CN107177361A - A kind of environment-friendlyflame flame retardant and its preparation technology - Google Patents
A kind of environment-friendlyflame flame retardant and its preparation technology Download PDFInfo
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- CN107177361A CN107177361A CN201710409538.1A CN201710409538A CN107177361A CN 107177361 A CN107177361 A CN 107177361A CN 201710409538 A CN201710409538 A CN 201710409538A CN 107177361 A CN107177361 A CN 107177361A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
Abstract
The invention discloses a kind of environment-friendlyflame flame retardant and its preparation technology, flame retardant component includes 10 20 parts of oxalic acid, 5 15 parts of TDE, 3 10 parts of triphenyl phosphate, 28 parts of magnesia, 3 10 parts of antimony oxide, 5 10 parts of diatomite, 10 20 parts of expanded graphite, 38 parts of silane coupler, 28 parts of superfine zinc borate, 5 15 parts of carbonized agent, 2 10 parts of bleeding agent, 3 10 parts of tartaric acid by weight, preparation technology of the present invention is simple, preparation process is environment friendly and pollution-free, obtained fire retardant effect is good, and will not discharge poisonous and harmful substances.
Description
Technical field
The present invention relates to technical field of flame retardant agent preparation, specially a kind of environment-friendlyflame flame retardant and its preparation technology.
Background technology
At present, known many articles for daily use include furniture, floor, wallpaper etc., its for life bring it is practical, attractive in appearance,
While fashion, many hidden danger are also there are；Substantial amounts of pernicious gas is produced during burning, not only to the healthy of people
It is unfavorable that safety belt comes, while also destroying the ecological environment on periphery.Although fire retardant is widely used in the various aspects of life,
But when carrying out flame retardant treatment to article, still suffer from new technical problem.Current majority flame retardant formulations, what is produced in use has
Evil gas has not only broken up ecological environment, while also contributing to the healthy of people.
The content of the invention
It is an object of the invention to provide a kind of environment-friendlyflame flame retardant and its preparation technology, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme：A kind of environment-friendlyflame flame retardant, flame retardant component is pressed
Parts by weight include 10-20 parts of oxalic acid, 5-15 parts of TDE, 3-10 parts of triphenyl phosphate, 2-8 parts of magnesia, three oxygen
Change 3-10 parts of two antimony, 5-10 parts of diatomite, 10-20 parts of expanded graphite, 3-8 parts of silane coupler, 2-8 parts of superfine zinc borate, charcoal
5-15 parts of agent, 2-10 parts of bleeding agent, 3-10 parts of tartaric acid.
It is preferred that, composition proportion preferably is：15 parts of oxalic acid, 10 parts of TDE, 7 parts of triphenyl phosphate, oxidation
5 parts of magnesium, 7 parts of antimony oxide, 8 parts of diatomite, 15 parts of expanded graphite, 6 parts of silane coupler, 5 parts of superfine zinc borate, carbonized agent
10 parts, 6 parts of bleeding agent, 7 parts of tartaric acid.
It is preferred that, its preparation technology comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Compared with prior art, the beneficial effects of the invention are as follows：Preparation technology of the present invention is simple, and preparation process environmental protection is without dirt
Dye, obtained fire retardant effect is good, and will not discharge poisonous and harmful substances；In addition, adding bromine hexichol second in the present invention
Alkane, triphenyl phosphate, can further increase fire resistance.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
The present invention provides following technical scheme：A kind of environment-friendlyflame flame retardant, flame retardant component includes grass by weight
Sour 10-20 parts, 5-15 parts of TDE, 3-10 parts of triphenyl phosphate, 2-8 parts of magnesia, 3-10 parts of antimony oxide, silicon
5-10 parts of diatomaceous earth, 10-20 parts of expanded graphite, 3-8 parts of silane coupler, 2-8 parts of superfine zinc borate, 5-15 parts of carbonized agent, infiltration
2-10 parts of agent, 3-10 parts of tartaric acid.
Embodiment one：
Flame retardant component by weight include 10 parts of oxalic acid, 5 parts of TDE, 3 parts of triphenyl phosphate, 2 parts of magnesia,
3 parts of antimony oxide, 5 parts of diatomite, 10 parts of expanded graphite, 3 parts of silane coupler, 2 parts of superfine zinc borate, 5 parts of carbonized agent, ooze
Saturating 2 parts of agent, 3 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Embodiment two：
Flame retardant component includes 20 parts of oxalic acid, 15 parts of TDE, 10 parts of triphenyl phosphate, magnesia 8 by weight
Part, 10 parts of antimony oxide, 10 parts of diatomite, 20 parts of expanded graphite, 8 parts of silane coupler, 8 parts of superfine zinc borate, carbonized agent
15 parts, 10 parts of bleeding agent, 10 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Embodiment three：
Flame retardant component by weight include 12 parts of oxalic acid, 7 parts of TDE, 4 parts of triphenyl phosphate, 3 parts of magnesia,
4 parts of antimony oxide, 6 parts of diatomite, 12 parts of expanded graphite, 4 parts of silane coupler, 3 parts of superfine zinc borate, 6 parts of carbonized agent, ooze
Saturating 4 parts of agent, 4 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Example IV：
Flame retardant component includes 18 parts of oxalic acid, 14 parts of TDE, 9 parts of triphenyl phosphate, magnesia 7 by weight
Part, 9 parts of antimony oxide, 9 parts of diatomite, 18 parts of expanded graphite, 7 parts of silane coupler, 7 parts of superfine zinc borate, carbonized agent 14
Part, 9 parts of bleeding agent, 9 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Embodiment five：
Flame retardant component includes 14 parts of oxalic acid, 12 parts of TDE, 8 parts of triphenyl phosphate, magnesia 6 by weight
Part, 5 parts of antimony oxide, 8 parts of diatomite, 14 parts of expanded graphite, 7 parts of silane coupler, 6 parts of superfine zinc borate, carbonized agent 7
Part, 8 parts of bleeding agent, 8 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Embodiment six：
Flame retardant component includes 15 parts of oxalic acid, 10 parts of TDE, 7 parts of triphenyl phosphate, magnesia 5 by weight
Part, 7 parts of antimony oxide, 8 parts of diatomite, 15 parts of expanded graphite, 6 parts of silane coupler, 5 parts of superfine zinc borate, carbonized agent 10
Part, 6 parts of bleeding agent, 7 parts of tartaric acid.
The preparation technology of the present embodiment comprises the following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Preparation technology of the present invention is simple, and preparation process is environment friendly and pollution-free, and obtained fire retardant effect is good, and will not release
Put poisonous and harmful substances；In addition, adding bromine diphenylethane, triphenyl phosphate in the present invention, it can further increase anti-flammability
Energy.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (3)
1. a kind of environment-friendlyflame flame retardant, it is characterised in that：Flame retardant component includes 10-20 parts of oxalic acid, ten bromines by weight
It is 5-15 parts of diphenylethane, 3-10 parts of triphenyl phosphate, 2-8 parts of magnesia, 3-10 parts of antimony oxide, 5-10 parts of diatomite, swollen
Swollen graphite 10-20 parts, 3-8 parts of silane coupler, 2-8 parts of superfine zinc borate, 5-15 parts of carbonized agent, 2-10 parts of bleeding agent, winestone
It is sour 3-10 parts.
2. a kind of environment-friendlyflame flame retardant according to claim 1, it is characterised in that：It is preferred that composition proportion be：Oxalic acid
15 parts, 10 parts of TDE, 7 parts of triphenyl phosphate, 5 parts of magnesia, 7 parts of antimony oxide, 8 parts of diatomite, expansion stone
15 parts of ink, 6 parts of silane coupler, 5 parts of superfine zinc borate, 10 parts of carbonized agent, 6 parts of bleeding agent, 7 parts of tartaric acid.
3. realize a kind of preparation technology of environment-friendlyflame flame retardant described in claim 1, it is characterised in that：Its preparation technology bag
Include following steps：
A, will oxalic acid, TDE, triphenyl phosphate, magnesia, bleeding agent, tartaric acid mix after add stirred tank in
Even stirring, stirred tank rotating speed is 1000 revs/min, and mixing time is 25min, and standing obtains intermixture A；
B, will antimony oxide, diatomite, expanded graphite, superfine zinc borate, carbonized agent mix after add grinder in grind, grind
Consume time as 30min, obtain mixture B；
C, the addition mixture B in intermixture A, add silane coupler afterwards, and heating response in reactor is added after mixing, plus
It is stirred continuously in thermal process, heating-up temperature is 40 DEG C, constant temperature 10min after heating 10min is warming up to 60 DEG C, heating again afterwards
10min, is slowly cooled to room temperature afterwards, stands 1h, that is, obtains fire retardant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710409538.1A CN107177361A (en) | 2017-06-02 | 2017-06-02 | A kind of environment-friendlyflame flame retardant and its preparation technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710409538.1A CN107177361A (en) | 2017-06-02 | 2017-06-02 | A kind of environment-friendlyflame flame retardant and its preparation technology |
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| CN107177361A true CN107177361A (en) | 2017-09-19 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880904A (en) * | 2017-12-12 | 2018-04-06 | 佛山早稻田科技服务有限公司 | A kind of environment friendly flame retardant |
| CN108102668A (en) * | 2017-12-27 | 2018-06-01 | 洛阳神佳窑业有限公司 | New flame retardant |
| CN114479182A (en) * | 2022-02-23 | 2022-05-13 | 无锡云启新材料有限公司 | Preparation method of professional rubber flame retardant |
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| CN103102134A (en) * | 2013-02-20 | 2013-05-15 | 上海宏胜电线电缆有限公司 | Fireproof and flame retardant mineral compound filling material and cable containing the same |
| CN104039927A (en) * | 2012-06-27 | 2014-09-10 | 江苏苏利精细化工股份有限公司 | Method for preparing melamine phosphate-based flame retardant |
| WO2016111717A1 (en) * | 2015-01-09 | 2016-07-14 | Chemtura Corporation | Process stabilization of polymer compositions comprising phosphorous containing flame retardants |
| CN105829430A (en) * | 2013-11-08 | 2016-08-03 | 松原国际股份有限公司 | Sulfenamides as flame retardants |
| CN106065309A (en) * | 2016-07-29 | 2016-11-02 | 合肥毅创钣金科技有限公司 | A kind of expansible graphite works in coordination with the polyurethane foam glue of the fire-retardant enhancing of kieselguhr |
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- 2017-06-02 CN CN201710409538.1A patent/CN107177361A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101824186A (en) * | 2009-12-09 | 2010-09-08 | 广州市创至峰塑料制品科技有限公司 | Flame retarding polypropylene compound |
| CN104039927A (en) * | 2012-06-27 | 2014-09-10 | 江苏苏利精细化工股份有限公司 | Method for preparing melamine phosphate-based flame retardant |
| CN103102134A (en) * | 2013-02-20 | 2013-05-15 | 上海宏胜电线电缆有限公司 | Fireproof and flame retardant mineral compound filling material and cable containing the same |
| CN105829430A (en) * | 2013-11-08 | 2016-08-03 | 松原国际股份有限公司 | Sulfenamides as flame retardants |
| WO2016111717A1 (en) * | 2015-01-09 | 2016-07-14 | Chemtura Corporation | Process stabilization of polymer compositions comprising phosphorous containing flame retardants |
| CN106065309A (en) * | 2016-07-29 | 2016-11-02 | 合肥毅创钣金科技有限公司 | A kind of expansible graphite works in coordination with the polyurethane foam glue of the fire-retardant enhancing of kieselguhr |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107880904A (en) * | 2017-12-12 | 2018-04-06 | 佛山早稻田科技服务有限公司 | A kind of environment friendly flame retardant |
| CN108102668A (en) * | 2017-12-27 | 2018-06-01 | 洛阳神佳窑业有限公司 | New flame retardant |
| CN114479182A (en) * | 2022-02-23 | 2022-05-13 | 无锡云启新材料有限公司 | Preparation method of professional rubber flame retardant |
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Application publication date: 20170919 |