CN101302452B - Diesel bio-additive - Google Patents
Diesel bio-additive Download PDFInfo
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- CN101302452B CN101302452B CN2007100279611A CN200710027961A CN101302452B CN 101302452 B CN101302452 B CN 101302452B CN 2007100279611 A CN2007100279611 A CN 2007100279611A CN 200710027961 A CN200710027961 A CN 200710027961A CN 101302452 B CN101302452 B CN 101302452B
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- diesel
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- acid
- oil
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Abstract
The invention discloses diesel bio-additives. The compositions by weight percentage of the diesel bio-additives are: 25 to 45 percent of fatty acid, 40 to 55 percent of solvent and 3 to 20 percent of modifier. The diesel bio-additives can be added into diesel fuel, can be soluble with the diesel fuel after full stirring, and can be used as fuel. With the addition of the diesel bio-additives, the amount of the diesel fuel is reduced and then the cost is reduced; after the diesel bio-additives prepared are mixed with the diesel fuel, no stratification occurs, thereby the thermal value is high and the chrominance and the quality index are similar to those of crude oil; the diesel bio-additives prepared are glutinous solid matter, is simple in preparation technique and convenient in transportation, and is pollution-free; and purchasers can purchase the diesel bio-additives and then mix the diesel bio-additives with the diesel fuel, thereby being very convenient.
Description
Technical field
The present invention relates to the derived energy chemical field, specifically, relate to a kind of diesel bio-additive.
Background technology
Diesel oil occupies very high share as a kind of important refining of petroleum product in various countries' fuel structure, be many oversize vehicles, power station, the main fuel of factory or the like.Along with expanding economy, the demand of following diesel oil can be increasing, and the exhaustion day by day of petroleum resources has promoted countries in the world to accelerate the developing steps of diesel oil alternative fuel and energy conservation.
The price of diesel oil is still than higher at present, if can adopt cheap raw material to replace diesel oil, that can reduce the consumption and the price of diesel oil.There are abundant Vegetable oil lipoprotein and animal oil and fat resource in China, and annual soya-bean oil output reaches 6,000 ten thousand tons, if good use in addition has very big market potential.
Summary of the invention
The objective of the invention is to overcome the problem that existing diesel oil exists, provide a kind of and can add in the diesel oil, can mix the diesel bio-additive that acts as a fuel and use with diesel oil.
For achieving the above object, the present invention has taked following technical scheme:
A kind of diesel bio-additive, form by following component and weight percentage:
Lipid acid 25~45%
Solvent 40~55%
Properties-correcting agent 3~20%.
In above-mentioned diesel bio-additive, the preferred weight percentage ratio of each component is:
Lipid acid 30~40%
Solvent 50~55%
Properties-correcting agent 8~15%.
In above-mentioned diesel bio-additive; The preferred animal, plant fatty acid of said lipid acid is like one or more the mixture in the fatty ester of animal oil and fat, linolic acid, linolenic oil, oleic acid, α-oleum lini, sodium laurate grease, glycerine, erucic acid quasi-grease, castor oil, plant-animal compound lard or the like.
In above-mentioned diesel bio-additive, said properties-correcting agent preferred fatty acid Soxylat A 25-7, polyoxyethylene glycol Octyl Ether, fatty diglycollic amide, polyoxyethylene alkylphenol ether, polyoxyethylene carboxylate, alkylol amide, alkyl benzene sulfonate, sorbitan list olein, soya-bean oil soap matter, sodium laurylsulfonate, lipid acid copper, silicone oil, alkyl nitric acid are dead drunk, one or more the mixture in the nonyl ethers, dodecyl polyethylene oxide ether.
In above-mentioned diesel bio-additive, said solvent does not have special requirement, and general solvent is all passable, like ethanolic soln, hexanaphthene, benzene or inorganic salt solution.
The preparation method of above-mentioned diesel bio-additive comprises the steps: in proportion lipid acid and solvent are heated to 50~90 ℃; And then adding properties-correcting agent, stir and promptly generated product in 5~10 minutes.
Compared with present technology, the present invention has following beneficial effect:
1. diesel bio-additive of the present invention can add in the diesel oil, can dissolve each other with diesel oil after fully stirring, and can be used as fuel and uses.Adding proportion as for diesel bio-additive and diesel oil need not special restriction, can adjust as required.The adding of diesel bio-additive has reduced the consumption of diesel oil, but its combustion efficacy is unaffected.The main raw material of diesel bio-additive is a lipid acid, and fatty acid source is wide, price is low, and the price of gained diesel bio-additive has promotional value than cheaply a lot of with the diesel oil of weight.
2. the prepared diesel bio-additive of the present invention is with after diesel oil mixes, and not stratified, calorific value is high, and colourity and quality index are similar with crude oil;
3. the prepared diesel bio-additive of the present invention is a kind of sticky solid thing, and preparation technology is simple, and is pollution-free, convenient transportation; The buyer can buy diesel bio-additive, goes back to be mixed with diesel oil again, and is very convenient.
Embodiment
Embodiment 1
The linolenic oil of 40 weight % and 75% ethanolic soln of 52 weight % are added in the reaction kettle, be heated to 80 ℃; The sorbitan list olein of adding 8 weight % in reaction kettle stirs then, reacts promptly to generate product in 5 minutes.
Embodiment 2
The oleic acid of 35 weight % and the hexanaphthene of 50 weight % are added in the reaction kettle, be heated to 50 ℃; The dodecyl polyethylene oxide ether of adding 15 weight % in reaction kettle stirs then, reacts promptly to generate product in 6 minutes.
Embodiment 3
The soya-bean oil soap matter of 30 weight % and the benzene of 55 weight % are added in the reaction kettle, be heated to 60 ℃; The alkylol amide of adding 15 weight % in reaction kettle stirs then, reacts promptly to generate product in 8 minutes.
Embodiment 4
The castor oil of 40 weight % and the sodium chloride solution of 40 weight % are added in the reaction kettle, be heated to 90 ℃; The aliphatic acid polyethenoxy ether of adding 20 weight % in reaction kettle stirs then, reacts promptly to generate product in 10 minutes.
Embodiment 5
The fatty ester of the glycerine of 25 weight % and 20% ethanolic soln of 55 weight % are added in the reaction kettle, be heated to 85 ℃; The polyoxyethylene alkylphenol ether of adding 20 weight % in reaction kettle stirs then, reacts promptly to generate product in 6 minutes.
Performance specification:
The prepared diesel bio-additive that obtains of the present invention is brown, the solid dope, and not stratified with the diesel oil back of dissolving each other, calorific value is high, and colourity and quality index are similar with crude oil.The fuel oil that obtains after prepared diesel bio-additive that obtains and diesel oil dissolve each other can be used as various large combustion machines, the power station, and industrial fuel, the feedback result of use is good, is as good as with former diesel oil.
Claims (5)
1. diesel bio-additive is characterized in that being made up of following component and weight percentage:
Lipid acid 25~45%
Solvent 40~55%
Properties-correcting agent 3~20%;
Said properties-correcting agent is one or more the mixture in aliphatic acid polyethenoxy ether, polyoxyethylene glycol Octyl Ether, fatty diglycollic amide, polyoxyethylene alkylphenol ether, polyoxyethylene carboxylate, alkylol amide, alkyl benzene sulfonate, sorbitan list olein, soya-bean oil soap matter, sodium laurylsulfonate, lipid acid copper, silicone oil, nonyl ethers, the dodecyl polyethylene oxide ether;
Said solvent is ethanolic soln, hexanaphthene, benzene or inorganic salt solution.
2. diesel bio-additive as claimed in claim 1 is characterized in that the weight percentage of said component is:
Lipid acid 30~40%
Solvent 50~55%
Properties-correcting agent 8~15%.
3. diesel bio-additive as claimed in claim 1 is characterized in that said lipid acid is animal, plant fatty acid.
4. diesel bio-additive as claimed in claim 3 is characterized in that said animal, plant fatty acid is one or more the mixture in the fatty ester, erucic acid quasi-grease, castor oil, plant-animal compound lard of animal oil and fat, linolic acid, linolenic oil, oleic acid, α-oleum lini, sodium laurate grease, glycerine.
5. the method for preparing the described diesel bio-additive of claim 1 is characterized in that comprising the steps: in proportion lipid acid and solvent are heated to 50~90 ℃; And then adding properties-correcting agent, stir and promptly generated product in 5~10 minutes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2007100279611A CN101302452B (en) | 2007-05-11 | 2007-05-11 | Diesel bio-additive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2007100279611A CN101302452B (en) | 2007-05-11 | 2007-05-11 | Diesel bio-additive |
Publications (2)
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CN101302452A CN101302452A (en) | 2008-11-12 |
CN101302452B true CN101302452B (en) | 2012-03-21 |
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CN2007100279611A Expired - Fee Related CN101302452B (en) | 2007-05-11 | 2007-05-11 | Diesel bio-additive |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104178359A (en) * | 2014-07-22 | 2014-12-03 | 郭俊旺 | Reaction preparation method of animal-plant oil fat microemulsion |
CN104357097A (en) * | 2014-07-22 | 2015-02-18 | 郭俊旺 | Preparation method of animal and plant grease microemulsion fuel oil |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1896194A (en) * | 2005-07-22 | 2007-01-17 | 金学刚 | Micro-emulsion fatty acid diesel oil and its production |
CN1931969A (en) * | 2005-09-13 | 2007-03-21 | 刘有望 | Biofuel oil and its prepn process |
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2007
- 2007-05-11 CN CN2007100279611A patent/CN101302452B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1896194A (en) * | 2005-07-22 | 2007-01-17 | 金学刚 | Micro-emulsion fatty acid diesel oil and its production |
CN1931969A (en) * | 2005-09-13 | 2007-03-21 | 刘有望 | Biofuel oil and its prepn process |
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Granted publication date: 20120321 Termination date: 20140511 |