-mentioned mixing time is 20-30 minutes.
The advantages of the present invention are as follows:
The present invention be exactly in order to solve the above-mentioned technical problem, and provide clean environmental-protective diesel emulsifying agent, with the emulsifying agent produce Diesel oil emulsification there is long shelf-life, up to not being demulsified within more than 12 years, can long term storage, oily intersolubility is good, and water repellency is good, Substantial amounts of water can be added, water content is high, cost is low, sulfur content is low, good environmental protection, the row of pernicious gas can be greatly lowered Put.Emulsifying agent of the present invention can require that carrying out configuration is adapted to its diesel oil emulsification according to internal combustion engine condition.
Embodiment
With reference to embodiment, the present invention is described further.Following examples are only several specific realities of the present invention Example is applied, but the design concept of the present invention is not limited thereto, all changes for carrying out unsubstantiality to the present invention using this design, The behavior for invading the scope of the present invention should be belonged to.
Method in following embodiments, is conventional method unless otherwise instructed.
Percentage composition in following embodiments is weight/mass percentage composition unless otherwise instructed.
Embodiment 1
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:0.4 part of monoethanolamine, ethanol 40 Part, 10 parts of isooctyl ester nitrate, 5 parts of ferrocene, 6 parts of toluene, 4 parts of BTA, 11 parts of cyclohexylamine, 8 parts of stannous chloride.It is made Preparation Method step is as follows:Take monoethanolamine, ethanol, isooctyl ester nitrate, ferrocene, toluene, BTA, the ring of the parts by weight Hexylamine, stannous chloride are added in stirring container, are stirred 20 minutes, are produced.
Embodiment 2
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:Clean environmental-protective diesel emulsifying agent, It is to be prepared from by following components by the parts by weight:12 parts of monoethanolamine, 5 parts of methanol, 0.5 part of amyl nitrate, ferrocene 0.1 Part, 0.01 part of toluene, 1 part of BTA, 0.3 part of cyclohexylamine, 1 part of stannous chloride.Its preparation methods steps are as follows:Take described Monoethanolamine, methanol, amyl nitrate, ferrocene, toluene, BTA, cyclohexylamine, the stannous chloride of parts by weight are added to stirring In container, stir 30 minutes, produce.
Embodiment 3
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:Clean environmental-protective diesel emulsifying agent, It is to be prepared from by following components by the parts by weight:2 parts of monoethanolamine, 25 parts of methanol, 5 parts of isooctyl ester nitrate, ferrocene 3 Part, 4 parts of toluene, 3 parts of BTA, 7 parts of cyclohexylamine, 4 parts of stannous chloride.Its preparation methods steps are as follows:Take the weight The monoethanolamine, methanol, isooctyl ester nitrate, ferrocene, toluene, BTA, cyclohexylamine, stannous chloride of part, which are added to stirring, to be held In device, stir 25 minutes, produce.
Embodiment 4
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:5 parts of monoethanolamine, 15 parts of ethanol, 2 parts of amyl nitrate, 2 parts of ferrocene, 2 parts of toluene, 2 parts of BTA, 4 parts of cyclohexylamine, 3 parts of stannous chloride.Its preparation method Step is as follows:Take monoethanolamine, ethanol, amyl nitrate, ferrocene, toluene, BTA, cyclohexylamine, the chlorine of the parts by weight Change is cuprous to be added in stirring container, is stirred 22 minutes, is produced.
Embodiment 5
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:4 parts of monoethanolamine, 20 parts of methanol, 3 parts of isooctyl ester nitrate, 2.5 parts of ferrocene, 2.5 parts of toluene, 2.5 parts of BTA, 5 parts of cyclohexylamine, 3.5 parts of stannous chloride. Its preparation methods steps are as follows:Take monoethanolamine, methanol, isooctyl ester nitrate, ferrocene, toluene, the nitrogen of benzo three of the parts by weight Azoles, cyclohexylamine, stannous chloride are added in stirring container, are stirred 27 minutes, are produced.
Embodiment 6
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:1 part of monoethanolamine, 10 parts of methanol, 7 parts of amyl nitrate, 4 parts of ferrocene, 4 parts of toluene, 3 parts of BTA, 9 parts of cyclohexylamine, 6 parts of stannous chloride.Its preparation method Step is as follows:Take monoethanolamine, methanol, amyl nitrate, ferrocene, toluene, BTA, cyclohexylamine, the chlorine of the parts by weight Change is cuprous to be added in stirring container, is stirred 24 minutes, is produced.
Embodiment 7
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:10 parts of monoethanolamine, ethanol 30 Part, 2 parts of isooctyl ester nitrate, 1 part of ferrocene, 1 part of toluene, BTA 1,1 part of cyclohexylamine, 2 parts of stannous chloride.Its preparation side Method step is as follows:Take monoethanolamine, ethanol, isooctyl ester nitrate, ferrocene, toluene, BTA, the hexamethylene of the parts by weight Amine, stannous chloride are added in stirring container, are stirred 26 minutes, are produced.
Embodiment 8
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:7 parts of monoethanolamine, 7 parts of methanol, 7 parts of isooctyl ester nitrate, 3 parts of ferrocene, 3 parts of toluene, BTA 3,3 parts of cyclohexylamine, 7 parts of stannous chloride.Its preparation method Step is as follows:Take the monoethanolamines of the parts by weight, methanol, isooctyl ester nitrate, ferrocene, toluene, BTA, cyclohexylamine, Stannous chloride is added in stirring container, is stirred 26 minutes, is produced.
Embodiment 9
Clean environmental-protective diesel emulsifying agent, it is to be prepared from by following components by the parts by weight:1 part of monoethanolamine, 10 parts of ethanol, 10 parts of amyl nitrate, 1 part of ferrocene, 1 part of toluene, BTA 1,1 part of cyclohexylamine, 1 part of stannous chloride.Its preparation method is walked It is rapid as follows:Take the monoethanolamines of the parts by weight, ethanol, amyl nitrate, ferrocene, toluene, BTA, cyclohexylamine, chlorination It is cuprous to be added in stirring container, stir 26 minutes, produce.
The product that 1-9 of the embodiment of the present invention is obtained is added after 7-18 times of weight water and diesel oil are mixed with arbitrary ratio and is made Diesel oil emulsification and the diesel oil emulsification as made from patent No. ZL201210139070.6 and ZL201210072369.4 method are examined Survey, testing result such as following table:
The product that 1-9 of the embodiment of the present invention is obtained adds after 7-18 times of weight water and diesel oil are mixed with arbitrary ratio and emulsification is made Diesel oil and the diesel oil emulsification as made from patent No. ZL201210139070.6 and ZL201210072369.4 method are stored into the 8th Year, diesel oil emulsification made from patent No. ZL201210139070.6 and ZL201210072369.4 method occurs in that lamination, And diesel oil emulsification made from 1-9 products of the embodiment of the present invention is not to still occurring lamination, current inventive embodiments 1-9 products Obtained diesel oil emulsification, which has been housed 12 years, does not occur lamination, it was demonstrated that stability of the present invention substantially compares the patent No. Diesel oil emulsification is good made from ZL201210139070.6 and ZL201210072369.4.

Claims (6)

1. clean environmental-protective diesel emulsifying agent, it is characterised in that it is to be prepared from by following components by the parts by weight:Monoethanolamine 5 parts -40 parts of 0.4 part -12 parts, ethanol or methanol, isooctyl ester nitrate or 0.5 part -10 parts of amyl nitrate, ferrocene 0.1 - 5 parts of part, 0.01 part -6 parts of toluene, 1 part -4 parts of BTA, 0.3 part -11 parts of cyclohexylamine, stannous chloride 1 part -8 Part.
2. the described cleaning diesel oil emulsifier described in claim 1, it is characterised in that it is by the weight by following components Part is prepared from:2 parts -5 parts of monoethanolamine, ethanol or 15 parts -25 parts of methanol, isooctyl ester nitrate or amyl nitrate 2 parts -5 Part, 2 parts -3 parts of ferrocene, 2 parts -4 parts of toluene, 2 parts -3 parts of BTA, 4 parts -7 parts of cyclohexylamine, stannous chloride 3 - 4 parts of part.
3. the described cleaning diesel oil emulsifier described in claim 1, it is characterised in that it is by the weight by following components Part is prepared from:3 parts of 20 parts of 4 parts of monoethanolamine, ethanol or methanol, isooctyl ester nitrate or amyl nitrate, 2.5 parts of ferrocene, first 2.5 parts of benzene, 2.5 parts of BTA, 5 parts of cyclohexylamine, 3.5 parts of stannous chloride.
4. the described cleaning diesel oil emulsifier described in claim 1, it is characterised in that described monoethanolamine is monoethanolamine, two Any one in monoethanolamine, triethanolamine.
5. the preparation method of the clean environmental-protective diesel emulsifying agent described in claim 1,2,3 or 4, it is characterised in that step is as follows: Take the monoethanolamine for meeting the parts by weight, ethanol or methanol, isooctyl ester nitrate or amyl nitrate, ferrocene, toluene, benzo three Nitrogen azoles, cyclohexylamine, stannous chloride are added in stirring container, are sufficiently stirred for, and are produced.
6. the preparation method of clean environmental-protective diesel emulsifying agent according to claim 5, it is characterised in that during described stirring Between be 20-30 minutes.
CN201710644170.7A 2017-08-01 2017-08-01 Clean environmental-protective diesel emulsifying agent Pending CN107216922A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585942A (en) * 2012-03-19 2012-07-18 刘少君 Concentration emulsified diesel fuel and preparation method thereof
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN104694177A (en) * 2013-12-06 2015-06-10 青岛惠城石化科技有限公司 Clean composite diesel oil fuel for vehicles
CN104789280A (en) * 2014-12-26 2015-07-22 淄博坤圆能源技术有限公司 Environmental-friendly clean diesel oil and preparing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585942A (en) * 2012-03-19 2012-07-18 刘少君 Concentration emulsified diesel fuel and preparation method thereof
CN102643692A (en) * 2012-05-08 2012-08-22 刘少君 Concentrated emulsified diesel fuel and preparation method thereof
CN104694177A (en) * 2013-12-06 2015-06-10 青岛惠城石化科技有限公司 Clean composite diesel oil fuel for vehicles
CN104789280A (en) * 2014-12-26 2015-07-22 淄博坤圆能源技术有限公司 Environmental-friendly clean diesel oil and preparing method thereof

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Application publication date: 20170929