CN107126827B - A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers - Google Patents
A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers Download PDFInfo
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- CN107126827B CN107126827B CN201710356000.9A CN201710356000A CN107126827B CN 107126827 B CN107126827 B CN 107126827B CN 201710356000 A CN201710356000 A CN 201710356000A CN 107126827 B CN107126827 B CN 107126827B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/38—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by oxidation; by combustion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/91—Bacteria; Microorganisms
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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Abstract
The invention discloses a kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, are mainly made of the raw material of following weight parts：1~3 part of 0~3 part of 0~5 part of 0~15 part of 0~15 part of 0~15 part of 15~30 parts of stabilized chlorine solutions of chlorine, chitosan, amino acid, ethylene urea, ammonium chloride, ethanoic acid hydroxide inner salt, the PH conditioning agents and 75~85 parts of pure water of concentration range 0.0001%~1%.The key point of the present invention is the proportioning application method and environment of chlorine dioxide and polymeric type high molecular purifying agent, and the present invention not only can be with high-efficient purification formaldehyde, and wide spectrum kills bacterium while can also purifying VOC.Concentration only have 0.05% simultaneously pH value chlorine dioxide in the case of 10 11 oxidisability in stability rising, proportioning and alkaline environment in the present invention can obviously delay the gasification of chlorine dioxide, the clean-up effect for enhancing chlorine dioxide is the formaldehyde VOC cleansers of i.e. efficient wide spectrum again.
Description
Technical field
The invention belongs to formaldehyde purifying agent technical fields, particularly relate to a kind of high-efficiency broad spectrum long-acting type formaldehyde VOC
Cleanser.
Background technology
Chlorine dioxide is internationally recognized safe and non-toxic disinfectant, nothing " three cause " effect, both carcinogenic, teratogenesis, mutagenesis,
Simultaneously in disinfecting process also with organic matter occur chlorination generate can generate " three-induced effect " organic chloride or its
Its toxic substance.Any influence, including the influence in terms of Physiology and biochemistry will not be generated when 100ppm or less to human body.In sky
It is most widely applied in gas purification, tap water purifying, food sterilization.
Air clearing product in the prior art divides into Liang great schools by stringent：One kind is nontoxic and efficient dioxy
Change chlorine：Chlorine dioxide action principle simply strong oxidizing property, it is not only nontoxic to purify almost all of organic toxin.So
And because he is easy gasification, continuing purge effect can not occur to the pollution of some deep layers, usually be evaluated as short-acting product by people,
It is easy rebound.Another major class product category is exactly to select the high-molecular organic material for being easy that polymerisation occurs with formaldehyde, this
Class product disadvantage specific aim is very strong, most of all just for single chemical industry toxin, such as purifying formaldehyde, just just for formaldehyde,
The replacement product again of benzene is purified, however chemical industry toxin VOC would generally reach hundreds of, it is surprising to administer cost completely.
Or purification product in the prior art simply can be with the pollution administration of wide spectrum using chlorine dioxide, but acts on
Superficial, endurance is insufficient, is easy rebound；Single goes to pollute for individual event, only understands formaldehyde in people and does not know about other
It is not exclusively administered in the case of toxin, with the raising of people's environmental requirement, it will be trend of the times to administer comprehensively.
Invention content
The present invention provides a kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers to overcome the shortcomings of the prior art,
This patent focuses on to study the integrated use of chlorine dioxide and polymeric type cleanser, develops a kind of formaldehyde of i.e. efficient wide spectrum again
The influence factors such as formula and suitable environment pH coexist with solve that chlorine dioxide and polymeric type purify ingredient in VOC cleansers.
The present invention is achieved by the following technical solutions：A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, under
State the raw material composition of parts by weight：20~25 parts of stabilized chlorine solutions of chlorine, 5~8 parts of chitosan, 3~5 parts of amino acid, ethylene urea 2
80~83 parts of~6 parts, 2~4 parts of ammonium chloride, 1~3 part of ethanoic acid hydroxide inner salt, 2~3 parts of pH adjusting agent and pure water；Made
Stabilized chlorine solutions of chlorine is the ClO 2 solution that concentration range is 0.03%~0.1%, high-efficiency broad spectrum long-acting type first
The pH value of aldehyde VOC cleansers is 10~11.
As the preferred embodiment of the present invention, high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers by following weight parts original
Material composition：22 parts of stabilized chlorine solutions of chlorine, 6 parts of chitosan, 4 parts of amino acid, 4 parts of ethylene urea, 3 parts of ammonium chloride, glycine three
81 parts of 2 parts of methylamine inner salt, 2 parts of pH adjusting agent and pure water.
Table one：The formula range and effect of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers of the present invention are sketched
The beneficial effects of the invention are as follows：The key point of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers of the present invention is titanium dioxide
The proportioning application method and environment of chlorine and polymeric type high molecular purifying agent, the present invention not only can be with high-efficient purification formaldehyde, can be with
Wide spectrum kills bacterium while purifying VOC.Chlorine dioxide has superpower oxidisability, and most of high-molecular organic materials all can not
It is coexisted with him, and chlorine dioxide working efficiency superelevation, does not need to prodigious concentration and be just enough to complete purification.The study found that
Concentration only have 0.05% simultaneously pH value chlorine dioxide in the case of 10-11 oxidisability in stability rising, find simultaneously
There are several polymerization constituents that can coexist, these proportionings in high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers of the present invention and alkalinity
Environment can also obviously delay the gasification of chlorine dioxide, enhance the clean-up effect of chlorine dioxide.
Specific implementation mode
Below in conjunction with specific embodiment, the present invention is described in detail.
Embodiment 1：A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, are made of the raw material of following weight parts：Concentration
0.03% 19 parts of stabilized chlorine solutions of chlorine, 5 parts of chitosan, 5 parts of amino acid, 6 parts of ethylene urea, 2 parts of ammonium chloride, glycine three
The pH value of 81 parts of 1 part of methylamine inner salt, 1 part of pH adjusting agent and pure water, cleanser is 10~11.The present invention adds each recipe ingredient
Enter to be uniformly dispersed in pure water and can be used, purifying formaldehyde rate 98%, VOC purifying rates 76%.
Embodiment 2：A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, are made of the raw material of following weight parts：Concentration
0.06% 20 parts of stabilized chlorine solutions of chlorine, 8 parts of chitosan, 4 parts of amino acid, 2 parts of ethylene urea, 3 parts of ammonium chloride, glycine three
The pH value of 81 parts of 2 parts of methylamine inner salt, 2 parts of pH adjusting agent and pure water, cleanser is 10~11.The present invention adds each recipe ingredient
Enter to be uniformly dispersed in pure water and can be used, purifying formaldehyde rate 99%, VOC purifying rates 78%.
Embodiment 3：A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, are made of the raw material of following weight parts：Concentration
0.1% 17 parts of stabilized chlorine solutions of chlorine, 6 parts of chitosan, 3 parts of amino acid, 4 parts of ethylene urea, 4 parts of ammonium chloride, glycine three
The pH value of 80 parts of 3 parts of methylamine inner salt, 3 parts of pH adjusting agent and pure water, cleanser is 10~11.The present invention adds each recipe ingredient
Enter to be uniformly dispersed in pure water and can be used, purifying formaldehyde rate 99%, VOC purifying rates 84%.
Technical solution in the present invention includes whole formula components and ratio range and prioritization scheme, does not play master on a small quantity
It wants the ingredient of catharsis to change, is also contained in the claims of this patent, for example chlorine dioxide coordinates other
High molecular purifying agent, this in the present invention is used in mixed way pattern and method is the core of technical solution.
Finally it should be noted that the above content is merely illustrative of the technical solution of the present invention, rather than the present invention is protected
The limitation of range, those skilled in the art to technical scheme of the present invention carry out it is simple modification or equivalent replacement,
All without departing from the spirit and scope of technical solution of the present invention.
Claims (2)
1. a kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers, it is characterised in that：The high-efficiency broad spectrum long-acting type formaldehyde VOC is net
Agent is made of the raw material of following weight parts：20~25 parts of stabilized chlorine solutions of chlorine, 5~8 parts of chitosan, amino acid 3~5
Part, 2~6 parts of ethylene urea, 2~4 parts of ammonium chloride, 1~3 part of ethanoic acid hydroxide inner salt, 2~3 parts of pH adjusting agent and pure water 80
~83 parts；Used stabilized chlorine solutions of chlorine is the ClO 2 solution that concentration range is 0.03%~0.1%, the height
The pH values for imitating broad-spectrum long-acting type formaldehyde VOC cleansers are 10~11.
2. a kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers according to claim 1, it is characterised in that：It is described efficient
Broad-spectrum long-acting type formaldehyde VOC cleansers are made of the raw material of following weight parts：22 parts of stabilized chlorine solutions of chlorine, 6 parts of chitosan,
81 parts of 4 parts of amino acid, 4 parts of ethylene urea, 3 parts of ammonium chloride, 2 parts of ethanoic acid hydroxide inner salt, 2 parts of pH adjusting agent and pure water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710356000.9A CN107126827B (en) | 2017-05-16 | 2017-05-16 | A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710356000.9A CN107126827B (en) | 2017-05-16 | 2017-05-16 | A kind of high-efficiency broad spectrum long-acting type formaldehyde VOC cleansers |
Publications (2)
| Publication Number | Publication Date |
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| CN107126827A CN107126827A (en) | 2017-09-05 |
| CN107126827B true CN107126827B (en) | 2018-08-17 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108939862A (en) * | 2018-06-22 | 2018-12-07 | 广州怡轩环保科技有限公司 | Methanal disintegrant |
| CN111440467A (en) * | 2020-05-27 | 2020-07-24 | 湖南开美新材料科技有限公司 | Latex wall paint additive with formaldehyde removing effect and preparation method thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10028090A1 (en) * | 2000-06-07 | 2002-01-10 | P & W Invest Vermoegensverwalt | Process for impregnating an object or substance with a solution containing an oxidizing agent |
| CN101537307B (en) * | 2009-03-26 | 2012-11-28 | 梁宗贵 | Methanol remover and preparation method thereof |
| CN101658759A (en) * | 2009-08-03 | 2010-03-03 | 浙江大学 | Formaldehyde purifying agent and preparation method thereof |
| CN101810874B (en) * | 2009-12-15 | 2013-04-24 | 北京欧凯纳斯科技有限公司 | Sustained-release chlorine dioxide gel, preparation method and application thereof |
| WO2011079120A1 (en) * | 2009-12-23 | 2011-06-30 | Resonant Biosciences, Llc | Apparatus and method for treatment of volatile organic compounds in air emissions produced during fermentation processes |
| CN104667331A (en) * | 2013-11-29 | 2015-06-03 | 末丽华 | Air purified solution |
| CN105013305A (en) * | 2014-04-29 | 2015-11-04 | 江苏瑞丰科技实业有限公司 | Multifunctional efficient air purifying agent and using method thereof |
| CN105268302A (en) * | 2015-11-03 | 2016-01-27 | 连云港岚宝电子科技有限公司 | Slow-release type indoor formaldehyde-clearing agent |
| CN106550941B (en) * | 2016-11-08 | 2020-11-06 | 东北大学秦皇岛分校 | Stable chlorine dioxide disinfectant |
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