CN107099362A - 一种汽车车身金属结构件防腐油及制备工艺 - Google Patents
一种汽车车身金属结构件防腐油及制备工艺 Download PDFInfo
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- CN107099362A CN107099362A CN201710385776.3A CN201710385776A CN107099362A CN 107099362 A CN107099362 A CN 107099362A CN 201710385776 A CN201710385776 A CN 201710385776A CN 107099362 A CN107099362 A CN 107099362A
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- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 2
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- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 2
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- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M167/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound, a non-macromolecular compound and a compound of unknown or incompletely defined constitution, each of these compounds being essential
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2209/084—Acrylate; Methacrylate
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- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
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- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/045—Polyureas; Polyurethanes
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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- C10M2223/045—Metal containing thio derivatives
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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Abstract
本发明涉及一种汽车车身金属结构件防腐油,由以下重量百分比原料组成,石油磺酸钠3%—5%、环烷酸锌1%—5%、二聚油酸单酯5%—10%、成膜剂2%—13%、抗氧化剂0.5%—3.5%、苯并三氮唑0.1%—1.5%、苯甲酸单乙醇胺1.1%—2.5%、二烷基二硫代磷酸锌2.1%—3%、烷基酚聚氧乙烯醚2%—5%、油酸聚氧乙烯酯1.5%—5%、壬基酚氧乙烯醚1.1—2%、辛基酚氧乙烯醚0—1.5%、余量为基础油。本发明原料成本低廉,生产过程简单易学,一方面可有效的降低汽车金属构建防腐有的生产成本,另一方面可有效的提高汽车金属构建防腐油的表面附着能力和耐候能力,并降低防腐油生产和使用时对周边环境的污染性,从而有效的提高防腐油有效的防护时间,降低防腐油的使用成本、腐作业的成本和防腐作业的劳动强度。
Description
技术领域
本发明涉一种汽车车身金属结构件防腐油及制备工艺,属汽车技术领域。
背景技术
随着汽车在生产和日常使用时,往往需要对车身上的金属构建进行防护处理,其中在汽车生产过程中,对车身喷涂防腐油是提高汽车车身金属构建防腐能力的主要手段,但在实际使用中发现,当前所使用的汽车车身金属构件防腐油往往存在生产原料成本相对较高,生产工艺复杂,生产效率低下,防腐油在金属件表面的附着能力差及防腐油的耐候性能不足等缺陷,从而导致当前的防腐油使用成本相对较高,且需要频繁对汽车车身金属构建进行防腐油喷淋作业,增导致汽车车身防腐作业成本增加的同时,也增加了劳动强度,同时当前所使用的防腐油的原料中往往含有毒性及污染性较大的原料,因此防腐油的环境亲和性相对较差,从而导致当前的防腐油在生产和使用中易造成严重的环境污染,因此针对这一问题,迫切需要开发一种全新的汽车车身防腐油及其生产工艺,以满足实际使用的需要。
发明内容
针对现有技术上存在的不足,本发明提供一种汽车车身金属结构件防腐油及制备工艺。
为了实现上述目的,本发明是通过如下的技术方案来实现:
一种汽车车身金属结构件防腐油,由以下重量百分比原料组成,石油磺酸钠3%—5%、环烷酸锌1%—5%、二聚油酸单酯5%—10%、成膜剂2%—13%、抗氧化剂0.5%—3.5%、苯并三氮唑0.1%—1.5%、苯甲酸单乙醇胺1.1%—2.5%、二烷基二硫代磷酸锌2.1%—3%、烷基酚聚氧乙烯醚2%—5%、油酸聚氧乙烯酯1.5%—5%、壬基酚氧乙烯醚1.1—2%、辛基酚氧乙烯醚0—1.5%、余量为基础油。
进一步的,所述的成膜剂为丙烯酸树脂成膜剂、丁二烯树脂成膜剂、聚氨酯成膜剂、硝酸纤维成膜剂中的任意一种。
进一步的,所述的抗氧化剂为2,6-二叔丁基-4-甲基苯酚。
进一步的,所述的基础油为全损耗系统油。
进一步的,所述的二聚油酸单酯由二元脂肪酸和聚乙二醇单烷基醚按照1:1比例混合到二甲苯溶剂中,混合均匀后加热到140℃—150℃,并在占二元脂肪酸和聚乙二醇单烷基醚混合物总量0.5%—1%的催还剂参与条件下反应8—12小时制备而成。
进一步的,所述的聚乙二醇单烷基醚中烷基是C1—C22。
进一步的,所述的二甲苯溶剂使用量为二元脂肪酸和聚乙二醇单烷基醚混合物总量的10%—20%。
进一步的,所述的催化剂为甲基苯磺酸、钛酸四丁酯、二氯三锡中的任意一种。
一种汽车车身金属结构件防腐油制备工艺,其制备方法为:
将基础油在5—15分钟内,匀速加热至100—150℃,并保持匀速单向搅拌状态下保温3—5分钟,然后将石油磺酸钠、环烷酸锌依次匀速添加到基础油内,与基础油混合均匀并反应10—20分钟,然后将基础油温度自然冷却至60℃—80℃,然后向基础油中加入苯并三氮唑、苯甲酸单乙醇胺、二烷基二硫代磷酸锌、烷基酚聚氧乙烯醚、油酸聚氧乙烯酯,与基础油混合均匀并反应2—3小时,最后将剩余物料依次添加到基础油中,并在60℃—80℃恒温条件下搅拌3—10分钟,搅拌均匀后通过50—100目过滤筛网过滤后即可得到成品。
本发明原料成本低廉,生产过程简单易学,一方面可有效的降低汽车金属构建防腐有的生产成本,另一方面可有效的提高汽车金属构建防腐油的表面附着能力和耐候能力,并降低防腐油生产和使用时对周边环境的污染性,从而有效的提高防腐油有效的防护时间,降低防腐油的使用成本、腐作业的成本和防腐作业的劳动强度。
具体实施方式
为使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解,下面结合具体实施方式,进一步阐述本发明。
实施例1
一种汽车车身金属结构件防腐油,由以下重量百分比原料组成,石油磺酸钠3%、环烷酸锌1%、二聚油酸单酯8%、成膜剂2%、抗氧化剂1%、苯并三氮唑1.5%、苯甲酸单乙醇胺2.5%、二烷基二硫代磷酸锌3%、烷基酚聚氧乙烯醚3%、油酸聚氧乙烯酯2%、壬基酚氧乙烯醚2%、辛基酚氧乙烯醚0.5%、余量为基础油。
本实施例中,所述的成膜剂为丙烯酸树脂成膜剂。
本实施例中,所述的抗氧化剂为2,6-二叔丁基-4-甲基苯酚。
本实施例中,所述的基础油为全损耗系统油。
本实施例中,所述的二聚油酸单酯由二元脂肪酸和聚乙二醇单烷基醚按照1:1比例混合到二甲苯溶剂中,混合均匀后加热到150℃,并在占二元脂肪酸和聚乙二醇单烷基醚混合物总量1%的催还剂参与条件下反应12小时制备而成。
本实施例中,所述的聚乙二醇单烷基醚中烷基是C2—C18。
本实施例中,所述的二甲苯溶剂使用量为二元脂肪酸和聚乙二醇单烷基醚混合物总量的20%。
本实施例中,,所述的催化剂为甲基苯磺酸。
一种汽车车身金属结构件防腐油制备工艺,其制备方法为:
将基础油在10分钟内,匀速加热至100℃,并保持匀速单向搅拌状态下保温5分钟,然后将石油磺酸钠、环烷酸锌依次匀速添加到基础油内,与基础油混合均匀并反应10分钟,然后将基础油温度自然冷却至60℃,然后向基础油中加入苯并三氮唑、苯甲酸单乙醇胺、二烷基二硫代磷酸锌、烷基酚聚氧乙烯醚、油酸聚氧乙烯酯,与基础油混合均匀并反应2—3小时,最后将剩余物料依次添加到基础油中,并在80℃恒温条件下搅拌5分钟,搅拌均匀后通过800目过滤筛网过滤后即可得到成品。
实施例2
一种汽车车身金属结构件防腐油,由以下重量百分比原料组成,石油磺酸钠5%、环烷酸锌5%、二聚油酸单酯5%、成膜剂10%、抗氧化剂2%、苯并三氮唑0.5%、苯甲酸单乙醇胺1.1%、二烷基二硫代磷酸锌2.1%、烷基酚聚氧乙烯醚4%、油酸聚氧乙烯酯2%、壬基酚氧乙烯醚1.5%,余量为基础油。
本实施例中,所述的成膜剂为丁二烯树脂成膜剂。
本实施例中,,所述的抗氧化剂为2,6-二叔丁基-4-甲基苯酚。
本实施例中,,所述的基础油为全损耗系统油。
本实施例中,,所述的二聚油酸单酯由二元脂肪酸和聚乙二醇单烷基醚按照1:1比例混合到二甲苯溶剂中,混合均匀后加热到145℃,并在占二元脂肪酸和聚乙二醇单烷基醚混合物总量0.8%的催还剂参与条件下反应9小时制备而成。
本实施例中,,所述的聚乙二醇单烷基醚中烷基是C1—C22。
本实施例中,,所述的二甲苯溶剂使用量为二元脂肪酸和聚乙二醇单烷基醚混合物总量的15%。
本实施例中,,所述的催化剂为二氯三锡。
一种汽车车身金属结构件防腐油制备工艺,其制备方法为:
将基础油在12分钟内,匀速加热至140℃,并保持匀速单向搅拌状态下保温5分钟,然后将石油磺酸钠、环烷酸锌依次匀速添加到基础油内,与基础油混合均匀并反应10分钟,然后将基础油温度自然冷却至75℃,然后向基础油中加入苯并三氮唑、苯甲酸单乙醇胺、二烷基二硫代磷酸锌、烷基酚聚氧乙烯醚、油酸聚氧乙烯酯,与基础油混合均匀并反应2.5小时,最后将剩余物料依次添加到基础油中,并在75℃恒温条件下搅拌10分钟,搅拌均匀后通过100目过滤筛网过滤后即可得到成品。
本发明原料成本低廉,生产过程简单易学,一方面可有效的降低汽车金属构建防腐有的生产成本,另一方面可有效的提高汽车金属构建防腐油的表面附着能力和耐候能力,并降低防腐油生产和使用时对周边环境的污染性,从而有效的提高防腐油有效的防护时间,降低防腐油的使用成本、腐作业的成本和防腐作业的劳动强度。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解,本发明不受上述实施例的限制,上述实施例和说明书中描述的只是说明本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。
Claims (9)
1.一种汽车车身金属结构件防腐油,其特征在于:所述的汽车车身金属结构件防腐油由以下重量百分比原料组成,石油磺酸钠3%—5%、环烷酸锌1%—5%、二聚油酸单酯5%—10%、成膜剂2%—13%、抗氧化剂0.5%—3.5%、苯并三氮唑0.1%—1.5%、苯甲酸单乙醇胺1.1%—2.5%、二烷基二硫代磷酸锌2.1%—3%、烷基酚聚氧乙烯醚2%—5%、油酸聚氧乙烯酯1.5%—5%、壬基酚氧乙烯醚1.1—2%、辛基酚氧乙烯醚0—1.5%、余量为基础油。
2.根据权利要求1所述的一种汽车车身金属结构件防腐油,其特征在于:所述的成膜剂为丙烯酸树脂成膜剂、丁二烯树脂成膜剂、聚氨酯成膜剂、硝酸纤维成膜剂中的任意一种。
3.根据权利要求1所述的一种汽车车身金属结构件防腐油,其特征在于:所述的抗氧化剂为2,6-二叔丁基-4-甲基苯酚。
4.根据权利要求1所述的一种汽车车身金属结构件防腐油,其特征在于:所述的基础油为全损耗系统油。
5.根据权利要求1所述的一种汽车车身金属结构件防腐油,其特征在于:所述的二聚油酸单酯由二元脂肪酸和聚乙二醇单烷基醚按照1:1比例混合到二甲苯溶剂中,混合均匀后加热到140℃—150℃,并在占二元脂肪酸和聚乙二醇单烷基醚混合物总量0.5%—1%的催还剂参与条件下反应8—12小时制备而成。
6.根据权利要求5所述的一种汽车车身金属结构件防腐油,其特征在于:所述的聚乙二醇单烷基醚中烷基是C1—C22。
7.根据权利要求5所述的一种汽车车身金属结构件防腐油,其特征在于:所述的二甲苯溶剂使用量为二元脂肪酸和聚乙二醇单烷基醚混合物总量的10%—20%。
8.根据权利要求5所述的一种汽车车身金属结构件防腐油,其特征在于:所述的催化剂为甲基苯磺酸、钛酸四丁酯、二氯三锡中的任意一种。
9.一种汽车车身金属结构件防腐油制备工艺,其特征在于:所述的车车身金属结构件防腐油制备方法为:
将基础油在5—15分钟内,匀速加热至100—150℃,并保持匀速单向搅拌状态下保温3—5分钟,然后将石油磺酸钠、环烷酸锌依次匀速添加到基础油内,与基础油混合均匀并反应10—20分钟,然后将基础油温度自然冷却至60℃—80℃,然后向基础油中加入苯并三氮唑、苯甲酸单乙醇胺、二烷基二硫代磷酸锌、烷基酚聚氧乙烯醚、油酸聚氧乙烯酯,与基础油混合均匀并反应2—3小时,最后将剩余物料依次添加到基础油中,并在60℃—80℃恒温条件下搅拌3—10分钟,搅拌均匀后通过50—100目过滤筛网过滤后即可得到成品。
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