CN107033535A - A kind of environment-friendly resin artwork and its handicraft preparation method with long-acting aromatic - Google Patents
A kind of environment-friendly resin artwork and its handicraft preparation method with long-acting aromatic Download PDFInfo
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- CN107033535A CN107033535A CN201710167691.8A CN201710167691A CN107033535A CN 107033535 A CN107033535 A CN 107033535A CN 201710167691 A CN201710167691 A CN 201710167691A CN 107033535 A CN107033535 A CN 107033535A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08L61/14—Modified phenol-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
- C08J2361/14—Modified phenol-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
It is made the invention discloses a kind of environment-friendly resin artwork with long-acting aromatic and its handicraft preparation method, including following quality than each component of number：85 95 parts of Modified Water Soluble Phenolic Resin, 30 40 parts of filler, 20 30 parts of maleic anhydride inoculated polypropylene, 45 parts of photochromic composite granule, 79 parts of reinforcing agent, 0.8 1 parts of surfactant, 05 parts of curing agent, 5 10 parts of formaldehyde catching agent, 0.5 0.6 parts of antioxidant.The invention also discloses the method for above-mentioned environment-friendly resin artwork preparation technology product.Compared with prior art, the environment-friendly resin artwork of the present invention has ability of reverse photochromism feature, stealthy effect is reached by controlling the intensity and wave band of irradiation light that handicraft can be made consistent with surrounding environment color, interesting and mystique is good, also has the advantages that good toughness, intensity are high, weatherability is good, is easy to shaping and the demoulding, Environmental Safety.
Description
Technical field
The present invention relates to handicraft technical field, prepared by more particularly to a kind of environment-friendly resin artwork and its handicraft
Method.
Background technology
With the continuous improvement of people's living standards, resin craft is also increasingly favored by consumer, various
The various new technology product demand increases of traditional festival such as Christmas Day, Easter, Valentine's Day etc., interest, the hobby of consumer also exist
It is continually changing, excessively common decoration functions can not attract the eyeball of people.Therefore, new resin craft needs to introduce
New science and technology, new material, new design, new subject matter etc. are to strengthen the diversity and feature of product.And existing resin craft is also
There are some defects, be such as easily broken, content of beary metal is exceeded, cost is high, weather resisteant is bad, easily occur in knockout course incomplete
Portion, crude phenomenon, handicraft color function are single, it is necessary to spray multiple protective paint etc., it is impossible to meet the multi-faceted demand of people.
The content of the invention
It is an object of the present invention to for a kind of the above-mentioned not enough there is provided environment-friendly resin artwork of prior art, have
There is ability of reverse photochromism feature, reached by controlling the intensity and wave band of irradiation light that handicraft can be made consistent with surrounding environment color
To stealthy effect, interesting and mystique is good, and also with good toughness, intensity is high, weatherability is good, be easy to shaping and the demoulding, environmental protection
Safe the advantages of.
Another object of the present invention is to there is provided the method that above-mentioned environment-friendly resin artwork is prepared into handicraft.
The present invention is reaches that the technical scheme that above-mentioned purpose is used is：
A kind of environment-friendly resin artwork, including following quality are made than each component of number：
It is 85-95 parts of Modified Water Soluble Phenolic Resin, 30-40 parts of filler, 20-30 parts of maleic anhydride inoculated polypropylene, photochromic
4-5 parts of composite granule, 7-9 parts of reinforcing agent, 0.8-1 parts of surfactant, 0-5 parts of curing agent, 5-10 parts of formaldehyde catching agent, antioxygen
0.5-0.6 parts of agent.
Further, described Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 18-
20%th, formaldehyde 50-60%, urea 4-6%, cashew nut oil 6-10%, lignosulfonates 10-20%, 10wt% sodium hydroxide solution
1.5-5%。
Further, described photochromic composite granule is photochromic in Ultrafine Mica Surface coating by spray drying process
Oxide sol and obtain, the mass ratio of Ultrafine Mica and photochromic oxide sol is 10：1-3, wherein photochromic oxidation
Thing colloidal sol is any in photochromic tungsten oxide colloidal sol, photochromic titanium dioxide sol, photochromic molybdenum trioxide colloidal sol
Kind.
Further, described reinforcing agent is diphenyl ether type azopolyamide, the grafting of spiro-pyrans grafted chitosan, Luo oxazines
Any of chitosan.
Further, described filler is glass fibre and appointing in talcum powder, graphite microparticles, glass microballoon, chalazie
The one or two kinds of compoundings of meaning are formed.
Further, described surfactant is coconutalkyl oxalamide, neopelex, single tristearin
Any of acid glyceride or two kinds.
Further, described curing agent is any of melamine, hexamethylenetetramine.
Further, described antioxidant is any of antioxidant 1010, irgasfos 168, antioxidant 703.
Further, described formaldehyde catching agent is polyacrylamide solution.
A kind of method of above-mentioned environment-friendly resin artwork preparation technology product, comprises the following steps：
S1, preparation Modified Water Soluble Phenolic Resin：
Phenol 18-20wt% is added in reactor, heating melts to liquid, the sodium hydroxide solution of half is added, in 50-55
30-40min is stirred at DEG C, 10-20wt% lignosulfonates, 6-10wt% cashew nut oils, 4-6wt% urea are added into reactor,
Stir, formaldehyde is added into reactor and is heated up simultaneously, added in 30min and finish whole 50-60wt% formaldehyde and be warming up to
100 DEG C, 80 DEG C are cooled to after insulation reaction 10min, and insulation reaction is cooled to rapidly room temperature after 2 hours, adds remaining hydrogen-oxygen
Change after sodium solution, stirring 30min, decompression dehydration, discharging obtains Modified Water Soluble Phenolic Resin, standby, wherein sodium hydroxide is molten
The total amount of liquid is 1.5-5wt%, and the mass fraction of sodium hydroxide solution is 10wt%；
S2：Preparation formaldehyde catching agent：
Acrylamide is made into the 10wt% aqueous solution, in the mistake at 70~80 DEG C, adding the 1wt% that consumption is acrylamide quality
Ammonium sulfate obtains polyacrylamide solution after triggering Raolical polymerizable, 4~6h of reaction, standby；
S3：Modified Water Soluble Phenolic Resin is added water scattered, obtain mass fraction 60-65wt% Modified Water Soluble Phenolic Resin
Dispersion liquid, adds filler, antioxidant, photochromic composite granule, formaldehyde catching agent, maleic anhydride inoculated polypropylene, increasing afterwards
Strong agent, surfactant, stir, and after addition curing agent is stirred until homogeneous afterwards, vacuumize, are stripped, put after 15~20min
Put after 5~8 days, the polymethacrylate varnish of a floor height printing opacity high transparency is coated in product surface, you can obtain final
Product.
Compared with prior art, the environment-friendly resin artwork that the present invention is provided has ability of reverse photochromism feature, leads to
Spending intensity, wave band, time of control and regulation irradiation light etc. can make handicraft consistent with surrounding environment color and reach stealthy effect,
Interesting and mystique is good, also has the advantages that good toughness, intensity are high, weatherability is good, is easy to shaping and the demoulding, Environmental Safety.
The environment-friendly resin artwork that the present invention is provided is in preparation technology product, and handicraft surface is substantially flawless after the demoulding
Defect, only need to spray the mixing varnish of layer of transparent, resin craft is absorbed to the ultraviolet light of different-waveband varying strength, resin
Color change can be produced, also have stealthy effect, melt art and be practically applicable to one, can be used for various personages, animal, bonsai flower,
In terms of utensil jewellery, board extension, ornament, sculpture.
Above-mentioned is the general introduction of inventive technique scheme, and below in conjunction with embodiment, the present invention will be further described.
Embodiment：
In order that the purpose of the present invention and technical scheme and advantage are more clearly understood, elaborate with reference to embodiments.
It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
Embodiment 1：A kind of environment-friendly resin artwork that the present embodiment is provided, including following quality is than each group of number
Divide and be made：85 parts of Modified Water Soluble Phenolic Resin, 40 parts of filler, 20 parts of maleic anhydride inoculated polypropylene, photochromic composite powder
5 parts of body, 7 parts of reinforcing agent diphenyl ether type azopolyamide, 1 part of surfactant coconutalkyl oxalamide, curing agent trimerization
0 part of cyanamide, 10 parts of formaldehyde catching agent, 0.5 part of antioxidant 1010.
Wherein, Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 18%, formaldehyde 60%, urine
Element 4%, cashew nut oil 6%, lignosulfonates 10%, 10wt% sodium hydroxide solution 2%, cashew nut oil, lignosulfonates etc. are
Formed for that can buy or can make by oneself on existing market, be raw material well known in the art.Utilize urea, cashew nut oil, lignosulfonates
To phenolic resin modified, free formaldehyde in resin is reduced, water soluble phenol resin is obtained, the feature of environmental protection is good, and cost is low, fragility drop
It is low, toughness increase, chemicals-resistant, it is easy to be molded, it is easy to be stripped.
Photochromic composite granule is in the photochromic oxide sol of Ultrafine Mica Surface coating by spray drying process
And obtain, the mass ratio of Ultrafine Mica and photochromic oxide sol is 10：1-3, wherein photochromic oxide sol can be with
Any of photochromic tungsten oxide colloidal sol, photochromic titanium dioxide sol, photochromic molybdenum trioxide colloidal sol are selected, this
The mass ratio of the photochromic tungsten oxide colloidal sol of embodiment selection, Ultrafine Mica and photochromic oxide sol is 10：1, simultaneously
Here photochromic tungsten oxide colloidal sol, photochromic titanium dioxide sol, the preparation method of photochromic molybdenum trioxide colloidal sol are adopted
Prepared with existing common process method, resin can be provided with reversible photochromic effect, be absorbed to different-waveband different strong
The ultraviolet light of degree, resin can produce color change, also have stealthy effect, and spray drying process etc. has also been people in the art in addition
Member knows, no longer burdensome herein.Reinforcing agent is diphenyl ether type azopolyamide, spiro-pyrans grafted chitosan, Luo oxazine graft shells
Any of glycan, diphenyl ether type azopolyamide here exists according to remaining joyful grade《Plastics industry》" the diphenyl ether delivered
Method is prepared in synthesis, structure and the performance study of type azopolyamide ", the grafting of spiro-pyrans grafted chitosan, Luo oxazines
Chitosan is existed using Liu Maodong etc.《Northwest Normal University》" chitosan graft/doping spiro-pyrans, Luo the oxazines and its photic delivered
The method of the research of discoloration " is prepared from, and directly chromophoric group is introduced into reinforced resin, enhances resin photochromic
Durability, improve effect life-span of handicraft, the present embodiment uses diphenyl ether type azopolyamide.Filler can be selected
Glass fibre is formed with any one in talcum powder, graphite microparticles, glass microballoon, chalazie or two kinds of compoundings, glass fibre
It is scattered in and certain filling and humidification is played in resin, add the intensity of resin, serves the scattered effect of stress, this
Embodiment is using glass fibre and talcum powder in mass ratio 3：The filler of 2 compoundings；Surfactant can select coconut oil
Any of alkyl oxalamide, neopelex, glycerin monostearate or two kinds, it is compatible with other compositions
Property it is good, dispersion effect is good, promote each component between interpenetrate, strengthen each component intermolecular interaction effect；Curing agent can be with
Select any of melamine, hexamethylenetetramine；Antioxidant can select antioxidant 1010, irgasfos 168, antioxidant
Any of 703；Filler, surfactant, curing agent, antioxidant etc. are raw material well known to those skilled in the art；First
Aldehyde agent for capturing is polyacrylamide solution, further reduces the release of formaldehyde, strengthens the environmental-protecting performance of product.
The method that the present embodiment also provides above-mentioned environment-friendly resin artwork preparation technology product, comprises the following steps：
S1, preparation Modified Water Soluble Phenolic Resin：Raw material is weighed according to above-mentioned setting ratio, first adds phenol in reactor,
Heating melts to liquid, adds the sodium hydroxide solution of half, stirs 40min at 50 DEG C, lignin is added into reactor
Sulfonate, cashew nut oil, urea, are stirred, and formaldehyde is added into reactor and is heated up simultaneously, are added in 30min and are finished whole
Formaldehyde and it is warming up to after 100 DEG C, insulation reaction 10min and is cooled to 80 DEG C, insulation reaction is cooled to rapidly room temperature after 2 hours, plus
Enter after remaining sodium hydroxide solution, stirring 30min, decompression dehydration, discharging obtains Modified Water Soluble Phenolic Resin, standby, hydrogen
The mass fraction of sodium hydroxide solution is 10wt%.
S2：Preparation formaldehyde catching agent：
Acrylamide is made into the 10wt% aqueous solution, in the mistake at 70~80 DEG C, adding the 1wt% that consumption is acrylamide quality
Ammonium sulfate obtains polyacrylamide solution after triggering Raolical polymerizable, 4~6h of reaction, standby；
S3：Raw material is weighed by setting ratio, Modified Water Soluble Phenolic Resin is added water scattered, changing for mass fraction 60wt% is obtained
Property water soluble phenol resin dispersion liquid, afterwards add filler, antioxidant, photochromic composite granule, formaldehyde catching agent, maleic acid
Acid anhydride graft polypropylene, reinforcing agent, surfactant, stir, and after addition curing agent is stirred until homogeneous afterwards, vacuumize, 15
It is stripped after~20min, after placing 5~8 days, the polymethacrylate for coating a floor height printing opacity high transparency in product surface is clear
Paint, you can obtain end article.
Embodiment 2：The present embodiment provide a kind of environment-friendly resin artwork and its handicraft preparation method, its with
Embodiment 1 is essentially identical, and difference is：
A kind of environment-friendly resin artwork, including following quality are made than each component of number：Modified Water Soluble Phenolic Resin
95 parts, 30 parts of filler, 30 parts of maleic anhydride inoculated polypropylene, 4 parts of photochromic composite granule, reinforcing agent spiro-pyrans graft shell gather
It is 9 parts of sugar, 0.8 part of surfactant sodium dodecyl base benzene sulfonic acid sodium salt, 5 parts of curing agent hexamethylenetetramine, 5 parts of formaldehyde catching agent, anti-
168 0.6 parts of oxygen agent；The mass ratio of Ultrafine Mica and photochromic titanium dioxide sol is in wherein photochromic composite granule
5：1；Filler is glass fibre and graphite microparticles, glass microballoon in mass ratio 3：1：1 compounding is formed.
It is preferred that, Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 20%, formaldehyde 50%, urine
Element 6%, cashew nut oil 10%, lignosulfonates 12.5%, sodium hydroxide solution 1.5%.The step S3 in handicraft preparation process:
By Modified Water Soluble Phenolic Resin it is water-dispersible obtain mass fraction be 65wt% Modified Water Soluble Phenolic Resin dispersion liquid, it is standby
With.
Other are same as Example 1, no longer burdensome herein.
Embodiment 3：The present embodiment provide a kind of environment-friendly resin artwork and its handicraft preparation method, its with
Embodiment 1 is essentially identical, and difference is：
A kind of environment-friendly resin artwork, including following quality are made than each component of number：Modified Water Soluble Phenolic Resin
88 parts, 33 parts of filler, 25 parts of maleic anhydride inoculated polypropylene, 4.5 parts of photochromic composite granule, reinforcing agent Luo oxazine graft shells
8 parts of glycan, 0.9 part of surfactant glycerin monostearate, 2 parts of curing agent melamine, 6 parts of formaldehyde catching agent, antioxidant
703 0.5 parts；The mass ratio of Ultrafine Mica and photochromic molybdenum trioxide colloidal sol is 10 in wherein photochromic composite granule：3；
Filler is glass fibre and talcum powder, chalazie in mass ratio 2：2：1 compounding is formed.
It is preferred that, Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 18.5%, formaldehyde 50%,
Urea 4%, cashew nut oil 6%, lignosulfonates 20%, sodium hydroxide solution 1.5%.The step S3 in handicraft preparation process:Will
The water-dispersible Modified Water Soluble Phenolic Resin dispersion liquid for obtaining mass fraction for 65wt% of Modified Water Soluble Phenolic Resin, it is standby.
Other are same as Example 1, no longer burdensome herein.
Embodiment 4：The present embodiment provide a kind of environment-friendly resin artwork and its handicraft preparation method, its with
Embodiment 1 is essentially identical, and difference is：
A kind of environment-friendly resin artwork, including following quality are made than each component of number：Modified Water Soluble Phenolic Resin
90 parts, 36 parts of filler, 26 parts of maleic anhydride inoculated polypropylene, 5 parts of photochromic composite granule, reinforcing agent spiro-pyrans graft shell gather
It is 9 parts of sugar, 1 part of surfactant coconutalkyl oxalamide, 4 parts of curing agent hexamethylenetetramine, 8 parts of formaldehyde catching agent, anti-
168 0.6 parts of oxygen agent；The mass ratio of Ultrafine Mica and photochromic tungsten oxide colloidal sol is 10 in wherein photochromic composite granule：
1；Filler is glass fibre and glass microballoon in mass ratio 3：2 compoundings are formed.
It is preferred that, Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 19%, formaldehyde 52%, urine
Element 5%, cashew nut oil 7%, lignosulfonates 12%, sodium hydroxide solution 5%.The step S3 in handicraft preparation process:Will be modified
The water-dispersible Modified Water Soluble Phenolic Resin dispersion liquid for obtaining mass fraction for 65wt% of water soluble phenol resin, it is standby.
Other are same as Example 1, no longer burdensome herein.
Embodiment 5：The present embodiment provide a kind of environment-friendly resin artwork and its handicraft preparation method, its with
Embodiment 1 is essentially identical, and difference is：
A kind of environment-friendly resin artwork, including following quality are made than each component of number：Modified Water Soluble Phenolic Resin
92 parts, 38 parts of filler, 27 parts of maleic anhydride inoculated polypropylene, 5 parts of photochromic composite granule, reinforcing agent diphenyl ether type azo gather
7 parts of acid amides, 1 part of surfactant, 5 parts of curing agent melamine, 8 parts of formaldehyde catching agent, 0.6 part of antioxidant 1010；Wherein,
The mass ratio of Ultrafine Mica and photochromic titanium dioxide sol is 10 in photochromic composite granule：3；Surfactant is coconut palm
Seed oil alkyl oxalamide and glycerin monostearate in mass ratio 1：1 compounding is formed；Filler be glass fibre and graphite microparticles,
Chalazie in mass ratio 2：1：1 compounding is formed.
It is preferred that, Modified Water Soluble Phenolic Resin is made up of the component of following mass percent：Phenol 18%, formaldehyde 55%, urine
Element 5%, cashew nut oil 8%, lignosulfonates 11%, sodium hydroxide solution 3%.The step S3 in handicraft preparation process:Will be modified
The water-dispersible Modified Water Soluble Phenolic Resin dispersion liquid for obtaining mass fraction for 65wt% of water soluble phenol resin, it is standby.
Other are same as Example 1, no longer burdensome herein.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and changed.Therefore, the invention is not limited in embodiment disclosed and described above, to the one of invention
A little modifications and changes should also be as falling into the scope of the claims of the present invention.
Claims (10)
1. a kind of environment-friendly resin artwork with long-acting aromatic, it is characterised in that more each than number including following quality
Component is made：
It is 85-95 parts of Modified Water Soluble Phenolic Resin, 30-40 parts of filler, 20-30 parts of maleic anhydride inoculated polypropylene, photochromic
4-5 parts of composite granule, 7-9 parts of reinforcing agent, 0.8-1 parts of surfactant, 0-5 parts of curing agent, 5-10 parts of formaldehyde catching agent, antioxygen
0.5-0.6 parts of agent.
2. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described modification
Water soluble phenol resin is made up of the component of following mass percent：Phenol 18-20%, formaldehyde 50-60%, urea 4-6%, waist
Fruit oil 6-10%, lignosulfonates 10-20%, 10wt% sodium hydroxide solution 1.5-5%.
3. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described is photic
The composite granule that changes colour is obtained, Ultrafine Mica in the photochromic oxide sol of Ultrafine Mica Surface coating by spray drying process
Mass ratio with photochromic oxide sol is 10：1-3, wherein photochromic oxide sol is that photochromic tungsten oxide is molten
Any of glue, photochromic titanium dioxide sol, photochromic molybdenum trioxide colloidal sol.
4. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described enhancing
Agent is any of diphenyl ether type azopolyamide, spiro-pyrans grafted chitosan, Luo oxazine grafted chitosans.
5. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described filler
Formed for glass fibre with any one in talcum powder, graphite microparticles, glass microballoon, chalazie or two kinds of compoundings.
6. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described surface
Activating agent is any of coconutalkyl oxalamide, neopelex, glycerin monostearate or two kinds.
7. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described solidification
Agent is any of melamine, hexamethylenetetramine.
8. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described antioxygen
Agent is any of antioxidant 1010, irgasfos 168, antioxidant 703.
9. there is the environment-friendly resin artwork of long-acting aromatic as claimed in claim 1, it is characterised in that described formaldehyde
Agent for capturing is polyacrylamide solution.
10. a kind of one of the use claim 1-9 environment-friendly resin artwork preparation technology product with long-acting aromatic
Method, it is characterised in that comprise the following steps：
S1, preparation Modified Water Soluble Phenolic Resin：
Phenol 18-20wt% is added in reactor, heating melts to liquid, the sodium hydroxide solution of half is added, in 50-55
30-40min is stirred at DEG C, 10-20wt% lignosulfonates, 6-10wt% cashew nut oils, 4-6wt% urine are added into reactor
Element, is stirred, and formaldehyde is added into reactor and is heated up simultaneously, is added in 30min and is finished whole 50-60wt% formaldehyde and liter
Temperature is cooled to 80 DEG C to 100 DEG C after insulation reaction 10min, and insulation reaction is cooled to rapidly room temperature after 2 hours, adds remaining
After sodium hydroxide solution, stirring 30min, decompression dehydration, discharging obtains Modified Water Soluble Phenolic Resin, standby, wherein hydroxide
The total amount of sodium solution is 1.5-5wt%, and the mass fraction of sodium hydroxide solution is 10wt%；
S2：Preparation formaldehyde catching agent：
Acrylamide is made into the 10wt% aqueous solution, is the 1wt%'s of acrylamide quality at 70~80 DEG C, adding consumption
Ammonium persulfate obtains polyacrylamide solution after triggering Raolical polymerizable, 4~6h of reaction, standby；
S3：Modified Water Soluble Phenolic Resin is added water scattered, obtain mass fraction 60-65wt% Modified Water Soluble Phenolic Resin
Dispersion liquid, adds filler, antioxidant, photochromic composite granule, formaldehyde catching agent, maleic anhydride inoculated polypropylene, increasing afterwards
Strong agent, surfactant, stir, and after addition curing agent is stirred until homogeneous afterwards, vacuumize, are stripped, put after 15~20min
Put after 5~8 days, the polymethacrylate varnish of a floor height printing opacity high transparency is coated in product surface, you can obtain final
Product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710167691.8A CN107033535A (en) | 2017-03-20 | 2017-03-20 | A kind of environment-friendly resin artwork and its handicraft preparation method with long-acting aromatic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710167691.8A CN107033535A (en) | 2017-03-20 | 2017-03-20 | A kind of environment-friendly resin artwork and its handicraft preparation method with long-acting aromatic |
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| Publication Number | Publication Date |
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| CN107033535A true CN107033535A (en) | 2017-08-11 |
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|---|---|---|---|
| CN201710167691.8A Pending CN107033535A (en) | 2017-03-20 | 2017-03-20 | A kind of environment-friendly resin artwork and its handicraft preparation method with long-acting aromatic |
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| CN (1) | CN107033535A (en) |
Cited By (2)
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| CN109485846A (en) * | 2018-11-01 | 2019-03-19 | 武汉纺织大学 | Photosensitive colour-changing selfreparing intelligence nylon 6 and preparation method thereof |
| CN110525105A (en) * | 2019-09-16 | 2019-12-03 | 韩东 | A kind of funeral and interment handicraft and preparation method |
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Application publication date: 20170811 |