CN107236213A - A kind of flame-proof PVC wallpaper composite and preparation method thereof - Google Patents
A kind of flame-proof PVC wallpaper composite and preparation method thereof Download PDFInfo
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- CN107236213A CN107236213A CN201710469802.0A CN201710469802A CN107236213A CN 107236213 A CN107236213 A CN 107236213A CN 201710469802 A CN201710469802 A CN 201710469802A CN 107236213 A CN107236213 A CN 107236213A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/02—Cellulose; Modified cellulose
- C08J2401/04—Oxycellulose; Hydrocellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：100 parts of polyvinyl chloride resin；10 17 parts of nanocrystal cellulose, 9 14 parts of chitosan, 20 35 parts of APP, 59 parts of hydrotalcite, 25 parts of cocoyl glucoside, 37 parts of coupling agent, 50 60 parts of plasticizer, 12 parts of stabilizer, 12 parts of foaming agent.The flame-proof PVC wallpaper composite has good flame retardant effect, and the material has good pliability and stability, and service life is longer.
Description
Technical field
The present invention relates to wallpaper material field, more particularly to a kind of flame-proof PVC wallpaper composite and its preparation side
Method.
Background technology
Wallpaper is a kind of traditional decorative material for wall surface, with color is various, pattern abundant, safety and environmental protection, easy construction,
The advantages of affordable.In recent years in order to adapt to different Space, Places, different hobbies and different price levels,
There is polytype wallpaper available.According to the material of wallpaper, it can be divided into：High polymer material class wallpaper, pure paper class wallpaper,
Non-woven fabrics wallpaper, dry goods wallpaper, diatom great soil group wallpaper, natural material class wallpaper and stationery wallpaper, mica sheet class wallpaper,
Gold and silver paper tinsel class wallpaper and wall paper class wallpaper.Recently as the development of science and technology, some new type functional wallpapers are occurred in that, than
Such as：Computer special efficacy wallpaper, moisture absorption wallpaper, desinsection wallpaper, high temperature wallpaper, mildew-proof wallpaper, thermal insulating wall paper, heating wallpaper, report
Fire alarm wallpaper and disinfection wallpaper.
In the wallpaper of numerous kinds, the PVC plastic wallpaper in current high polymer material class wallpaper is that output is most, city
A kind of best wallpaper in field.PVC wallpaper has cheap, and designs and varieties are more, good permeability, widely applicable, and soundproof effect is good,
And the advantages of scrubbing resistance, widely used in various places, greatly beautified the living environment of people.But, without fire-retardant
The PVC wallpaper oxygen index (OI) of processing is only 21 or so, belongs to combustible material, there is potential fire risk.The fire-retardant side commonly used at present
Formula mostly be to use inorganic combustion inhibitor, easily crystallization separate out so that cause the paper moisture absorption and occur it is inter-adhesive, to the storage band of wallpaper
Carry out more problem.
Chinese patent CN201610005451.3 discloses a kind of wallpaper layer of PVC, according to the mass fraction, and its raw material is by following
Component is constituted：Plasticiser：250 parts；Thinner：70~80 parts；PVC450 resin-oatmeals：350~400 parts；High-temperature foaming agent：4~6
Part；Production of low-temperature foaming agent：6~10 parts；Brightening agent：80~120 parts；Titanium dioxide：40~60 parts；Coarse whiting：200~220 parts；Fine particle calcium carbonate：
40~60 parts；Stabilizer：6~10 parts.The invention uses the formula that high-temperature foaming agent and production of low-temperature foaming agent are combined, and realizes secondary
Foaming, for the first time when applying PVC claddings, production of low-temperature foaming agent works, and adds the pliability and printing flatness of paper, second
Used in embossing, high temperature causes high temperature foaming increase PVC thickness, improves the definition of embossing so that the two has concurrently, both meets
The preferable pliability of paper and printing flatness, there is preferably embossing definition again.But the fire resistance of the wallpaper still needs to change
Enter.
The content of the invention
It is an object of the invention to provide a kind of flame-proof PVC wallpaper composite and preparation method thereof, the flame-proof PVC wallpaper
There is good flame retardant effect with composite, and the material has a good pliability and stability, service life compared with
It is long.
To achieve the above object, the present invention uses following technical scheme：
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；10-17 parts of nanocrystal cellulose, 9-14 parts of chitosan, 20-35 parts of APP, neatly
5-9 parts of stone, 2-5 parts of cocoyl glucoside, 3-7 parts of coupling agent, 50-60 parts of plasticizer, 1-2 parts of stabilizer, 1-2 parts of foaming agent.
It is preferred that, the coupling agent is the mixture of aluminate coupling agent and silane coupler.
It is preferred that, the plasticizer is DOTP and Chloration aromatic base crude oil mass ratio is 3:5 mixture.
It is preferred that, the stabilizer is lemon acid rare earth.
It is preferred that, the foaming agent is AC foaming agents.
A kind of preparation method of flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 20-30min, the water-soluble of cocoyl glucoside is added dropwise thereto afterwards
Liquid, after being added dropwise to complete, continues to grind 30-45min, takes out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 40-60 DEG C, coupling agent, modified hydrotalcite powder, stabilizer and foaming agent is sequentially added afterwards
Continue to stir, flame-proof PVC wallpaper composite is made.
The invention has the advantages that,
Under nanocrystal cellulose grain diameter, specific surface area is big, with distinctive optical property and mechanical performance.Nanometer
Be present substantial amounts of hydroxyl in avicel cellulose surface, easily combined with APP, so that APP can be in PVC composite woods
It can be uniformly distributed in material with relatively stable, form flame-retardant layer.
Hydrotalcite is stratiform Mg-Al composite oxide, when it is heated constitution water laminated sheet hydroxyl and interlayer ion with water and
CO2Form abjection, so as to play fire retardation.Hydrotalcite is favorably improved the stability of PVC material simultaneously, can be effective
Extend the service life of flame-proof PVC wallpaper composite produced by the present invention.
Embodiment
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；10 parts of nanocrystal cellulose, 9 parts of chitosan, 20 parts of APP, 5 parts of hydrotalcite, cocounut oil
2 parts of base glucoside, 3 parts of coupling agent, 50 parts of plasticizer, 1 part of stabilizer, 1 part of foaming agent.
Wherein, coupling agent is the mixture of aluminate coupling agent and silane coupler；Plasticizer is DOTP and chlorinated aromatics
Oil quality ratio is 3:5 mixture；Stabilizer is lemon acid rare earth；Foaming agent is AC foaming agents.
The preparation method of the flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 20min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 30min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 40 DEG C, coupling agent is sequentially added afterwards, modified hydrotalcite powder, stabilizer and foaming agent continues
Stir, flame-proof PVC wallpaper composite is made.
Wallpaper is prepared by base paper of non-woven fabrics with composite using obtained flame-proof PVC wallpaper, its limit oxygen is measured and refers to
Count to remain to keep good character after 36.2%, and the wallpaper long-time use.
Embodiment 2
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；17 parts of nanocrystal cellulose, 14 parts of chitosan, 35 parts of APP, 9 parts of hydrotalcite, coconut palm
5 parts of oil base glucoside, 7 parts of coupling agent, 60 parts of plasticizer, 2 parts of stabilizer, 2 parts of foaming agent.
Wherein, coupling agent is the mixture of aluminate coupling agent and silane coupler；Plasticizer is DOTP and chlorinated aromatics
Oil quality ratio is 3:5 mixture；Stabilizer is lemon acid rare earth；Foaming agent is AC foaming agents.
The preparation method of the flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 30min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 45min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 60 DEG C, coupling agent is sequentially added afterwards, modified hydrotalcite powder, stabilizer and foaming agent continues
Stir, flame-proof PVC wallpaper composite is made.
Wallpaper is prepared by base paper of non-woven fabrics with composite using obtained flame-proof PVC wallpaper, its limit oxygen is measured and refers to
Count to remain to keep good character after 38.5%, and the wallpaper long-time use.
Embodiment 3
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；10 parts of nanocrystal cellulose, 14 parts of chitosan, 20 parts of APP, 9 parts of hydrotalcite, coconut palm
2 parts of oil base glucoside, 7 parts of coupling agent, 50 parts of plasticizer, 2 parts of stabilizer, 1 part of foaming agent.
Wherein, coupling agent is the mixture of aluminate coupling agent and silane coupler；Plasticizer is DOTP and chlorinated aromatics
Oil quality ratio is 3:5 mixture；Stabilizer is lemon acid rare earth；Foaming agent is AC foaming agents.
The preparation method of the flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 20min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 45min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 40 DEG C, coupling agent is sequentially added afterwards, modified hydrotalcite powder, stabilizer and foaming agent continues
Stir, flame-proof PVC wallpaper composite is made.
Wallpaper is prepared by base paper of non-woven fabrics with composite using obtained flame-proof PVC wallpaper, its limit oxygen is measured and refers to
Count to remain to keep good character after 45.6%, and the wallpaper long-time use.
Embodiment 4
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；17 parts of nanocrystal cellulose, 9 parts of chitosan, 35 parts of APP, 5 parts of hydrotalcite, cocounut oil
5 parts of base glucoside, 3 parts of coupling agent, 60 parts of plasticizer, 1 part of stabilizer, 2 parts of foaming agent.
Wherein, coupling agent is the mixture of aluminate coupling agent and silane coupler；Plasticizer is DOTP and chlorinated aromatics
Oil quality ratio is 3:5 mixture；Stabilizer is lemon acid rare earth；Foaming agent is AC foaming agents.
The preparation method of the flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 30min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 30min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 60 DEG C, coupling agent is sequentially added afterwards, modified hydrotalcite powder, stabilizer and foaming agent continues
Stir, flame-proof PVC wallpaper composite is made.
Wallpaper is prepared by base paper of non-woven fabrics with composite using obtained flame-proof PVC wallpaper, its limit oxygen is measured and refers to
Count to remain to keep good character after 40.3%, and the wallpaper long-time use.
Embodiment 5
A kind of flame-proof PVC wallpaper composite, in parts by weight, including following components：
100 parts of polyvinyl chloride resin；12 parts of nanocrystal cellulose, 11 parts of chitosan, 25 parts of APP, 7 parts of hydrotalcite, coconut palm
3 parts of oil base glucoside, 5 parts of coupling agent, 55 parts of plasticizer, 1 part of stabilizer, 2 parts of foaming agent.
Wherein, coupling agent is the mixture of aluminate coupling agent and silane coupler；Plasticizer is DOTP and chlorinated aromatics
Oil quality ratio is 3:5 mixture；Stabilizer is lemon acid rare earth；Foaming agent is AC foaming agents.
The preparation method of the flame-proof PVC wallpaper composite, comprises the following steps：
(1) hydrotalcite is put into grinder, grinds 25min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 45min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP are added afterwards,
It is uniformly mixed under the conditions of 50 DEG C, coupling agent is sequentially added afterwards, modified hydrotalcite powder, stabilizer and foaming agent continues
Stir, flame-proof PVC wallpaper composite is made.
Wallpaper is prepared by base paper of non-woven fabrics with composite using obtained flame-proof PVC wallpaper, its limit oxygen is measured and refers to
Count to remain to keep good character after 44.1%, and the wallpaper long-time use.
Claims (6)
1. a kind of flame-proof PVC wallpaper composite, it is characterised in that：In parts by weight, including following components：
100 parts of polyvinyl chloride resin；10-17 parts of nanocrystal cellulose, 9-14 parts of chitosan, 20-35 parts of APP, hydrotalcite 5-9
Part, 2-5 parts of cocoyl glucoside, 3-7 parts of coupling agent, 50-60 parts of plasticizer, 1-2 parts of stabilizer, 1-2 parts of foaming agent.
2. flame-proof PVC wallpaper composite according to claim 1, it is characterised in that：The coupling agent is Aluminate
The mixture of coupling agent and silane coupler.
3. flame-proof PVC wallpaper composite according to claim 1, it is characterised in that：The plasticizer be DOTP with
Chloration aromatic base crude oil mass ratio is 3:5 mixture.
4. flame-proof PVC wallpaper composite according to claim 1, it is characterised in that：The stabilizer is citric acid
Rare earth.
5. flame-proof PVC wallpaper composite according to claim 1, it is characterised in that：The foaming agent foams for AC
Agent.
6. a kind of preparation method of flame-proof PVC wallpaper composite, it is characterised in that comprise the following steps：
(1) hydrotalcite is put into grinder, grinds 20-30min, the aqueous solution of cocoyl glucoside is added dropwise thereto afterwards,
After being added dropwise to complete, continue to grind 30-45min, take out drying, modified hydrotalcite powder is made；
(2) polyvinyl chloride resin and plasticizer are well mixed, nanocrystal cellulose, chitosan and APP is added afterwards,
Be uniformly mixed under the conditions of 40-60 DEG C, sequentially add coupling agent afterwards, modified hydrotalcite powder, stabilizer and foaming agent after
It is continuous to stir, flame-proof PVC wallpaper composite is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710469802.0A CN107236213A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-proof PVC wallpaper composite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710469802.0A CN107236213A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-proof PVC wallpaper composite and preparation method thereof |
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Family
ID=59987646
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| CN201710469802.0A Withdrawn CN107236213A (en) | 2017-06-20 | 2017-06-20 | A kind of flame-proof PVC wallpaper composite and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108277687A (en) * | 2017-12-30 | 2018-07-13 | 重庆家宝装饰材料有限公司 | A kind of Edge curl preventing PVC wallpaper and preparation method thereof |
| CN114411422A (en) * | 2022-03-02 | 2022-04-29 | 杭州萧山正达纺织有限公司 | High-temperature-resistant flame-retardant composite fabric and preparation method thereof |
| CN115926338A (en) * | 2022-11-07 | 2023-04-07 | 盐城幼儿师范高等专科学校 | Environment-friendly PVC decorative plate and manufacturing process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005003254A1 (en) * | 2003-07-06 | 2005-01-13 | Karl Zimmermann Gmbh | Flame-retarding fire protection element |
| CN102587218A (en) * | 2011-12-12 | 2012-07-18 | 公安部四川消防研究所 | Composite wallpaper containing polyvinyl chloride |
| CN104177732A (en) * | 2014-08-25 | 2014-12-03 | 赵焕 | Epispastic wallpaper and preparation method thereof |
| CN106283877A (en) * | 2016-08-17 | 2017-01-04 | 福建农林大学 | Polrvinyl chloride wallpaper with non-woven paper as base material of high flame retardant and preparation method thereof |
-
2017
- 2017-06-20 CN CN201710469802.0A patent/CN107236213A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005003254A1 (en) * | 2003-07-06 | 2005-01-13 | Karl Zimmermann Gmbh | Flame-retarding fire protection element |
| CN102587218A (en) * | 2011-12-12 | 2012-07-18 | 公安部四川消防研究所 | Composite wallpaper containing polyvinyl chloride |
| CN104177732A (en) * | 2014-08-25 | 2014-12-03 | 赵焕 | Epispastic wallpaper and preparation method thereof |
| CN106283877A (en) * | 2016-08-17 | 2017-01-04 | 福建农林大学 | Polrvinyl chloride wallpaper with non-woven paper as base material of high flame retardant and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108277687A (en) * | 2017-12-30 | 2018-07-13 | 重庆家宝装饰材料有限公司 | A kind of Edge curl preventing PVC wallpaper and preparation method thereof |
| CN114411422A (en) * | 2022-03-02 | 2022-04-29 | 杭州萧山正达纺织有限公司 | High-temperature-resistant flame-retardant composite fabric and preparation method thereof |
| CN115926338A (en) * | 2022-11-07 | 2023-04-07 | 盐城幼儿师范高等专科学校 | Environment-friendly PVC decorative plate and manufacturing process thereof |
| CN115926338B (en) * | 2022-11-07 | 2024-02-23 | 盐城幼儿师范高等专科学校 | Environment-friendly PVC decorative plate and manufacturing process thereof |
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Application publication date: 20171010 |