CN101619249B - Alcohol-based fuel modifier, enhancer, alcohol-based liquid fuel after modification and enhancement and production process thereof - Google Patents
Alcohol-based fuel modifier, enhancer, alcohol-based liquid fuel after modification and enhancement and production process thereof Download PDFInfo
- Publication number
- CN101619249B CN101619249B CN2009100331412A CN200910033141A CN101619249B CN 101619249 B CN101619249 B CN 101619249B CN 2009100331412 A CN2009100331412 A CN 2009100331412A CN 200910033141 A CN200910033141 A CN 200910033141A CN 101619249 B CN101619249 B CN 101619249B
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- China
- Prior art keywords
- alcohol
- fuel
- reactor
- modifier
- toughener
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 279
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 109
- 239000003607 modifier Substances 0.000 title claims abstract description 105
- 239000007788 liquid Substances 0.000 title claims abstract description 77
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 230000004048 modification Effects 0.000 title claims abstract description 25
- 238000012986 modification Methods 0.000 title claims abstract description 25
- 239000003623 enhancer Substances 0.000 title claims abstract description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 52
- 229930195729 fatty acid Natural products 0.000 claims abstract description 52
- 239000000194 fatty acid Substances 0.000 claims abstract description 52
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 52
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 47
- -1 hydroxy ester Chemical class 0.000 claims abstract description 47
- 229910052742 iron Inorganic materials 0.000 claims abstract description 46
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 41
- 238000002485 combustion reaction Methods 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 31
- 230000006835 compression Effects 0.000 claims abstract description 27
- 238000007906 compression Methods 0.000 claims abstract description 27
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 26
- 239000012745 toughening agent Substances 0.000 claims description 97
- 125000003158 alcohol group Chemical group 0.000 claims description 89
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 58
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 55
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 48
- 235000013311 vegetables Nutrition 0.000 claims description 48
- 150000002191 fatty alcohols Chemical class 0.000 claims description 47
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 32
- 150000001298 alcohols Chemical class 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 14
- 230000002708 enhancing effect Effects 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 230000000704 physical effect Effects 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000001804 emulsifying effect Effects 0.000 claims description 8
- 238000009738 saturating Methods 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 4
- 210000000481 breast Anatomy 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims 2
- 230000008569 process Effects 0.000 abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000003208 petroleum Substances 0.000 abstract description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 4
- 229910021529 ammonia Inorganic materials 0.000 abstract 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 68
- 235000019198 oils Nutrition 0.000 description 68
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 241000196324 Embryophyta Species 0.000 description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 7
- 239000005642 Oleic acid Substances 0.000 description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 7
- 239000002283 diesel fuel Substances 0.000 description 6
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 5
- 239000000295 fuel oil Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- 244000068988 Glycine max Species 0.000 description 4
- 235000010469 Glycine max Nutrition 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 235000019483 Peanut oil Nutrition 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- BOVMXPKRBJWLBJ-UHFFFAOYSA-N benzene;iron Chemical compound [Fe].C1=CC=CC=C1 BOVMXPKRBJWLBJ-UHFFFAOYSA-N 0.000 description 2
- 239000002551 biofuel Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000312 peanut oil Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000003381 solubilizing effect Effects 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000003500 flue dust Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1811—Organic compounds containing oxygen peroxides; ozonides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
- C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention relates to an alcohol-based fuel modifier, an enhancer, an alcohol-based liquid fuel after modification and enhancement and a production process thereof, the proportioning of components of the modifier is that organic peroxide: ethanolamine: ammonia is equal to 1:0.5:1.1, and the proportioning of the components of the enhancer is that biscyclopentadienyl iron: aromatic hydrocarbon is equal to 1:6-10. The alcohol-based liquid fuel for a compression ignition engine comprises the following components by weight percent: 33.5-70% of low carbon alcohol, 2-7.5% of alcohol-based fuel modifier, 3-6% of hydroxy ester, 3-7% of ammonia, 5-8% of higher aliphatic alcohol, 4-6% of carboxylic fatty acid, 1-10% of alcohol-based fuel enhancer, 5-12% of higher aliphatic alcohol, 5-8% of carboxylic fatty acid and 1-2% of hydroxy ester. The fuel for an ignition internal combustion engine comprises the following components by weight percent: 43.3-80% of low carbon alcohol, 2-7.2% of alcohol-based fuel modifier, 6-8% of petroleum ether, 3-4.5% of ammonia, 2-6% of higher aliphatic alcohol, 4-12% of carboxylic fatty acid, 1-10% of alcohol-based fuel enhancer, 4-6% of higher aliphatic alcohol and 2-3% of carboxylic fatty acid. The invention adopts a new process of step-by-step oil formation, which is operated at normal temperature and normal pressure and has simple operation, no emissions of three wastes and safe use and transportation.
Description
Technical field
The invention belongs to the fuel chemical industry field, relate in particular to compression-ignited and the ignition internal combustion engine alcohol radical liquid fuel.
Background technology
Progress along with science and technology; the fast development of process of industrialization; caused global scarcity of resources and people to rely the progressively deterioration of the ecotope of complying with existence; just become the primary goal that all work are carried out for the reasonable development of earth resources and application and ecological environmental protection problem; under the guidance of this thought; luminous energy, heat energy, gravitational energy, wind energy, tidal energy, nuclear energy, biological chemistry energy etc. new forms of energy occur in succession, and tentatively demonstrate powerful vitality and the trend of Future New Energy Source development.
Methyl alcohol in the low-carbon alcohol is present in occurring in nature widely, be that thing is beautiful, inexpensive, aboundresources, clean fuel that the conversion cost is low, it can be from extractions such as coal, Sweet natural gas, oil field gas, plant, combustiblerefuses, it is again the byproduct of grain distillery, sugar refinery and other chemical industry of chemical fertilizer factory, generate carbonic acid gas and water after the burning, do not have other any objectionable impurities and flue dust, its Main physical and chemical property are as follows:
1, have higher energy loss-rate (under theoretical air-fuel ratio state) and be 3.07Kj/Kg, and diesel oil is 2.93Kj/Kg that the calorific value of methyl alcohol is 6.45Kj/Kg when apparatus of the internal-combustion engine uses, and diesel oil is 13.3~14.6Kj/Kg;
2, have wider ignition range, be calculated as 6~36.5% by volumetric ratio, and diesel oil is 1.59~8.2%;
3, relative density is 0.792 g/cc, fusing point-97.8 ℃, 64.5 ℃ of boiling points, 12.22 ℃ of flash-points, 463.89 ℃ of spontaneous ignition temperatures, vapour pressure 13.33KPa (100mmHg);
4, latent heat of vaporization 1109Kj/Kg, diesel oil 270Kj/Kg;
5, the about 0.7mm of viscosity
2About/s, diesel oil viscosity 2.5~8.5mm
2/ s;
6, because chemical structure, metal is had potential corrosion, nonmetal have a swelling effect, and the methyl alcohol add-on is larger, and effect is just more obvious.
As can be seen from the above analysis, it is feasible that low-carbon alcohol is used as fuel oil of IC engine, if use as better oil fuel, must solve two crucial common problems, one is not changing under the design variable state of engine, and low-carbon alcohol liquid is implemented modification, increase its combustion heat value, reduce the consumption of oil plant.Its two, change potential corrosion problem under the normal temperature state of low-carbon alcohol and the condition of high temperature, the oil plant that certainly uses as compressing ignition engine also will be considered the viscosity of liquid, increases lubricity.
Summary of the invention
The present invention seeks to, for above-mentioned two the crucial common problems of low-carbon alcohol fuel as the existence of dynamic property fuel, provide alcohol-based fuel modifier and toughener, and with this alcohol-based fuel modifier and toughener low-carbon alcohol fuel is carried out modification and enhancement process, obtain meeting the employed Novel alcohol-based liquid fuel of compression ignition engine and ignition internal combustion engine, simultaneously the present invention provides alcohol-based fuel modifier, toughener and the low-carbon alcohol production technique of liquid fuel after modification and enhancing.
For achieving the above object, the present invention has provided alcohol-based fuel modifier component and mix proportion scheme.
The present invention provides alcohol-based fuel modifier, and this alcohol-based fuel modifier component is organo-peroxide, thanomin, ammoniacal liquor.Proportioning is organo-peroxide between each component of this alcohol-based fuel modifier: thanomin: ammoniacal liquor=1: 0.5: 1.1, these three kinds of component materials generation addition reactions form alcohol-based fuel modifier stoste.For further improving the physicals of this properties-correcting agent stoste, in this properties-correcting agent stoste, add again vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat, generation is applied to the properties-correcting agent of alcohol radical liquid fuel, each component of the alcohol-based fuel modifier of this practical application and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1.In the technical program, organo-peroxide in the component adopts chemical analysis pure, can be following a kind of in all kinds of: tert-butyl peroxide, sec.-propyl superoxide, Peracetic Acid fourth fat, dibenzoyl peroxide; Vegetables oil in the component can be a kind of in the following all kinds of oil: peanut oil, rapeseed oil, Viscotrol C, soya-bean oil; High fatty alcohol in the component is to contain four carbon to the monobasic that contains 12 carbon or multi-alcohol; Carboxylic fatty acids in the component can be following a kind of in all kinds of: oleic acid, naphthenic acid; Phthalic acid two fat in the component can be following a kind of in all kinds of: industrial o-phthalic acid dibutyl ester, industrial dibutyl phthalate (DBP).The main component of this alcohol-based fuel modifier is NH
3C
14H
10O
4With RNH
22C
14H
10C
4, through test and research, find that the mutual solubility of the product of this alcohol-based fuel modifier addition reaction and low-carbon alcohol liquid is good, especially under alkaline state, secondary ionization constant K2 value about 10
-25Power has solved the potential corrosion problem of methanol solution under the normal temperature effectively, and under the condition of high temperature, above-mentioned adduction product shows stronger reductive agent effect, has promoted significantly the calorific value of fluid, has reduced the consumption of fluid and to the corrosive nature of parts; This properties-correcting agent has obvious alcoholization reaction to vegetables oil in addition, from other angle, has also impelled the alcoholization reaction of vegetables oil, increases calorific value, the cetane value of oil plant, has improved viscosity and the surface tension of oil plant, improves the oilness of oil plant with compatible.The alcohol-based fuel modifier that the technical program generates can be applicable to the alcohol radical liquid fuel modification of compression ignition engine and ignition internal combustion engine.
For achieving the above object, the present invention has provided alcohol-group fuel enhancer component and mix proportion scheme.
The alcohol-group fuel toughener that the present invention provides, this alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, this each component proportion of alcohol-group fuel toughener is, dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10, dicyclopentadienyl iron is dissolved in the aromatic hydrocarbon material, generate alcohol-group fuel toughener stoste, for further improving the physicals of this toughener stoste, in this alcohol-group fuel toughener stoste, add again vegetables oil or solvent oil, aniline, generation is applied to the toughener of alcohol radical liquid fuel, this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1.In the technical program, the dicyclopentadienyl iron in the component is that CR is pure, and aromatic hydrocarbon is industrial one-level, and vegetables oil is food grade, and aniline is analytical pure AR level.Aromatic hydrocarbon in the component can be following a kind of in all kinds of: benzene,toluene,xylene; Vegetables oil in the component can be following a kind of in all kinds of: peanut oil, rapeseed oil, Viscotrol C, soya-bean oil; Solvent oil in the component can be a kind of in NY-120 number, NY-200 number.The alcohol-group fuel toughener has played the effect of further enhancing alcohol-based fuel modifier, to reach the purpose that realizes the high quality oil plant.The toughener that adds vegetables oil and aniline generation in alcohol-group fuel toughener stoste is applicable to the compression ignition engine alcohol radical liquid fuel, and the toughener that adds solvent oil and aniline generation in alcohol-group fuel toughener stoste then is applicable to the ignition internal combustion engine alcohol radical liquid fuel.
For achieving the above object, the present invention gives component and the mix proportion scheme through the alcohol radical liquid fuel of modification and enhancing.
The given alcohol radical liquid fuel through modification and enhancing of the present invention has two kinds, and one is the alcohol radical liquid fuel that compression ignition engine uses, its two alcohol radical liquid fuel for the ignition internal combustion engine use.
The component and the weight percent that are used for the alcohol radical liquid fuel of compression ignition engine are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%.Use in the alcohol radical liquid fuel at this compression ignition engine, a kind of during described low-carbon alcohol is can be following all kinds of, methyl alcohol, ethanol, a kind of in propyl alcohol or the first and second pure alcohol mixtures, its purity requirement 〉=95% industrial goods, described hydroxyl fat can be Viscotrol C, a kind of in the turkey red oil, its purity is industrial goods, described alcohol-based fuel modifier be prepare in advance for subsequent use, each component of this alcohol-based fuel modifier and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1.With in alcohol radical liquid fuel, described alcohol-group fuel toughener also is to prepare in advance for subsequent usely at this compression ignition engine, and this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil: aniline=1: 6~10: 6~20: 1.
The alcohol radical liquid fuel component and the weight percent that are used for ignition internal combustion engine are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%.Use in the alcohol radical liquid fuel at this ignition internal combustion engine, described sherwood oil boiling point is a kind of in 60-90 ℃, 90-120 ℃, described alcohol-based fuel modifier be prepare in advance for subsequent use, each component of this alcohol-based fuel modifier and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1.With in alcohol radical liquid fuel, described alcohol-group fuel toughener also is to prepare in advance for subsequent usely at this ignition internal combustion engine, and this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: solvent oil: aniline=1: 6~10: 6~20: 1.
For achieving the above object, the present invention gives the production technique of alcohol-based fuel modifier,
The preparation of this properties-correcting agent is carried out in independent reactor, each component proportion of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, this each component proportion of alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight, because this moment, reaction was thermopositive reaction, for the control response intensity, will start agitator, dispel the heat, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) behind drop in temperature, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste, i.e. RNH again
22C
14H
10C
4With NH
3C
14H
10O
4Adduct;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5~2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
The alcohol-based fuel modifier of this production technique manufacture both had been applicable to the modification of compression ignition engine alcohol radical liquid fuel, also was applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel.
For achieving the above object, the present invention has provided the production technique that compression ignition engine is used the alcohol radical liquid fuel toughener with production technique and the ignition internal combustion engine of alcohol-group fuel toughener.
The compression ignition engine production technique of alcohol-group fuel toughener,
Compression ignition engine with each component of alcohol-group fuel toughener and proportioning is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil: aniline=1: 6~10: 6~20: 1.
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, this each component proportion of alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) with in the aromatic hydrocarbon of 6~10 parts of weight input reactor, start agitator and stir, until dicyclopentadienyl iron complete molten till, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps, namely in alcohol-group fuel toughener stoste, adds the vegetables oil of 6~20 parts of weight and the aniline of 1 part of weight, generate the toughener of practical application,
(3) with the vegetables oil of 6~20 parts of weight input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4) with the aniline of 1 part of weight input reactor, be stirred to and entirely namely be prepared into the toughener that is applicable to the compression ignition engine alcohol radical liquid fuel till molten.
The ignition internal combustion engine production technique of alcohol radical liquid fuel toughener,
Ignition internal combustion engine with each component of alcohol-group fuel toughener and proportioning is dicyclopentadienyl iron: aromatic hydrocarbon: solvent oil: aniline=1: 6~10: 6~20: 1.
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, this each component proportion of alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) with in the aromatic hydrocarbon of 6~10 parts of weight input reactor, start agitator and stir, until dicyclopentadienyl iron complete molten till, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps, namely in alcohol-group fuel toughener stoste, adds the solvent oil of 6~20 parts of weight and the aniline of 1 part of weight, generate the toughener of practical application,
(3) with the solvent oil of 6~20 parts of weight input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4) with the aniline of 1 part of weight input reactor, be stirred to and entirely namely be prepared into the toughener that is applicable to the ignition internal combustion engine alcohol radical liquid fuel till molten.
For achieving the above object, the present invention has provided the production technique of compression ignition engine with alcohol radical liquid fuel: the component of this fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare for subsequent use in advance;
What this fuel adopted is " substep becomes oil " production technique, and idiographic flow, condition are as follows:
(1) low-carbon alcohol is input in the large reactor,
(2) be input to alcohol-based fuel modifier in the reactor and stir, solution is turbid molten, and microdeposit is arranged,
(3) hydroxyl fat is input in the reactor and stirring, solution is mixed clear, the precipitation nothing,
(4) ammoniacal liquor is input in the reactor and stirring, emulsifying soln,
(5) high fatty alcohol is input in the reactor and stirring, this moment, solution was clear, saturating,
(6) carboxylic fatty acids is input in the reactor and stirring, it is bright clearly to form solution, and the pH value is 8.0-9.0, becomes oil to finish for the first time,
(7) the alcohol radical toughener is input in the reactor, the solution becomes breast, viscosity increases,
(8) again high fatty alcohol is input in the reactor, solution becomes is saturating clearly,
(9) again carboxylic fatty acids is input in the reactor and stirring, this moment, solution was clearly thoroughly shinny, and the pH value becomes oil for the second time for 7.0-7.5,
(10) again hydroxyl fat is input in the reactor, fluid is brighter, becomes oil to finish for the second time,
(11) fluid that becomes oil to finish secondary is put into product tank one-tenthization, and the one-tenthization time is no less than 30 minutes, makes fluid more stable, and this alcohol radical liquid fuel is applicable to compression ignition engine.
For achieving the above object, the present invention has provided the production technique of ignition internal combustion engine with alcohol radical liquid fuel.The component of this fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare for subsequent use in advance;
The employing of this fuel be " substep become oil " production technique, idiographic flow, condition are as follows:
(1) low-carbon alcohol is input in the reactor,
(2) alcohol-based fuel modifier is input in the reactor, starts agitator and stir,
(3) sherwood oil is input in the reactor, solution is clear,
(4) ammoniacal liquor is input in the reactor, emulsifying soln,
(5) high fatty alcohol is input in the reactor, solution becomes is clear,
(6) carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7.5-8.5, becomes for the first time oil,
(7) the alcohol-group fuel toughener is input in the reactor, the solution micro emulsion,
(8) again high fatty alcohol is inputted in the reactor, solution is bright clearly,
(9) again carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7-7.5, becomes oil to finish for the second time, and this alcohol radical liquid fuel is applicable to ignition internal combustion engine.
In above-mentioned two kinds of alcohol radical liquid fuel production processes, take low-carbon alcohol as main ingredient, minute two steps are added respectively alcohol-based fuel modifier and alcohol-group fuel toughener, have formed unique " substep becomes oil process ".Substep adds alcohol-based fuel modifier and alcohol-group fuel toughener sequentially in alcohol-group fuel, make and form the higher fatty acid formicester after the alcohol radical esterification and through changing the biofuel oil of chemical and physical properties, its every combustionproperty and physical and chemical index satisfy compression ignite, igniting internal combustion engine uses, we are different from blended fuel, petroleum fuel oils by the alcohol radical liquid fuel that this " substep becomes oil process " produces, and also are different from biofuel oil truly.
Advantage of the present invention is that by formed compressing ignition engine alcohol radical liquid fuel behind interpolation alcohol-based fuel modifier, the alcohol-group fuel toughener, its combustionproperty, important physical and chemical index are all high than commercially available diesel oil, non-secondary pollution.By formed ignition internal combustion engine alcohol radical liquid fuel behind interpolation alcohol-based fuel modifier, the alcohol-group fuel toughener, have high-octane rating (90~No. 98), not leaded, high-cleanness.The production of two kinds of alcohol-group fuels of the present invention need not special professional equipment, under normal temperature, normal pressure, to adjust parameter few, simple.Three-waste free pollution in the production process, operation, transportation safety.Alcohol radical liquid fuel of the present invention is used in various vehicles, and energy decrease Vehicular exhaust has also been broken away from the dependency to petroleum resources to the pollution of environment, is a kind of novel liquid fuel that is conducive to scale operation, popularization, application.
Specific embodiment
Embodiment one: the production of alcohol-based fuel modifier
The production of present embodiment alcohol-based fuel modifier is carried out in independent reactor, to produce 100 kilograms properties-correcting agent as example, the weight of each component of properties-correcting agent is: 12.3 kilograms of dibenzoyl peroxide, 6.2 kilograms of thanomins, 13.6 kilograms of ammoniacal liquor, 12.3 kilograms of soybean oil, 24.7 kilograms of octanols, 18.6 kilograms of oleic acid, 12.3 kilograms of dibutylesters, technical process is: (1) is poured dibenzoyl peroxide in the reactor into, (2) pour into again thanomin in the reactor, start agitator this moment, the control temperature of reaction, make them in 90 ℃ of-100 ℃ of scopes, can not allow reaction too strong, this moment, solid-state dibenzoyl peroxide generated RNH
22C
14H
10C
4(3) ammoniacal liquor is poured in the reactor, formed transparent inclusion-free liquid NH
3C
14H
10O
4(4) it is mixed sticking soybean oil to be poured in the reactor into solution becomes again; (5) octanol is poured into thinningly in the reactor released transparent liquid, (6) are poured oleic acid into and are adjusted the pH value in the reactor between 7-7.5, and (7) are poured dibutylester in the reactor at last, the clear printing opacity of solution becomes.
Embodiment two: the compression ignition engine production of alcohol-group fuel toughener
Present embodiment is to produce 100 kilograms compression ignition engine alcohol-group fuel toughener as example, each composition of toughener and weight are: 5 kilograms of dicyclopentadienyl iron, 50 kilograms of dimethylbenzene, 40 kilograms in soya-bean oil, 5 kilograms of aniline, the preparation of this toughener is carried out in independent reactor, concrete steps: (1) is poured dicyclopentadienyl iron in the reactor into, and (2) are poured dimethylbenzene into and stirred the inclusion-free that mixes in the reactor; (3) soya-bean oil is poured into mix in the reactor transparent, (4) with aniline pour in the reactor become clear emit after bright for subsequent use.The whole process reaction of present embodiment is solubilizing reaction, safety, without the three wastes.
Embodiment three: the ignition internal combustion engine production of alcohol-group fuel toughener
Present embodiment is to produce 100 kilograms of ignition internal combustion engine alcohol-group fuel tougheners as example, and each composition of toughener and weight are: 3.2 kilograms of Dicyclopentadiene (DCPD) benzene iron, 32.6 kilograms of dimethylbenzene, 61 kilograms of solvent oils (No. 200), 3.2 kilograms of aniline.The preparation of this toughener is carried out in independent reactor, concrete steps: (1) is passed to Dicyclopentadiene (DCPD) benzene iron in the reactor, and (2) are input to dimethylbenzene in the reactor, and agitator begins to stir; (3) solvent oil is input in the reactor, still stirs into limpid transparent liquid, (4) are input to aniline in the reactor, and it is limpid transparent to stir after five minutes solution, for subsequent use without emitting after the precipitated impurities.The whole process reaction of present embodiment is solubilizing reaction, safety, without the three wastes.
Embodiment four: the production that is used for the compression ignition engine liquid methanol fuel after modification and enhancing, and to produce 1000 kilograms of fuel finished products as example.
At first for subsequent use according to above-described embodiment one preparation and the alcohol-based fuel modifier that obtains, according to above-described embodiment two preparations and to obtain the alcohol-group fuel toughener for subsequent use,
(1) 620 kilograms of methyl alcohol (purity 〉=95%) are input in the large reactor,
(2) will prepare 50 kilograms of alcohol-based fuel modifiers for subsequent use and be input in the reactor and stir,
(3) 40 kilograms of Viscotrol C are input in the reactor, this moment, fluid was clear,
(4) 50 kilograms of ammoniacal liquor are input to emulsifying soln in the reactor,
(5) it is clear 60 kilograms of octanols to be input in the reactor solution,
(6) 50 kilograms of oleic acid are input in the reactor, become for the first time oil, fluid is bright clearly, and the pH value is 8.0-9.0;
(7) 30 kilograms of alcohol-group fuel tougheners are input in the reactor, emulsifying soln becomes sticky;
(8) 50 kilograms of octanols are input in the reactor, solution is saturating clearly,
(9) 30 kilograms of oleic acid are input in the reactor, solution is bright clearly,
(10) 20 kilograms of Viscotrol C are input in the reactor, solution is more clear bright, and the pH value is 7.0-7.5, becomes oil to finish for the second time.
By test and test, obtain the liquid methanol fuel oil that compression ignition engine is used by above-mentioned " substep becomes oil process " production, can become high cold-resistant oil plant, its pour point can arrive-30 ℃, providing " the each department relative risk is 10% lowest temperature table " to produce with using this oil fuel temperature fraction of coverage by standard GB/T 252-2000 appendix B can reach 86%, only have Inner Mongolia Autonomous Region, Xinjiang Uygur Autonomous Regions, Heilongjiang Province that the use of-No. 50 oil fuel of three to five months is arranged throughout the year; In the constant situation of production prices, alternative different trade mark solar oil rates 86%.
Embodiment five: the production that is used for the ignition internal combustion engine liquid methanol fuel after modification and enhancing, and to produce 1000 kilograms of fuel finished products as example.
At first for subsequent use according to above-described embodiment one preparation and the alcohol-based fuel modifier that obtains, according to above-described embodiment three preparations and to obtain the alcohol-group fuel toughener for subsequent use.
(1) 654 kilograms of methyl alcohol are input in the reactor,
(2) 50 kilograms of alcohol-based fuel modifiers are input in the reactor, start agitator,
(3) 80 kilograms of sherwood oils are input in the reactor, solution is clear,
(4) 16 kilograms of ammoniacal liquor are input in the reactor, emulsifying soln,
(5) 60 kilograms of octanols are input in the reactor, solution becomes is clear,
(6) 50 kilograms of oleic acid are input in the reactor, solution is saturating clearly, and the pH value is 7.5-8.5, becomes for the first time oil;
(7) 40 kilograms of alcohol-group fuel tougheners are input in the reactor, emulsifying soln,
(8) with in 40 kilograms of input reactors of octanol, solution is clear,
(9) 10 kilograms of oleic acid are input in the reactor, solution is bright clearly, and the pH value is 7-7.5, becomes for the second time oil.
The ignition internal combustion engine of acquisition that present embodiment is produced is equivalent to unleaded clean fuel oil No. 93 with combustionproperty, fuel consumption, the carbonization index of liquid methanol fuel oil.
Claims (9)
1. alcohol-based fuel modifier is characterized in that:
This alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor,
Each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1.
2. alcohol-based fuel modifier is characterized in that:
Described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat,
Each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1.
3. the production technique of an alcohol-based fuel modifier is characterized in that:
The preparation of this properties-correcting agent is carried out in independent reactor, each composition weight proportioning of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, each composition weight proportioning of this alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight, because this moment, reaction was thermopositive reaction, for the control response intensity, will start agitator, dispel the heat, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) behind drop in temperature, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste again;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5~2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
The alcohol-based fuel modifier of this production technique manufacture both had been applicable to the modification of compression ignition engine alcohol radical liquid fuel, also was applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel.
4. alcohol radical liquid fuel through modification and enhancing, it is characterized in that: the component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, and this alcohol radical liquid fuel is applicable to compression ignition engine;
Described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, and each composition weight proportioning of this alcohol-based fuel modifier is: organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1; Perhaps, described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat, each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1;
Described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10; Perhaps, described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, vegetables oil or solvent oil, aniline, each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1.
5. alcohol radical liquid fuel through modification and enhancing, it is characterized in that: the component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, each component concentration sum is 100%, and this alcohol radical liquid fuel is applicable to ignition internal combustion engine;
Described alcohol-based fuel modifier component is that organo-peroxide, thanomin, ammoniacal liquor, this alcohol-based fuel modifier are respectively organized weight distribution ratio and is organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1; Perhaps, described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat, this alcohol-based fuel modifier is respectively organized weight distribution ratio, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1;
Described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10; Perhaps, described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, vegetables oil or solvent oil, aniline, each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1.
6. alcohol radical liquid fuel production technique through modification and enhancing is characterized in that:
The component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare for subsequent use in advance;
Described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, and each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1; Perhaps, described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat, each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1;
Described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10; Perhaps, described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, vegetables oil or solvent oil, aniline, each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1;
What this alcohol radical liquid fuel adopted is " substep becomes oil " production technique, and idiographic flow, condition are as follows:
(1) the 33.5-70% low-carbon alcohol is input in the large reactor,
(2) be input to the 2-7.5% alcohol-based fuel modifier in the reactor and stir, solution is turbid molten, and microdeposit is arranged,
(3) 3-6% hydroxyl fat is input in the reactor and stirring, solution is mixed clear, the precipitation nothing,
(4) 3-7% ammoniacal liquor is input in the reactor and stirring, emulsifying soln,
(5) the 5-8% high fatty alcohol is input in the reactor and stirring, this moment, solution was clear, saturating,
(6) the 4-6% carboxylic fatty acids is input in the reactor and stirring, it is bright clearly to form solution, and the pH value is 8.0-9.0, becomes oil to finish for the first time,
(7) 1-10% alcohol-group fuel toughener is input in the reactor, the solution becomes breast, viscosity increases,
(8) again the 5-12% high fatty alcohol is input in the reactor, solution becomes is saturating clearly,
(9) again the 5-8% carboxylic fatty acids is input in the reactor and stirring, this moment, solution was clearly thoroughly shinny, and the pH value becomes oil for the second time for 7.0-7.5,
(10) again 1-2% hydroxyl fat is input in the reactor, fluid is brighter, becomes oil to finish for the second time,
The fluid that (11) will become oil to finish is for the second time put into product tank one-tenthization, and the one-tenthization time is no less than 30 minutes, makes fluid more stable, and this alcohol radical liquid fuel is applicable to compression ignition engine.
7. a kind of alcohol radical liquid fuel production technique through modification and enhancing according to claim 6 is characterized in that:
The preparation of described alcohol-based fuel modifier is carried out in independent reactor, each composition weight proportioning of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, each composition weight proportioning of this alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight, because this moment, reaction was thermopositive reaction, for the control response intensity, will start agitator, dispel the heat, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) behind drop in temperature, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste again;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5~2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
The alcohol-based fuel modifier of this production technique manufacture both had been applicable to the modification of compression ignition engine alcohol radical liquid fuel, also was applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel;
The preparation of described alcohol-group fuel toughener is carried out in independent reactor, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1,
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, this each composition weight proportioning of alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) with in the aromatic hydrocarbon of 6~10 parts of weight input reactor, start agitator and stir, until dicyclopentadienyl iron complete molten till, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps,
(3) with the vegetables oil of 6~20 parts of weight or solvent oil input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4) with the aniline of 1 part of weight input reactor, be stirred to complete molten till,
In its step (3), be applicable to the compression ignition engine alcohol radical liquid fuel if add the prepared toughener of finishing of vegetables oil; Be applicable to the ignition internal combustion engine alcohol radical liquid fuel if add the prepared toughener of finishing of solvent oil.
8. alcohol radical liquid fuel production technique through modification and enhancing is characterized in that:
The component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, each component concentration sum is 100%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare for subsequent use in advance;
Described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat, each composition weight proportioning of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1;
Described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10; Perhaps, described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, vegetables oil or solvent oil, aniline, each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1;
The employing of this fuel be " substep become oil " production technique, idiographic flow, condition are as follows:
(1) the 43.3-80% low-carbon alcohol is input in the reactor,
(2) the 2-7.2% alcohol-based fuel modifier is input in the reactor, starts agitator and stir,
(3) the 6-8% sherwood oil is input in the reactor, solution is clear,
(4) 3-4.5% ammoniacal liquor is input in the reactor, emulsifying soln,
(5) the 2-6% high fatty alcohol is input in the reactor, solution becomes is clear,
(6) the 4-12% carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7.5-8.5, becomes for the first time oil,
(7) 1-10% alcohol-group fuel toughener is input in the reactor, the solution micro emulsion,
(8) again with in the 4-6% high fatty alcohol input reactor, solution is bright clearly,
(9) again the 2-3% carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7-7.5, becomes oil to finish for the second time, and this alcohol radical liquid fuel is applicable to ignition internal combustion engine.
9. a kind of alcohol radical liquid fuel production technique through modification and enhancing according to claim 8 is characterized in that:
The preparation of described alcohol-based fuel modifier is carried out in independent reactor, each composition weight proportioning of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5~2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, each composition weight proportioning of this alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight, because this moment, reaction was thermopositive reaction, for the control response intensity, will start agitator, dispel the heat, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) behind drop in temperature, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste again;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5~2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
The alcohol-based fuel modifier of this production technique manufacture both had been applicable to the modification of compression ignition engine alcohol radical liquid fuel, also was applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel;
The preparation of described alcohol-group fuel toughener is carried out in independent reactor, and each composition weight proportioning of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6~10: 6~20: 1,
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, this each composition weight proportioning of alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6~10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) with in the aromatic hydrocarbon of 6~10 parts of weight input reactor, start agitator and stir, until dicyclopentadienyl iron complete molten till, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps,
(3) with the vegetables oil of 6~20 parts of weight or solvent oil input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4) with the aniline of 1 part of weight input reactor, be stirred to complete molten till,
In its step (3), be applicable to the compression ignition engine alcohol radical liquid fuel if add the prepared toughener of finishing of vegetables oil; Be applicable to the ignition internal combustion engine alcohol radical liquid fuel if add the prepared toughener of finishing of solvent oil.
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CN104726143B (en) * | 2013-12-21 | 2016-09-07 | 田伟 | A kind of methanol gasoline |
CN106520230B (en) * | 2016-12-07 | 2018-06-12 | 黑龙江省能源环境研究院 | A kind of methanol fuel compound additive for contributing to compressing ignition engine cold start-up |
CN108659894A (en) * | 2017-04-01 | 2018-10-16 | 深圳华联世纪生物工程股份有限公司 | A kind of biological alcohol-based fuel formulations cleaning diesel fuel formulation and technique |
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US5696060A (en) * | 1996-04-15 | 1997-12-09 | The Lubrizol Corporation | Acylated nitrogen compounds useful as additives for lubricating oil and fuel compositions |
CN1394941A (en) * | 2002-08-16 | 2003-02-05 | 薛峰 | Microemulsified compound diesel additive |
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