CN107057497A - A kind of exterior wall transparent watertight glue and preparation method thereof - Google Patents
A kind of exterior wall transparent watertight glue and preparation method thereof Download PDFInfo
- Publication number
- CN107057497A CN107057497A CN201710354185.XA CN201710354185A CN107057497A CN 107057497 A CN107057497 A CN 107057497A CN 201710354185 A CN201710354185 A CN 201710354185A CN 107057497 A CN107057497 A CN 107057497A
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- Prior art keywords
- exterior wall
- parts
- transparent watertight
- watertight glue
- glue
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of exterior wall transparent watertight glue, the raw material that the exterior wall includes following mass fraction with transparent watertight glue are prepared from：0.1 0.2 parts of 60 70 parts of acrylic emulsion, 20 30 parts of silicone acrylic emulsion, 0.3 0.5 parts of thickener, 5 10 parts of coalescents, 0.5 1 parts of defoamer and pH value conditioning agent；The invention also discloses preparation method of the above-mentioned exterior wall with transparent watertight glue.The exterior wall transparent watertight glue of the present invention has an excellent film forming, soft, tough and tensile to resist stress produced during basic unit's shape cracking, and coating is colourless, transparent, will not destroy former wall decoration effect after coating, is not in turn yellow, be stained with the phenomenons such as dirt；The preparation method of the present invention is simple, easy to control, and manufacturing cost is low, and application method is easy, can directly spray, applies, brushes, scrape on metope.
Description
Technical field
The invention belongs to building material technical field, be related to marine glue, and in particular to a kind of exterior wall with transparent watertight glue and
Its preparation method.
Background technology
Marine glue belongs to chemical products, and its feature has flexible height, waterproof damp proof insulation, cohesive force by force and cracking resistance cohesive force is strong
Deng.Wherein, exterior wall transparent watertight glue is that, using extraordinary copolymer emulsion as base-material, admixture synthetic rubber latex modifying agent, surface are lived
The refined colourless exterior wall waterproofing coatings of macromolecule flexible and transparent such as property agent, plasticizer.Exterior wall transparent watertight glue is used for exterior wall
Decoration, not only waterproof but also attractive in appearance, was the common used material of exterior wall waterproofing coating.
Existing external wall waterproof glue is mainly using JS polymer cement-base waterproof coatings etc., and liquid material is by styrene-acrylic emulsion or VAE
Emulsion is constituted, and a certain proportion of cement is added when using.Be not suitable for using such exterior wall for the outdoor metope for having pasted ceramic tile
Marine glue material, because ceramic tile can be covered, does not reach the effect for keeping exterior wall attractive in appearance and clean and tidy.In addition, such exterior wall is anti-
Glue material fabrication process is complicated, could be brushed after stirring 5-10min is needed before construction, stir to prevent when also needing to during construction
Sink to the bottom, thus manufacturing cost is higher.
The content of the invention
In view of the above, the technical problem to be solved in the present invention is：A kind of exterior wall transparent watertight glue and its system are provided
Preparation Method, reaches strong viscosity and high-effective water-proof performance, reaches protection basic unit waterproof effect, and can retain the ceramic tile in original basic unit face
Aesthetic.
In order to solve the above technical problems, the present invention is adopted the following technical scheme that：
A kind of exterior wall transparent watertight glue, the raw material that the exterior wall includes following mass fraction with transparent watertight glue are prepared from：
60-70 parts of acrylic emulsion；
20-30 parts of silicone acrylic emulsion；
0.3-0.5 parts of thickener；
5-10 parts of coalescents；
0.5-1 parts of defoamer；
0.1-0.2 parts of pH value conditioning agent；
4-9 parts of water.
Further, the thickener uses alkali swelling type thickener.Thickening effect is reached using alkali swelling type thickener
High, viscosity stability is good, good water-retaining property effect, and neutralizes speed soon, and easy to use, compatibility is good, will not be with other components
Flocculate.
Further, the coalescents use one in alcohol ester 12, propandiol butyl ether or propylene glycol methyl ether acetate
Plant or two or more mixing.Such coalescents compatibility is good, and volatility is low, is easily absorbed by latex particle, can be formed excellent
Continuous film, and environmental-protecting performance is superior.
Further, the defoamer uses silicone emulsion defoamer.Defoamer cost of manufacture can effectively be solved high, froth breaking
Effect difference problem.
Further, in the silicone emulsion defoamer by mass percentage, it is included：Silicone oil cream 5.5-7%, CMC-
It is Na 0.5-0.8%, sorbitan oleate 1.1-1.3%, polyoxyethylene sorbitan monooleate 0.45-0.6%, hard
Resin acid 1.1-1.3%, levelling agent O 0.6-0.8%.
Further, the pH value conditioning agent uses AMP95 type pH values conditioning agent, citric acid, acetic acid and lactic acid, carbonic acid
One or both of sodium, potassium carbonate are mixed above.
Further, the content of the acrylic emulsion is set to 60-62%.
Further, the content of the silicone acrylic emulsion is set to 22-30%.
Further, the content of the coalescents is set to 5-5.6%.
A kind of exterior wall transparent watertight glue preparation method, comprises the following steps：
（1）, in production kettle add the acrylic emulsion that has measured of weighing balance, the weight measured should be accurately, during blowing in the person of feeding intake
Way can not be left；
（2）, feed intake after water of being weighed with weighing balance, stir, mixer rotating speed first maintains 350-450r/min；
（3）, with electronics kilogram claim weigh material silicone acrylic emulsion, thickener, coalescents, defoamer respectively, it is standby；
（4）, first put into after emulsion material, 5min into production kettle, then put into coalescents, froth breaking put into again after stirring 5min
Agent；The rotating speed of mixer is improved to 500-550r/min, thickener is slow added into；
（5）, when slurry is substantially thickened, the rotating speed of mixer is improved to 600-800r/min, adding PH conditioning agents makes breast
Liquid PH scopes are stable in 8-9；
（6）, feed intake and finish after, mixer is stirred for 15min-30min, produces product.
In preferred scheme, electronics kilogram claims the addition for weighing material to be respectively accurately controlled in ± 0.01kg.
The present invention provides a kind of exterior wall transparent watertight glue and preparation method thereof, has as follows excellent relative to prior art
Point and effect：
The exterior wall transparent watertight glue of the present invention has excellent film forming, and soft, tough and tensile can resist when basic unit's shape ftractures is produced
Raw stress, coating is colourless, transparent, will not destroy former wall decoration effect after coating, is not in turn yellow, be stained with the phenomenons such as dirt；
In addition, the preparation method of the present invention is simple, easy to control, manufacturing cost is low, and application method is easy, can directly spray, applies, brushes, scrape
On metope.
Embodiment
With reference to embodiment, the embodiment to the present invention is described in further detail.Following examples are used for
Illustrate the present invention, but be not limited to the scope of the present invention.
Embodiment 1
A kind of exterior wall transparent watertight glue and preparation method thereof described in a preferred embodiment of the present invention, the production for preparing to use is set
Have：Pulp blender, production kettle, electronics kilogram claim and fork truck.
Exterior wall transparent watertight glue, is prepared from by the raw material of following mass parts：60 parts of acrylic emulsion, silicone acrylic emulsion
20 parts, 0.5 part of thickener, 10 parts of coalescents, 1 part of defoamer, 8.4 parts of 0.1 part of pH value conditioning agent and water.
In this preferred embodiment, the thickener uses alkali swelling type thickener, and coalescents use alcohol ester 12, froth breaking
Agent uses silicone emulsion defoamer, and pH value conditioning agent uses AMP95 type pH value conditioning agents.
In this preferred embodiment, it is included in the silicone emulsion defoamer by mass percentage：Silicone oil cream 5.5%,
CMC-Na 0.5%, sorbitan oleate 1.1%, polyoxyethylene sorbitan monooleate 0.45%, stearic acid
1.1%th, levelling agent O 0.6%.
The exterior wall is with transparent watertight glue preparation method and step：
（1）, in production kettle add the acrylic emulsion that has measured of weighing balance, the weight measured should be accurately, during blowing in the person of feeding intake
Way can not be left；
（2）, feed intake after water of being weighed with weighing balance, stir, mixer rotating speed first maintains 350-450r/min；
（3）, with electronics kilogram claim weigh material silicone acrylic emulsion, thickener, coalescents, defoamer respectively, it is standby；
（4）, first put into after emulsion material, 5min into production kettle, then put into coalescents, froth breaking put into again after stirring 5min
Agent；The rotating speed of mixer is improved to 500-550r/min, thickener is slow added into；
（5）, when slurry is substantially thickened, the rotating speed of mixer is improved to 600-800r/min, adding PH conditioning agents makes breast
Liquid PH scopes are stable in 8-9；
（6）, feed intake and finish after, mixer is stirred for 15min-30min, produces product.
Before feeding intake, check whether production kettle outlet at bottom closes, according to factory formula list blanking.Each former material is weighed with metering
Material, the weight measured should be accurate, and the person of feeding intake midway can not be left during blowing；
Feed intake after finishing, above material should put playback in time.15min-30min is stirred for, is kept sample.Film is after solid
（12-24 hours）Form transparent waterproof glued membrane.The product for weighing 1kg is kept sample, and is tested by Quality Inspector, and it is qualified to examine
Blowing afterwards；Blowing is finished, and production kettle and mixer are cleaned with clear water, and cleaning waste water pours into conservation tank.
Embodiment 2
A kind of exterior wall transparent watertight glue of one of the present embodiment, this preferred embodiment 2 is compared with Example 1 compared with only base
Plinth formula rate is different, and wherein preparation method is identical.
Exterior wall transparent watertight glue, is prepared from by the raw material of following mass parts：70 parts of acrylic emulsion, silicone acrylic emulsion
20 parts, 0.3 part of thickener, 5 parts of coalescents, 0.5 part of defoamer, 4 parts of 0.2 part of pH value conditioning agent and water.
In this preferred embodiment, the thickener uses alkali swelling type thickener, and coalescents use alcohol ester 12, froth breaking
Agent uses silicone emulsion defoamer, and pH value conditioning agent uses AMP95 type pH value conditioning agents.
In this preferred embodiment, it is included in the silicone emulsion defoamer by mass percentage：Silicone oil cream 5.5%,
CMC-Na 0.5%, sorbitan oleate 1.1%, polyoxyethylene sorbitan monooleate 0.45%, stearic acid
1.1%th, levelling agent O 0.6%.
Embodiment 3
A kind of exterior wall transparent watertight glue of one of the present embodiment, this preferred embodiment 3 is compared with Example 1 compared with only base
Plinth formula rate is different, and wherein preparation method is identical.
Exterior wall transparent watertight glue, is prepared from by the raw material of following mass parts：60 parts of acrylic emulsion, silicone acrylic emulsion
30 parts, 0.3 part of thickener, 5 parts of coalescents, 0.5 part of defoamer, 4.1 parts of 0.1 part of pH value conditioning agent and water.
In this preferred embodiment, the thickener uses alkali swelling type thickener, and coalescents use propandiol butyl ether, disappeared
Infusion uses silicone emulsion defoamer, and pH value conditioning agent uses citric acid.
In this preferred embodiment, it is included in the silicone emulsion defoamer by mass percentage：Silicone oil cream 7%,
CMC-Na 0.8%, sorbitan oleate 1.3%, polyoxyethylene sorbitan monooleate 0.6%, stearic acid 1.3%,
Levelling agent O 0.8%.
Embodiment 4
A kind of exterior wall transparent watertight glue of one of the present embodiment, this preferred embodiment 4 is compared with Example 1 compared with only base
Plinth formula rate is different, and wherein preparation method is identical.
Exterior wall transparent watertight glue, is prepared from by the raw material of following mass parts：62 parts of acrylic emulsion, silicone acrylic emulsion
22 parts, 0.4 part of thickener, 5.6 parts of coalescents, 0.85 part of defoamer, 9 parts of 0.15 part of pH value conditioning agent and water.
In this preferred embodiment, the thickener uses alkali swelling type thickener, and coalescents use propandiol butyl ether, disappeared
Infusion uses silicone emulsion defoamer, and pH value conditioning agent uses citric acid.
In this preferred embodiment, it is included in the silicone emulsion defoamer by mass percentage：Silicone oil cream 7%,
CMC-Na 0.8%, sorbitan oleate 1.3%, polyoxyethylene sorbitan monooleate 0.6%, stearic acid 1.3%,
Levelling agent O 0.8%.
With reference to GB/T 9755-2001《Exterior wall coating material of synthetic resin emulsion》What is obtained in standard, each embodiment of detection is outer
The performance of wall transparent watertight glue, detection project is related to water resistance, coating heatproof variability and weatherability etc..
| Classification | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Appearance of film | Into transparence after film forming | Into transparence after film forming | Into transparence after film forming | Into transparence after film forming |
| Water resistance | Water resistance 85 hours is without exception | Water resistance 115 hours is without exception | Water resistance 105 hours is without exception | Water resistance 96 hours is without exception |
| Application property | Brush two roads accessible | Brush two roads accessible | Brush two roads accessible | Brush two roads accessible |
| Coating temperature-change resistance（5 circulations） | It is without exception | It is without exception | It is without exception | It is without exception |
| Anti- salt solution permeability | 90 hours without exception | 120 hours without exception | 112 hours without exception | 105 hours without exception |
Existing exterior wall is without exception with water resistance 24-48 hours of transparent watertight glue, and anti-salt solution permeability 24-48 is small
When it is without exception, coating temperature-change resistance can only by 2-3 time circulates.Thus exterior wall has with the performance of transparent watertight glue in the present embodiment
It is significantly improved.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, should all be included within the scope of the present invention.Therefore, it is of the invention
Protection domain should be determined by the scope of protection defined in the claims.
Claims (10)
1. a kind of exterior wall transparent watertight glue, it is characterised in that the exterior wall includes the original of following mass fraction with transparent watertight glue
Material is prepared from：
60-70 parts of acrylic emulsion；
20-30 parts of silicone acrylic emulsion；
0.3-0.5 parts of thickener；
5-10 parts of coalescents；
0.5-1 parts of defoamer；
0.1-0.2 parts of pH value conditioning agent；
4-9 parts of water.
2. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The thickener is increased using alkali swelling type
Thick dose.
3. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The coalescents use alcohol ester ten
2nd, one or both of propandiol butyl ether or propylene glycol methyl ether acetate are mixed above.
4. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The defoamer is disappeared using silicone emulsion
Infusion.
5. exterior wall according to claim 4 transparent watertight glue, it is characterised in that：Matter is pressed in the silicone emulsion defoamer
Percentages are measured, it is included：Silicone oil cream 5.5-7%, CMC-Na 0.5-0.8%, sorbitan oleate 1.1-1.3%, polyoxy
Ethene Arlacel-80 0.45-0.6%, stearic acid 1.1-1.3%, levelling agent O 0.6-0.8%.
6. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The pH value conditioning agent uses AMP95
Type pH value conditioning agent, citric acid, acetic acid and lactic acid, one or both of sodium carbonate, potassium carbonate are mixed above.
7. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The content of the acrylic emulsion is set
For 60-62%.
8. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The content of the silicone acrylic emulsion is set to
22-30%。
9. exterior wall according to claim 1 transparent watertight glue, it is characterised in that：The content of the coalescents is set to
5-5.6%。
10. a kind of exterior wall transparent watertight glue preparation method, it is characterised in that comprise the following steps：
（1）, in production kettle add the emulsion that has measured of weighing balance, the weight measured should be accurate, and the person of feeding intake halfway can not during blowing
Leave；
（2）, feed intake after water of being weighed with weighing balance, stir, mixer rotating speed first maintains 350-450r/min；
（3）, with electronics kilogram claim weigh material emulsion, thickener, coalescents, defoamer respectively, it is standby；
（4）, first put into after emulsion material, 5min into production kettle, then put into coalescents, froth breaking put into again after stirring 5min
Agent；The rotating speed of mixer is improved to 500-550r/min, thickener is slow added into；
（5）, when slurry is substantially thickened, the rotating speed of mixer is improved to 600-800r/min, adding PH conditioning agents makes breast
Liquid PH scopes are stable in 8-9；
（6）, feed intake and finish after, mixer is stirred for 15min-30min, produces product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354185.XA CN107057497A (en) | 2017-05-18 | 2017-05-18 | A kind of exterior wall transparent watertight glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710354185.XA CN107057497A (en) | 2017-05-18 | 2017-05-18 | A kind of exterior wall transparent watertight glue and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107057497A true CN107057497A (en) | 2017-08-18 |
Family
ID=59609376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710354185.XA Pending CN107057497A (en) | 2017-05-18 | 2017-05-18 | A kind of exterior wall transparent watertight glue and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108049508A (en) * | 2017-11-28 | 2018-05-18 | 中国二十冶集团有限公司 | Toilet warterproof maintenance construction method |
| CN109439078A (en) * | 2018-11-14 | 2019-03-08 | 广东建王防水科技有限公司 | Environment-friendly waterproof coating for exterior wall and preparation method thereof |
| CN109501290A (en) * | 2019-01-03 | 2019-03-22 | 武汉思唯电子有限公司 | A kind of packaging method that display equipment in open air is waterproof and dampproof |
| CN111876100A (en) * | 2020-08-14 | 2020-11-03 | 赣州市犇牛防水建材有限公司 | Strong transparent waterproof glue for outer wall and preparation method thereof |
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| CN101357309A (en) * | 2008-09-26 | 2009-02-04 | 贺明波 | Silicon oil foam killer |
| CN101735750A (en) * | 2010-01-13 | 2010-06-16 | 康信勇 | Waterproof glue for external wall ceramic tile |
| CN102295868A (en) * | 2010-06-25 | 2011-12-28 | 苏州美亚美建筑涂料有限公司 | Silicone-acrylic latex paint |
| CN102558995A (en) * | 2012-01-06 | 2012-07-11 | 长沙大禹建筑防水工程有限公司 | Waterproof adhesive for outer walls and preparing method thereof |
| CN103589260A (en) * | 2013-11-08 | 2014-02-19 | 青岛益群漆业集团有限公司 | Super-weather-resistant elastic exterior wall coating |
| CN106608720A (en) * | 2016-11-11 | 2017-05-03 | 北京仁创生态环保科技股份公司 | Waterproof and breathable paint composition, waterproof and breathable material and preparation method thereof |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101357309A (en) * | 2008-09-26 | 2009-02-04 | 贺明波 | Silicon oil foam killer |
| CN101735750A (en) * | 2010-01-13 | 2010-06-16 | 康信勇 | Waterproof glue for external wall ceramic tile |
| CN102295868A (en) * | 2010-06-25 | 2011-12-28 | 苏州美亚美建筑涂料有限公司 | Silicone-acrylic latex paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108049508A (en) * | 2017-11-28 | 2018-05-18 | 中国二十冶集团有限公司 | Toilet warterproof maintenance construction method |
| CN109439078A (en) * | 2018-11-14 | 2019-03-08 | 广东建王防水科技有限公司 | Environment-friendly waterproof coating for exterior wall and preparation method thereof |
| CN109501290A (en) * | 2019-01-03 | 2019-03-22 | 武汉思唯电子有限公司 | A kind of packaging method that display equipment in open air is waterproof and dampproof |
| CN111876100A (en) * | 2020-08-14 | 2020-11-03 | 赣州市犇牛防水建材有限公司 | Strong transparent waterproof glue for outer wall and preparation method thereof |
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Application publication date: 20170818 |
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