CN107164078A - A kind of production method of the cosmetic oil based on emblic kernel - Google Patents
A kind of production method of the cosmetic oil based on emblic kernel Download PDFInfo
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- CN107164078A CN107164078A CN201710251047.9A CN201710251047A CN107164078A CN 107164078 A CN107164078 A CN 107164078A CN 201710251047 A CN201710251047 A CN 201710251047A CN 107164078 A CN107164078 A CN 107164078A
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- Prior art keywords
- emblic
- kernel
- ethanol
- ethyl acetate
- extraction
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/02—Pretreatment
- C11B1/04—Pretreatment of vegetable raw material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B1/00—Production of fats or fatty oils from raw materials
- C11B1/10—Production of fats or fatty oils from raw materials by extracting
- C11B1/104—Production of fats or fatty oils from raw materials by extracting using super critical gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0092—Mixtures
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
A kind of production method of the cosmetic oil based on emblic kernel, belongs to cosmetics processing technique field.The present invention by emblic kernel by drying, be crushed to certain particle size；Add after ethanol and the pretreatment of ethyl acetate microwave radiation technology, supercritical CO is carried out using ethanol and ethyl acetate as entrainer2Extraction, pressure is extraction under the conditions of 20~30MPa, 45~50 DEG C of temperature；Then separated in knockout drum at pressure 3MPa~6MPa, 25~30 DEG C of temperature.After reclaiming ethanol and ethyl acetate through vacuum distillation, extraction oil obtains anti-oxidant emblic nucleolus oil by adding carnosine, Tea Polyphenols and lycopene composite antioxidant after solubilising.Extraction rate of the present invention is fast, recovery rate is high, no solvent residue, and the high quality oils water activity of acquisition is low, with anti-oxidant and vegetative cell function, and water retention property and Storage are all good, can be used as in cosmetics of super quality base starting material.
Description
Technical field
The invention belongs to cosmetics processing technique field, it is related to the production method of cosmetic oil.
Background technology
General principle：Emblic kernel oil-containing more than 20%.Be generally wherein unrighted acid, in emblic nucleolus oil with
Based on α-leukotrienes and α-linoleic acid, the main fatty acid composition of emblic nucleolus oil is alpha-linolenic acid, linoleic acid, oleic acid, palm fibre
Palmitic acid acid and 5 kinds of aliphatic acid such as stearic acid, its percentage contents sum is up to more than 98%.Many insatiable hungers in emblic nucleolus oil
It is alpha-linolenic acid and linoleic acid with aliphatic acid, the two percentage contents sum is more than 60%, wherein content highest how unsaturated
Aliphatic acid is alpha-linolenic acid, and its percentage contents is more than 44%.Meanwhile, also containing abundant squalene and sterol, palmitic acid,
The multiple biological activities composition such as 3- ethyls -4- methyl-pyrrols -2,5- diketone and pohytol, therefore, can make soft for cosmetics
Soft lubrication, the effect of skin nutrition cell.Lycopene can promote the growth and regeneration of cell, and beauty Eradicates wrinkles maintain skin to be good for
The effects such as health, anti-aging, skin allergy can be substantially improved, eliminate dry skin and itch because caused by allergic
Sense, makes us feeling relaxed happy.Carnosine can remove the aliphatic acid over oxidation for making cell membrane during oxidative stress and be formed
Active oxygen radical（ROS）And alpha-beta unsaturated aldehyde.The effect that the aging and skin that skin can be prevented are brightened, carnosine can
Prevent free radical from producing, repair skin injury, the function with vegetative cell.
The principle of microwave treatment is to penetrate spe medium using frequency electromagnetic waves, reaches the inside for being extracted material, microwave
Heat energy can be quickly converted to and make the temperature rapid increase of cell interior.When the pressure of cell interior exceedes the ability to bear of cell
When, cell will rupture, and active ingredient is i.e. from intracellular outflow, and be dissolved in spe medium at a lower temperature.
Supercritical CO2The principle of fluid extraction separation is the relation of the solvability using supercritical fluid and its density,
Influence i.e. using pressure and temperature to supercritical fluid solvability and extract.In the supercritical state, will be overcritical
Fluid is contacted with material to be separated, make its selectively polarity size, boiling point height it is different with molecular size range into
Divide and extract successively.Certainly, the extract obtained by each pressure limit of correspondence is unlikely to be single, but can be with control condition
The blending constituent of optimal proportion is obtained, then supercritical fluid is become common gases by the method for decompression, heating, is extracted
Material is then wholly or substantially separated out, so that the purpose of separating-purifying is reached, so supercritical CO2Fluid extraction process is by extracting
Combined with separation process.Supercritical CO2The sharpest edges of fluid extraction are no solvent residues, and natural active matter is obtained
It is effectively maintained.In the present invention, ethanol and ethyl acetate are in supercritical CO2Play entrainer during fluid extraction,
Extraction efficiency can be improved.And different from general organic solvent, provide that ethanol and ethyl acetate are fair according to GB 2760-96
Perhaps the flavorant used, for cosmetics more without toxic side effect.Extraction under the conditions of 45-60 DEG C, high vacuum carry out
The recyclable ethanol of vacuum distillation and ethyl acetate obtain product.The grease extracted at the process conditions has the same of bioactivity
When, its antioxidation activity is low, easy oxidation deterioration.Carnosine, Tea Polyphenols and tomato red have extraordinary antioxygenic property, three
Also there is synergy in the presence of simultaneously, antioxidation activity is greatly improved.But carnosine and Tea Polyphenols do not dissolve in grease, kind
Lycopene is water insoluble, it is impossible to which three is directly added into grease, finds carnosine and Tea Polyphenols being dissolved in after water by studying, plus
The binary compound emulsifying agent for entering HLB value 5-6 monoglyceride and HLB value 12-15 nonionic polyoxyethylene monolaurate can
To promote lycopene to dissolve, add in grease and form the particulate of Water-In-Oil and dispersed, effect very well, then uses ultrasonic wave
Concussion is uniformly mixed so as to obtain the emblic nucleolus oil with antioxidation activity high bioactivity, and it contains abundant nutriment, can use
Make the matrix of cosmetics.
The content of the invention
It is an object of the invention to provide a kind of production method of the cosmetic oil based on emblic kernel, for productionization
The matrix oil of cosmetic.Supercritical CO after being pre-processed by microwave radiation technology2Fluid extraction emblic nucleolus oil, addition carnosine, tea
Polyphenol and lycopene improve antioxidation activity, obtain the active emblic nucleolus oil of antioxidation biology of functionalization.
This method by emblic kernel by drying, being crushed to after certain particle size；Add ethanol and ethyl acetate microwave is auxiliary
Pretreatment is helped, supercritical CO is used under certain process conditions afterwards2Fluid extraction vegetable oil and active ingredient, vacuum distillation are returned
Receive after ethanol and ethyl acetate, then antioxidation activity is improved using certain method addition Tea Polyphenols etc., obtain with anti-oxidant work
The emblic nucleolus oil of property high bioactivity.The major advantage of this method is supercritical CO at the process conditions2Fluid extraction
The emblic nucleolus oil of gained, bioactive substance content is high, loses small.Have after adding carnosine, Tea Polyphenols and lycopene
Good anti-oxidation characteristics, the grease produced with this method can make the matrix oil of cosmetics, contain a large amount of bioactivity and battalion
Support material.
The present invention is achieved by the following technical solutions.
A kind of production method of cosmetic oil based on emblic kernel of the present invention, as follows.
1）By emblic kernel by drying, be crushed to certain particle size.
2）Ethanol and the pretreatment of ethyl acetate microwave radiation technology.
3）Using ethanol and ethyl acetate as entrainer supercritical CO2Fluid extraction.
4）Ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Add carnosine, Tea Polyphenols and lycopene and improve anti-oxidation characteristics.
The microwave radiation technology pretreatment, refers to and is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
The supercritical CO2Fluid extraction, refers in extractor under the conditions of pressure is 20~30MPa, 45~50 DEG C of temperature
Extraction；Separated in knockout drum at pressure 3MPa~5MPa, 25~30 DEG C of temperature.
The raising inoxidizability.Refer to and carnosine and Tea Polyphenols are dissolved in distilled water, add HLB value 5-6 monoglyceride and HLB
The binary compound emulsifying agent of value 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C,
It is allowed to be completely dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the emblic nucleolus oil obtained by extraction and quickly stir, point
Uniform single-phase oily liquids is dissipated into, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease
（Mass ratio）It is not less than 0.01%, obtains the active emblic nucleolus oil of antioxidation biology of functionalization.
Its main principle steps：1. by emblic kernel by drying, be crushed to certain particle size；2. ethanol and acetic acid second
Ester microwave radiation technology is pre-processed；3. carry out supercritical CO using ethanol and ethyl acetate as entrainer in certain process conditions2Fluid extracts
Take.4. ethanol and ethyl acetate are reclaimed in vacuum distillation；5. adding carnosine, Tea Polyphenols and lycopene improves anti-oxidation characteristics.With
The major advantage of this method is supercritical CO at the process conditions2Emblic nucleolus oil obtained by fluid extraction, bioactivity
Content of material is high, loses small, adding has high anti-oxidation characteristic after carnosine, Tea Polyphenols and lycopene, improves storage phase, prevent
It is rotten.The grease of this method production can make the matrix oil of cosmetics, contain a large amount of bioactivity and nutriment.
Beneficial effects of the present invention：The present invention provides a kind of objectively high bioactivity cosmetics with antioxidation activity
With the production method of oil.This method can efficiently extract high activity emblic nucleolus oil with objective, have compared to solvent extraction
The characteristic of no solvent residue, has high anti-oxidation activity by adding composite antioxidant, can be used for cosmetic base oil
Production.
Embodiment
The present invention will be described further by following examples.
Microwave Extraction reaction system used in the embodiment of the present invention is the SOS-1100 series of products of French PR OLABO companies,
Supercritical CO2Equipment is the U.S. morning 300L type in Guangzhou.
Embodiment 1.
1）By emblic kernel by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 5-10 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then by said mixture supercritical CO2Equipment extracts 3h, extraction conditions：Pressure is 25MP in extractor
Extracted under the conditions of a, 45~50 DEG C of temperature；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）3rd）Obtained lipidic compounds are walked, are vacuumized at 40-50 DEG C, ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 30-40 DEG C, make
Be completely dissolved, above-mentioned solution is slowly added dropwise into the 3rd）Walk in the emblic nucleolus oil obtained by extraction and quickly stir, disperse
Into uniform single-phase oily liquids, mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Matter
Amount ratio）It is not less than 0.01%, obtains the active emblic nucleolus oil of antioxidation biology of functionalization.
Embodiment 2.
1）By emblic kernel by drying, be crushed to 30 mesh sieve.
2）Ethanol and ethyl acetate submergence are added, is handled 8 minutes in 2450MHz with Microwave Extraction reaction system.
3）Then said mixture is extracted into 2h, extraction conditions with supercritical CO 2 equipment：Pressure is 25MP in extractor
Extracted under the conditions of a, temperature 45 C；Separated in knockout drum at pressure 3MPa, 25 DEG C of temperature.
4）The lipidic compounds that 3) step is obtained, are vacuumized at 50 DEG C, and ethanol and ethyl acetate are reclaimed in vacuum distillation.
5）Inoxidizability will be improved.Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride and HLB value is added
The binary compound emulsifying agent of 12-15 nonionic polyoxyethylene monolaurate, adds lycopene and heats 40 DEG C, be allowed to
Fully dissolved, above-mentioned solution is slowly added dropwise into the 4th）Walk in the emblic nucleolus oil obtained by extraction and quickly stir, be dispersed into
Even single-phase oily liquids, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene total content in grease（Mass ratio）
It is not less than 0.3%, obtains the active emblic nucleolus oil of antioxidation biology of functionalization.
Claims (1)
1. a kind of production method of the cosmetic oil based on emblic kernel, it is characterized in that as follows：
（1）By emblic kernel by drying, be crushed to certain particle size；
（2）Appropriate ethanol and ethyl acetate is added in the emblic kernel of crushing, Microwave Pretreatment 3-10 minutes makes cell
Broken wall；
（3）By step（2）The mixture of gained uses supercritical CO using ethanol and ethyl acetate as entrainer2With pressure in extractor
Extracted under the conditions of 20~30MPa of power, 45~50 DEG C of temperature；Then with pressure 3MPa~4MPa, temperature in knockout drum
Separated at 25~30 DEG C；
（4）By step（3）Grease is obtained, at 45-60 DEG C, pumping high vacuum carries out vacuum distillation and reclaims removing ethanol and acetic acid second
Ester, obtains emblic nucleolus oil；
（5）Carnosine and Tea Polyphenols are dissolved in distilled water, HLB value 5-6 monoglyceride is added and the non-ionic of HLB value 12-15 is gathered
The binary compound emulsifying agent of oxygen ethene monolaurate, adds lycopene and heats 30-40 DEG C, be allowed to be completely dissolved, will be above-mentioned
Solution is slowly added dropwise into step（4）Stir in emblic nucleolus oil obtained by extraction and quickly, be dispersed into uniform single-phase oily
Liquid, is mixed with ultrasonic oscillation；Carnosine, Tea Polyphenols and the lycopene mass ratio of total content in grease are not less than 0.01%,
Obtain the active emblic nucleolus oil of antioxidation biology of functionalization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251047.9A CN107164078A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on emblic kernel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251047.9A CN107164078A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on emblic kernel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107164078A true CN107164078A (en) | 2017-09-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710251047.9A Withdrawn CN107164078A (en) | 2017-04-18 | 2017-04-18 | A kind of production method of the cosmetic oil based on emblic kernel |
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| Country | Link |
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| CN (1) | CN107164078A (en) |
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2017
- 2017-04-18 CN CN201710251047.9A patent/CN107164078A/en not_active Withdrawn
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Application publication date: 20170915 |
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