CN103710873A - Nonwoven cloth sound absorbing cotton containing graphene - Google Patents

Nonwoven cloth sound absorbing cotton containing graphene Download PDF

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Publication number
CN103710873A
CN103710873A CN201310601337.3A CN201310601337A CN103710873A CN 103710873 A CN103710873 A CN 103710873A CN 201310601337 A CN201310601337 A CN 201310601337A CN 103710873 A CN103710873 A CN 103710873A
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CN
China
Prior art keywords
parts
nonwoven cloth
sound absorbing
nonwoven fabric
back layer
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Pending
Application number
CN201310601337.3A
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Chinese (zh)
Inventor
王黎明
孙益民
章云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU YUEFEI NEW ACOUSTIC MATERIAL CO Ltd
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WUHU YUEFEI NEW ACOUSTIC MATERIAL CO Ltd
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Priority to CN201310601337.3A priority Critical patent/CN103710873A/en
Publication of CN103710873A publication Critical patent/CN103710873A/en
Pending legal-status Critical Current

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Abstract

The invention relates to sound absorbing cotton, in particular to nonwoven cloth sound absorbing cotton containing graphene. The nonwoven cloth sound absorbing cotton is composed of a top face layer, a back layer and a fiber cotton layer clamped between the top face layer and the back layer, the top face layer and the back layer are made of nonwoven cloth, and the nonwoven cloth is formed by, by weight, 100 parts of isotactic polypropylene, 5-7 parts of vinyl acetate, 2-3 parts of acrylic acid-2-hydroxy propyl ester, 1-2 parts of isocyanate, 4-5 parts of silica, 2-3 parts of sodium tripolyphosphate, 12-15 parts of epoxidized soybean oil, 1-2 parts of graphene, 1-2 parts of cetyl trimethyl ammonium bromide, 3-4 parts of radix isatidis, 1-2 parts of dyer woad leaf, 2-3 parts of houttuynia cordata and 4-5 parts of auxiliary through a melt-blowing method. The nonwoven cloth which is excellent in mechanical performance and dense in cloth quality is taken as an outer layer material, so that leakage of interlayer fiber cotton is effectively prevented, effect of environment friendliness and safety, heat resistance and flame retardancy, sound absorbing and denoising and the like is realized, and the nonwoven cloth sound absorbing cotton is wide in application prospect.

Description

A kind of nonwoven fabric acoustical cotton that contains Graphene
Technical field
The present invention relates to a kind of acoustical cotton, be specifically related to a kind of nonwoven fabric acoustical cotton that contains Graphene.
Background technology
Acoustical cotton is the effect materials such as a class set absorbing sound and lowering noise, control tonequality and decoration, be widely used in the places such as household, music hall, cinema, automobile, factory building, traditional acoustical cotton material is mainly the materials such as glass fibre, polyester fiber, rock wool, mineral wool, yet there is certain defect in acoustical cotton prepared by these materials, as poor in the feature of environmental protection, cause a disease carcinogenic, inflammable, water imbibition is poor, service life is short etc., therefore, be necessary to improve original acoustical cotton material, to improve its Environmental Safety, improve user's experience; Nonwoven fabric is undoubtedly a kind of desirable alternative materials, it have moisture retardant, pliable and tough light weight, good permeability, can recycle, the advantage such as nontoxic, coordinate again other sound-absorbing materials, can effectively improve the defect of existing acoustical cotton, promote sound-absorbing, soundproof effect.
Summary of the invention
The object of the invention is to, for the deficiency of current material, provide a kind of nonwoven fabric acoustical cotton that contains Graphene, make it have good mechanical property, and environmental protection flame retardant, sound absorption and noise isolation, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of nonwoven fabric acoustical cotton that contains Graphene, by top coat, back layer, and the cellucotton layer being clipped between top coat and back layer forms, described top coat, back layer adopts nonwoven cloth material, nonwoven fabric described in it is characterized in that is made by meltblown by the raw material of following weight portion: isotactic polypropylene 100, vinylacetate 5-7, 2-hydroxypropyl acrylate 2-3, isocyanates 1-2, silica 4-5, sodium phosphate trimer 2-3, epoxidized soybean oil 12-15, Graphene 1-2, softex kw 1-2, Radix Isatidis 3-4, folium isatidis 1-2, cordate houttuynia 2-3, auxiliary agent 4-5,
Described auxiliary agent is made by the raw material of following weight portion:.
Described a kind of nonwoven fabric acoustical cotton that contains Graphene, is characterized in that, nonwoven cloth material is made by following step:
(1) Radix Isatidis, folium isatidis, cordate houttuynia mixed and pulverize as 200-250 order powder, then the powder air blast to gained, seethes it, and to spray form epoxidized soybean oil in the powder seething, the two is fully mixed;
(2) isotactic polypropylene is heated to molten condition, adds step (1) material, stir;
(3) in step (2) material, add other residual components, fully stir, mix, by nozzle, spray silk and make nonwoven fabric.
Beneficial effect of the present invention is, the raw materials such as the Graphene adding in isotactic polypropylene, silica have effectively improved the mechanical property of material, and its pliable and tough wear-resisting, stretch-proof is impacted; Add in addition the natural plant fibres such as Chinese herbal medicine, increased the absorbing sound and lowering noise effect of material.The nonwoven cloth material that these raw materials are made is as the exterior material of acoustical cotton, and cloth matter is closely knit, can be good at preventing interlayer cellucotton seepage, Environmental Safety, and heat-proof combustion-resistant, absorbing sound and lowering noise, reusable edible, application prospect is extensive.
The specific embodiment
Embodiment
A kind of nonwoven fabric acoustical cotton that contains Graphene, by top coat, back layer, and the cellucotton layer being clipped between top coat and back layer forms, described top coat, back layer adopt nonwoven cloth material, and the nonwoven fabric described in it is characterized in that is made by meltblown by the raw material of following weight portion: isotactic polypropylene 100, vinylacetate 7,2-hydroxypropyl acrylate 3, isocyanates 2, silica 5, sodium phosphate trimer 3, epoxidized soybean oil 14, Graphene 2, softex kw 2, Radix Isatidis 4, folium isatidis 2, cordate houttuynia 3, auxiliary agent 5;
Above-mentioned auxiliary agent is made by the raw material of following weight portion: mica 30, nano-sized carbon 1, antioxidant MB 1, aluminate coupling agent DL-411 3, Sodium Benzoate 1,582-2 amino resins 4, actinolite 2, urea 1, cyanuric acid zinc 2, epoxyoleic acid butyl ester 35, n-propyl gallate 3, coix seed oil 1, vanadium carbide 2, Tea Polyphenols 1; Preparation method sends into mica, actinolite in calcining furnace and calcine 2-3 hour at 720-740 ℃, then, takes out, and sends in the hydrochloric acid solution of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other residual components, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
A nonwoven fabric acoustical cotton that contains Graphene, its top coat and back layer nonwoven cloth material are made by following step:
(1) Radix Isatidis, folium isatidis, cordate houttuynia being mixed and pulverize is 250 order powder, and then the powder air blast to gained, seethes it, and to spray form epoxidized soybean oil in the powder seething, the two is fully mixed;
(2) isotactic polypropylene is heated to molten condition, adds step (1) material, stir;
(3) in step (2) material, add other residual components, fully stir, mix, by nozzle, spray silk and make nonwoven fabric.
The performance test results of acoustical cotton of the present invention is:
The comprehensive Noise Reduction coefficient (NRC) of the thick product of 5cm: 0.87
Anti-flammability: B1 level
Hygroscopicity :≤5%.

Claims (2)

1. a nonwoven fabric acoustical cotton that contains Graphene, by top coat, back layer, and the cellucotton layer being clipped between top coat and back layer forms, described top coat, back layer adopts nonwoven cloth material, nonwoven fabric described in it is characterized in that is made by meltblown by the raw material of following weight portion: isotactic polypropylene 100, vinylacetate 5-7, 2-hydroxypropyl acrylate 2-3, isocyanates 1-2, silica 4-5, sodium phosphate trimer 2-3, epoxidized soybean oil 12-15, Graphene 1-2, softex kw 1-2, Radix Isatidis 3-4, folium isatidis 1-2, cordate houttuynia 2-3, auxiliary agent 4-5,
Described auxiliary agent is made by the raw material of following weight portion: mica 30-40, nano-sized carbon 1-2, antioxidant MB 1-2, aluminate coupling agent DL-411 3-4, Sodium Benzoate 1-2,582-2 amino resins 3-4, actinolite 2-3, urea 1-2, cyanuric acid zinc 2-3, epoxyoleic acid butyl ester 35-40, n-propyl gallate 2-3, coix seed oil 1-2, vanadium carbide 2-3, Tea Polyphenols 1-2; Preparation method sends into mica, actinolite in calcining furnace and calcine 2-3 hour at 720-740 ℃, then, takes out, and sends in the hydrochloric acid solution of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other residual components, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
2. a kind of nonwoven fabric acoustical cotton that contains Graphene as claimed in claim 1, is characterized in that, described nonwoven fabric is made by following step:
(1) Radix Isatidis, folium isatidis, cordate houttuynia mixed and pulverize as 200-250 order powder, then the powder air blast to gained, seethes it, and to spray form epoxidized soybean oil in the powder seething, the two is fully mixed;
(2) isotactic polypropylene is heated to molten condition, adds step (1) material, stir;
(3) in step (2) material, add other residual components, fully stir, mix, by nozzle, spray silk and make nonwoven fabric.
CN201310601337.3A 2013-11-25 2013-11-25 Nonwoven cloth sound absorbing cotton containing graphene Pending CN103710873A (en)

Priority Applications (1)

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CN201310601337.3A CN103710873A (en) 2013-11-25 2013-11-25 Nonwoven cloth sound absorbing cotton containing graphene

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CN201310601337.3A CN103710873A (en) 2013-11-25 2013-11-25 Nonwoven cloth sound absorbing cotton containing graphene

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Publication number Priority date Publication date Assignee Title
CN104562450A (en) * 2015-01-05 2015-04-29 芜湖环瑞汽车内饰件有限公司 Graphene oxide-polyurethane composite emulsion wrapped polypropylene nonwoven acoustic absorbing material for inner decoration of automobile
CN108018653A (en) * 2018-01-09 2018-05-11 山东省圣泉生物质石墨烯研究院 A kind of spunlace non-woven cloth, preparation method and the usage
CN108823797A (en) * 2018-07-27 2018-11-16 铜陵熙成塑料制品有限公司 A kind of modification nonwoven cloth material and preparation method thereof
CN113230747A (en) * 2021-06-08 2021-08-10 广州康滤净化科技有限公司 Graphene composite sound insulation filter cotton and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104562450A (en) * 2015-01-05 2015-04-29 芜湖环瑞汽车内饰件有限公司 Graphene oxide-polyurethane composite emulsion wrapped polypropylene nonwoven acoustic absorbing material for inner decoration of automobile
CN108018653A (en) * 2018-01-09 2018-05-11 山东省圣泉生物质石墨烯研究院 A kind of spunlace non-woven cloth, preparation method and the usage
CN108018653B (en) * 2018-01-09 2019-09-06 山东省圣泉生物质石墨烯研究院 A kind of spunlace non-woven cloth, preparation method and the usage
CN108823797A (en) * 2018-07-27 2018-11-16 铜陵熙成塑料制品有限公司 A kind of modification nonwoven cloth material and preparation method thereof
CN113230747A (en) * 2021-06-08 2021-08-10 广州康滤净化科技有限公司 Graphene composite sound insulation filter cotton and preparation method thereof

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Application publication date: 20140409

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