CN101619249A - Alcohol-based fuel modifier, enhancer, alcohol-based liquid fuel after modification and enhancement and production process thereof - Google Patents

Alcohol-based fuel modifier, enhancer, alcohol-based liquid fuel after modification and enhancement and production process thereof Download PDF

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CN101619249A
CN101619249A CN200910033141A CN200910033141A CN101619249A CN 101619249 A CN101619249 A CN 101619249A CN 200910033141 A CN200910033141 A CN 200910033141A CN 200910033141 A CN200910033141 A CN 200910033141A CN 101619249 A CN101619249 A CN 101619249A
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alcohol
fuel
reactor
input
toughener
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CN101619249B (en
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孙广玉
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/1811—Organic compounds containing oxygen peroxides; ozonides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention relates to an alcohol-based fuel modifier, an enhancer, an alcohol-based liquid fuel after modification and enhancement and a production process thereof, the proportioning of components of the modifier is that organic peroxide: ethanolamine: ammonia is equal to 1:0.5:1.1, and the proportioning of the components of the enhancer is that biscyclopentadienyl iron: aromatic hydrocarbon is equal to 1:6-10. The alcohol-based liquid fuel for a compression ignition engine comprises the following components by weight percent: 33.5-70% of low carbon alcohol, 2-7.5% of alcohol-based fuel modifier, 3-6% of hydroxy ester, 3-7% of ammonia, 5-8% of higher aliphatic alcohol, 4-6% of carboxylic fatty acid, 1-10% of alcohol-based fuel enhancer, 5-12% of higher aliphatic alcohol, 5-8% of carboxylic fatty acid and 1-2% of hydroxy ester. The fuel for an ignition internal combustion engine comprises the following components by weight percent: 43.3-80% of low carbon alcohol, 2-7.2% of alcohol-based fuel modifier, 6-8% of petroleum ether, 3-4.5% of ammonia, 2-6% of higher aliphatic alcohol, 4-12% of carboxylic fatty acid, 1-10% of alcohol-based fuel enhancer, 4-6% of higher aliphatic alcohol and 2-3% of carboxylic fatty acid. The invention adopts a new process of step-by-step oil formation, which is operated at normal temperature and normal pressure and has simple operation, no emissions of three wastes and safe use and transportation.

Description

Alcohol-based fuel modifier, toughener, through modification and enhanced alcohol radical liquid fuel and production technique thereof
Technical field
The invention belongs to the fuel chemical field, relate in particular to compression-ignited and the ignition internal combustion engine alcohol radical liquid fuel.
Background technology
Along with progress of science and technology; the fast development of process of industrialization; caused global scarcity of resources and people to rely the progressively deterioration of the ecotope of complying with existence; just become the primary goal that all work are carried out for the reasonable development of earth resources and application and ecological environmental protection problem; under the guidance of this thought; luminous energy, heat energy, gravitational energy, wind energy, tidal energy, nuclear energy, biological chemistry energy or the like new forms of energy occur in succession, and tentatively demonstrate powerful vitality and the trend of Future New Energy Source development.
Methyl alcohol in the low-carbon alcohol is present in occurring in nature widely, be thing U.S., inexpensive, aboundresources, clean fuel that the conversion cost is low, it can be from extractions such as coal, Sweet natural gas, oil field gas, plant, combustiblerefuses, it is again the byproduct of grain distillery, sugar refinery and other chemical industry of chemical fertilizer factory, the burning back generates carbonic acid gas and water, do not have other any objectionable impurities and flue dust, its Main physical and chemical property are as follows:
1, have higher energy loss-rate (under theoretical air-fuel ratio state) and be 3.07Kj/Kg, and diesel oil is 2.93Kj/Kg that the calorific value of methyl alcohol is 6.45Kj/Kg when using on apparatus of the internal-combustion engine, and diesel oil is 13.3～14.6Kj/Kg;
2, have the ignition range of broad, be calculated as 6～36.5%, and diesel oil is 1.59～8.2% by volumetric ratio;
3, relative density 0.792 gram/cubic centimetre, fusing point-97.8 ℃, 64.5 ℃ of boiling points, 12.22 ℃ of flash-points, 463.89 ℃ of spontaneous ignition temperatures, vapour pressure 13.33KPa (100mmHg);
4, latent heat of vaporization 1109Kj/Kg, diesel oil 270Kj/Kg;
5, the about 0.7mm of viscosity 2About/s, diesel oil viscosity 2.5～8.5mm 2/ s;
6, because chemical structure, metal is had potential corrosion, nonmetal have a swelling effect, and the methyl alcohol add-on is big more, and effect is just obvious more.
As can be seen from the above analysis, it is feasible that low-carbon alcohol is used as fuel oil of IC engine, if use as better oil fuel, must solve two crucial common problems, one is not changing under the design variable state of engine, and low-carbon alcohol liquid is implemented modification, increase its combustion heat value, reduce the consumption of oil plant.Its two, change potential corrosion problem under the normal temperature state of low-carbon alcohol and the condition of high temperature, the oil plant that uses as compressing ignition engine also will be considered the viscosity of liquid certainly, increases lubricity.
Summary of the invention
The present invention seeks to, at above-mentioned two the crucial common problems of low-carbon alcohol fuel as the existence of dynamic property fuel, provide alcohol-based fuel modifier and toughener, and low-carbon alcohol fuel is carried out modification processing and enhancement process with this alcohol-based fuel modifier and toughener, obtain meeting the employed novel alcohol radical liquid fuel of compression ignition engine and ignition internal combustion engine, the present invention simultaneously provides alcohol-based fuel modifier, toughener and the low-carbon alcohol production technique of liquid fuel after modification and enhancing.
For achieving the above object, the present invention has provided alcohol-based fuel modifier component and mix proportion scheme.
The present invention provides alcohol-based fuel modifier, and this alcohol-based fuel modifier component is organo-peroxide, thanomin, ammoniacal liquor.Proportioning is organo-peroxide between each component of this alcohol-based fuel modifier: thanomin: ammoniacal liquor=1: 0.5: 1.1, these three kinds of component materials generation addition reactions form alcohol-based fuel modifier stoste.For further improving the physicals of this properties-correcting agent stoste, in this properties-correcting agent stoste, add vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat again, generation is applied to the properties-correcting agent of alcohol radical liquid fuel, each component of the alcohol-based fuel modifier of this practical application and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1.In the technical program, organo-peroxide in the component adopts chemical analysis pure, can be following a kind of in all kinds of: tert-butyl peroxide, sec.-propyl superoxide, Peracetic Acid fourth fat, dibenzoyl peroxide; Vegetables oil in the component can be a kind of in the following all kinds of oil: peanut oil, rapeseed oil, Viscotrol C, soya-bean oil; High fatty alcohol in the component is to contain four carbon to monobasic that contains 12 carbon or multi-alcohol; Carboxylic fatty acids in the component can be following a kind of in all kinds of: oleic acid, naphthenic acid; Phthalic acid two fat in the component can be following a kind of in all kinds of: industrial o-phthalic acid dibutyl ester, industrial dibutyl phthalate (DBP).The main component of this alcohol-based fuel modifier is NH 3C 14H 10O 4With RNH 22C 14H 10C 4, through test and research, find that the mutual solubility of the product of this alcohol-based fuel modifier addition reaction and low-carbon alcohol liquid is good, especially under alkaline state, secondary ionization constant K2 value about 10 -25Power has solved the potential corrosion problem of methanol solution under the normal temperature effectively, and under the condition of high temperature, above-mentioned adduction product shows stronger reductive agent effect, has promoted the calorific value of fluid significantly, has reduced the consumption of fluid and to the corrosive nature of parts; This properties-correcting agent has tangible alcoholization reaction to vegetables oil in addition, from other angle, has also impelled the alcoholization reaction of vegetables oil, increases calorific value, the cetane value of oil plant, has improved the viscosity and the surface tension of oil plant, and the oilness that improves oil plant is with compatible.The alcohol-based fuel modifier that the technical program generates can be applicable to the alcohol radical liquid fuel modification of compression ignition engine and ignition internal combustion engine.
For achieving the above object, the present invention has provided alcohol-group fuel enhancer component and mix proportion scheme.
The alcohol-group fuel toughener that the present invention provides, this alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, each set of dispense ratio of this alcohol-group fuel toughener is, dicyclopentadienyl iron: aromatic hydrocarbon=1: 6～10, dicyclopentadienyl iron is dissolved in the aromatic hydrocarbon material, generate alcohol-group fuel toughener stoste, for further improving the physicals of this toughener stoste, in this alcohol-group fuel toughener stoste, add vegetables oil or solvent oil again, aniline, generation is applied to the toughener of alcohol radical liquid fuel, this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6～10: 6～20: 1.In the technical program, the dicyclopentadienyl iron in the component is that CR is pure, and aromatic hydrocarbon is industrial one-level, and vegetables oil is a food grade, and aniline is analytical pure AR level.Aromatic hydrocarbon in the component can be following a kind of in all kinds of: benzene,toluene,xylene; Vegetables oil in the component can be following a kind of in all kinds of: peanut oil, rapeseed oil, Viscotrol C, soya-bean oil; Solvent oil in the component can be a kind of in NY-120 number, NY-200 number.The alcohol-group fuel toughener has played the effect of further enhancing alcohol-based fuel modifier, to reach the purpose that realizes the high quality oil plant.The toughener that adds vegetables oil and aniline generation in alcohol-group fuel toughener stoste is applicable to the compression ignition engine alcohol radical liquid fuel, and the toughener that adds solvent oil and aniline generation in alcohol-group fuel toughener stoste then is applicable to the ignition internal combustion engine alcohol radical liquid fuel.
For achieving the above object, the present invention gives component and the mix proportion scheme through modification and enhanced alcohol radical liquid fuel.
What the present invention was given has two kinds through modification and enhanced alcohol radical liquid fuel, and one is the alcohol radical liquid fuel that compression ignition engine uses, its two alcohol radical liquid fuel for the ignition internal combustion engine use.
The component and the weight percent that are used for the alcohol radical liquid fuel of compression ignition engine are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%.Use in the alcohol radical liquid fuel at this compression ignition engine, a kind of during described low-carbon alcohol is can be following all kinds of, methyl alcohol, ethanol, a kind of in the propyl alcohol or the first and second pure alcohol mixtures, its purity requirement 〉=95% industrial goods, described hydroxyl fat can be Viscotrol C, a kind of in the turkey red oil, its purity is industrial goods, described alcohol-based fuel modifier be prepare in advance standby, each component of this alcohol-based fuel modifier and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1.With in alcohol radical liquid fuel, described alcohol-group fuel toughener also is to prepare standbyly in advance at this compression ignition engine, and this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil: aniline=1: 6～10: 6～20: 1.
The alcohol radical liquid fuel component and the weight percent that are used for ignition internal combustion engine are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%.Use in the alcohol radical liquid fuel at this ignition internal combustion engine, described sherwood oil boiling point is a kind of in 60-90 ℃, 90-120 ℃, described alcohol-based fuel modifier be prepare in advance standby, each component of this alcohol-based fuel modifier and proportioning are organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1.With in alcohol radical liquid fuel, described alcohol-group fuel toughener also is to prepare standbyly in advance at this ignition internal combustion engine, and this each component of alcohol-group fuel toughener and proportioning are dicyclopentadienyl iron: aromatic hydrocarbon: solvent oil: aniline=1: 6～10: 6～20: 1.
For achieving the above object, the present invention gives the production technique of alcohol-based fuel modifier,
The preparation of this properties-correcting agent is carried out in independent reactor, each set of dispense ratio of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, each set of dispense ratio of this alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight,,, will start agitator, dispel the heat for the control response intensity because this moment, reaction was thermopositive reaction, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) after temperature descends, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste, i.e. RNH again 22C 14H 10C 4With NH 3C 14H 10O 4Adduct;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5～2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
This production technique is produced the modification that the alcohol-based fuel modifier for preparing both had been applicable to the compression ignition engine alcohol radical liquid fuel, also is applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel.
For achieving the above object, the present invention has provided the production technique that compression ignition engine is used the alcohol radical liquid fuel toughener with the production technique and the ignition internal combustion engine of alcohol-group fuel toughener.
The compression ignition engine production technique of alcohol-group fuel toughener,
Compression ignition engine with each component of alcohol-group fuel toughener and proportioning is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil: aniline=1: 6～10: 6～20: 1.
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, each set of dispense ratio of this alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6～10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) in the aromatic hydrocarbon input reactor with 6～10 parts of weight, start agitator and stir, till dicyclopentadienyl iron is molten entirely, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps, promptly in alcohol-group fuel toughener stoste, adds the vegetables oil of 6～20 parts of weight and the aniline of 1 part of weight, generate the toughener of practical application,
(3) with the vegetables oil of 6～20 parts of weight input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4), be stirred to and promptly be prepared into the toughener that is applicable to the compression ignition engine alcohol radical liquid fuel till molten entirely with the aniline of 1 part of weight input reactor.
The ignition internal combustion engine production technique of alcohol radical liquid fuel toughener,
Ignition internal combustion engine with each component of alcohol-group fuel toughener and proportioning is dicyclopentadienyl iron: aromatic hydrocarbon: solvent oil: aniline=1: 6～10: 6～20: 1.
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, each set of dispense ratio of this alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6～10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) in the aromatic hydrocarbon input reactor with 6～10 parts of weight, start agitator and stir, till dicyclopentadienyl iron is molten entirely, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps, promptly in alcohol-group fuel toughener stoste, adds the solvent oil of 6～20 parts of weight and the aniline of 1 part of weight, generate the toughener of practical application,
(3) with the solvent oil of 6～20 parts of weight input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4), be stirred to and promptly be prepared into the toughener that is applicable to the ignition internal combustion engine alcohol radical liquid fuel till molten entirely with the aniline of 1 part of weight input reactor.
For achieving the above object, the present invention has provided the production technique of compression ignition engine with alcohol radical liquid fuel: the component of this fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare standby in advance;
What this fuel adopted is " substep becomes oil " production technique, and idiographic flow, condition are as follows:
(1) low-carbon alcohol is input in the big reactor,
(2) be input to alcohol-based fuel modifier in the reactor and stir, solution is turbid molten, and microdeposit is arranged,
(3) hydroxyl fat is input in the reactor and stirring, solution mixes clear, and precipitation does not have,
(4) ammoniacal liquor is input in the reactor and stirring, emulsifying soln,
(5) high fatty alcohol is input in the reactor and stirring, this moment, solution was clear, saturating,
(6) carboxylic fatty acids is input in the reactor and stirring, it is bright clearly to form solution, and the pH value is 8.0-9.0, becomes oil to finish for the first time,
(7) the alcohol radical toughener is input in the reactor, the solution becomes breast, viscosity increases,
(8) once more high fatty alcohol is input in the reactor, solution becomes is saturating clearly,
(9) once more carboxylic fatty acids is input in the reactor and stirring, this moment, solution was shinny clearly thoroughly, and the pH value becomes oil for the second time for 7.0-7.5,
(10) once more hydroxyl fat is input in the reactor, fluid is brighter, becomes oil to finish for the second time,
(11) fluid that becomes oil to finish secondary is put into product tank one-tenthization, and the one-tenthization time is no less than 30 minutes, makes fluid more stable, and this alcohol radical liquid fuel is applicable to compression ignition engine.
For achieving the above object, the present invention has provided the production technique of ignition internal combustion engine with alcohol radical liquid fuel.The component of this fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare standby in advance;
The employing of this fuel be " substep become oil " production technique, idiographic flow, condition are as follows:
(1) low-carbon alcohol is input in the reactor,
(2) alcohol-based fuel modifier is input in the reactor, starts agitator and stir,
(3) sherwood oil is input in the reactor, solution is clear,
(4) ammoniacal liquor is input in the reactor, emulsifying soln,
(5) high fatty alcohol is input in the reactor, solution becomes is clear,
(6) carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7.5-8.5, becomes oil for the first time,
(7) the alcohol-group fuel toughener is input in the reactor, the solution micro emulsion,
(8) once more high fatty alcohol is imported in the reactor, solution is bright clearly,
(9) once more carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7-7.5, becomes oil to finish for the second time, and this alcohol radical liquid fuel is applicable to ignition internal combustion engine.
In above-mentioned two kinds of alcohol radical liquid fuel production processes, be main ingredient with the low-carbon alcohol, divide two steps to add alcohol-based fuel modifier and alcohol-group fuel toughener respectively, formed unique " substep becomes oil process ".Substep adds alcohol-based fuel modifier and alcohol-group fuel toughener sequentially in alcohol-group fuel, make and form the higher fatty acid formicester after the alcohol radical esterification and through changing the biofuel oil of chemical and physical properties, its every combustionproperty and physical and chemical index satisfy compression ignite, igniting internal combustion engine uses, we are different from blended fuel, petroleum fuel oils by the alcohol radical liquid fuel that this " substep becomes oil process " produces, and also are different from biofuel oil truly.
Advantage of the present invention is that by formed compressing ignition engine alcohol radical liquid fuel behind interpolation alcohol-based fuel modifier, the alcohol-group fuel toughener, its combustionproperty, important physical and chemical index are all than commercially available diesel oil height, non-secondary pollution.By formed ignition internal combustion engine alcohol radical liquid fuel behind interpolation alcohol-based fuel modifier, the alcohol-group fuel toughener, has high-octane rating (90～No. 98), not leaded, high clean.The production of two kinds of alcohol-group fuels of the present invention need not special professional equipment, under normal temperature, normal pressure, ordering parameter is few, and is simple.Three-waste free pollution in the production process, operation, transportation safety.Alcohol radical liquid fuel of the present invention is used in various vehicles, can reduce the pollution of Vehicular exhaust to environment significantly, has also broken away from the dependency to petroleum resources, is a kind of novel liquid fuel that helps scale operation, popularization, application.
Specific embodiment
Embodiment one: the production of alcohol-based fuel modifier
The production of present embodiment alcohol-based fuel modifier is carried out in independent reactor, to produce 100 kilograms properties-correcting agent is example, the weight of each component of properties-correcting agent is: 12.3 kilograms of dibenzoyl peroxide, 6.2 kilograms of thanomins, 13.6 kilograms of ammoniacal liquor, 12.3 kilograms of soybean oil, 24.7 kilograms of octanols, 18.6 kilograms of oleic acid, 12.3 kilograms of dibutylesters, technical process is: (1) is poured dibenzoyl peroxide in the reactor into, (2) pour into thanomin in the reactor again, start agitator this moment, control reaction temperature, make them in 90 ℃ of-100 ℃ of scopes, can not allow reaction too strong, this moment, solid-state dibenzoyl peroxide generated RNH 22C 14H 10C 4(3) ammoniacal liquor is poured in the reactor, formed transparent inclusion-free liquid NH 3C 14H 10O 4(4) soybean oil being poured in the reactor into solution becomes mixes sticking again; (5) octanol is poured into thinningly in the reactor released transparent liquid, (6) are poured oleic acid into and are adjusted the pH value in the reactor between 7-7.5, and (7) are poured dibutylester in the reactor at last, the clear printing opacity of solution becomes.
Embodiment two: the compression ignition engine production of alcohol-group fuel toughener
Present embodiment is an example to produce 100 kilograms compression ignition engine alcohol-group fuel toughener, each composition of toughener and weight are: 5 kilograms of dicyclopentadienyl iron, 50 kilograms of dimethylbenzene, 40 kilograms in soya-bean oil, 5 kilograms of aniline, the preparation of this toughener is carried out in independent reactor, concrete steps: (1) is poured dicyclopentadienyl iron in the reactor into, and (2) are poured dimethylbenzene into and stirred the inclusion-free that mixes in the reactor; (3) soya-bean oil is poured into mix in the reactor transparent, (4) with aniline pour in the reactor become clear emit after bright standby.The whole process reaction of present embodiment is a solubilizing reaction, safety, the no three wastes.
Embodiment three: the ignition internal combustion engine production of alcohol-group fuel toughener
Present embodiment is an example to produce 100 kilograms of ignition internal combustion engine alcohol-group fuel tougheners, and each composition of toughener and weight are: 3.2 kilograms of Dicyclopentadiene (DCPD) benzene iron, 32.6 kilograms of dimethylbenzene, 61 kilograms of solvent oils (No. 200), 3.2 kilograms of aniline.The preparation of this toughener is carried out in independent reactor, concrete steps: (1) is passed to Dicyclopentadiene (DCPD) benzene iron in the reactor, and (2) are input to dimethylbenzene in the reactor, and agitator begins to stir; (3) solvent oil is input in the reactor, still stirs into limpid transparent liquid, (4) are input to aniline in the reactor, and it is limpid transparent to stir after five minutes solution, emits standby after the no precipitated impurities.The whole process reaction of present embodiment is a solubilizing reaction, safety, the no three wastes.
Embodiment four: the production that is used for the compression ignition engine liquid methanol fuel after modification and enhancing is example to produce 1000 kilograms of fuel finished products.
At first standby according to the foregoing description one preparation and the alcohol-based fuel modifier that obtains, according to the foregoing description two preparations and to obtain the alcohol-group fuel toughener standby,
(1) methyl alcohol (purity 〉=95%) is input in the big reactor for 620 kilograms,
(2) will prepare standby alcohol-based fuel modifier and be input in the reactor for 50 kilograms and stir,
(3) Viscotrol C is input in the reactor for 40 kilograms, this moment, fluid was clear,
(4) ammoniacal liquor is input to emulsifying soln in the reactor for 50 kilograms,
(5) it is clear 60 kilograms of octanols to be input in the reactor solution,
(6) oleic acid is input in the reactor for 50 kilograms, becomes oil for the first time, fluid is bright clearly, and the pH value is 8.0-9.0;
(7) the alcohol-group fuel toughener is input in the reactor for 30 kilograms, emulsifying soln becomes sticky;
(8) octanol is input in the reactor for 50 kilograms, solution is saturating clearly,
(9) oleic acid is input in the reactor for 30 kilograms, solution is bright clearly,
(10) Viscotrol C is input in the reactor for 20 kilograms, solution is more clear bright, and the pH value is 7.0-7.5, becomes oil to finish for the second time.
By test and test, obtain the liquid methanol fuel oil that compression ignition engine is used by above-mentioned " substep becomes oil process " production, can become high cold-resistant oil plant, its pour point can arrive-30 ℃, providing " the each department relative risk is 10% lowest temperature table " to produce with using this oil fuel temperature fraction of coverage by standard GB 252-2000 appendix B can reach 86%, only have Inner Mongolia Autonomous Region, Xinjiang Uygur Autonomous Regions, Heilongjiang Province that the use of-No. 50 oil fuel of three to five months is arranged throughout the year; Under the constant situation of production prices, alternative different trade mark solar oil rates 86%.
Embodiment five: the production that is used for the ignition internal combustion engine liquid methanol fuel after modification and enhancing is example to produce 1000 kilograms of fuel finished products.
At first standby according to the foregoing description one preparation and the alcohol-based fuel modifier that obtains, according to the foregoing description three preparations and to obtain the alcohol-group fuel toughener standby.
(1) methyl alcohol is input in the reactor for 654 kilograms,
(2) alcohol-based fuel modifier is input in the reactor for 50 kilograms, starts agitator,
(3) sherwood oil is input in the reactor for 80 kilograms, solution is clear,
(4) ammoniacal liquor is input in the reactor for 16 kilograms, emulsifying soln,
(5) octanol is input in the reactor for 60 kilograms, solution becomes is clear,
(6) oleic acid is input in the reactor for 50 kilograms, solution is saturating clearly, and the pH value is 7.5-8.5, becomes oil for the first time;
(7) the alcohol-group fuel toughener is input in the reactor for 40 kilograms, emulsifying soln,
(8) with in 40 kilograms of input reactors of octanol, solution is clear,
(9) oleic acid is input in the reactor for 10 kilograms, solution is bright clearly, and the pH value is 7-7.5, becomes oil for the second time.
The ignition internal combustion engine of acquisition that present embodiment is produced is equivalent to unleaded clean fuel oil No. 93 with combustionproperty, fuel consumption, the carbonization index of liquid methanol fuel oil.

Claims (10)

1, a kind of alcohol-based fuel modifier is characterized in that:
This alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor,
Each set of dispense ratio of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1.1.
2, according to the described alcohol-based fuel modifier of claim, it is characterized in that:
Described alcohol-based fuel modifier component is, organo-peroxide, thanomin, ammoniacal liquor, vegetables oil, high fatty alcohol, carboxylic fatty acids, phthalic acid two fat,
Each set of dispense ratio of this alcohol-based fuel modifier is organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1.
3, a kind of alcohol-group fuel toughener is characterized in that:
This alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon,
Each set of dispense ratio of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6～10.
4, alcohol-group fuel toughener according to claim 3 is characterized in that:
Described alcohol-group fuel enhancer component is, dicyclopentadienyl iron, aromatic hydrocarbon, vegetables oil or solvent oil, aniline,
Each set of dispense ratio of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6～10: 6～20: 1.
5, a kind of through modification and enhanced alcohol radical liquid fuel, it is characterized in that: the component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-1 2%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, this alcohol radical liquid fuel is applicable to compression ignition engine.
6, a kind of through modification and enhanced alcohol radical liquid fuel, it is characterized in that: the component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, this alcohol radical liquid fuel is applicable to ignition internal combustion engine.
7, a kind of production technique of alcohol-based fuel modifier is characterized in that:
The preparation of this properties-correcting agent is carried out in independent reactor, each set of dispense ratio of this alcohol-based fuel modifier is, organo-peroxide: thanomin: ammoniacal liquor: vegetables oil: high fatty alcohol: carboxylic fatty acids: phthalic acid two fat=1: 0.5: 1.1: 1: 2: 1.5～2: 1
At first, preparation alcohol-based fuel modifier stoste, the component of this alcohol-based fuel modifier stoste is, organo-peroxide, thanomin, ammoniacal liquor, each set of dispense ratio of this alcohol-based fuel modifier stoste is, organo-peroxide: thanomin: ammoniacal liquor=1: 0.5: 1, alcohol-based fuel modifier stoste prepares according to the following steps
(1) in the organo-peroxide input reactor with 1 part of weight,
(2) in the thanomin input reactor with 0.5 part of weight,,, will start agitator, dispel the heat for the control response intensity because this moment, reaction was thermopositive reaction, 90 ℃ of-100 ℃ of scopes of solution temperature control,
(3) after temperature descends, in the ammoniacal liquor input reactor with 1.1 parts of weight, form transparent, pure alcohol-based fuel modifier stoste, i.e. RNH again 22C 14H 10C 4With NH 3C 14H 10O 4Adduct;
Secondly, alcohol-based fuel modifier stoste is carried out its physical properties adjustment according to the following steps,
(4) in the vegetables oil input reactor with 1 part of weight,
(5) in the high fatty alcohol input reactor with 2 parts of weight,
(6) in the carboxylic fatty acids input reactor with 1.5～2 parts of weight, measure the pH value between 7-7.5,
(7) in the phthalic acid two fat input reactor with 1 part of weight, the clear printing opacity of solution becomes,
This production technique is produced the modification that the alcohol-based fuel modifier for preparing both had been applicable to the compression ignition engine alcohol radical liquid fuel, also is applicable to the modification of ignition internal combustion engine alcohol radical liquid fuel.
8, a kind of production technique of alcohol-group fuel toughener is characterized in that:
The preparation of this toughener is carried out in independent reactor, and each set of dispense ratio of this alcohol-group fuel toughener is dicyclopentadienyl iron: aromatic hydrocarbon: vegetables oil or solvent oil: aniline=1: 6～10: 6～20: 1,
At first, preparation alcohol-group fuel toughener stoste, the former fluid component of this alcohol-group fuel toughener is, dicyclopentadienyl iron, aromatic hydrocarbon, each set of dispense ratio of this alcohol-group fuel toughener stoste is dicyclopentadienyl iron: aromatic hydrocarbon=1: 6～10,
(1) in the dicyclopentadienyl iron input reactor with 1 part of weight,
(2) in the aromatic hydrocarbon input reactor with 6～10 parts of weight, start agitator and stir, till dicyclopentadienyl iron is molten entirely, form alcohol-group fuel toughener stoste,
Secondly, alcohol-group fuel toughener stoste is carried out the physical properties adjustment according to the following steps,
(3) with the vegetables oil of 6～20 parts of weight or solvent oil input reactor, stir, form till limpid, transparent, the inclusion-free liquid,
(4) with the aniline of 1 part of weight input reactor, be stirred to complete molten till,
In its step (3), be applicable to the compression ignition engine alcohol radical liquid fuel if add the prepared toughener of finishing of vegetables oil; Be applicable to the ignition internal combustion engine alcohol radical liquid fuel if add the prepared toughener of finishing of solvent oil.
9, a kind of through modification and enhanced alcohol radical liquid fuel production technique, it is characterized in that:
The component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 33.5-70%, alcohol-based fuel modifier 2-7.5%, hydroxyl fat 3-6%, ammoniacal liquor 3-7%, high fatty alcohol 5-8%, carboxylic fatty acids 4-6%, alcohol-group fuel toughener 1-10%, high fatty alcohol 5-12%, carboxylic fatty acids 5-8%, hydroxyl fat 1-2%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare standby in advance;
What this alcohol radical liquid fuel adopted is " substep becomes oil " production technique, and idiographic flow, condition are as follows:
(1) the 33.5-70% low-carbon alcohol is input in the big reactor,
(2) be input to the 2-7.5% alcohol-based fuel modifier in the reactor and stir, solution is turbid molten, and microdeposit is arranged,
(3) 3-6% hydroxyl fat is input in the reactor and stirring, solution mixes clear, and precipitation does not have,
(4) 3-7% ammoniacal liquor is input in the reactor and stirring, emulsifying soln,
(5) the 5-8% high fatty alcohol is input in the reactor and stirring, this moment, solution was clear, saturating,
(6) the 4-6% carboxylic fatty acids is input in the reactor and stirring, it is bright clearly to form solution, and the pH value is 8.0-9.0, becomes oil to finish for the first time,
(7) 1-10% alcohol radical toughener is input in the reactor, the solution becomes breast, viscosity increases,
(8) once more the 5-12% high fatty alcohol is input in the reactor, solution becomes is saturating clearly,
(9) once more the 5-8% carboxylic fatty acids is input in the reactor and stirring, this moment, solution was shinny clearly thoroughly, and the pH value becomes oil for the second time for 7.0-7.5,
(10) once more 1-2% hydroxyl fat is input in the reactor, fluid is brighter, becomes oil to finish for the second time,
(11) fluid that will become oil to finish is for the second time put into product tank one-tenthization, and the one-tenthization time is no less than 30 minutes, makes fluid more stable, and this alcohol radical liquid fuel is applicable to compression ignition engine.
10, a kind of through modification and enhanced alcohol radical liquid fuel production technique, it is characterized in that:
The component of this alcohol radical liquid fuel and weight percent are: low-carbon alcohol 43.3-80%, alcohol-based fuel modifier 2-7.2%, sherwood oil 6-8%, ammoniacal liquor 3-4.5%, high fatty alcohol 2-6%, carboxylic fatty acids 4-12%, alcohol-group fuel toughener 1-10%, high fatty alcohol 4-6%, carboxylic fatty acids 2-3%, and wherein alcohol-based fuel modifier and alcohol-group fuel toughener prepare standby in advance;
The employing of this fuel be " substep become oil " production technique, idiographic flow, condition are as follows:
(1) the 43.3-80% low-carbon alcohol is input in the reactor,
(2) the 2-7.2% alcohol-based fuel modifier is input in the reactor, starts agitator and stir,
(3) the 6-8% sherwood oil is input in the reactor, solution is clear,
(4) 3-4.5% ammoniacal liquor is input in the reactor, emulsifying soln,
(5) the 2-6% high fatty alcohol is input in the reactor, solution becomes is clear,
(6) the 4-12% carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7.5-8.5, becomes oil for the first time,
(7) 1-10% alcohol-group fuel toughener is input in the reactor, the solution micro emulsion,
(8) once more with in the 4-6% high fatty alcohol input reactor, solution is bright clearly,
(9) once more the 2-3% carboxylic fatty acids is input in the reactor, solution is bright clearly, and the pH value is 7-7.5, becomes oil to finish for the second time, and this alcohol radical liquid fuel is applicable to ignition internal combustion engine.
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Family Cites Families (9)

* Cited by examiner, † Cited by third party
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CN101402890A (en) * 2008-11-12 2009-04-08 王宇 Methanol gasoline additive and process for producing methanol gasoline
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