CN107117817A - Green metal bright glaze and preparation method thereof - Google Patents

Green metal bright glaze and preparation method thereof Download PDF

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Publication number
CN107117817A
CN107117817A CN201710444467.9A CN201710444467A CN107117817A CN 107117817 A CN107117817 A CN 107117817A CN 201710444467 A CN201710444467 A CN 201710444467A CN 107117817 A CN107117817 A CN 107117817A
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Prior art keywords
parts
glaze
frit
green
green metal
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CN201710444467.9A
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CN107117817B (en
Inventor
任子恩
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Fujian Dehua County Zijia Crafts Co ltd
Jingdejunchuang Technology Development Co ltd
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Huzhou Bandung Residential Environmental Protection Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/32Burning methods
    • C04B33/34Burning methods combined with glazing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The present invention relates to a kind of green metal bright glaze, it is made up of each component of following weight fraction:32~41 parts of frit, 7~10 parts of demantoid, 3.5~4.5 parts of allochite, 3~4 parts of chlorite, 8~10 parts of ball clay, 6~9 parts of kaolinite, 17~19 parts of calcite, 8~12 parts of kieselguhr, 15~18 parts of mud shale, 20~25 parts of glaze fruit, 0.5~1.2 part of aquamarine, wherein, the frit is made up of each component of following weight fraction:25~33 parts of quartz, 12~14 parts of dolomite, 8~13 parts of green bean rock, 3~6 parts of germanite powder, 17~22 parts of high temperature sand, 2.5~4 parts of boric acid, 1~2 part of strontium carbonate.The invention further relates to the preparation method of the green metal bright glaze, the product prepared with it, its glaze shows the gloss of metal-like in green, and can match in excellence or beauty high-class metal product.

Description

Green metal bright glaze and preparation method thereof
Technical field
The present invention relates to ceramic glaze field, more particularly, to a kind of green metal bright glaze and preparation method thereof.
Background technology
Metal-lustrous glaze is a kind of decorative art glaze grown up in recent years, can be on Wall or floor tile or daily with it Various color patterns are printed on the Bottle & Can of decorative ceramics, after burning till have minute surface as metallic luster effect, and can show it is red, The a variety of colors such as Huang, silver, can cater to the appreciation requirement of a part of user.The product of current green metal bright glaze is less, skill It is still immature.
The content of the invention
The purpose of the present invention is that there is provided a kind of green metal bright glaze and preparation method thereof the problem of being directed to above-mentioned.
The object of the invention is achieved by the following technical programs:
A kind of green metal bright glaze is provided, is made up of each component of following weight fraction:32~41 parts of frit, demantoid 7~ 10 parts, 3.5~4.5 parts of allochite, 3~4 parts of chlorite, 8~10 parts of ball clay, 6~9 parts of kaolinite, 17~19 parts of calcite, wood Section soil 8~12 parts, 15~18 parts of mud shale, glaze fruit 20~25 parts, 0.5~1.2 part of aquamarine, wherein, the frit by with The each component composition of lower weight fraction:25~33 parts of quartz, 12~14 parts of dolomite, 8~13 parts of green bean rock, germanite powder 3~6 Part, 17~22 parts of high temperature sand, 2.5~4 parts of boric acid, 1~2 part of strontium carbonate.
Preferably, the green metal bright glaze is made up of each component of following weight fraction:35 parts of frit, demantoid 8 Part, 4 parts of allochite, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, 10 parts of kieselguhr, 16 parts of mud shale, 22 parts of glaze fruit, 1 part of aquamarine, wherein, the frit is made up of each component of following weight fraction:26 parts of quartz, dolomite 13 parts, 11 parts of green bean rock, 5 parts of germanite powder, 20 parts of high temperature sand, 3 parts of boric acid, 1.5 parts of strontium carbonate.
Present invention also offers the preparation method of the green metal bright glaze, comprise the following steps:
S1. weighed by frit formula, be well mixed and load crucible, melted at a temperature of 750~1100 DEG C, insulation 10~ 20min, pours into quenching in cold water and, into fine particle, dries and crush, ball milling crosses 300 mesh sieves, obtains frit standby;
S2. weighed by green metal gloss glaze formula, to expect:Ball:Water=1:2:0.6~0.65 enters ball milling 3h, goes out after mill 300 mesh sieves tail over 0.1%, obtain green metal bright glaze.
In use, drenching glaze on blank, glazing 0.2~0.3mm of thickness enters tunnel cave oxidizing flame and burnt till, and obtains green gold Belong to gloss glazing effect.
Experiment shows that when firing process etc. of matching somebody with somebody of various raw material influences very big to glazing effect.
Compared with prior art, the invention has the advantages that:
The invention provides a kind of green metal bright glaze, the product prepared with it, its glaze shows gold in green Belong to the gloss of texture, can match in excellence or beauty high-class metal product.
Embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1
Present embodiment discloses a kind of green metal bright glaze, it is made up of each component of following weight fraction:32 parts of frit, emerald green pomegranate 7 parts of stone, 3.5 parts of allochite, 3 parts of chlorite, 8 parts of ball clay, 6 parts of kaolinite, 17 parts of calcite, 8 parts of kieselguhr, mud shale 15 Part, 20 parts of glaze fruit, 0.5 part of aquamarine, wherein, the frit is made up of each component of following weight fraction:33 parts of quartz, in vain 14 parts of marble, 13 parts of green bean rock, 6 parts of germanite powder, 22 parts of high temperature sand, 4 parts of boric acid, 2 parts of strontium carbonate.
Embodiment 2
Present embodiment discloses a kind of green metal bright glaze, it is made up of each component of following weight fraction:41 parts of frit, emerald green pomegranate 10 parts of stone, 4.5 parts of allochite, 4 parts of chlorite, 10 parts of ball clay, 9 parts of kaolinite, 19 parts of calcite, 12 parts of kieselguhr, mud shale 18 parts, 25 parts of glaze fruit, 1.2 parts of aquamarine, wherein, the frit is made up of each component of following weight fraction:25 parts of quartz, 12 parts of dolomite, 8 parts of green bean rock, 3 parts of germanite powder, 17 parts of high temperature sand, 2.5 parts of boric acid, 1 part of strontium carbonate.
Embodiment 3
Present embodiment discloses a kind of green metal bright glaze, it is made up of each component of following weight fraction:35 parts of frit, emerald green pomegranate 8 parts of stone, 4 parts of allochite, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, 10 parts of kieselguhr, mud shale 16 Part, 22 parts of glaze fruit, 1 part of aquamarine, wherein, the frit is made up of each component of following weight fraction:26 parts of quartz, white clouds 13 parts of stone, 11 parts of green bean rock, 5 parts of germanite powder, 20 parts of high temperature sand, 3 parts of boric acid, 1.5 parts of strontium carbonate.
Embodiment 4
Present embodiment discloses a kind of green metal bright glaze, it is made up of each component of following weight fraction:40 parts of frit, emerald green pomegranate 9 parts of stone, 4.2 parts of allochite, 3.8 parts of chlorite, 8.5 parts of ball clay, 7 parts of kaolinite, 17.5 parts of calcite, 9 parts of kieselguhr, mud page 17 parts of rock, 24 parts of glaze fruit, 0.8 part of aquamarine, wherein, the frit is made up of each component of following weight fraction:Quartz 30 Part, 12.5 parts of dolomite, 12 parts of green bean rock, 4 parts of germanite powder, 18 parts of high temperature sand, 3.5 parts of boric acid, 1.8 parts of strontium carbonate.
Embodiment 5
The components by weight percent of any embodiment of Example 1~4 prepares green metal bright glaze, and preparation process is as follows:
S1. weighed by frit formula, be well mixed and load crucible, melted at a temperature of 750 DEG C, be incubated 20min, pour into cold water Middle quenching is into fine particle, and drying is broken, and ball milling crosses 300 mesh sieves, obtains frit standby;
S2. weighed by green metal gloss glaze formula, to expect:Ball:Water=1:2:0.6 enters ball milling 3h, goes out 300 mesh sieves after mill 0.1% is tailed over, green metal bright glaze is obtained.
Embodiment 6
The components by weight percent of any embodiment of Example 1~4 prepares green metal bright glaze, and preparation process is as follows:
S1. weighed by frit formula, be well mixed and load crucible, melted at a temperature of 1100 DEG C, be incubated 10min, pour into cold Quenching is into fine particle in water, and drying is broken, and ball milling crosses 300 mesh sieves, obtains frit standby;
S2. weighed by green metal gloss glaze formula, to expect:Ball:Water=1:2:0.65 enters ball milling 3h, goes out 300 mesh sieves after mill 0.1% is tailed over, green metal bright glaze is obtained.
Embodiment 7
The components by weight percent of any embodiment of Example 1~4 prepares green metal bright glaze, and preparation process is as follows:
S1. weighed by frit formula, be well mixed and load crucible, melted at a temperature of 950 DEG C, be incubated 15min, pour into cold water Middle quenching is into fine particle, and drying is broken, and ball milling crosses 300 mesh sieves, obtains frit standby;
S2. weighed by green metal gloss glaze formula, to expect:Ball:Water=1:2:0.63 enters ball milling 3h, goes out 300 mesh sieves after mill 0.1% is tailed over, green metal bright glaze is obtained.

Claims (3)

1. a kind of green metal bright glaze, it is characterised in that be made up of each component of following percentage by weight:Frit 32~41 Part, 7~10 parts of demantoid, 3.5~4.5 parts of allochite, 3~4 parts of chlorite, 8~10 parts of ball clay, 6~9 parts of kaolinite, Fang Xie 17~19 parts of stone, 8~12 parts of kieselguhr, 15~18 parts of mud shale, 20~25 parts of glaze fruit, 0.5~1.2 part of aquamarine, wherein, The frit is made up of each component of following weight fraction:25~33 parts of quartz, 12~14 parts of dolomite, 8~13 parts of green bean rock, 3~6 parts of germanite powder, 17~22 parts of high temperature sand, 2.5~4 parts of boric acid, 1~2 part of strontium carbonate.
2. green metal bright glaze according to claim 1, it is characterised in that be grouped by each group of following parts by weight Into:35 parts of frit, 8 parts of demantoid, 4 parts of allochite, 3.5 parts of chlorite, 9 parts of ball clay, 8 parts of kaolinite, 18 parts of calcite, knaur 10 parts of soil, 16 parts of mud shale, 22 parts of glaze fruit, 1 part of aquamarine, wherein, the frit is grouped by each group of following weight fraction Into:26 parts of quartz, 13 parts of dolomite, 11 parts of green bean rock, 5 parts of germanite powder, 20 parts of high temperature sand, 3 parts of boric acid, 1.5 parts of strontium carbonate.
3. the preparation method of green metal bright glaze according to claim 1 or claim 2, it is characterised in that comprise the following steps:
S1. weighed by frit formula, be well mixed and load crucible, melted at a temperature of 750~1100 DEG C, insulation 10~ 20min, pours into quenching in cold water and, into fine particle, dries and crush, ball milling crosses 300 mesh sieves, obtains frit standby;
S2. weighed by green metal gloss glaze formula, to expect:Ball:Water=1:2:0.6~0.65 enters ball milling 3h, goes out after mill 300 mesh sieves tail over 0.1%, obtain green metal bright glaze.
CN201710444467.9A 2017-06-13 2017-06-13 Green metallic luster glaze and preparation method thereof Active CN107117817B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107555791A (en) * 2017-09-29 2018-01-09 晋晓瞳 A kind of sea blue glaze and preparation method thereof
CN109052969A (en) * 2018-10-19 2018-12-21 东北大学 A method of devitrified glass is produced using andradite type red mud
CN111233432A (en) * 2020-03-05 2020-06-05 吴志勇 Imitation Ge kiln ceramic introduced with barren raw materials and preparation process thereof
CN113955942A (en) * 2021-12-22 2022-01-21 广东简一(集团)陶瓷有限公司 High-hardness glaze and preparation method thereof
CN114656151A (en) * 2022-05-26 2022-06-24 佛山市东鹏陶瓷发展有限公司 Polished tile wear-resistant glaze and preparation method thereof

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CN103030430A (en) * 2012-12-12 2013-04-10 醴陵陶润实业发展有限公司 Method for preparing gorgeous space-time glaze

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CN103030430A (en) * 2012-12-12 2013-04-10 醴陵陶润实业发展有限公司 Method for preparing gorgeous space-time glaze

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107555791A (en) * 2017-09-29 2018-01-09 晋晓瞳 A kind of sea blue glaze and preparation method thereof
CN109052969A (en) * 2018-10-19 2018-12-21 东北大学 A method of devitrified glass is produced using andradite type red mud
CN111233432A (en) * 2020-03-05 2020-06-05 吴志勇 Imitation Ge kiln ceramic introduced with barren raw materials and preparation process thereof
CN113955942A (en) * 2021-12-22 2022-01-21 广东简一(集团)陶瓷有限公司 High-hardness glaze and preparation method thereof
CN113955942B (en) * 2021-12-22 2022-03-15 广东简一(集团)陶瓷有限公司 High-hardness glaze and preparation method thereof
CN114656151A (en) * 2022-05-26 2022-06-24 佛山市东鹏陶瓷发展有限公司 Polished tile wear-resistant glaze and preparation method thereof

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Denomination of invention: Green metallic luster glaze and its preparation method

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