CN109331644A - A kind of antimicrobial form anion air purifying preparation and preparation method - Google Patents
A kind of antimicrobial form anion air purifying preparation and preparation method Download PDFInfo
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- CN109331644A CN109331644A CN201811228840.8A CN201811228840A CN109331644A CN 109331644 A CN109331644 A CN 109331644A CN 201811228840 A CN201811228840 A CN 201811228840A CN 109331644 A CN109331644 A CN 109331644A
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- air purifying
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- bamboo vinegar
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- 150000001450 anions Chemical class 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 73
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 29
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 75
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 75
- 241001330002 Bambuseae Species 0.000 claims abstract description 75
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 75
- 239000011425 bamboo Substances 0.000 claims abstract description 75
- 239000000052 vinegar Substances 0.000 claims abstract description 72
- 235000021419 vinegar Nutrition 0.000 claims abstract description 71
- 239000007788 liquid Substances 0.000 claims abstract description 41
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 40
- 239000011941 photocatalyst Substances 0.000 claims abstract description 35
- 239000000341 volatile oil Substances 0.000 claims abstract description 34
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 31
- 241000196324 Embryophyta Species 0.000 claims abstract description 31
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 25
- 238000000746 purification Methods 0.000 claims abstract description 25
- 229940105847 calamine Drugs 0.000 claims abstract description 20
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 20
- 229910052864 hemimorphite Inorganic materials 0.000 claims abstract description 20
- 239000011787 zinc oxide Substances 0.000 claims abstract description 20
- 235000014692 zinc oxide Nutrition 0.000 claims abstract description 20
- CPYIZQLXMGRKSW-UHFFFAOYSA-N zinc;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+3].[Fe+3].[Zn+2] CPYIZQLXMGRKSW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 55
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 36
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 29
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 19
- 239000003595 mist Substances 0.000 claims description 19
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 19
- 239000000843 powder Substances 0.000 claims description 18
- 229910052613 tourmaline Inorganic materials 0.000 claims description 17
- 229940070527 tourmaline Drugs 0.000 claims description 17
- 239000011032 tourmaline Substances 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 13
- 238000012545 processing Methods 0.000 claims description 12
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- 235000010216 calcium carbonate Nutrition 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000012286 potassium permanganate Substances 0.000 claims description 9
- 239000013049 sediment Substances 0.000 claims description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 7
- 239000006228 supernatant Substances 0.000 claims description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- 244000242564 Osmanthus fragrans Species 0.000 claims description 4
- 235000019083 Osmanthus fragrans Nutrition 0.000 claims description 4
- 241000220317 Rosa Species 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 3
- 240000005385 Jasminum sambac Species 0.000 claims description 3
- 240000002505 Pogostemon cablin Species 0.000 claims description 3
- 235000011751 Pogostemon cablin Nutrition 0.000 claims description 3
- 241000251468 Actinopterygii Species 0.000 claims description 2
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 241000208181 Pelargonium Species 0.000 claims description 2
- 244000178231 Rosmarinus officinalis Species 0.000 claims description 2
- 244000172533 Viola sororia Species 0.000 claims description 2
- 239000000284 extract Substances 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 12
- 230000001954 sterilising effect Effects 0.000 abstract description 12
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 9
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 35
- 239000000463 material Substances 0.000 description 13
- 229940105329 carboxymethylcellulose Drugs 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000004408 titanium dioxide Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 6
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 238000004887 air purification Methods 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229910052624 sepiolite Inorganic materials 0.000 description 2
- 235000019355 sepiolite Nutrition 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 241001116389 Aloe Species 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 241000717739 Boswellia sacra Species 0.000 description 1
- 240000007436 Cananga odorata Species 0.000 description 1
- 235000007571 Cananga odorata Nutrition 0.000 description 1
- 240000003538 Chamaemelum nobile Species 0.000 description 1
- 235000007866 Chamaemelum nobile Nutrition 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000331528 Chlorophytum capense Species 0.000 description 1
- 240000007311 Commiphora myrrha Species 0.000 description 1
- 235000006965 Commiphora myrrha Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 235000004692 Eucalyptus globulus Nutrition 0.000 description 1
- 240000007002 Eucalyptus tereticornis Species 0.000 description 1
- 235000019134 Eucalyptus tereticornis Nutrition 0.000 description 1
- 239000004863 Frankincense Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000007265 Myrrhis odorata Nutrition 0.000 description 1
- 241000896292 Odontothrips loti Species 0.000 description 1
- 240000008254 Rosa chinensis Species 0.000 description 1
- 235000000664 Rosa chinensis Nutrition 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000001139 anti-pruritic effect Effects 0.000 description 1
- 230000002155 anti-virotic effect Effects 0.000 description 1
- 239000003908 antipruritic agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 150000002628 limonene derivativess Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/2073—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental & Geological Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of antimicrobial form anion air purifying preparation and preparation methods.The air purifying preparation is made by following steps: a, preparing anion mixed liquor；B, photocatalyst mixed liquor is prepared；C, raw liquid of bamboo vinegar is subjected to purification process using calcium carbonate, calamine, active carbon；D, bamboo vinegar, anion mixed liquor, photocatalyst mixed liquor, natural plant essential oils after purification are mixed and is activated to get antimicrobial form anion air purifying preparation.The method has the advantages that the bamboo vinegar antibacterial sterilization of the present invention after purification is with better function; it is not volatile; and it is effectively combined with photocatalyst component and anion release component; with efficient sterilizing and except multi-efficiencies such as formaldehyde, release anions; raw material sources are extensive simultaneously, and cheap, environmentally protective; it, can be with large-scale production with very strong practicability.
Description
Technical field
The present invention relates to air purification fields, and in particular to the preparation of anion air purifying preparation, more particularly, to one kind
Antimicrobial form anion air purifying preparation and preparation method.
Background technique
Air purifying preparation refers to using absorption, decomposition principle possessed by natural material itself, by modern science and technology
Processing is formed by with the product eliminated pernicious gas in air, dispel various odor functions.Current air purifying preparation one
As be divided into three kinds: the first is formulated using essence, and the air purifying preparation of this method preparation can only be covered smelly with fragrance
Taste, can not decompose foul smell, and chemical component also easily causes secondary pollution.Second is formulated using pure industrial chemicals,
Although the air purifying preparation effect of this method preparation is preferable, have a single function, poor safety performance, and is not easy to transport and save.
The third is made of to be contained a large amount of biological inoculum in this air purifying preparation using biological agent, decomposed the speed of stink odor
Degree is slower, and clean-up effect is undesirable.
Bamboo vinegar is exactly a Plant Extracts, it is to collect bamboo wood in pyrolytic during bamboo wood is made charcoal
The gas of generation, and this gas is cooled down to obtained liquid substance at normal temperature.Bamboo vinegar contains nearly 300 kinds of natural polymers
Organic compound has various functions such as deodorization, fungi-proofing antivirus, antipruritic anti-inflammatory.In terms of air cleaning, by bamboo vinegar with
Photocatalyst material, anion releasable material combine, and can be made into multi-functional air purifying preparation, attract attention in recent years.
Number of patent application 201510370985.1 discloses a kind of anion, far infrared and composite functional antibiosis and sterilization agent
Preparation method, including sorting: select high-quality raw liquid of bamboo vinegar as main material, auxiliary material allotment, heat-activated processing, filling system
At: using raw liquid of bamboo vinegar as carrier, anion function material or far-infrared functional material is added, by being activated,
Functional antibiosis and sterilization agent is made, itself effect of bamboo vinegar is made full use of, and increase functional material, optimization and raising
Effect in air cleaning antibiotic and sterilizing, in terms of taste removal.
Number of patent application 201010265493.3 discloses a kind of multiple aperture carbon granule air purifying preparation and its production method, more
Aperture carbon granule air purifying preparation is by powdered carbon, concave convex rod, sepiolite, zeolite, cationic surfactant, pore creating material and bamboo vinegar system
It is standby to form.Above-mentioned multiple aperture carbon granule air purifying preparation design rationally, by powdered carbon and nanometer mineral matters attapulgite, sepiolite and
Original plant charcoal adsorption capacity is improved 5 times or more by processing by zeolite etc., the adsorption capacity of active carbon improve 2 times with
On, and increasing cationic surfactant and bamboo vinegar increases the effect of bactericidal.
Number of patent application 201710231506.7 discloses a kind of concave-convex stick air purification agent, the original including following parts by weight
Material: attapulgite modified 50 ~ 70 parts, active 40 ~ 70 parts of powdered carbon, 2 ~ 6 parts of chamomile essential oil, 2 ~ 6 parts of Cananga odorata quintessence oil, olibanum essential oil
2 ~ 6 parts, 5 ~ 10 parts of bamboo vinegar, 6 ~ 10 parts of glycerine, 8 ~ 12 parts of ethyl alcohol, 1 ~ 2 part of chitin, 6 ~ 8 parts of sodium fluoride, tartaric acid 4 ~ 5
Part, 8 ~ 10 parts of neopelex, 80% or more purity 2 ~ 12 parts of 5 ~ 10 parts of zeolite, sodium sulphate.
Number of patent application 201610372792.4 discloses a Plant Extracts air purifying preparation preparation method, by 20 ~
30 parts by weight (similarly hereinafter) bamboo vinegar, 3 ~ 5 parts of dipentenes, 3 ~ 5 parts of tea polyphenols, 5 ~ 10 parts of bracketplant folk prescription essential oils, 1 ~ 3 part of blue gum folk prescription
Essential oil, 2 ~ 4 parts of ivy folk prescription essential oils, 1 ~ 3 part of myrrh folk prescription essential oil, 2 ~ 5 parts of aloe folk prescription essential oils, 0.3 ~ 0.5 part of Chinese rose list
Square essential oil, 0.3 ~ 0.5 part of plant emulsifier Tea Saponin and 100 ~ 300 parts of deionized waters, are all added in reaction kettle, and stirring rises
Temperature keeps the temperature 1 hour to 45 ~ 50 DEG C, is naturally cooling to 40 DEG C with bottom discharge, plant extraction liquid emulsion is made；It is emulsified by 100 parts
Liquid is compounded with 5 parts of arginine, 5 parts of SODIUM PERCARBONATEs is made air purifying preparation stoste.
It can be seen that bamboo vinegar material for air purification in the prior art has a single function, and with photocatalyst material, anion
Releasable material combines the method for preparing air purifying preparation, often simply mixes raw liquid of bamboo vinegar and other components, and
Heating and filtering and obtain, the problems such as antibacterial sterilization effect is poor and volatile, cannot really play the function of bamboo vinegar antibacterial sterilization
Effect, affects the development and application of bamboo vinegar air purifying preparation.
Summary of the invention
Effectively to solve above-mentioned technical problem, the invention proposes a kind of antimicrobial form anion air purifying preparation and preparation sides
Method can effectively improve the antibacterial sterilization function of bamboo vinegar, and have photocatalysis except multi-efficiencies such as formaldehyde, release anions.
The specific technical solution of the present invention is as follows:
A kind of preparation method of antimicrobial form anion air purifying preparation, the air purifying preparation are by tourmaline micro mist, nanoscale
Titanium dioxide, lanthana, cerium oxide, sodium carboxymethylcellulose, water are mixed to form anion mixed liquor, nanometer titanium dioxide titanium valve
End, potassium permanganate, water form photocatalyst mixed liquor and calcium carbonate, calamine, activated carbon purification treated that bamboo vinegar is abundant
Mixing is activated and is made.Specific preparation step are as follows:
A, tourmaline is ground, the micro mist that partial size is 10000 mesh is obtained, with Nano titanium dioxide, lanthana, cerium oxide, carboxylic
Sodium carboxymethylcellulose pyce is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
Supernatant is obtained by filtration in the pH value of liquid, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils are uniformly mixed, and heating is activated, after filtering off sediment, i.e.,
Obtain antimicrobial form anion air purifying preparation.
Preferably, in the step a, 26 ~ 30 parts by weight of tourmaline micro mist, 2 ~ 5 parts by weight of Nano titanium dioxide, oxidation
3 ~ 6 parts by weight of lanthanum, 3 ~ 6 parts by weight of cerium oxide, 8 ~ 12 parts by weight of carboxymethyl cellulose, 41 ~ 58 parts by weight of water.
Preferably, in the step b, the mass concentration of liquor potassic permanganate is 5 ~ 10%.
Preferably, in the step b, 25 ~ 30 parts by weight of nano titanium dioxide powder, 30 ~ 45 parts by weight of water, potassium permanganate
30 ~ 40 parts by weight of solution.
Preferably, in the step c, reconciling pH value is 5 ~ 6.
Preferably, in the step c, 76 ~ 85 parts by weight of raw liquid of bamboo vinegar, 5 ~ 8 parts by weight of calcium carbonate, 4 ~ 6 weight of calamine
Measure part, 6 ~ 10 parts by weight of active carbon.
Preferably, in the step d, natural plant essential oils be sweet osmanthus, jasmine, Pogostemon cablin, rose, lavender, violet,
It extracts and obtains at least one of fish pelargonium, rosemary natural plants.
Preferably, in the step d, the temperature of activation processing is 80 ~ 85 DEG C, and the time is 30 ~ 40min.
Preferably, in the step d, 22 ~ 26 parts by weight of bamboo vinegar after purification, 14 ~ 30 parts by weight of water, anion mixing
20 ~ 23 parts by weight of liquid, 18 ~ 22 parts by weight of photocatalyst mixed liquor, 10 ~ 15 parts by weight of natural plant essential oils.
Bamboo vinegar is a kind of liquid mixture that constituent is considerably complicated, mainly by water, organic acid, phenols, ketone, alcohol
The material compositions such as class have broad spectrum antibacterial, but since it is with highly acid and multiple harmful substances, cannot be directly used to human body
Surface limits its application on daily cleaning health field, is only used for the cleaning deodorization of feed lot at present.And by bamboo vinegar
The plain ingredient of bamboo jade-like stone purified by rectifying, has broad spectrum antibacterial, to humans and animals safety, the scope of application is wider.This hair
It is bright that calamine and calcium carbonate is added in bamboo-vinegar, then adjust pH value with alkali, bamboo jade-like stone element can be obtained, further using active carbon into
Row is de-tasted except color, is obtained the bamboo vinegar of polishing purification, is significantly enhanced the antibacterial sterilization function of bamboo vinegar.
Above content of the present invention also proposes a kind of antimicrobial form anion air purifying preparation, is made by following steps: a, will be electric
Gas stone micro mist, Nano titanium dioxide, lanthana, cerium oxide, sodium carboxymethylcellulose are added to the water to form anion mixed liquor；
B, nano titanium dioxide powder, liquor potassic permanganate are added to the water and are mixed to prepare photocatalyst mixed liquor；C, by raw liquid of bamboo vinegar
Purification process is carried out using calcium carbonate, calamine, active carbon；D, bamboo vinegar, the anion made from step c after purification are mixed
Liquid, photocatalyst mixed liquor, natural plant essential oils are mixed and are activated, and filter out sediment to obtain the final product.
The invention has the benefit that
1. antimicrobial form anion air will be mixed with anion liquid, photocatalyst liquid after raw liquid of bamboo vinegar purifying purification by proposing
The method of cleanser.
2. by the present invention in that being handled with calcium carbonate and calamine raw liquid of bamboo vinegar, and utilizing bicarbonate soda
Liquid carries out the adjusting of pH value, achievees the purpose that raw liquid of bamboo vinegar polishing purification, so that bamboo vinegar antibacterial sterilization function after purification
Can be stronger, it is not volatile.
3. the purifying bamboo vinegar, photocatalyst component and anion release component in air purifying preparation prepared by the present invention are effective
In conjunction with efficient sterilizing and except multi-efficiencies such as formaldehyde, release anions.
4. air purifying preparation prepared by the present invention, raw material sources are extensive, and cheap, environmentally protective, have very strong practical
Property, it can be with large-scale production.
Specific embodiment
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 28 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
3 parts by weight of titanium, 4 parts by weight of lanthana, 5 parts by weight of cerium oxide, 9 parts by weight of carboxymethyl cellulose, 51 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 27 parts by weight of nano titanium dioxide powder, 39 parts by weight of water, 34 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 7%；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
The pH value of liquid is 5.5, and supernatant is obtained by filtration, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；Its
In, 81 parts by weight of raw liquid of bamboo vinegar, 7 parts by weight of calcium carbonate, 5 parts by weight of calamine, 7 parts by weight of active carbon；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation, wherein 25 parts by weight of bamboo vinegar, 22 parts by weight of water, anion mixed liquor 21 after purification
Parts by weight, 19 parts by weight of photocatalyst mixed liquor, 14 parts by weight of natural plant essential oils；Natural plant essential oils are to extract in sweet osmanthus
It arrives；The temperature of activation processing is 83 DEG C, time 34min.
Embodiment 2
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 26 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
2 parts by weight of titanium, 3 parts by weight of lanthana, 3 parts by weight of cerium oxide, 8 parts by weight of carboxymethyl cellulose, 58 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 25 parts by weight of nano titanium dioxide powder, 45 parts by weight of water, 30 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 5%；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
The pH value of liquid is 5, and supernatant is obtained by filtration, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；Wherein,
85 parts by weight of raw liquid of bamboo vinegar, 5 parts by weight of calcium carbonate, 4 parts by weight of calamine, 6 parts by weight of active carbon；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation；Wherein, after purification 22 parts by weight of bamboo vinegar, 30 parts by weight of water, anion mixed liquor 20
Parts by weight, 18 parts by weight of photocatalyst mixed liquor, 10 parts by weight of natural plant essential oils；Natural plant essential oils are to extract in jasmine
It arrives；The temperature of activation processing is 80 DEG C, time 40min.
Embodiment 3
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 30 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
5 parts by weight of titanium, 6 parts by weight of lanthana, 6 parts by weight of cerium oxide, 12 parts by weight of carboxymethyl cellulose, 41 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 30 parts by weight of nano titanium dioxide powder, 30 parts by weight of water, 40 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 10%；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
The pH value of liquid is 6, and supernatant is obtained by filtration, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；Wherein,
76 parts by weight of raw liquid of bamboo vinegar, 8 parts by weight of calcium carbonate, 6 parts by weight of calamine, 10 parts by weight of active carbon；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation；Wherein, after purification 26 parts by weight of bamboo vinegar, 14 parts by weight of water, anion mixed liquor 23
Parts by weight, 22 parts by weight of photocatalyst mixed liquor, 15 parts by weight of natural plant essential oils；Natural plant essential oils are to extract in Pogostemon cablin
It arrives；The temperature of activation processing is 85 DEG C, time 30min.
Embodiment 4
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 27 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
3 parts by weight of titanium, 4 parts by weight of lanthana, 4 parts by weight of cerium oxide, 9 parts by weight of carboxymethyl cellulose, 53 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 26 parts by weight of nano titanium dioxide powder, 41 parts by weight of water, 33 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 6%；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
The pH value of liquid is 5, and supernatant is obtained by filtration, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；Wherein,
82 parts by weight of raw liquid of bamboo vinegar, 6 parts by weight of calcium carbonate, 5 parts by weight of calamine, 7 parts by weight of active carbon；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation；Wherein, after purification 23 parts by weight of bamboo vinegar, 26 parts by weight of water, anion mixed liquor 21
Parts by weight, 19 parts by weight of photocatalyst mixed liquor, 11 parts by weight of natural plant essential oils；Natural plant essential oils are to extract in rose
It arrives；The temperature of activation processing is 81 DEG C, time 38min.
Embodiment 5
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 29 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
4 parts by weight of titanium, 5 parts by weight of lanthana, 5 parts by weight of cerium oxide, 11 parts by weight of carboxymethyl cellulose, 46 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 29 parts by weight of nano titanium dioxide powder, 33 parts by weight of water, 38 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 9%；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
The pH value of liquid is 6, and supernatant is obtained by filtration, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；Wherein,
78 parts by weight of raw liquid of bamboo vinegar, 7 parts by weight of calcium carbonate, 6 parts by weight of calamine, 9 parts by weight of active carbon；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation；Wherein, after purification 25 parts by weight of bamboo vinegar, 18 parts by weight of water, anion mixed liquor 22
Parts by weight, 21 parts by weight of photocatalyst mixed liquor, 14 parts by weight of natural plant essential oils；Natural plant essential oils are to extract in rose
It arrives；The temperature of activation processing is 84 DEG C, time 32min.
Comparative example 1
A, tourmaline is ground to the micro mist of 10000 mesh, with Nano titanium dioxide, lanthana, cerium oxide, carboxymethyl cellulose
Sodium is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；Wherein, 28 parts by weight of tourmaline micro mist, nanoscale titanium dioxide
3 parts by weight of titanium, 4 parts by weight of lanthana, 5 parts by weight of cerium oxide, 9 parts by weight of carboxymethyl cellulose, 51 parts by weight of water；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；Wherein, 27 parts by weight of nano titanium dioxide powder, 39 parts by weight of water, 34 parts by weight of liquor potassic permanganate；Potassium permanganate
The mass concentration of solution is 7%；
C, active carbon is added to raw liquid of bamboo vinegar and is mixed, filter, the bamboo vinegar of refinement treatment is made；Wherein, bamboo vinegar
93 parts by weight of activated carbon of stoste, 9 parts by weight；
D, the bamboo vinegar of refinement treatment made from step c is added to the water uniformly mixed, is mixed with anion made from step a
Photocatalyst mixed liquor made from liquid, step b, natural plant essential oils are uniformly mixed, and heating is activated, and filter out sediment,
Up to antimicrobial form anion air purifying preparation；Wherein, 25 parts by weight of bamboo vinegar of refinement treatment, 22 parts by weight of water, anion are mixed
Close 21 parts by weight of liquid, 19 parts by weight of photocatalyst mixed liquor, 14 parts by weight of natural plant essential oils；Natural plant essential oils are to mention in sweet osmanthus
It obtains；The temperature of activation processing is 83 DEG C, time 34min.
Air purifying preparation made from above-described embodiment 1 ~ 5 and comparative example 1, test its antibacterial circle diameter, formaldehyde removal rate and
Anion burst size, method or the condition for testing characterization are as follows:
Antibacterial circle diameter (anti-microbial property): measuring the anti-microbial property of air purifying preparation produced by the present invention using Odontothrips loti, choosing
Escherichia coli, staphylococcus aureus and saccharomyces cerevisiae are selected as test strain, is 10 according to standard method preparation concentration6cfu/
Solid medium is poured into the culture dish that diameter is 15cm respectively by the bacteria suspension of mL, and after to be solidified, 0.5mL bacteria suspension is added,
It is uneven using sterile coating rod figure, then the Oxford cup of sterilization treatment is placed on the primary surface of solid culture containing bacterium, it instils in cup
200 μ L of air purifying preparation produced by the present invention, then bacterium is cultivated for 24 hours at 37 DEG C, and fungi cultivates 48h at 30 DEG C, takes out
After measure antibacterial circle diameter.
Formaldehyde removal rate: in 1m3Closed Laboratory Module in carry out that formaldehyde is taken to test, take 36% formalin 0.5ml to instill
On fritter filter paper, then filter paper is put into a polyethylene pipe to (formaldehyde instrument measurement pipe), is inserted into from thieff hatch, opens electric fan and purple
Outer light lamp tube blows 10 ~ 15min of polyethylene pipe with hair dryer, observes concentration of formaldehyde with formaldehyde direct-reading instrument, reaches about to concentration
Stop when 0.65ppm or so, stablize about 15 ~ 20min, close electric fan, measures concentration in cabin, it is initially dense as formaldehyde at this time
Degree, formaldehyde measurement use U.S. Inter-scan4160 type Formaldehyde analyzer, are then placed in 5mL air cleaning produced by the present invention
Agent tests concentration of formaldehyde when 6h and 12h, and utilizes the ratio calculation formaldehyde removal rate of concentration difference and initial concentration.
Anion burst size: taking 10mL air purifying preparation produced by the present invention, is 25 DEG C in temperature, relative humidity 55%
Under tested, using daily output COM-3010PRO anionic textiles instrument, constantly test and the anion for recording different distance be average
Concentration measures and calculates the anion burst size of anion air purifying preparation produced by the present invention after complete equipilibrium.
The results are shown in Table 1.
Table 1:
Claims (10)
1. a kind of preparation method of antimicrobial form anion air purifying preparation, it is characterised in that: the air purifying preparation is will be electrical
Stone micro mist, Nano titanium dioxide, lanthana, cerium oxide, sodium carboxymethylcellulose, water are mixed to form anion mixed liquor, receive
After rice titania powder, potassium permanganate, water form photocatalyst mixed liquor and calcium carbonate, calamine, activated carbon purification processing
Bamboo vinegar be sufficiently mixed, be activated and be made；Specific preparation step are as follows:
A, tourmaline is ground, the micro mist that partial size is 10000 mesh is obtained, with Nano titanium dioxide, lanthana, cerium oxide, carboxylic
Sodium carboxymethylcellulose pyce is added to the water, and high-speed stirred is uniform, forms anion mixed liquor；
B, it after nano titanium dioxide powder being added to the water mixing dispersion, is uniformly mixed with liquor potassic permanganate, photocatalyst is made
Mixed liquor；
C, raw liquid of bamboo vinegar, calcium carbonate and calamine are added in reactor, are uniformly mixed, it is molten that sodium bicarbonate adjusting is added
Supernatant is obtained by filtration in the pH value of liquid, and active carbon is added and is mixed, filters, the bamboo vinegar of purifying is made；
D, the bamboo vinegar made from step c after purification is added to the water it is uniformly mixed, with anion mixed liquor made from step a,
Photocatalyst mixed liquor made from step b, natural plant essential oils be uniformly mixed, heating be activated, filter out sediment to get
Antimicrobial form anion air purifying preparation.
2. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid a, 26 ~ 30 parts by weight of tourmaline micro mist, 2 ~ 5 parts by weight of Nano titanium dioxide, 3 ~ 6 parts by weight of lanthana, cerium oxide 3 ~ 6
Parts by weight, 8 ~ 12 parts by weight of carboxymethyl cellulose, 41 ~ 58 parts by weight of water.
3. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid b, the mass concentration of liquor potassic permanganate is 5 ~ 10%.
4. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid b, 25 ~ 30 parts by weight of nano titanium dioxide powder, 30 ~ 45 parts by weight of water, 30 ~ 40 parts by weight of liquor potassic permanganate.
5. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid c, reconciling pH value is 5 ~ 6.
6. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid c, 76 ~ 85 parts by weight of raw liquid of bamboo vinegar, 5 ~ 8 parts by weight of calcium carbonate, 4 ~ 6 parts by weight of calamine, 6 ~ 10 parts by weight of active carbon.
7. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid d, natural plant essential oils be sweet osmanthus, jasmine, Pogostemon cablin, rose, lavender, violet, fish pelargonium, in rosemary at least
It extracts and obtains in a kind of natural plants.
8. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid d, the temperature of activation processing is 80 ~ 85 DEG C, and the time is 30 ~ 40min.
9. a kind of preparation method of antimicrobial form anion air purifying preparation according to claim 1, it is characterised in that: the step
In rapid d, 22 ~ 26 parts by weight of bamboo vinegar, 14 ~ 30 parts by weight of water, 20 ~ 23 parts by weight of anion mixed liquor, photocatalyst after purification
18 ~ 22 parts by weight of mixed liquor, 10 ~ 15 parts by weight of natural plant essential oils.
10. a kind of antimicrobial form anion air purifying preparation that any one of claim 1 ~ 9 the method is prepared.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109999609A (en) * | 2019-02-28 | 2019-07-12 | 濮阳宏业环保新材料股份有限公司 | A kind of composition, preparation method and application removing formaldehyde |
| CN110756029A (en) * | 2019-10-31 | 2020-02-07 | 芜湖春天里环保科技有限公司 | Macromolecule formaldehyde decomposer based on titanium dioxide and preparation method thereof |
| CN112246083A (en) * | 2020-09-04 | 2021-01-22 | 秦立新 | Negative oxygen ion air purifying agent, and preparation method and application thereof |
| CN112844004A (en) * | 2019-11-27 | 2021-05-28 | 湖南尚鑫新材料科技有限公司 | Spray type air purifying agent and preparation method thereof |
| CN113546206A (en) * | 2021-08-18 | 2021-10-26 | 孙中宝 | Method for preparing liquid capable of releasing far infrared rays, bioelectricity and negative oxygen ions |
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2018
- 2018-10-22 CN CN201811228840.8A patent/CN109331644A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109999609A (en) * | 2019-02-28 | 2019-07-12 | 濮阳宏业环保新材料股份有限公司 | A kind of composition, preparation method and application removing formaldehyde |
| CN110756029A (en) * | 2019-10-31 | 2020-02-07 | 芜湖春天里环保科技有限公司 | Macromolecule formaldehyde decomposer based on titanium dioxide and preparation method thereof |
| CN112844004A (en) * | 2019-11-27 | 2021-05-28 | 湖南尚鑫新材料科技有限公司 | Spray type air purifying agent and preparation method thereof |
| CN112246083A (en) * | 2020-09-04 | 2021-01-22 | 秦立新 | Negative oxygen ion air purifying agent, and preparation method and application thereof |
| CN113546206A (en) * | 2021-08-18 | 2021-10-26 | 孙中宝 | Method for preparing liquid capable of releasing far infrared rays, bioelectricity and negative oxygen ions |
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Application publication date: 20190215 |