CN100587029C - Hydrocarbon oil and preparation method thereof - Google Patents
Hydrocarbon oil and preparation method thereof Download PDFInfo
- Publication number
- CN100587029C CN100587029C CN200610031990A CN200610031990A CN100587029C CN 100587029 C CN100587029 C CN 100587029C CN 200610031990 A CN200610031990 A CN 200610031990A CN 200610031990 A CN200610031990 A CN 200610031990A CN 100587029 C CN100587029 C CN 100587029C
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- CN
- China
- Prior art keywords
- oil
- honey locust
- chinese honey
- hydrocarbon oil
- camphor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 35
- 229930195733 hydrocarbon Natural products 0.000 title claims description 34
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 34
- 238000002360 preparation method Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 241000931143 Gleditsia sinensis Species 0.000 claims abstract description 28
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 26
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 15
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 13
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 13
- 229960000846 camphor Drugs 0.000 claims abstract description 13
- 229930008380 camphor Natural products 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003921 oil Substances 0.000 claims description 80
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 238000005886 esterification reaction Methods 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 230000020477 pH reduction Effects 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 230000032050 esterification Effects 0.000 claims 2
- 239000000654 additive Substances 0.000 abstract description 7
- 230000000996 additive effect Effects 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 6
- 125000003118 aryl group Chemical group 0.000 abstract description 3
- 239000000779 smoke Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000002893 slag Substances 0.000 abstract 1
- COEZWFYORILMOM-UHFFFAOYSA-N sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonic acid Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-N 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 66
- 239000003209 petroleum derivative Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 3
- -1 Oleum Gossypii semen Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000010499 rapseed oil Substances 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Fats And Perfumes (AREA)
Abstract
The invention relates to a kind of carbon-hydrogen oil and the method for preparing the same, belonging to chemical industry field. It takes plant Chinese honey locust oil and methanol as raw material, acetone, ligroine, camphor and saturated sodium chloride as additive. The process comprises acidifying, esterifying, adding additive for adjustment and getting aromatic carbon- hydrogen oil with bright gold yellow color. The invention is characterized by no black smoke and no peculiar smell discharge, no waste material discharge, no pollution to environment, no harm to human being, high caloricvalue, cheap price, coincident factors with state standard. The product can be used as new energy for enterprise to replace diesel, the flash point of oil is high, exploration limit is 1.9%, fire point is high, and utilization is safe. The Chinese honey locust oil is leftover bits and pieces or slag, and the utilization protects ecological resources, and the economic and social benefit is pretty good.
Description
[technical field]
The present invention relates to a kind of hydrocarbon oil and method for making thereof, belong to chemical technology field.
[background technology]
At present, along with the minimizing day by day of petroleum resources, and price is constantly surging, and making some is the enterprise of the energy with the petroleum products, and product cost constantly increases, and has increased the weight of business and consumer's burden; Petroleum products the time will produce a large amount of toxic gases in burning in addition, both contaminate environment, and it is healthy to damage people again.Therefore, a lot of people are seeking the new energy, to substitute the petroleum products that reduces day by day, overcome because of the oil difficulty brought to the business and consumer and inconvenient of raising the price.
[summary of the invention]
For alleviation reduces day by day because of petroleum resources, petroleum product price goes up day by day, the many difficulties and the inconvenience that bring to the business and consumer,---hydrocarbon oil, another object of the present invention provide this novel fuel---production method of hydrocarbon oil that the purpose of this invention is to provide a kind of novel fuel that replaces diesel oil.
For solving its technical problem, the present invention for realizing the used technical scheme of goal of the invention is: (one) hydrocarbon oil: selecting Chinese honey locust oil for use is vegetables oil, the tankage or the dregs of fat as rape oil, soybean oil, peanut oil, Oleum Gossypii semen, tea-seed oil are raw material, after processing treatment, add methyl alcohol and appropriate amount of catalysts and additive, add an amount of emulsifying agent again, mix mix well the hydrocarbon oil finished product.The composition of this hydrocarbon oil and the weight percent of each composition are: methyl alcohol 60～75, Chinese honey locust oil 15～30, acetone 1～2, sherwood oil 1～2, camphor 0.5～1, saturated nacl aqueous solution 5～7.5.Wherein: methyl alcohol (CH
4CH
3OH) be achromaticity and clarification liquid, irritating smell is arranged, stability is preferably arranged, inflammable.
Chinese honey locust oil: be the rejectable waste of vegetables oil, yellow black liquid is golden yellow liquid after the refinement, have aromatic odour, belongs to mixture.
Acetone (CH
3COCH
3): colourless transparent liquid, kerosene oil-gas is arranged, very easily burning belongs to organic mixture, can increase fuel value.
Camphor: white crystal, fragrance can burn, and selecting it is can remove peculiar smell in the hydrocarbon oil because of it as additive, makes its limpid, delicate fragrance.
Saturated nacl aqueous solution: colourless transparent liquid, selecting it is additive, is because of it can increase density, reduces point of ignition, makes hydrocarbon oil safe in utilization.
(2) method of production hydrocarbon oil, it comprises the steps:
1. get the raw materials ready: get all the desired raw material, catalyzer, additive ready by prescription, stand-by;
2. with the processing of Chinese honey locust oleic acid: with joining Chinese honey locust oil put into acidification pool, add 7% the vitriol oil, be heated to 230～250 °, make its abundant acidifying;
3. esterification reaction: the oil of the Chinese honey locust after the acidifying is joined methanol mixed with institute, and adding alkali catalyst again carries out esterification reaction, promptly obtains the thick hydrocarbon oil of neutral;
4. allotment: add in the thick hydrocarbon oil that 3. step is obtained comprise fully and mix the additive of acetone, sherwood oil, camphor and mix well, add saturated nacl aqueous solution and an amount of emulsifying agent then, thoroughly mix, mix well, promptly get hydrocarbon oil of the present invention.
Wherein: the catalyzer in the described esterification reaction is caustic soda or similar alkaline matter, main effect is a neutralizing acid, the emulsifying agent in the described adaptation step, and main effect is: its hydrocarbon oil and saturated nacl aqueous solution are carried out emulsification, thereby reduce its flash-point and point of ignition, also can reduce its cost.
The invention has the beneficial effects as follows: 1. the present invention adopts Chinese honey locust oil to be raw material, and Chinese honey locust oil is the tankage or the dregs of fat of vegetables oil, generally be to abandon in the presence of waste product in the past, after now it being added suitable non-petroleum product, become the fuel oil that a kind of energy substitutes petroleum products, this fuel oil after testing, every index all reaches the standard of fuel of country, its still not a kind of utilization of waste material, turn waste into wealth, the more important thing is the vegetalitas fuel that has found a kind of energy to substitute petroleum products such as diesel oil, help alleviating the tensity of oil supply, important practical sense is arranged.2. because the raw material that the present invention adopts is extensive, low price, production method is easy, and cost is low, at present, 5000 yuan per ton of the diesel-fuel price on the market, and as long as hydrocarbon oil is per ton 3000 yuan, therefore this oil has the good market competitiveness.3. hydrocarbon oil of the present invention, the nonirritant peculiar smell, and have aromatic odour, color and luster is limpid, is golden transparent liquid, no black smoke produces in combustion processes, free from extraneous odour is discharged, and does not also have waste material in the production process and discharges, and environment is not produced any pollution, do not damage HUMAN HEALTH, belong to a kind of Green Product.4. because of being added with saturated nacl aqueous solution and emulsifying agent in the hydrocarbon oil of the present invention, thus its flash-point height, limits of explosion 1.9%, the point of ignition height, the flames of anger can not caught fire, and than diesel oil safety, price is more cheap in the use.
[embodiment]
The method for making 1 of hydrocarbon oil, it comprises the steps:
Embodiment 1:
1. get the raw materials ready: get Chinese honey locust oil 30%, methyl alcohol 60%, acetone 2%, sherwood oil 2%, camphor 1%, saturated nacl aqueous solution 5%, stand-by;
2. acidifying: Chinese honey locust oil is put into acidification pool, add the vitriol oil of Chinese honey locust weight of oil 7%, be heated to 230 ℃～250 ℃ simultaneously, stir;
3. esterification reaction: with Chinese honey locust oil and methanol mixed after the acidifying, add an amount of caustic soda again and carry out esterification reaction, promptly obtain thick hydrocarbon oil;
4. allotment: with mixing behind thick hydrocarbon oil adding acetone, sherwood oil, the camphor, add saturated nacl aqueous solution and emulsifying agent at last, stir, promptly obtain the hydrocarbon oil finished product.
Embodiment 2: the method for making 2 of hydrocarbon oil comprises the steps:
1. get the raw materials ready: get Chinese honey locust oil 15%, methyl alcohol 75%, acetone 1%, sherwood oil 1%, camphor 0.5%, saturated nacl aqueous solution 7.5%, stand-by;
2. acidifying: Chinese honey locust oil is put into acidification pool, add the vitriol oil of Chinese honey locust weight of oil 7%, be heated to 230 ℃～250 ℃ simultaneously, stir;
3. esterification reaction: with Chinese honey locust oil and methanol mixed after the acidifying, add an amount of caustic soda again and carry out esterification reaction, promptly obtain thick hydrocarbon oil;
4. allotment: the thick hydrocarbon oil that will obtain adds and mixes after institute is equipped with acetone, sherwood oil, camphor, then adding be equipped with saturated nacl aqueous solution and emulsifying agent, stir, promptly obtain the hydrocarbon oil finished product.
Embodiment 3: hydrocarbon oil and method for making 3 thereof comprise the steps:
1. get the raw materials ready: get Chinese honey locust oil 20%, methyl alcohol 70%, acetone 2%, sherwood oil 1.5%, camphor 0.5%, saturated nacl aqueous solution 6%, stand-by;
2. acidifying: Chinese honey locust oil is put into acidification pool, add the vitriol oil of Chinese honey locust weight of oil 7%, be heated to 230 ℃～250 ℃ simultaneously, stir;
3. esterification reaction: with Chinese honey locust oil and methanol mixed after the acidifying, add an amount of caustic soda again and carry out esterification reaction, promptly obtain thick hydrocarbon oil;
4. allotment: with mixing behind thick hydrocarbon oil adding acetone, sherwood oil, the camphor, add saturated nacl aqueous solution and emulsifying agent then, stir, promptly obtain the hydrocarbon oil finished product.
Claims (1)
1, a kind of method for making of hydrocarbon oil is characterized in that: the raw material and the proportioning thereof of hydrocarbon oil are as follows: raw material is: Chinese honey locust oil, methyl alcohol, acetone, sherwood oil, camphor and saturated nacl aqueous solution;
Their weight percent is: Chinese honey locust oil 15～30, methyl alcohol 60～75, acetone 1～2, sherwood oil 1～2, camphor 0.5～1, saturated nacl aqueous solution 5～7.5;
Make through following steps:
1. get the raw materials ready: get all the various raw materials ready by said ratio;
2. with the processing of Chinese honey locust oleic acid: institute is equipped with Chinese honey locust oil puts into acidification pool, add the vitriol oil of 7% Chinese honey locust weight of oil, be heated to 230～250 ℃, make its abundant acidifying;
3. esterification: with the oil of the Chinese honey locust after the acidifying be equipped with methanol mixed, add the alkali catalyst caustic soda again and carry out esterification, promptly obtain the thick hydrocarbon oil of neutral;
4. allotment: add institute in the thick hydrocarbon oil that step is obtained in 3. and be equipped with acetone, sherwood oil and camphor and mix and mix thoroughly, then adding be equipped with saturated nacl aqueous solution and an amount of emulsifying agent, thoroughly mix, mix well and promptly get the hydrocarbon oil product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610031990A CN100587029C (en) | 2006-07-16 | 2006-07-16 | Hydrocarbon oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610031990A CN100587029C (en) | 2006-07-16 | 2006-07-16 | Hydrocarbon oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085928A CN101085928A (en) | 2007-12-12 |
| CN100587029C true CN100587029C (en) | 2010-02-03 |
Family
ID=38937089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610031990A Expired - Fee Related CN100587029C (en) | 2006-07-16 | 2006-07-16 | Hydrocarbon oil and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100587029C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102688719A (en) * | 2012-06-14 | 2012-09-26 | 龚坤 | Special equipment for generating hydrocarbon oil |
| CN106336887A (en) * | 2015-07-09 | 2017-01-18 | 岳阳市中发科技有限公司 | Production method for hydrocarbon oil |
| CN107474995B (en) * | 2017-08-29 | 2020-04-17 | 深圳市百顺源节能科技有限公司 | Composition for efficiently cleaning carbon deposit and oil sludge in engine and preparation method thereof |
| CN114032124B (en) * | 2021-07-30 | 2022-08-30 | 三亚星油藤科技服务有限公司 | M100 methanol fuel mother liquor additive for methanol vehicle and preparation method thereof |
-
2006
- 2006-07-16 CN CN200610031990A patent/CN100587029C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN101085928A (en) | 2007-12-12 |
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| C14 | Grant of patent or utility model | ||
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| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20071212 Assignee: Changde Zhongnan Energy Development Co.,Ltd. Assignor: Gong Kun Contract record no.: 2013430000055 Denomination of invention: Hydrocarbon oil and preparation method thereof Granted publication date: 20100203 License type: Exclusive License Record date: 20130509 |
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| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| ASS | Succession or assignment of patent right |
Owner name: CHANGDE ZHONGNAN ENERGY DEVELOPMENT CO., LTD. Free format text: FORMER OWNER: GONG KUN Effective date: 20141203 |
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Effective date of registration: 20141203 Address after: 415000, Hunan province Changde Wuling District three branch offices long mountain community (Hunan University of Arts and Science chemistry and chemical engineering on the third floor of the east side Room 301) Patentee after: Changde Zhongnan Energy Development Co.,Ltd. Address before: The 3 group of 415000 Changde province Hunan city Wuling District Lu Shan Yudai Bridge Village Patentee before: Gong Kun |
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Denomination of invention: Hydrocarbon oil and preparation method thereof Effective date of registration: 20170424 Granted publication date: 20100203 Pledgee: Changde Caixin technology Company limited by guarantee Pledgor: Changde Zhongnan Energy Development Co.,Ltd. Registration number: 2017430000022 |
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