CN107117817B - Green metallic luster glaze and preparation method thereof - Google Patents
Green metallic luster glaze and preparation method thereof Download PDFInfo
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- CN107117817B CN107117817B CN201710444467.9A CN201710444467A CN107117817B CN 107117817 B CN107117817 B CN 107117817B CN 201710444467 A CN201710444467 A CN 201710444467A CN 107117817 B CN107117817 B CN 107117817B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to a green metallic luster glaze which comprises the following components in parts by weight: 32-41 parts of a frit, 7-10 parts of emerald garnet, 3.5-4.5 parts of green cord stone, 3-4 parts of chlorite, 8-10 parts of ball clay, 6-9 parts of kaolinite, 17-19 parts of calcite, 8-12 parts of suberin, 15-18 parts of mud shale, 20-25 parts of a glaze fruit and 0.5-1.2 parts of sea sapphire, wherein the frit comprises the following components in parts by weight: 25-33 parts of quartz, 12-14 parts of dolomite, 8-13 parts of mung bean rock, 3-6 parts of germanite powder, 17-22 parts of high-temperature sand, 2.5-4 parts of boric acid and 1-2 parts of strontium carbonate. The invention also relates to a preparation method of the green metallic luster glaze, and a product prepared by using the green metallic luster glaze, wherein the glaze surface of the product is green, presents metallic luster, and can be comparable to high-grade metallic products.
Description
Technical Field
the invention relates to the field of ceramic glaze, in particular to green metallic luster glaze and a preparation method thereof.
Background
The metallic glaze is a decorative artistic glaze developed in recent years, which can be used to print various designs and patterns on wall and floor tiles or bottles and cans of daily-use display porcelain, and after firing, it has mirror metallic luster effect, and can present various colors of red, yellow and silver, etc., and can meet the appreciation requirements of some users. At present, the green metallic luster glaze has fewer products and immature technique.
Disclosure of Invention
The invention aims to solve the problems and provides a green metallic luster glaze and a preparation method thereof.
The purpose of the invention is realized by the following technical scheme:
The green metallic luster glaze comprises the following components in parts by weight: 32-41 parts of a frit, 7-10 parts of emerald garnet, 3.5-4.5 parts of green cord stone, 3-4 parts of chlorite, 8-10 parts of ball clay, 6-9 parts of kaolinite, 17-19 parts of calcite, 8-12 parts of suberin, 15-18 parts of mud shale, 20-25 parts of a glaze fruit and 0.5-1.2 parts of sea sapphire, wherein the frit comprises the following components in parts by weight: 25-33 parts of quartz, 12-14 parts of dolomite, 8-13 parts of mung bean rock, 3-6 parts of germanite powder, 17-22 parts of high-temperature sand, 2.5-4 parts of boric acid and 1-2 parts of strontium carbonate.
Preferably, the green metallic luster glaze consists of the following components in parts by weight: 35 parts of frit, 8 parts of emerald garnet, 4 parts of green cord stone, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, 10 parts of suberin, 16 parts of shale, 22 parts of glazes and 1 part of sea sapphire, wherein the frit comprises the following components in parts by weight: 26 parts of quartz, 13 parts of dolomite, 11 parts of mung bean rock, 5 parts of germanite powder, 20 parts of high-temperature sand, 3 parts of boric acid and 1.5 parts of strontium carbonate.
The invention also provides a preparation method of the green metallic luster glaze, which comprises the following steps:
S1, weighing according to a frit formula, uniformly mixing, loading into a crucible, melting at the temperature of 750-1100 ℃, preserving heat for 10-20 min, pouring into cold water, quenching into fine particles, drying, crushing, and ball-milling through a 300-mesh sieve to obtain a frit for later use;
s2, weighing according to a formula of the green metallic luster glaze, and mixing the following materials: ball: water = 1: 2: grinding for 3h in a ball mill of 0.6-0.65, and sieving with a 300-mesh sieve to obtain green metallic luster glaze, wherein the sieved residue is 0.1 percent after the grinding.
When the green metal glaze is used, glaze is sprayed on the blank, the glazing thickness is 0.2-0.3 mm, and the blank enters a tunnel kiln to be oxidized and fired by flame, so that the green metal glaze effect is obtained.
Experiments show that the ratio of various raw materials, the sintering process and the like have great influence on the glaze effect.
compared with the prior art, the invention has the following beneficial effects:
The invention provides a green metallic luster glaze, and a product prepared from the green metallic luster glaze, wherein the glaze surface of the product is green, presents metallic luster, and can be comparable to high-grade metal products.
Detailed Description
The present invention will be further described with reference to the following examples.
example 1
The embodiment discloses a green metallic luster glaze which comprises the following components in parts by weight: 32 parts of frit, 7 parts of emerald garnet, 3.5 parts of green cord stone, 3 parts of chlorite, 8 parts of ball clay, 6 parts of kaolinite, 17 parts of calcite, 8 parts of suberin, 15 parts of shale, 20 parts of glaze fruit and 0.5 part of sea sapphire, wherein the frit comprises the following components in parts by weight: 33 parts of quartz, 14 parts of dolomite, 13 parts of mung bean rock, 6 parts of germanite powder, 22 parts of high-temperature sand, 4 parts of boric acid and 2 parts of strontium carbonate.
example 2
the embodiment discloses a green metallic luster glaze which comprises the following components in parts by weight: 41 parts of frit, 10 parts of emerald garnet, 4.5 parts of green cord stone, 4 parts of chlorite, 10 parts of ball clay, 9 parts of kaolinite, 19 parts of calcite, 12 parts of suberin, 18 parts of shale, 25 parts of glaze fruit and 1.2 parts of sea sapphire, wherein the frit comprises the following components in parts by weight: 25 parts of quartz, 12 parts of dolomite, 8 parts of mung bean rock, 3 parts of germanite powder, 17 parts of high-temperature sand, 2.5 parts of boric acid and 1 part of strontium carbonate.
Example 3
the embodiment discloses a green metallic luster glaze which comprises the following components in parts by weight: 35 parts of frit, 8 parts of emerald garnet, 4 parts of green cord stone, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, 10 parts of suberin, 16 parts of shale, 22 parts of glazes and 1 part of sea sapphire, wherein the frit comprises the following components in parts by weight: 26 parts of quartz, 13 parts of dolomite, 11 parts of mung bean rock, 5 parts of germanite powder, 20 parts of high-temperature sand, 3 parts of boric acid and 1.5 parts of strontium carbonate.
Example 4
the embodiment discloses a green metallic luster glaze which comprises the following components in parts by weight: 40 parts of frit, 9 parts of emerald garnet, 4.2 parts of green cord stone, 3.8 parts of chlorite, 8.5 parts of ball clay, 7 parts of kaolinite, 17.5 parts of calcite, 9 parts of suberin, 17 parts of shale, 24 parts of glazes and 0.8 part of sapphire, wherein the frit comprises the following components in parts by weight: 30 parts of quartz, 12.5 parts of dolomite, 12 parts of mung bean rock, 4 parts of germanite powder, 18 parts of high-temperature sand, 3.5 parts of boric acid and 1.8 parts of strontium carbonate.
example 5
The green metallic luster glaze is prepared from the components in any embodiment of the embodiments 1-4 by weight, and the preparation steps are as follows:
S1, weighing according to a frit formula, uniformly mixing, loading into a crucible, melting at the temperature of 750 ℃, preserving heat for 20min, pouring into cold water, quenching into fine particles, drying, crushing, and ball-milling through a 300-mesh sieve to obtain a frit for later use;
S2, weighing according to a formula of the green metallic luster glaze, and mixing the following materials: ball: water = 1: 2: grinding for 3h in a ball mill for 0.6, and sieving with a 300-mesh sieve to obtain green metallic luster glaze, wherein the sieved residue is 0.1 percent after the grinding.
Example 6
The green metallic luster glaze is prepared from the components in any embodiment of the embodiments 1-4 by weight, and the preparation steps are as follows:
S1, weighing according to a frit formula, uniformly mixing, loading into a crucible, melting at 1100 ℃, preserving heat for 10min, pouring into cold water, quenching into fine particles, drying, crushing, and ball-milling through a 300-mesh sieve to obtain a frit for later use;
S2, weighing according to a formula of the green metallic luster glaze, and mixing the following materials: ball: water = 1: 2: grinding for 3h in a ball mill of 0.65, and sieving with a 300-mesh sieve to obtain green metallic luster glaze with the residue of 0.1 percent after being discharged.
Example 7
The green metallic luster glaze is prepared from the components in any embodiment of the embodiments 1-4 by weight, and the preparation steps are as follows:
S1, weighing according to a frit formula, uniformly mixing, loading into a crucible, melting at 950 ℃, preserving heat for 15min, pouring into cold water, quenching into fine particles, drying, crushing, and ball-milling through a 300-mesh sieve to obtain a frit for later use;
S2, weighing according to a formula of the green metallic luster glaze, and mixing the following materials: ball: water = 1: 2: grinding for 3h in a ball mill of 0.63, and sieving with a 300-mesh sieve to obtain green metallic luster glaze with the residue of 0.1 percent after being discharged.
Claims (3)
1. the green metallic luster glaze is characterized by comprising the following components in percentage by weight: 32-41 parts of a frit, 7-10 parts of emerald garnet, 3.5-4.5 parts of green cord stone, 3-4 parts of chlorite, 8-10 parts of ball clay, 6-9 parts of kaolinite, 17-19 parts of calcite, 8-12 parts of suberin, 15-18 parts of mud shale, 20-25 parts of a glaze fruit and 0.5-1.2 parts of sea sapphire, wherein the frit comprises the following components in parts by weight: 25-33 parts of quartz, 12-14 parts of dolomite, 8-13 parts of mung bean rock, 3-6 parts of germanite powder, 17-22 parts of high-temperature sand, 2.5-4 parts of boric acid and 1-2 parts of strontium carbonate.
2. the green metallic luster glaze according to claim 1, which is characterized by comprising the following components in parts by weight: 35 parts of frit, 8 parts of emerald garnet, 4 parts of green cord stone, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, 10 parts of suberin, 16 parts of shale, 22 parts of glazes and 1 part of sea sapphire, wherein the frit comprises the following components in parts by weight: 26 parts of quartz, 13 parts of dolomite, 11 parts of mung bean rock, 5 parts of germanite powder, 20 parts of high-temperature sand, 3 parts of boric acid and 1.5 parts of strontium carbonate.
3. The process for the preparation of green metallic lustrous glaze according to claim 1 or 2, characterized in that it comprises the following steps:
S1, weighing according to a frit formula, uniformly mixing, loading into a crucible, melting at the temperature of 750-1100 ℃, preserving heat for 10-20 min, pouring into cold water, quenching into fine particles, drying, crushing, and ball-milling through a 300-mesh sieve to obtain a frit for later use;
s2, weighing according to a formula of the green metallic luster glaze, and mixing the following materials: ball: water = 1: 2: grinding for 3h in a ball mill of 0.6-0.65, and sieving with a 300-mesh sieve to obtain green metallic luster glaze, wherein the sieved residue is 0.1 percent after the grinding.
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| CN107555791A (en) * | 2017-09-29 | 2018-01-09 | 晋晓瞳 | A kind of sea blue glaze and preparation method thereof |
| CN109052969B (en) * | 2018-10-19 | 2020-09-15 | 东北大学 | Method for producing microcrystalline glass by using calcium iron garnet type red mud |
| CN111233432A (en) * | 2020-03-05 | 2020-06-05 | 吴志勇 | Imitation Ge kiln ceramic introduced with barren raw materials and preparation process thereof |
| CN113955942B (en) * | 2021-12-22 | 2022-03-15 | 广东简一(集团)陶瓷有限公司 | High-hardness glaze and preparation method thereof |
| CN114656151A (en) * | 2022-05-26 | 2022-06-24 | 佛山市东鹏陶瓷发展有限公司 | Polished tile wear-resistant glaze and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103030430A (en) * | 2012-12-12 | 2013-04-10 | 醴陵陶润实业发展有限公司 | Method for preparing gorgeous space-time glaze |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103030430A (en) * | 2012-12-12 | 2013-04-10 | 醴陵陶润实业发展有限公司 | Method for preparing gorgeous space-time glaze |
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Effective date of registration: 20191111 Address after: 362500 Ziyun Development Zone, three class town, Dehua County, Quanzhou, Fujian Applicant after: FUJIAN DEHUA COUNTY ZIJIA CRAFTS CO.,LTD. Address before: Room 305, floor 3, health intelligent manufacturing center, No. 2, Jingba Road, Huangjia Park, Jingyang Economic Development Zone, Jingde County, Xuancheng City, Anhui Province Applicant before: Jingdejunchuang Technology Development Co.,Ltd. Effective date of registration: 20191111 Address after: Room 305, floor 3, health intelligent manufacturing center, No. 2, Jingba Road, Huangjia Park, Jingyang Economic Development Zone, Jingde County, Xuancheng City, Anhui Province Applicant after: Jingdejunchuang Technology Development Co.,Ltd. Address before: 313000 Hong Kong Qiao Town, Zhejiang, Huzhou province Changxing County Hongqiao Industrial Park Applicant before: HUZHOU WANLONG RESIDENTIAL ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
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Denomination of invention: Green metallic luster glaze and its preparation method Effective date of registration: 20200914 Granted publication date: 20191206 Pledgee: China Postal Savings Bank Limited by Share Ltd. Dehua County branch Pledgor: FUJIAN DEHUA COUNTY ZIJIA CRAFTS Co.,Ltd. Registration number: Y2020980006035 |
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