CN104726147A - Oil phase of porous granular ammonium nitrate fuel oil explosive and preparation method thereof - Google Patents
Oil phase of porous granular ammonium nitrate fuel oil explosive and preparation method thereof Download PDFInfo
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- CN104726147A CN104726147A CN201510079048.0A CN201510079048A CN104726147A CN 104726147 A CN104726147 A CN 104726147A CN 201510079048 A CN201510079048 A CN 201510079048A CN 104726147 A CN104726147 A CN 104726147A
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Abstract
The invention discloses high-performance low-cost environment-friendly oil phase of porous granular ammonium nitrate fuel oil explosive and a preparation method thereof. The oil phase is micro-emulsified oil or emulsified oil and is prepared from the following components in percentage by mass: 10-90 percent of fuel oil, 5-70 percent of an emulsifier and 5-80 percent of a solvent by means of mixing. The porous granular ammonium nitrate fuel oil explosive prepared by the oil phase has excellent explosion performance, relatively low production cost and excellent environment-friendly effect.
Description
Technical field
The invention belongs to preparation of fuel field, particularly a kind of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase and preparation method thereof.
Background technology
It is reported, at present for the oil phase mainly diesel oil of porous particulated ammonium oil explosive, along with petroleum is more and more shorter, the development research of its substitute products is more and more important.Some experts and scholars has done certain research to diesel oil surrogate.As No. CN201110251807.9, China Patent No. discloses the application of biofuel in porous particulated ammonium oil explosive; China Patent No. CN201310130151.4 discloses the application of life waste oil in porous particulated ammonium oil explosive; Although the oils product disclosed in patent can reach the requirement of production technique, all there is certain weak point.Biofuel is that a kind of production technique is simple, environmental protection, cheap fuel, but due to the mixing uniformity of biofuel and ammonium nitrate poor, the blast performance of ammonium nitrate is decreased.Life waste oil Component comparison is complicated, and quality product is restive, prepared porous particulated ammonium oil explosive unstable properties.
Summary of the invention
The object of the present invention is to provide a kind of preparation technology simple high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase and preparation method thereof.
The technical solution realizing the object of the invention is: a kind of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase, is made up of the following component represented with mass percent and proportioning: oil fuel 10 ~ 90%, emulsifying agent 5 ~ 70%, solvent 5 ~ 80%.
Described oil fuel is the one or more kinds of mixtures of diesel oil, lubricating oil, gasoline, vegetables oil, animal oil, coal liquifaction; Emulsifying agent is one or more mixture of oleic acid ester, polyisobutene succinimide, Soxylat A 25-7, tween, Triton, Sodium dodecylbenzene sulfonate; Solvent is the one or more kinds of mixtures of water, aqueous organopolysiloxane, inorganic salt solution; Aqueous organopolysiloxane is the one or more kinds of mixtures of ethanolic soln, propanol solution, methanol solution, and aqueous organopolysiloxane mass percent concentration is: 40-50%, 30-60%, or 10-70%; Inorganic salt solution is the one or more kinds of mixtures of nitrate solution, carbonate solution, sulfate liquor, sulfonate solution, and inorganic salt solution mass percent concentration is: 40-50%, 30-60%, or 10-70%.
Present invention also offers the preparation method of above-mentioned high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase, comprise the steps:
The first step, mixes oil fuel and emulsifying agent;
Second step, in the mixed solution that the first step obtains, add solvent even.
The present invention compared with prior art, its remarkable advantage: the mixing uniformity of (1) high-performance and low-cost environment-friendly type of the present invention porous particulated ammonium oil explosive oil phase and ammonium nitrate is better than diesel oil, biofuel, life waste oil etc.(2) explosion properties (explosion velocity, brisance, acting ability) using high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase of the present invention to prepare is better than current porous particulated ammonium oil explosive.(3) to compare diesel oil safer in the transport of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase of the present invention.(4) to compare diesel oil lower for high-performance and low-cost environment-friendly type porous grain ammonium nitrate-fuel oil mixture oil phase price of the present invention.
Embodiment
High-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase of the present invention, is made up of the following component represented with mass percent and proportioning: oil fuel 10 ~ 90%, emulsifying agent 5 ~ 70%, solvent 5 ~ 80%.
Prepare the method for above-mentioned high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase, comprise the steps:
10-90% oil fuel, 5-70% emulsifying agent and 5-80% solvent are mixed at normal temperatures, forms high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase; Described oil fuel is one or more mixture of diesel oil, lubricating oil, gasoline, vegetables oil, animal oil, coal liquifaction; Described emulsifying agent is one or more mixture of oleic acid ester, polyisobutene succinic diamide, Soxylat A 25-7, tween, Triton, Sodium dodecylbenzene sulfonate; Described solvent is one or more mixture of water, aqueous organopolysiloxane, inorganic salt solution.
Further illustrate with embodiment below.
Embodiment 1: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: diesel oil 40%, lubricating oil 2%, oleic acid ester 8%, ethanol 20%, water 30%.
Operation steps: lubricating oil, diesel oil, oleic acid ester mix by the first step; It is the aqueous ethanolic solution of 40% that dissolve with ethanol is formed concentration in water by second step; The aqueous ethanolic solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 2: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: diesel oil 30%, vegetables oil 20%, polyisobutene succinic diamide 10%, tween 5%, saltpetre 5%, water 30%.
Operation steps: vegetables oil, diesel oil, polyisobutene succinic diamide, tween mix by the first step; It is the Alkitrate of 14% that saltpetre is dissolved in water formation concentration by second step; The Alkitrate that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 3: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: coal liquifaction 15%, vegetables oil 20%, Triton 10%, Sodium dodecylbenzene sulfonate 5%, methyl alcohol 25%, water 25%.
Operation steps: coal liquifaction, vegetables oil mix by the first step; Triton, Sodium dodecylbenzene sulfonate, dissolve with methanol are formed methanol aqueous solution in water by second step; The methanol aqueous solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 4: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: diesel oil 50%, vegetables oil 40%, SPAN2.5%, Sodium dodecylbenzene sulfonate 2.5%, water 5%.
Operation steps: diesel oil, vegetables oil, SPAN mix by the first step; Sodium dodecylbenzene sulfonate is dissolved in water and forms the aqueous solution by second step; The aqueous solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms oil in water emulsion, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 5: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: diesel oil 30%, animal oil 15%, Soxylat A 25-7 10%, SPAN5%, methyl alcohol 15%, water 25%.
Operation steps: diesel oil, animal oil, Soxylat A 25-7, SPAN mix by the first step; Dissolve with methanol is formed 37.5% methanol aqueous solution in water by second step; The methanol aqueous solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 6: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: coal liquifaction 15%, vegetables oil 20%, Triton 10%, SPAN5%, methyl alcohol 25%, water 25%.
Operation steps: coal liquifaction, vegetables oil, SPAN mix by the first step; Triton, dissolve with methanol are formed methanol aqueous solution in water by second step; The methanol aqueous solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 7: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: animal oil 30%, vegetables oil 10%, SPAN10%, polyisobutene succinic diamide 5%, saltpetre 5%, water 40%.
Operation steps: animal oil, vegetables oil, SPAN, polyisobutene succinic diamide mix by the first step; Saltpetre is dissolved in water and forms Alkitrate by second step; The Alkitrate that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Embodiment 8: to produce 20 kilograms of high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases, the mass percent of each component of selection high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase is: coal liquifaction 15%, biofuel 20%, oleic acid ester 10%, Sodium dodecylbenzene sulfonate 5%, ethanol 25%, water 25%.
Operation steps: coal liquifaction, biofuel, oleic acid ester mix by the first step; Sodium dodecylbenzene sulfonate, dissolve with ethanol are formed aqueous ethanolic solution in water by second step; The aqueous ethanolic solution that second step is prepared by the 3rd step joins in the obtained mixture of the first step to stir and forms microemulting oil, obtains high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phase.
Except above embodiment, all the other high-performance and low-cost environment-friendly type porous particulated ammonium oil explosive oil phases all can be implemented by the method for above-mentioned eight embodiments.
Claims (7)
1. a porous particulated ammonium oil explosive oil phase, is characterized in that: described porous particulated ammonium oil explosive oil phase is microemulting oil or oil in water emulsion.
2. porous particulated ammonium oil explosive oil phase according to claim 1, is characterized in that: described microemulting oil or oil in water emulsion are water-in-oil-type structure or oil-in-water-type structure.
3. porous particulated ammonium oil explosive oil phase according to claim 1, is characterized in that: described microemulting oil or oil in water emulsion are by 10-90% oil fuel, 5-70% emulsifying agent and 5-80% solvent composition; Described per-cent is mass percent.
4. porous particulated ammonium oil explosive oil phase according to claim 3, is characterized in that: described oil fuel is the one or more kinds of mixtures of diesel oil, lubricating oil, gasoline, vegetables oil, animal oil, coal liquifaction; Emulsifying agent is one or more mixture of oleic acid ester, polyisobutene succinimide, Soxylat A 25-7, tween, Triton, Sodium dodecylbenzene sulfonate; Solvent is the one or more kinds of mixtures of water, aqueous organopolysiloxane, inorganic salt solution.
5. porous particulated ammonium oil explosive oil phase according to claim 4, it is characterized in that: described aqueous organopolysiloxane is the one or more kinds of mixtures of ethanolic soln, propanol solution, methanol solution, aqueous organopolysiloxane mass percent concentration is: 40-50%, 30-60%, or 10-70%.
6. porous particulated ammonium oil explosive oil phase according to claim 4, it is characterized in that: described inorganic salt solution is the one or more kinds of mixtures of nitrate solution, carbonate solution, sulfate liquor, sulfonate solution, inorganic salt solution mass percent concentration is: 40-50%, 30-60%, or 10-70%.
7. porous particulated ammonium oil explosive oil phase according to claim 1, is characterized in that: described microemulting oil or the preparation method of oil in water emulsion comprise the steps:
The first step, mixes oil fuel and emulsifying agent;
Second step, in the mixed solution that the first step obtains, add solvent even.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111253198A (en) * | 2020-04-01 | 2020-06-09 | 江西吉安国泰特种化工有限责任公司 | Formula and production process of detonator-free sensitivity emulsified granular ammonium nitrate fuel oil explosive |
| CN111704517A (en) * | 2020-07-02 | 2020-09-25 | 安徽金奥博化工科技有限公司 | Low-cost environment-friendly special oil for ammonium nitrate fuel oil explosive and preparation method thereof |
| CN112919998A (en) * | 2021-03-24 | 2021-06-08 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing high-temperature sensitization process emulsion explosive from coal-to-liquid intermediate product and preparation method thereof |
| CN112919999A (en) * | 2021-03-24 | 2021-06-08 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing puffed ammonium nitrate explosive from coal-to-liquid intermediate and preparation method thereof |
| CN112939710A (en) * | 2021-03-24 | 2021-06-11 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed ammonium nitrate fuel oil explosive by using coal-to-liquid intermediate product and preparation method thereof |
| CN112939709A (en) * | 2021-03-24 | 2021-06-11 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed emulsion explosive by using coal-to-liquid intermediate product and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045662A (en) * | 2006-03-31 | 2007-10-03 | 南京理工大学 | High-energy powder emulsified explosive and preparation method thereof |
| CN101555183A (en) * | 2009-05-26 | 2009-10-14 | 北京星宇惠龙科技发展有限责任公司 | Granular emulsion explosive and its producing method |
| CN102417428A (en) * | 2011-08-29 | 2012-04-18 | 福建海峡科化股份有限公司 | Application of biodiesel as oil phase material to production of on-site mix-filling emulsion (glue) matrix |
| CN103382143A (en) * | 2013-07-05 | 2013-11-06 | 倪欧琪 | High-performance low-cost environment-friendly porous granular ammonium nitrate-fuel oil explosive and preparation method thereof |
-
2015
- 2015-02-13 CN CN201510079048.0A patent/CN104726147A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045662A (en) * | 2006-03-31 | 2007-10-03 | 南京理工大学 | High-energy powder emulsified explosive and preparation method thereof |
| CN101555183A (en) * | 2009-05-26 | 2009-10-14 | 北京星宇惠龙科技发展有限责任公司 | Granular emulsion explosive and its producing method |
| CN102417428A (en) * | 2011-08-29 | 2012-04-18 | 福建海峡科化股份有限公司 | Application of biodiesel as oil phase material to production of on-site mix-filling emulsion (glue) matrix |
| CN103382143A (en) * | 2013-07-05 | 2013-11-06 | 倪欧琪 | High-performance low-cost environment-friendly porous granular ammonium nitrate-fuel oil explosive and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111253198A (en) * | 2020-04-01 | 2020-06-09 | 江西吉安国泰特种化工有限责任公司 | Formula and production process of detonator-free sensitivity emulsified granular ammonium nitrate fuel oil explosive |
| CN111704517A (en) * | 2020-07-02 | 2020-09-25 | 安徽金奥博化工科技有限公司 | Low-cost environment-friendly special oil for ammonium nitrate fuel oil explosive and preparation method thereof |
| CN112919998A (en) * | 2021-03-24 | 2021-06-08 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing high-temperature sensitization process emulsion explosive from coal-to-liquid intermediate product and preparation method thereof |
| CN112919999A (en) * | 2021-03-24 | 2021-06-08 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing puffed ammonium nitrate explosive from coal-to-liquid intermediate and preparation method thereof |
| CN112939710A (en) * | 2021-03-24 | 2021-06-11 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed ammonium nitrate fuel oil explosive by using coal-to-liquid intermediate product and preparation method thereof |
| CN112939709A (en) * | 2021-03-24 | 2021-06-11 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed emulsion explosive by using coal-to-liquid intermediate product and preparation method thereof |
| CN112939709B (en) * | 2021-03-24 | 2022-04-22 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed emulsion explosive by using coal-to-liquid intermediate product and preparation method thereof |
| CN112939710B (en) * | 2021-03-24 | 2022-04-22 | 葛洲坝易普力湖北昌泰民爆有限公司 | Oil phase for preparing on-site mixed ammonium nitrate fuel oil explosive by using coal-to-liquid intermediate product and preparation method thereof |
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Application publication date: 20150624 |