CN102690674A - Production method for hydrocarbon oil for vehicles - Google Patents

Production method for hydrocarbon oil for vehicles Download PDF

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Publication number
CN102690674A
CN102690674A CN2012101882325A CN201210188232A CN102690674A CN 102690674 A CN102690674 A CN 102690674A CN 2012101882325 A CN2012101882325 A CN 2012101882325A CN 201210188232 A CN201210188232 A CN 201210188232A CN 102690674 A CN102690674 A CN 102690674A
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CN
China
Prior art keywords
hydrocarbon oil
gasoline
product
composite additive
percent
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Pending
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CN2012101882325A
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Chinese (zh)
Inventor
龚坤
龚胜
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Individual
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Individual
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Priority to CN2012101882325A priority Critical patent/CN102690674A/en
Publication of CN102690674A publication Critical patent/CN102690674A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

The invention discloses a production method for hydrocarbon oil for vehicles. The production method comprises the following process flows: preparing a main raw material; preparing auxiliary raw materials; preparing a compound additive; synthesizing; filtering; and obtaining a finished product. The hydrocarbon oil is prepared through synthetic reaction in a reaction tank at normal temperature under normal pressure, and is prepared from 85 to 88 percent of main raw material, namely absolute methanol, and 2 to 5 percent of n-butyl alcohol, 8 to 10 percent of No.93 gasoline, and 0.05 to 0.1 percent of compound additive, which are auxiliary raw materials. The raw materials are wide in sources and cheap, the production cost is low, the hydrocarbon oil is convenient to use, three wastes are not discharged in the production process, the hydrocarbon oil is environment-friendly in the using process, the tail gas emission of the hydrocarbon oil is 50 percent lower than that of gasoline, and the hydrocarbon oil is new green energy; due to the compound additive, the product has high stability and is more safe than the gasoline; the hydrocarbon oil is widely applied and can serve as a novel liquid fuel to replace a gasoline product; and after the product is detected by a national detection department, various indexes of the product meet the national standards; and through trial of wide users, the product is popular with the users and has significance for relieving the strain of gasoline supply.

Description

A kind of working method of automobile-used hydrocarbon oil
Technical field
The present invention relates to a kind of working method of automobile-used hydrocarbon oil, belong to chemical technology field.
Background technology
At present, along with the minimizing day by day of petroleum resources, and price is constantly surging, and making some is the automobile or the power car of the energy with the petroleum products, because of the oil product cost constantly increases, has increased the weight of the running cost of automobile, has also increased human consumer's burden; Petroleum products the time will produce a large amount of toxic gases in burning in addition, both contaminate environment, and it is healthy to damage people again.Therefore, much human is all being sought the new energy, to substitute the petroleum products that reduces day by day, overcome because of oil raise the price to automobilism and human consumer bring difficult and inconvenient.
Summary of the invention
For alleviating because of petroleum resources reduce day by day, petroleum product price goes up day by day, the many difficulties and the inconvenience of bringing for automobile and human consumer, and the novel fuel that the purpose of this invention is to provide a kind of instead gasoline is the working method of automobile-used hydrocarbon oil.
For solving its technical problem, the technical scheme that the present invention adopts is: the technical process of the working method of this automobile-used hydrocarbon oil is: main starting material → auxiliary raw material → composite additive → synthetic → filtration → finished product; Wherein main starting material are: anhydrous methanol; Auxiliary raw material is: propyl carbinol or 93# gasoline; Composite additive is formulated by the weight percent of 1:1:1:2 by sanitas, octane promoter, stablizer and emulsifying agent; Adopt the principle of normal temperature, normal pressure and building-up reactions.Its working method comprises following concrete steps:
1. get all the following materials of weight proportions ready: main starting material anhydrous methanol 85-88%, auxiliary raw material propyl carbinol 2-5%, 93# gasoline 8-10%, composite additive 0.05-0.1%;
2. main starting material anhydrous methanol is sent in the retort with transfer pump;
3. raw-materially simultaneously auxiliary raw material propyl carbinol, 93# gasoline and composite additive are added respectively in the retort defeated main, stirred 15-20 minute, under normal temperature, normal pressure, make various raw materials fully emulsified in retort, become synthetic liquid;
4. will synthesize liquid and filter, the mesh of filter is the 100-200 order;
5. barrelling is after the assay was approved put in storage.
Wherein said composite additive is by sanitas, octane promoter, stablizer and emulsifying agent, and the weight percent of pressing 1:1:1:2 is formulated; The sanitas of especially said composite additive is that sulphite, octane promoter are that MTBE, stablizer are complex lead salt, and emulsifying agent is O/W or W/O; By sulphite: the weight proportion of MTBE: complex lead salt: O/W or W/O ﹦ 1:1:1:2 mixes fully to stir and forms;
Wherein said sanitas and octane promoter can reduce corrodibility, increase anti-knocking property and stability, can also make it fully emulsified simultaneously, react more abundant, more thorough;
Wherein said methyl alcohol (CH 4CH 3OH) be achromaticity and clarification liquid, have higher octane value, low price, wide material sources;
Said propyl carbinol is (CH 3CH 2CH 2CH 2OH), be a kind of colourless liquid with fume flavor, can be used as organic synthesis intermediate, also can be used for making tensio-active agent, have emulsifying property preferably, can also shorten the reaction times simultaneously;
Said 93# gasoline, outward appearance are transparent liquid, and staple is C 4-C 12Aliphatic hydrocarbon and cyclic hydrocar-bons, and contain a small amount of aromatic hydrocarbon and sulfide, have higher octane value and good anti-knocking property, sufficient combustion, carbon distribution is few, non-corrosiveness, the source is wide, can gather materials on the spot, and not only can increase fuel value, and can also solve the automobile starting performance.
The invention has the beneficial effects as follows: 1. technology of the present invention has extensive applicability; Can substitute petroleum products as a kind of novel liquid fuel; This product is business men quality supervision and inspection institute 2011-3-23 Hunan inspection B2011-W10493 survey report through the Hunan Province; According to GB ∕ T23799-2009 " Vehicular methanol petrol (M85) ", (10 of C2 ~ C8), lead contents etc. detect, and conclusion is: " the project conformance with standard of examining require " to outward appearance, methyl alcohol+higher alcohols; On probation through users, well received, the anxiety of alleviating oil supply is significant;
2. the present invention has tangible economic benefit: because the raw material that the present invention adopts is extensive, and low price, production technique is advanced; Its production cost is low, and is easy to use, and production cost only needs 3 yuan/liter at present; And petrol price is 6.7 yuan/liter, therefore has favorable economic benefit;
3. hydrocarbon oil of the present invention has the feature of environmental protection; Because contain small amount of carbon atom and sulphur content in this product, not only environmental protection is a three-waste free discharge in process of production, and more environmental protection in use, its exhaust emissions will be lower than gasoline 50%, so this product also belongs to a kind of green novel energy source;
4. hydrocarbon oil of the present invention has security, because the present invention has adopted composite additive, makes its product have certain stability, and compare its flash-point with gasoline high, and the flames of anger is nonflammable, and is non-explosive, and transportation is with storage and use more safer than gasoline.
Embodiment
Embodiment 1:
1. get the raw materials ready: press anhydrous methanol 85%, propyl carbinol 5%, gasoline 9% and composite additive 1%;
2. anhydrous methanol is pumped into retort with special oil;
3. simultaneously propyl carbinol, gasoline and composite additive are added respectively in the retort,, make various raw materials fully emulsified in retort through 15-20 minute, synthetic;
4. last warp filters and forms.
Wherein said composite additive is by the MTBE of the sulphite of sanitas, octane promoter, the complex lead salt of stablizer, the O/W of emulsifying agent or W/O, and the weight percent of pressing 1:1:1:2 is formulated.Wherein said methyl alcohol (CH 4CH 3OH) be achromaticity and clarification liquid, have higher octane value, low price, wide material sources; Said propyl carbinol is (CH 3CH 2CH 2CH 2OH), be a kind of colourless liquid with fume flavor, can be used as organic synthesis intermediate, also can be used for making tensio-active agent, have emulsifying property preferably, can also shorten the reaction times simultaneously; Said 93# gasoline, outward appearance are transparent liquid, and staple is C 4-C 12Aliphatic hydrocarbon and cyclic hydrocar-bons, and contain a small amount of aromatic hydrocarbon and sulfide, have higher octane value and good anti-knocking property, sufficient combustion, carbon distribution is few, non-corrosiveness, the source is wide, can gather materials on the spot, and not only can increase fuel value, and can also solve the automobile starting performance.
Embodiment 2:
1. get the raw materials ready: anhydrous methanol 88%, propyl carbinol 2%, 93# gasoline 9.5% and composite additive 0.5%;
2. anhydrous methanol is added in the retort with special-purpose oil pump;
3. simultaneously propyl carbinol, gasoline and composite additive are added respectively in the retort,, make various raw materials fully emulsified in reaction kettle through 15-20 minute, synthetic; 4. last warp filters and forms.
Wherein said composite additive is by the MTBE of the sulphite of sanitas, octane promoter, the complex lead salt of stablizer, the O/W of emulsifying agent or W/O, and the weight percent of pressing 1:1:1:2 is formulated;
Wherein said methyl alcohol (CH 4CH 3OH) be achromaticity and clarification liquid, have higher octane value, low price, wide material sources; Said propyl carbinol is (CH 3CH 2CH 2CH 2OH), be a kind of colourless liquid with fume flavor, can be used as organic synthesis intermediate, also can be used for making tensio-active agent, have emulsifying property preferably, can also shorten the reaction times simultaneously; Said 93# gasoline, outward appearance are transparent liquid, and staple is C 4-C 12Aliphatic hydrocarbon and cyclic hydrocar-bons, and contain a small amount of aromatic hydrocarbon and sulfide, have higher octane value and good anti-knocking property, sufficient combustion, carbon distribution is few, non-corrosiveness, the source is wide, can gather materials on the spot, and not only can increase fuel value, and can also solve the automobile starting performance.
Embodiment 3:
1. get all the following materials of weight proportions ready: anhydrous methanol 85%, propyl carbinol 4%, 93# gasoline 10% and composite additive 1%;
2. anhydrous methanol is added in the retort with special-purpose oil pump;
3. simultaneously propyl carbinol, gasoline and composite additive are added respectively in the retort, warp warp 15 ∽ 20 minutes make various raw materials fully emulsified in reaction kettle, and are synthetic;
4. last warp filters and forms.
Wherein said composite additive is formulated by the weight percent of 1:1:1:2 by sanitas, octane promoter, stablizer and emulsifying agent;
Wherein said methyl alcohol (CH 4CH 3OH) be achromaticity and clarification liquid, have higher octane value, low price, wide material sources; Said propyl carbinol is (CH 3CH 2CH 2CH 2OH), be a kind of colourless liquid with fume flavor, can be used as organic synthesis intermediate, also can be used for making tensio-active agent, have emulsifying property preferably, can also shorten the reaction times simultaneously; Said 93# gasoline, outward appearance are transparent liquid, and staple is C 4-C 12Aliphatic hydrocarbon and cyclic hydrocar-bons, and contain a small amount of aromatic hydrocarbon and sulfide, have higher octane value and good anti-knocking property, sufficient combustion, carbon distribution is few, non-corrosiveness, the source is wide, can gather materials on the spot, and not only can increase fuel value, and can also solve the automobile starting performance.

Claims (3)

1. the working method of an automobile-used hydrocarbon oil, its technical process is: main starting material → auxiliary raw material → composite additive → synthetic → filtration → finished product, it is characterized in that: its method comprises following concrete steps:
1. get all the following materials of weight proportions ready: main starting material anhydrous methanol 85-88%, auxiliary raw material propyl carbinol 2-5%, 93# gasoline 8-10%, composite additive 0.05-0.1%;
2. main starting material anhydrous methanol is sent in the retort with transfer pump;
3. raw-materially simultaneously auxiliary raw material propyl carbinol, 93# gasoline and composite additive are added respectively in the retort defeated main, stirred 15-20 minute, under normal temperature, normal pressure, make various raw materials fully emulsified in retort, become synthetic liquid;
4. will synthesize liquid and filter, the mesh of filter is the 100-200 order;
5. barrelling is after the assay was approved put in storage.
2. the working method of automobile-used hydrocarbon oil according to claim 1, it is characterized in that: said composite additive is by sanitas, octane promoter, stablizer and emulsifying agent, and the weight percent of pressing 1:1:1:2 is formulated.
3. the working method of automobile-used hydrocarbon oil according to claim 1 and 2, it is characterized in that: the sanitas of said composite additive is that sulphite, octane promoter are that MTBE, stablizer are complex lead salt, and emulsifying agent is O/W or W/O.
CN2012101882325A 2012-06-09 2012-06-09 Production method for hydrocarbon oil for vehicles Pending CN102690674A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104147971A (en) * 2014-08-18 2014-11-19 龚坤 Production system for MCH-40 hydrocarbon power oil
CN108441269A (en) * 2018-02-09 2018-08-24 邹进 A kind of compound hydrogen fuel and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3660357B2 (en) * 1994-03-02 2005-06-15 ウィリアム・シー・オーア Unleaded MMT fuel composition
CN101955809A (en) * 2010-09-13 2011-01-26 于涛 Vehicle high-proportion methanol gasoline and preparation method thereof
CN102399601A (en) * 2010-09-17 2012-04-04 东莞市智造生物科技有限公司 High-cleanliness methanol gasoline

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3660357B2 (en) * 1994-03-02 2005-06-15 ウィリアム・シー・オーア Unleaded MMT fuel composition
CN101955809A (en) * 2010-09-13 2011-01-26 于涛 Vehicle high-proportion methanol gasoline and preparation method thereof
CN102399601A (en) * 2010-09-17 2012-04-04 东莞市智造生物科技有限公司 High-cleanliness methanol gasoline

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104147971A (en) * 2014-08-18 2014-11-19 龚坤 Production system for MCH-40 hydrocarbon power oil
CN104147971B (en) * 2014-08-18 2016-02-03 龚坤 The production system of the hydrocarbon power oil of a kind of MCH-40
CN108441269A (en) * 2018-02-09 2018-08-24 邹进 A kind of compound hydrogen fuel and preparation method thereof

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Application publication date: 20120926