CN107142719B - A kind of textile fabric formaldehyde expellent and its preparation and application - Google Patents
A kind of textile fabric formaldehyde expellent and its preparation and application Download PDFInfo
- Publication number
- CN107142719B CN107142719B CN201710405218.9A CN201710405218A CN107142719B CN 107142719 B CN107142719 B CN 107142719B CN 201710405218 A CN201710405218 A CN 201710405218A CN 107142719 B CN107142719 B CN 107142719B
- Authority
- CN
- China
- Prior art keywords
- parts
- expellent
- textile fabric
- rectorite
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 169
- 239000004744 fabric Substances 0.000 title claims abstract description 46
- 239000004753 textile Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 230000004048 modification Effects 0.000 claims abstract description 20
- 238000012986 modification Methods 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 15
- 125000003118 aryl group Chemical group 0.000 claims abstract description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- LWFBRHSTNWMMGN-UHFFFAOYSA-N 4-phenylpyrrolidin-1-ium-2-carboxylic acid;chloride Chemical compound Cl.C1NC(C(=O)O)CC1C1=CC=CC=C1 LWFBRHSTNWMMGN-UHFFFAOYSA-N 0.000 claims abstract description 12
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- 241001062009 Indigofera Species 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 16
- 239000012153 distilled water Substances 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 12
- 239000000341 volatile oil Substances 0.000 claims description 12
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 11
- 239000000661 sodium alginate Substances 0.000 claims description 11
- 235000010413 sodium alginate Nutrition 0.000 claims description 11
- 229940005550 sodium alginate Drugs 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- 230000010355 oscillation Effects 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 claims description 6
- NKHAVTQWNUWKEO-NSCUHMNNSA-N monomethyl fumarate Chemical compound COC(=O)\C=C\C(O)=O NKHAVTQWNUWKEO-NSCUHMNNSA-N 0.000 claims description 6
- 229940005650 monomethyl fumarate Drugs 0.000 claims description 6
- 235000011449 Rosa Nutrition 0.000 claims description 5
- 241001116389 Aloe Species 0.000 claims description 4
- 235000011399 aloe vera Nutrition 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 3
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 239000010634 clove oil Substances 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- 235000011468 Albizia julibrissin Nutrition 0.000 claims description 2
- 244000111056 Chinese albizia Species 0.000 claims description 2
- AJXBTRZGLDTSST-UHFFFAOYSA-N amino 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)ON AJXBTRZGLDTSST-UHFFFAOYSA-N 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 230000005855 radiation Effects 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003463 adsorbent Substances 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 150000002460 imidazoles Chemical class 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- -1 pharmacy Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 206010011224 Cough Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003444 anaesthetic effect Effects 0.000 description 1
- 208000022531 anorexia Diseases 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 206010061428 decreased appetite Diseases 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention proposes a kind of textile fabric formaldehyde expellent and its preparations and application, the textile fabric formaldehyde expellent includes following parts by weight component: 8-14 parts of nano modification rectorite, 2-5 parts of 1- vinyl imidazole, 1-4 parts of methyl guanamines, 0.2-0.7 parts of guanylurea phosphate, 1.2-1.8 parts of antibacterial agent, 0.5-2 parts of aromatic, 0.1-0.4 parts of surfactant, 3-8 parts of polyvinyl alcohol, distill appropriate amount of water, the present invention has high-specific surface area and self-cleaning with textile fabric expellent made from technique to be reasonably formulated, 55% or more is improved compared to conventional adsorbent active carbon porosity, extension of validity 3 times or more, and with excellent antistatic, antibacterial and mouldproof, the effect of radiation protection and softening fabric, except aldehyde rate is up to 99. in 20min 2%, efficiently quickly.
Description
Technical field
The present invention relates to formaldehyde expellent technical fields, and in particular to a kind of textile fabric formaldehyde expellent and its preparation and
Using.
Background technique
Formaldehyde is a kind of colourless, gas of irritant smell, soluble easily in water, alcohol, ether.Formaldehyde has widely in the industry
Purposes.It is usually used in weaving, dyestuff, leather, resin, paint, plastics, rubber, pharmacy, explosive etc..Therefore the pollution master of formaldehyde
Product more than deriving from.Formaldehyde is mainly manifested in following aspect to the harm of human body: formaldehyde can be with the plasm of body cell
In protein combine, change protein interior structure and simultaneously solidify, kill livestock power to have.Initially stimulation eye is glutinous at low concentrations
Film stimulates the upper respiratory tract at high concentrations, causes cough, uncomfortable in chest, while neck has constriction, and mucous membrane is made to fester, Jin Er
Lung causes inflammation.It can cause appetite stimulator, anorexia, weight loss, weak, insomnia after inhaled formaldehyde；If often in contact with
It can generate to quick phenomenon, and skin histology can be caused to fester.Formaldehyde Central nervous system has anesthetic effect, especially to eyesight
There is strong toxic action.Furthermore formaldehyde can also inhereditary material in damaging cells, be suspicious carcinogen.Long Term Contact first
Aldehyde gas can cause headache, it is weak and feeble, perspire irregular, Temperature changing, pulse quickening, fash, eczema, redness etc..Therefore
Formaldehyde is classified as suspicious carcinogen and important environmental contaminants by the World Health Organization (WHO) and Environmental Protection Agency USA.
Due to consideration that the toxicity of formaldehyde, clear stipulaties are forbidden adding formaldehyde into food in China " food hygiene law ".It goes in weaving
Industry China and countries in the world government all define the limitation of formaldehyde, or formulate the environmental protection label method of textile.In recent years due to
People occupy main improvement of terms, and China has promulgated " sanitary standard of formaldehyde in indoor air "
Therefore developing and establishing the method for quick and precisely removing formaldehyde in fabric increasingly seems important.Currently, the prior art
In, such as Chinese patent CN101502748A " deodouring agent for removing formaldehyde ", provide the method and reagent for removing formaldehyde.But by
In the aqueous solution that the formula is based on removing odors, covered by removing odors and being added flavor component.And assistant concentration is not
Height, so to remove the formaldehyde of slow release on solid matter, just relatively difficult, effect will not be too stable.
Summary of the invention
In view of the above problems, the invention proposes a kind of textile fabric formaldehyde expellent and its preparation and application,
There is high-specific surface area and self-cleaning with textile fabric expellent made from technique to be reasonably formulated, compared to conventional adsorbent
Active carbon porosity improves 55% or more, 3 times or more of extension of validity, and with excellent antistatic, antibacterial and mouldproof,
The effect of radiation protection and softening fabric, 20min is interior except aldehyde rate is up to 99.2%, efficiently quickly.
In order to achieve the above purpose, the following technical solution is employed by the present invention:
A kind of textile fabric formaldehyde expellent, including following parts by weight component: 8-14 parts of nano modification rectorite, 1- second
2-5 parts of alkenyl imidazoles, 1-4 parts of methyl guanamines, 0.2-0.7 parts of guanylurea phosphate, 1.2-1.8 parts of antibacterial agent, aromatic 0.5-2
Part, 0.1-0.4 parts of surfactant, 3-8 parts of polyvinyl alcohol, distillation appropriate amount of water.
Preferably, the nano modification rectorite is specially nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, system
Standby steps are as follows: rectorite being added in the distilled water of its 10 times of quality, is placed in 75 DEG C of high-speed stirred 5min in dispersion machine, then
It is added thereto and accounts for the octadecyltrimethylammonium chloride of rectorite quality 3% and account for the mixed solution of rectorite quality 5%, after
Continuous high-speed stirred 30-40min, is freeze-dried to obtain powder；Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, ball is placed in
Ball milling ball milling 8-10h in grinding machine, after taking out drying.
Preferably, it is counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas additive amount is 1-7%, nanometer Mayan
Blue additive amount is 5-10%.
Preferably, the mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate quality hundred
Dividing content is 1-3%, and sodium carbonate mass percentage is 2-7%.
Preferably, the antibacterial agent is the monomethyl fumarate of the mass ratio of the material 0.5-0.8:1, methyl carbamate mixing
Object.
Preferably, the aromatic is Rosa Damascana, aloe essential oil, Radix Glycyrrhizae essential oil, Peppermint essential oil, clove oil, silk tree
One of peel essential oil or numerous compositions.
Preferably, the surfactant is the mixture of the lauryl glucosyl of mass ratio 2:1, alkanolamide.
Preferably, textile fabric formaldehyde expellent, preparation step are as follows: by 1- vinyl imidazole, methyl guanamines, amidine phosphate
Base urea is blended, and the distilled water of 6-7 times of three's gross mass is added thereto, then 60 DEG C of stirring 15-20min tire out nano modification
Support stone, surfactant, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto after
Continuous constant temperature oscillation handles 30-40min, and filtering is drying to obtain textile fabric formaldehyde expellent.
Preferably, textile fabric formaldehyde expellent and distilled water solution is configured to by solid-to-liquid ratio 0.5-1:10 to use.
Due to using above-mentioned technical solution, the beneficial effects of the present invention are:
1) present invention has high-specific surface area and self-cleaning with textile fabric expellent made from technique to be reasonably formulated,
Compared to conventional adsorbent active carbon porosity improve 55% or more, 3 times or more of extension of validity, and have excellent
The effect of antistatic, antibacterial and mouldproof, radiation protection and softening fabric, 20min is interior except aldehyde rate is up to 99.2%, efficiently quickly.
2) with nanometer mesoporous aluminas and the filling-modified rectorite of nanometer Mayan indigo plant intercalation, porous steric configuration is stabilized,
Rectorite uniform pore diameter degree is improved, the persistence of hole absorption is peomoted.Nanometer mesoporous aluminas large specific surface area, into
One step improves adsorbable porosity, enhances the effect of short-term quick adsorption, while having good antistatic, radiation protection
Effect；Nanometer Mayan indigo plant has good self-cleaning, and the service life of expellent can be improved while guaranteeing formaldehyde absorbing.
3) addition antibacterial agent, aromatic are conducive to improve the comprehensive performance of fabric, improve the comfort level and quality of fabric,
And antibacterial agent, aromatic, surfactant help to cooperate 1- vinyl imidazole, the nitrogen-containing heterocycle in methyl guanamines, amino, Asia
Effect is driven away in the decomposition that amino etc. improves PARA FORMALDEHYDE PRILLS(91,95), inherently removes formaldehyde.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the invention is clearly and completely described.Based on the embodiment of the present invention, the common skill in this field
Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
Embodiment 1:
A kind of textile fabric formaldehyde expellent, including following parts by weight component: 12 parts of nano modification rectorite, 1- ethylene
4 parts of base imidazoles, 2 parts of methyl guanamines, 0.6 part of guanylurea phosphate, 1.6 parts of antibacterial agent, 2 parts of aromatic, 0.3 part of surfactant,
5 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, preparation step
It is as follows: rectorite to be added in the distilled water of its 10 times of quality, be placed in 75 DEG C of high-speed stirred 5min in dispersion machine, then thereto
Addition accounts for the octadecyltrimethylammonium chloride of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, are placed in ball mill
Ball milling ball milling 8-10h, after taking out drying.It is counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas additive amount is
4%, nanometer Mayan indigo plant additive amount is 10%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein alginic acid
Sodium mass percentage is 2%, and sodium carbonate mass percentage is 5%.
Wherein, antibacterial agent is monomethyl fumarate, the methyl carbamate mixture of the mass ratio of the material 0.6:1；Aromatic
For Rosa Damascana, cortex albiziae essential oil composition；Surfactant is lauryl glucosyl, the alkanolamide of mass ratio 2:1
Mixture.
Textile fabric formaldehyde expellent preparation step is as follows: 1- vinyl imidazole, methyl guanamines, guanylurea phosphate is total
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then other surplus stocks are added thereto and continue constant temperature vibration
Processing 30-40min is swung, filtering is drying to obtain textile fabric formaldehyde expellent.
Embodiment 2:
A kind of textile fabric formaldehyde expellent, including following parts by weight component: 10 parts of nano modification rectorite, 1- ethylene
3 parts of base imidazoles, 1 part of methyl guanamines, 0.2 part of guanylurea phosphate, 1.2 parts of antibacterial agent, 1.5 parts of aromatic, surfactant 0.4
Part, 8 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, preparation step
It is as follows: rectorite to be added in the distilled water of its 10 times of quality, be placed in 75 DEG C of high-speed stirred 5min in dispersion machine, then thereto
Addition accounts for the octadecyltrimethylammonium chloride of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, are placed in ball mill
Ball milling ball milling 8-10h, after taking out drying.It is counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas additive amount is
7%, nanometer Mayan indigo plant additive amount is 8%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Mass percentage is 3%, and sodium carbonate mass percentage is 6%.
Wherein, antibacterial agent is monomethyl fumarate, the methyl carbamate mixture of the mass ratio of the material 0.8:1；Aromatic
For Rosa Damascana, aloe essential oil composition；Surfactant is the lauryl glucosyl of mass ratio 2:1, alkanolamide
Mixture.
Textile fabric formaldehyde expellent preparation step is as follows: 1- vinyl imidazole, methyl guanamines, guanylurea phosphate is total
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then other surplus stocks are added thereto and continue constant temperature vibration
Processing 30-40min is swung, filtering is drying to obtain textile fabric formaldehyde expellent.
Embodiment 3:
A kind of textile fabric formaldehyde expellent, including following parts by weight component: 8 parts of nano modification rectorite, 1- ethylene
2 parts of base imidazoles, 4 parts of methyl guanamines, 0.7 part of guanylurea phosphate, 1.5 parts of antibacterial agent, 0.5 part of aromatic, surfactant 0.2
Part, 3 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, preparation step
It is as follows: rectorite to be added in the distilled water of its 10 times of quality, be placed in 75 DEG C of high-speed stirred 5min in dispersion machine, then thereto
Addition accounts for the octadecyltrimethylammonium chloride of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, are placed in ball mill
Ball milling ball milling 8-10h, after taking out drying.It is counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas additive amount is
5%, nanometer Mayan indigo plant additive amount is 5%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Mass percentage is 1%, and sodium carbonate mass percentage is 2%.
Wherein, antibacterial agent is monomethyl fumarate, the methyl carbamate mixture of the mass ratio of the material 0.5:1；Aromatic
For aloe essential oil；Surfactant is the mixture of the lauryl glucosyl of mass ratio 2:1, alkanolamide.
Textile fabric formaldehyde expellent preparation step is as follows: 1- vinyl imidazole, methyl guanamines, guanylurea phosphate is total
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then other surplus stocks are added thereto and continue constant temperature vibration
Processing 30-40min is swung, filtering is drying to obtain textile fabric formaldehyde expellent.
Embodiment 4:
A kind of textile fabric formaldehyde expellent, including following parts by weight component: 14 parts of nano modification rectorite, 1- ethylene
5 parts of base imidazoles, 3 parts of methyl guanamines, 0.5 part of guanylurea phosphate, 1.8 parts of antibacterial agent, 1.7 parts of aromatic, surfactant 0.1
Part, 6 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, preparation step
It is as follows: rectorite to be added in the distilled water of its 10 times of quality, be placed in 75 DEG C of high-speed stirred 5min in dispersion machine, then thereto
Addition accounts for the octadecyltrimethylammonium chloride of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, are placed in ball mill
Ball milling ball milling 8-10h, after taking out drying.It is counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas additive amount is
1%, nanometer Mayan indigo plant additive amount is 6%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Mass percentage is 2%, and sodium carbonate mass percentage is 7%.
Wherein, antibacterial agent is monomethyl fumarate, the methyl carbamate mixture of the mass ratio of the material 0.6:1；Aromatic
For Rosa Damascana, Peppermint essential oil, clove oil composition；Surfactant is lauryl glucosyl, the alkane of mass ratio 2:1
The mixture of alkylolamides.
Textile fabric formaldehyde expellent preparation step is as follows: 1- vinyl imidazole, methyl guanamines, guanylurea phosphate is total
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then other surplus stocks are added thereto and continue constant temperature vibration
Processing 30-40min is swung, filtering is drying to obtain textile fabric formaldehyde expellent.
Formaldehyde expellent made from the embodiment of the present invention 1 is configured to solution (solid-to-liquid ratio 1:10), is then added
In the formaldehyde standard solution of 0.1mg/ml, under confined conditions, sufficiently oscillation mixing detects through spectrophotometer, aldehyde is removed after 10min
Rate up to after 80%, 20min remove aldehyde rate up to 99%.
Formaldehyde expellent made from the embodiment of the present invention 1 is configured to solution (solid-to-liquid ratio 1:10), by fabric to be processed
(content of formaldehyde 476.6-512.7mg/kg) is placed in solution, is cleaned fabric with clear water after immersion 20min under room temperature, is surveyed
Obtaining content of formaldehyde on fabric is 48.7-62.4mg/kg, meets national standard, and fabric carries out tracking and monitoring, 2- to treated
Content of formaldehyde is less than 5mg/kg on fabric after 2.5h.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (8)
1. a kind of textile fabric formaldehyde expellent, which is characterized in that including following parts by weight component: nano modification rectorite 8-
14 parts, 2-5 parts of 1- vinyl imidazole, 1-4 parts of methyl guanamines, 0.2-0.7 parts of guanylurea phosphate, 1.2-1.8 parts of antibacterial agent, fragrance
0.5-2 parts of agent, 0.1-0.4 parts of surfactant, 3-8 parts of polyvinyl alcohol, distillation appropriate amount of water；The nano modification rectorite is specific
For nanometer mesoporous aluminas/nanometer Mayan indigo plant property of modified rectorite, preparation step is as follows: rectorite is added to the steaming of its 10 times of quality
In distilled water, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, the octadecyl three for accounting for rectorite quality 3% is then added thereto
Ammonio methacrylate and the mixed solution for accounting for rectorite quality 5% continue high-speed stirred 30-40min, are freeze-dried to obtain powder；It will
Powder, nanometer mesoporous aluminas, nanometer Mayan indigo plant are blended, and are placed in ball milling ball milling 8-10h in ball mill, after taking out drying.
2. textile fabric formaldehyde expellent according to claim 1, it is characterised in that: it is counted by weight base unit weight of rectorite,
The nanometer mesoporous aluminas additive amount is 1-7%, and nanometer Mayan indigo plant additive amount is 5-10%.
3. textile fabric formaldehyde expellent according to claim 1, it is characterised in that: the mixed solution is sodium alginate
With the mixed aqueous solution of sodium carbonate, wherein sodium alginate mass percentage is 1-3%, and sodium carbonate mass percentage is 2-
7%.
4. textile fabric formaldehyde expellent according to claim 1, it is characterised in that: the antibacterial agent is the mass ratio of the material
Monomethyl fumarate, the methyl carbamate mixture of 0.5-0.8:1.
5. textile fabric formaldehyde expellent according to claim 1, it is characterised in that: the aromatic be Rosa Damascana,
One of aloe essential oil, Radix Glycyrrhizae essential oil, Peppermint essential oil, clove oil, silk tree peel essential oil or numerous compositions.
6. textile fabric formaldehyde expellent according to claim 1, it is characterised in that: the surfactant is mass ratio
The mixture of the lauryl glucosyl of 2:1, alkanolamide.
7. textile fabric formaldehyde expellent according to claim 1-6, which is characterized in that preparation step is as follows:
1- vinyl imidazole, methyl guanamines, guanylurea phosphate are blended, thereto the distilled water of 6-7 times of three's gross mass of addition, 60 DEG C
15-20min is stirred, is then added thereto nano modification rectorite, surfactant, polyvinyl alcohol, constant temperature oscillation 40-
60min, then other surplus stocks are added thereto and continue constant temperature oscillation processing 30-40min, filtering is drying to obtain textile fabric
Formaldehyde expellent.
8. the application of the textile fabric formaldehyde expellent as made from claim 7, it is characterised in that: by textile fabric formaldehyde
Expellent and distilled water are configured to solution by solid-to-liquid ratio 0.5-1:10 and use.
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