CN107142719A - A kind of weaving face fabric formaldehyde expellent and its preparation and application - Google Patents
A kind of weaving face fabric formaldehyde expellent and its preparation and application Download PDFInfo
- Publication number
- CN107142719A CN107142719A CN201710405218.9A CN201710405218A CN107142719A CN 107142719 A CN107142719 A CN 107142719A CN 201710405218 A CN201710405218 A CN 201710405218A CN 107142719 A CN107142719 A CN 107142719A
- Authority
- CN
- China
- Prior art keywords
- parts
- expellent
- face fabric
- weaving face
- rectorite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 172
- 239000004744 fabric Substances 0.000 title claims abstract description 47
- 238000009941 weaving Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 230000004048 modification Effects 0.000 claims abstract description 20
- 238000012986 modification Methods 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 15
- 125000003118 aryl group Chemical group 0.000 claims abstract description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 13
- LWFBRHSTNWMMGN-UHFFFAOYSA-N 4-phenylpyrrolidin-1-ium-2-carboxylic acid;chloride Chemical compound Cl.C1NC(C(=O)O)CC1C1=CC=CC=C1 LWFBRHSTNWMMGN-UHFFFAOYSA-N 0.000 claims abstract description 12
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- 239000012153 distilled water Substances 0.000 claims description 14
- 241001062009 Indigofera Species 0.000 claims description 12
- 238000000498 ball milling Methods 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 12
- 239000000341 volatile oil Substances 0.000 claims description 12
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 11
- 239000000661 sodium alginate Substances 0.000 claims description 11
- 235000010413 sodium alginate Nutrition 0.000 claims description 11
- 229940005550 sodium alginate Drugs 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 8
- 230000010355 oscillation Effects 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 claims description 6
- NKHAVTQWNUWKEO-NSCUHMNNSA-N monomethyl fumarate Chemical compound COC(=O)\C=C\C(O)=O NKHAVTQWNUWKEO-NSCUHMNNSA-N 0.000 claims description 6
- 229940005650 monomethyl fumarate Drugs 0.000 claims description 6
- 235000011449 Rosa Nutrition 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 241001116389 Aloe Species 0.000 claims description 4
- 235000011399 aloe vera Nutrition 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 3
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 239000010634 clove oil Substances 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- 235000011468 Albizia julibrissin Nutrition 0.000 claims description 2
- 244000111056 Chinese albizia Species 0.000 claims description 2
- AJXBTRZGLDTSST-UHFFFAOYSA-N amino 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)ON AJXBTRZGLDTSST-UHFFFAOYSA-N 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 230000005855 radiation Effects 0.000 abstract description 4
- 239000003463 adsorbent Substances 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 4
- 150000002460 imidazoles Chemical class 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- -1 pharmacy Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 206010011224 Cough Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000003444 anaesthetic effect Effects 0.000 description 1
- 208000022531 anorexia Diseases 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 206010061428 decreased appetite Diseases 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000003805 vibration mixing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention proposes a kind of weaving face fabric formaldehyde expellent and its preparation and application, and the weaving face fabric formaldehyde expellent includes following parts by weight component：8 14 parts of nano modification rectorite, 125 parts of vinyl imidazole, 14 parts of methyl guanamines, 0.2 0.7 parts of guanylurea phosphate, 1.2 1.8 parts of antiseptic, 0.5 2 parts of aromatic, 0.1 0.4 parts of surfactant, 38 parts of polyvinyl alcohol, distill appropriate amount of water, the present invention has high-specific surface area and self-cleaning with rational be formulated with weaving face fabric expellent made from technique, more than 55% is improved compared to conventional adsorbent activated carbon porosity, extension of validity more than 3 times, and with excellent antistatic, antibacterial and mouldproof, radiation proof and effect of softening fabric, except aldehyde rate is up to 99.2% in 20min, it is efficiently quick.
Description
Technical field
The present invention relates to formaldehyde expellent technical field, and in particular to a kind of weaving face fabric formaldehyde expellent and its prepare and
Using.
Background technology
Formaldehyde is a kind of colourless, gas of irritant smell, soluble in water, alcohol, ether.Formaldehyde has widely in the industry
Purposes.It is usually used in weaving, dyestuff, leather, resin, paint, plastics, rubber, pharmacy, explosive etc..Therefore the pollution master of formaldehyde
To derive from the product of the above.Harm of the formaldehyde to human body is mainly manifested in following aspect：Formaldehyde can be with body cell plasm
In protein combine, change protein interior structure and simultaneously solidify, so that with killing livestock power.Initially eye is stimulated to stick at low concentrations
Film, the upper respiratory tract is stimulated in high concentration, causes cough, uncomfortable in chest, while neck has constriction, and mucous membrane is festered, Jin Er
Lung causes inflammation.Anorexia, apocleisis, weight loss, weak, insomnia can be caused after inhaled formaldehyde；If often in contact with
It can produce to quick phenomenon, and skin histology can be caused to fester.Formaldehyde Central nervous system has anesthetic effect, especially to eyesight
There is strong toxic action.In addition the inhereditary material that formaldehyde can also be in damaging cells, is suspicious carcinogen.Long Term Contact first
Aldehyde gas can cause headache, it is weak and feeble, perspire irregular, Temperature changing, pulse quickening, fash, eczema, redness etc..Therefore
Formaldehyde is classified as suspicious carcinogen and important environmental contaminants by the World Health Organization (WHO) and Environmental Protection Agency USA.
Due to consideration that the toxicity of formaldehyde, China《Food hygiene law》Middle clear stipulaties are forbidden adding formaldehyde into food.In weaving row
Industry China and countries in the world government all define the limitation of formaldehyde, or formulate the environmental protection label method of textile.In the last few years due to
People occupy main improvement of terms, and China has promulgated《The sanitary standard of formaldehyde in indoor air》
Therefore the method for developing and setting up formaldehyde in quick and precisely removal fabric increasingly seems important.At present, prior art
In, there is provided the method and reagent for removing formaldehyde by such as Chinese patent CN101502748A " deodouring agent for removing formaldehyde ".But, by
It is the aqueous solution based on going to eliminate the unusual smell in the formula, is covered by going to eliminate the unusual smell and adding flavor component.And assistant concentration is not
Height, so to remove the formaldehyde slowly discharged on solid matter, just relatively difficult, effect also will not be too stable.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of weaving face fabric formaldehyde expellent and its preparation and application,
There is high-specific surface area and self-cleaning with weaving face fabric expellent made from technique with rational be formulated, compared to conventional adsorbent
Activated carbon porosity improves more than 55%, more than 3 times of extension of validity, and with excellent antistatic, antibacterial and mouldproof,
It is efficiently quick except aldehyde rate is up to 99.2% in radiation proof and effect of softening fabric, 20min.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of weaving face fabric formaldehyde expellent, including following parts by weight component：8-14 parts of nano modification rectorite, 1- second
2-5 parts of alkenyl imidazoles, 1-4 parts of methyl guanamines, 0.2-0.7 parts of guanylurea phosphate, 1.2-1.8 parts of antiseptic, aromatic 0.5-2
Part, 0.1-0.4 parts of surfactant, 3-8 parts of polyvinyl alcohol, distillation appropriate amount of water.
It is preferred that, the nano modification rectorite is specially the blue property of modified rectorite in a nanometer mesoporous aluminas/nanometer Mayan, system
Standby step is as follows：In the distilled water that rectorite is added to its 10 times of quality, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, then
Add thereto and account for the OTAC of rectorite quality 3% and account for the mixed solution of rectorite quality 5%, after
Continuous high-speed stirred 30-40min, is freeze-dried to obtain powder；By powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan, ball is placed in
Ball milling ball milling 8-10h in grinding machine, takes out after drying.
It is preferred that, counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas addition is 1-7%, nanometer Mayan
Blue addition is 5-10%.
It is preferred that, the mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate quality hundred
It is 1-3% to divide content, and sodium carbonate weight/mass percentage composition is 2-7%.
It is preferred that, the antiseptic compares 0.5-0.8 for the amount of material:1 monomethyl fumarate, methyl carbamate mixing
Thing.
It is preferred that, the aromatic is Rosa Damascana, aloe essential oil, radix glycyrrhizae essential oil, Peppermint essential oil, clove oil, silk tree
One or more compositions in peel essential oil.
It is preferred that, the surfactant is mass ratio 2:1 lauryl glucosyl, the mixture of alkanolamide.
It is preferred that, weaving face fabric formaldehyde expellent, preparation process is as follows：By 1- vinyl imidazoles, methyl guanamines, amidine phosphate
Base urea is blended, and the distilled water of 6-7 times of three's gross mass is added thereto, and then 60 DEG C of stirring 15-20min tire out nano modification
Support stone, surfactant, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto after
Continuous constant temperature oscillation processing 30-40min, filtering is drying to obtain weaving face fabric formaldehyde expellent.
It is preferred that, weaving face fabric formaldehyde expellent and distilled water are pressed into solid-to-liquid ratio 0.5-1:10, which are configured to solution, uses.
Due to using above-mentioned technical scheme, the beneficial effects of the invention are as follows：
1) present invention has high-specific surface area and self-cleaning with rational be formulated with weaving face fabric expellent made from technique,
Compared to conventional adsorbent activated carbon porosity improve more than 55%, more than 3 times of extension of validity, and with excellent
It is efficiently quick except aldehyde rate is up to 99.2% in effect of antistatic, antibacterial and mouldproof, radiation proof and softening fabric, 20min.
2) with the filling-modified rectorite of the blue intercalation of nanometer mesoporous aluminas and nanometer Mayan, porous steric configuration is stabilized,
Rectorite uniform pore diameter degree is improved, the persistence of hole absorption is helped lend some impetus to.Nanometer mesoporous aluminas specific surface area is big, enters
One step improves adsorbable porosity, enhances the effect of short-term quick adsorption, while having good antistatic, radiation proof
Effect；Nanometer Mayan indigo plant has good self-cleaning, and the usage cycles of expellent can be improved while formaldehyde absorbing is ensured.
3) addition antiseptic, aromatic are conducive to improving the combination property of fabric, improve the comfort level and quality of fabric,
And antiseptic, aromatic, surfactant help to coordinate 1- vinyl imidazoles, the nitrogen heterocyclic ring in methyl guanamines, amino, Asia
Effect is driven away in the decomposition that amino etc. improves PARA FORMALDEHYDE PRILLS(91,95), inherently removes formaldehyde.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
Embodiment 1：
A kind of weaving face fabric formaldehyde expellent, including following parts by weight component：12 parts of nano modification rectorite, 1- ethene
4 parts of base imidazoles, 2 parts of methyl guanamines, 0.6 part of guanylurea phosphate, 1.6 parts of antiseptic, 2 parts of aromatic, 0.3 part of surfactant,
5 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially the blue property of modified rectorite in a nanometer mesoporous aluminas/nanometer Mayan, preparation process
It is as follows：In the distilled water that rectorite is added to its 10 times of quality, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, then thereto
Addition accounts for the OTAC of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues at a high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan are placed in ball mill
Ball milling ball milling 8-10h, takes out after drying.Counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas addition is
4%, nanometer Mayan indigo plant addition is 10%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein alginic acid
Sodium weight/mass percentage composition is 2%, and sodium carbonate weight/mass percentage composition is 5%.
Wherein, antiseptic compares 0.6 for the amount of material:1 monomethyl fumarate, methyl carbamate mixture；Aromatic
For Rosa Damascana, cortex albiziae essential oil composition；Surfactant is mass ratio 2:1 lauryl glucosyl, alkanolamide
Mixture.
Weaving face fabric formaldehyde expellent preparation process is as follows：1- vinyl imidazoles, methyl guanamines, guanylurea phosphate is common
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto continuation constant temperature shake
Processing 30-40min is swung, filtering is drying to obtain weaving face fabric formaldehyde expellent.
Embodiment 2：
A kind of weaving face fabric formaldehyde expellent, including following parts by weight component：10 parts of nano modification rectorite, 1- ethene
3 parts of base imidazoles, 1 part of methyl guanamines, 0.2 part of guanylurea phosphate, 1.2 parts of antiseptic, 1.5 parts of aromatic, surfactant 0.4
Part, 8 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially the blue property of modified rectorite in a nanometer mesoporous aluminas/nanometer Mayan, preparation process
It is as follows：In the distilled water that rectorite is added to its 10 times of quality, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, then thereto
Addition accounts for the OTAC of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues at a high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan are placed in ball mill
Ball milling ball milling 8-10h, takes out after drying.Counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas addition is
7%, nanometer Mayan indigo plant addition is 8%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Weight/mass percentage composition is 3%, and sodium carbonate weight/mass percentage composition is 6%.
Wherein, antiseptic compares 0.8 for the amount of material:1 monomethyl fumarate, methyl carbamate mixture；Aromatic
For Rosa Damascana, aloe essential oil composition；Surfactant is mass ratio 2:1 lauryl glucosyl, alkanolamide
Mixture.
Weaving face fabric formaldehyde expellent preparation process is as follows：1- vinyl imidazoles, methyl guanamines, guanylurea phosphate is common
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto continuation constant temperature shake
Processing 30-40min is swung, filtering is drying to obtain weaving face fabric formaldehyde expellent.
Embodiment 3：
A kind of weaving face fabric formaldehyde expellent, including following parts by weight component：8 parts of nano modification rectorite, 1- ethene
2 parts of base imidazoles, 4 parts of methyl guanamines, 0.7 part of guanylurea phosphate, 1.5 parts of antiseptic, 0.5 part of aromatic, surfactant 0.2
Part, 3 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially the blue property of modified rectorite in a nanometer mesoporous aluminas/nanometer Mayan, preparation process
It is as follows：In the distilled water that rectorite is added to its 10 times of quality, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, then thereto
Addition accounts for the OTAC of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues at a high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan are placed in ball mill
Ball milling ball milling 8-10h, takes out after drying.Counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas addition is
5%, nanometer Mayan indigo plant addition is 5%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Weight/mass percentage composition is 1%, and sodium carbonate weight/mass percentage composition is 2%.
Wherein, antiseptic compares 0.5 for the amount of material:1 monomethyl fumarate, methyl carbamate mixture；Aromatic
For aloe essential oil；Surfactant is mass ratio 2:1 lauryl glucosyl, the mixture of alkanolamide.
Weaving face fabric formaldehyde expellent preparation process is as follows：1- vinyl imidazoles, methyl guanamines, guanylurea phosphate is common
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto continuation constant temperature shake
Processing 30-40min is swung, filtering is drying to obtain weaving face fabric formaldehyde expellent.
Embodiment 4：
A kind of weaving face fabric formaldehyde expellent, including following parts by weight component：14 parts of nano modification rectorite, 1- ethene
5 parts of base imidazoles, 3 parts of methyl guanamines, 0.5 part of guanylurea phosphate, 1.8 parts of antiseptic, 1.7 parts of aromatic, surfactant 0.1
Part, 6 parts of polyvinyl alcohol, distillation appropriate amount of water.
Wherein, nano modification rectorite is specially the blue property of modified rectorite in a nanometer mesoporous aluminas/nanometer Mayan, preparation process
It is as follows：In the distilled water that rectorite is added to its 10 times of quality, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, then thereto
Addition accounts for the OTAC of rectorite quality 3% and accounts for the mixed solution of rectorite quality 5%, continues at a high speed
30-40min is stirred, powder is freeze-dried to obtain；Powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan are placed in ball mill
Ball milling ball milling 8-10h, takes out after drying.Counted by weight base unit weight of rectorite, the nanometer mesoporous aluminas addition is
1%, nanometer Mayan indigo plant addition is 6%；Mixed solution is sodium alginate and sodium carbonate and mixed aqueous solution, wherein sodium alginate
Weight/mass percentage composition is 2%, and sodium carbonate weight/mass percentage composition is 7%.
Wherein, antiseptic compares 0.6 for the amount of material:1 monomethyl fumarate, methyl carbamate mixture；Aromatic
For Rosa Damascana, Peppermint essential oil, clove oil composition；Surfactant is mass ratio 2:1 lauryl glucosyl, alkane
The mixture of alkylolamides.
Weaving face fabric formaldehyde expellent preparation process is as follows：1- vinyl imidazoles, methyl guanamines, guanylurea phosphate is common
It is mixed, the distilled water of 6-7 times of three's gross mass, 60 DEG C of stirring 15-20min, then by nano modification rectorite, table are added thereto
Face activating agent, polyvinyl alcohol are added thereto, constant temperature oscillation 40-60min, then by other surplus stocks be added thereto continuation constant temperature shake
Processing 30-40min is swung, filtering is drying to obtain weaving face fabric formaldehyde expellent.
Formaldehyde expellent made from the embodiment of the present invention 1 is configured into solution, and (solid-to-liquid ratio is 1:10), then add
In 0.1mg/ml formaldehyde standard liquid, under confined conditions, fully vibration mixing detects through spectrophotometer, aldehyde is removed after 10min
Rate up to after 80%, 20min except aldehyde rate up to 99%.
Formaldehyde expellent made from the embodiment of the present invention 1 is configured into solution, and (solid-to-liquid ratio is 1:10), by pending fabric
(content of formaldehyde is 476.6-512.7mg/kg) is placed in solution, is soaked after 20min with the clean fabric of clear water, is surveyed under room temperature condition
It is 48.7-62.4mg/kg to obtain content of formaldehyde on fabric, meets national standard, and be tracked monitoring, 2- to the fabric after processing
Content of formaldehyde is less than 5mg/kg on fabric after 2.5h.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic；And these modification or
Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (9)
1. a kind of weaving face fabric formaldehyde expellent, it is characterised in that including following parts by weight component：Nano modification rectorite 8-
14 parts, 2-5 parts of 1- vinyl imidazoles, 1-4 parts of methyl guanamines, 0.2-0.7 parts of guanylurea phosphate, 1.2-1.8 parts of antiseptic, fragrance
0.5-2 parts of agent, 0.1-0.4 parts of surfactant, 3-8 parts of polyvinyl alcohol, distillation appropriate amount of water.
2. weaving face fabric formaldehyde expellent according to claim 1, it is characterised in that the nano modification rectorite is specific
For the blue property of modified rectorite of nanometer mesoporous aluminas/nanometer Mayan, preparation process is as follows：Rectorite is added to the steaming of its 10 times of quality
In distilled water, 75 DEG C of high-speed stirred 5min in dispersion machine are placed in, the octadecyl three for accounting for rectorite quality 3% is then added thereto
Ammonio methacrylate and the mixed solution for accounting for rectorite quality 5%, continue high-speed stirred 30-40min, are freeze-dried to obtain powder；Will
Powder, nanometer mesoporous aluminas, the indigo plant blending of nanometer Mayan, are placed in ball milling ball milling 8-10h in ball mill, take out after drying.
3. weaving face fabric formaldehyde expellent according to claim 2, it is characterised in that：Counted by weight base unit weight of rectorite,
The nanometer mesoporous aluminas addition is 1-7%, and nanometer Mayan indigo plant addition is 5-10%.
4. weaving face fabric formaldehyde expellent according to claim 2, it is characterised in that：The mixed solution is sodium alginate
With sodium carbonate and mixed aqueous solution, wherein sodium alginate weight/mass percentage composition is 1-3%, and sodium carbonate weight/mass percentage composition is 2-
7%.
5. weaving face fabric formaldehyde expellent according to claim 1, it is characterised in that：The antiseptic is the amount ratio of material
0.5-0.8:1 monomethyl fumarate, methyl carbamate mixture.
6. weaving face fabric formaldehyde expellent according to claim 1, it is characterised in that：The aromatic be Rosa Damascana,
One or more compositions in aloe essential oil, radix glycyrrhizae essential oil, Peppermint essential oil, clove oil, silk tree peel essential oil.
7. weaving face fabric formaldehyde expellent according to claim 1, it is characterised in that：The surfactant is mass ratio
2:1 lauryl glucosyl, the mixture of alkanolamide.
8. the weaving face fabric formaldehyde expellent according to claim any one of 1-7, it is characterised in that preparation process is as follows：
By 1- vinyl imidazoles, methyl guanamines, guanylurea phosphate blending, the distilled water of 6-7 times of three's gross mass, 60 DEG C are added thereto
15-20min is stirred, is then added thereto nano modification rectorite, surfactant, polyvinyl alcohol, constant temperature oscillation 40-
60min, then other surplus stocks are added thereto continuation constant temperature oscillation processing 30-40min, filtering is drying to obtain weaving face fabric
Formaldehyde expellent.
9. the application of weaving face fabric formaldehyde expellent made from preparation method according to claim 8, it is characterised in that：It will spin
Knitted fabric formaldehyde expellent presses solid-to-liquid ratio 0.5-1 with distilled water:10, which are configured to solution, uses.
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| CN110420635A (en) * | 2019-08-07 | 2019-11-08 | 山东卓高新材料有限公司 | A kind of indoor furniture formaldehyde closing catalysis material and preparation method thereof |
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| CN102154825A (en) * | 2011-01-26 | 2011-08-17 | 柳志明 | Formaldehyde exterminator for textile fabrics and preparation and application methods thereof |
| CN102747602A (en) * | 2012-04-05 | 2012-10-24 | 龚䶮 | Formaldehyde removing reagent for treating formaldehyde-containing fabric, and use method thereof |
| CN103111038A (en) * | 2013-03-09 | 2013-05-22 | 谭志刚 | Efficient formaldehyde removing agent and preparation method thereof |
| CN106381683A (en) * | 2016-10-21 | 2017-02-08 | 东华大学 | Preparation method of formaldehyde removing jacquard knitted fabric |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102154825A (en) * | 2011-01-26 | 2011-08-17 | 柳志明 | Formaldehyde exterminator for textile fabrics and preparation and application methods thereof |
| CN102747602A (en) * | 2012-04-05 | 2012-10-24 | 龚䶮 | Formaldehyde removing reagent for treating formaldehyde-containing fabric, and use method thereof |
| CN103111038A (en) * | 2013-03-09 | 2013-05-22 | 谭志刚 | Efficient formaldehyde removing agent and preparation method thereof |
| CN106381683A (en) * | 2016-10-21 | 2017-02-08 | 东华大学 | Preparation method of formaldehyde removing jacquard knitted fabric |
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| CN110420635A (en) * | 2019-08-07 | 2019-11-08 | 山东卓高新材料有限公司 | A kind of indoor furniture formaldehyde closing catalysis material and preparation method thereof |
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