CN107914353B - Release agent for acrylic production - Google Patents
Release agent for acrylic production Download PDFInfo
- Publication number
- CN107914353B CN107914353B CN201711324434.7A CN201711324434A CN107914353B CN 107914353 B CN107914353 B CN 107914353B CN 201711324434 A CN201711324434 A CN 201711324434A CN 107914353 B CN107914353 B CN 107914353B
- Authority
- CN
- China
- Prior art keywords
- parts
- resin
- acrylic
- release agent
- montmorillonite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 22
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 16
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 229920002749 Bacterial cellulose Polymers 0.000 claims abstract description 16
- 241001474374 Blennius Species 0.000 claims abstract description 16
- 229920001807 Urea-formaldehyde Polymers 0.000 claims abstract description 16
- 239000005016 bacterial cellulose Substances 0.000 claims abstract description 16
- 239000003822 epoxy resin Substances 0.000 claims abstract description 16
- 239000003208 petroleum Substances 0.000 claims abstract description 16
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 16
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 15
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 15
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 15
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 15
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 15
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 15
- 239000003549 soybean oil Substances 0.000 claims abstract description 15
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 18
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000003292 glue Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 238000009991 scouring Methods 0.000 abstract description 3
- 239000000499 gel Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
- B29C33/62—Releasing, lubricating or separating agents based on polymers or oligomers
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Lubricants (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a release agent for acrylic production, which consists of the following substances: epoxy resin, petroleum resin, urea resin, acrylic resin, epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed gel, bacterial cellulose, ethylene glycol and water. The release agent prepared by the invention has good temperature resistance, wear resistance and repeated scouring resistance, effectively improves the surface smoothness of the acrylic sheet, has good adhesion and stable quality, and has strong market competitiveness and popularization and use values.
Description
Technical Field
The invention belongs to the technical field of acrylic processing treatment, and particularly relates to a release agent for acrylic production.
Background
Acrylic, also known as plexiglass, is chemically known as polymethyl methacrylate and is transparent like glass. Acrylic has good chemical stability, easy dyeing, easy processing and beautiful appearance, is widely popular with people and is widely applied to modern people life.
In the process of processing and forming acrylic, a die plays a crucial role, and the surface state and the size precision of the die directly influence the quality of a product. Since the mold is generally made of an alloy material, the heated raw material mixture is easily adhered to the surface of the mold during the molding process, and is difficult to fall off, so that a release agent is required to improve the release efficiency and quality. The existing mold release agent mostly has the problems of weak anti-scouring capability, low thermal stability, poor mold release effect and the like.
Disclosure of Invention
The invention aims to solve the existing problems and provides a release agent for acrylic production.
The invention is realized by the following technical scheme:
a release agent for acrylic production is composed of the following substances in parts by weight:
60-65 parts of epoxy resin, 12-16 parts of petroleum resin, 8-13 parts of urea-formaldehyde resin, 6-10 parts of acrylic resin, 3-5 parts of epoxidized soybean oil, 2-4 parts of sodium hexametaphosphate, 7-11 parts of montmorillonite, 1-2 parts of nonylphenol polyoxyethylene ether, 1-3 parts of seaweed gel, 2-4 parts of bacterial cellulose, 10-14 parts of ethylene glycol and 260-280 parts of water.
Preferably, the composition consists of the following substances in parts by weight:
63-65 parts of epoxy resin, 14-16 parts of petroleum resin, 11-13 parts of urea-formaldehyde resin, 8-10 parts of acrylic resin, 4-5 parts of epoxidized soybean oil, 3-4 parts of sodium hexametaphosphate, 9-11 parts of montmorillonite, 1.5-2 parts of nonylphenol polyoxyethylene ether, 2-3 parts of seaweed gel, 3-4 parts of bacterial cellulose, 12-14 parts of ethylene glycol and 270-280 parts of water.
Preferably, the composition consists of the following substances in parts by weight:
63 parts of epoxy resin, 14 parts of petroleum resin, 11 parts of urea-formaldehyde resin, 8 parts of acrylic resin, 4 parts of epoxidized soybean oil, 3 parts of sodium hexametaphosphate, 9 parts of montmorillonite, 1.5 parts of nonylphenol polyoxyethylene ether, 2 parts of seaweed gel, 3 parts of bacterial cellulose, 12 parts of ethylene glycol and 270 parts of water.
Furthermore, the particle size of the montmorillonite is 800-1000 meshes.
A preparation method of a release agent for acrylic production comprises the following steps:
(1) firstly, mixing epoxy resin, petroleum resin, urea resin and acrylic resin together, putting the mixture into a reaction kettle, heating the mixture to keep the temperature in the reaction kettle at 70-75 ℃, and continuously stirring the mixture for 40-45 min for later use;
(2) and (2) adding epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed glue, bacterial cellulose, ethylene glycol and water into the reaction kettle treated in the step (1), heating to keep the temperature in the reaction kettle at 50-55 ℃ and the pressure at 0.3-0.5 MPa, continuously stirring for 1-2 hours, and taking out.
Compared with the prior art, the invention has the following advantages:
the components of the release agent are specially matched and adjusted, wherein epoxy resin, petroleum resin, urea-formaldehyde resin and acrylic resin are compounded to be used as a main film forming substance, the corrosion resistance and temperature resistance are good, the added montmorillonite is a lamellar structure filler, the release efficiency and effect are improved, the surface smoothness of an acrylic plate is enhanced, the spreading and smoothness of an integral film layer of the release agent are improved by the added seaweed glue and bacterial cellulose, and the dispersion and fusion performance between the montmorillonite and a film forming matrix are improved. Under the combined action of the components, the release agent prepared by the invention has good temperature resistance, wear resistance and repeated scouring resistance, effectively improves the surface smoothness of the acrylic sheet, has good adhesion and stable quality, and has strong market competitiveness and popularization and use values.
Detailed Description
Example 1
A release agent for acrylic production is composed of the following substances in parts by weight:
60 parts of epoxy resin, 12 parts of petroleum resin, 8 parts of urea-formaldehyde resin, 6 parts of acrylic resin, 3 parts of epoxidized soybean oil, 2 parts of sodium hexametaphosphate, 7 parts of montmorillonite, 1 part of nonylphenol polyoxyethylene ether, 1 part of seaweed gel, 2 parts of bacterial cellulose, 10 parts of ethylene glycol and 260 parts of water.
Furthermore, the particle size of the montmorillonite is 800-1000 meshes.
A preparation method of a release agent for acrylic production comprises the following steps:
(1) firstly, mixing epoxy resin, petroleum resin, urea resin and acrylic resin together, putting the mixture into a reaction kettle, heating the mixture to keep the temperature in the reaction kettle at 70 ℃, and continuously stirring the mixture for 40min for later use;
(2) and (2) adding epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed glue, bacterial cellulose, ethylene glycol and water into the reaction kettle treated in the step (1), heating to keep the temperature in the reaction kettle at 50 ℃ and the pressure at 0.3MPa, continuously stirring for 1h, and taking out.
Example 2
A release agent for acrylic production is composed of the following substances in parts by weight:
63 parts of epoxy resin, 14 parts of petroleum resin, 11 parts of urea-formaldehyde resin, 8 parts of acrylic resin, 4 parts of epoxidized soybean oil, 3 parts of sodium hexametaphosphate, 9 parts of montmorillonite, 1.5 parts of nonylphenol polyoxyethylene ether, 2 parts of seaweed gel, 3 parts of bacterial cellulose, 12 parts of ethylene glycol and 270 parts of water.
Furthermore, the particle size of the montmorillonite is 800-1000 meshes.
A preparation method of a release agent for acrylic production comprises the following steps:
(1) firstly, mixing epoxy resin, petroleum resin, urea resin and acrylic resin together, putting the mixture into a reaction kettle, heating the mixture to keep the temperature in the reaction kettle at 73 ℃, and continuously stirring the mixture for 43min for later use;
(2) and (2) adding epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed glue, bacterial cellulose, ethylene glycol and water into the reaction kettle treated in the step (1), heating to keep the temperature in the reaction kettle at 52 ℃ and the pressure at 0.4MPa, continuously stirring for 1.5h, and taking out.
Example 3
A release agent for acrylic production is composed of the following substances in parts by weight:
65 parts of epoxy resin, 16 parts of petroleum resin, 13 parts of urea-formaldehyde resin, 10 parts of acrylic resin, 5 parts of epoxidized soybean oil, 4 parts of sodium hexametaphosphate, 11 parts of montmorillonite, 2 parts of nonylphenol polyoxyethylene ether, 3 parts of seaweed gel, 4 parts of bacterial cellulose, 14 parts of ethylene glycol and 280 parts of water.
Furthermore, the particle size of the montmorillonite is 800-1000 meshes.
A preparation method of a release agent for acrylic production comprises the following steps:
(1) firstly, mixing epoxy resin, petroleum resin, urea resin and acrylic resin together, putting the mixture into a reaction kettle, heating the mixture to keep the temperature in the reaction kettle at 75 ℃, and continuously stirring the mixture for 45min for later use;
(2) and (2) adding epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed glue, bacterial cellulose, ethylene glycol and water into the reaction kettle treated in the step (1), heating to keep the temperature in the reaction kettle at 55 ℃ and the pressure at 0.5MPa, continuously stirring for 2 hours, and taking out.
Experimental performance tests on the release agent prepared by the invention show that the continuous demolding time can reach more than 26 times, the continuous demolding time is prolonged by more than 10 times compared with the commercially available common release agent, the high-temperature weight loss rate of the release agent is not more than 1.2%, and the surface smoothness of the produced acrylic sheet is high. The release agent has good and stable comprehensive use quality, and has good economic benefit and popularization and use value.
Claims (5)
1. The release agent for acrylic production is characterized by comprising the following substances in parts by weight:
60-65 parts of epoxy resin, 12-16 parts of petroleum resin, 8-13 parts of urea-formaldehyde resin, 6-10 parts of acrylic resin, 3-5 parts of epoxidized soybean oil, 2-4 parts of sodium hexametaphosphate, 7-11 parts of montmorillonite, 1-2 parts of nonylphenol polyoxyethylene ether, 1-3 parts of seaweed gel, 2-4 parts of bacterial cellulose, 10-14 parts of ethylene glycol and 260-280 parts of water.
2. The release agent for acrylic production as claimed in claim 1, characterized by consisting of the following substances in parts by weight:
63-65 parts of epoxy resin, 14-16 parts of petroleum resin, 11-13 parts of urea-formaldehyde resin, 8-10 parts of acrylic resin, 4-5 parts of epoxidized soybean oil, 3-4 parts of sodium hexametaphosphate, 9-11 parts of montmorillonite, 1.5-2 parts of nonylphenol polyoxyethylene ether, 2-3 parts of seaweed gel, 3-4 parts of bacterial cellulose, 12-14 parts of ethylene glycol and 270-280 parts of water.
3. The release agent for acrylic production as claimed in claim 1, characterized by consisting of the following substances in parts by weight:
63 parts of epoxy resin, 14 parts of petroleum resin, 11 parts of urea-formaldehyde resin, 8 parts of acrylic resin, 4 parts of epoxidized soybean oil, 3 parts of sodium hexametaphosphate, 9 parts of montmorillonite, 1.5 parts of nonylphenol polyoxyethylene ether, 2 parts of seaweed gel, 3 parts of bacterial cellulose, 12 parts of ethylene glycol and 270 parts of water.
4. The release agent for acrylic production as claimed in any one of claims 1 to 3, wherein the particle size of the montmorillonite is 800 to 1000 mesh.
5. A method for preparing the release agent for acrylic production according to any one of claims 1 to 3, characterized by comprising the following steps:
(1) firstly, mixing epoxy resin, petroleum resin, urea resin and acrylic resin together, putting the mixture into a reaction kettle, heating the mixture to keep the temperature in the reaction kettle at 70-75 ℃, and continuously stirring the mixture for 40-45 min for later use;
(2) and (2) adding epoxidized soybean oil, sodium hexametaphosphate, montmorillonite, nonylphenol polyoxyethylene ether, seaweed glue, bacterial cellulose, ethylene glycol and water into the reaction kettle treated in the step (1), heating to keep the temperature in the reaction kettle at 50-55 ℃ and the pressure at 0.3-0.5 MPa, continuously stirring for 1-2 hours, and taking out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711324434.7A CN107914353B (en) | 2017-12-13 | 2017-12-13 | Release agent for acrylic production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711324434.7A CN107914353B (en) | 2017-12-13 | 2017-12-13 | Release agent for acrylic production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107914353A CN107914353A (en) | 2018-04-17 |
| CN107914353B true CN107914353B (en) | 2020-04-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711324434.7A Expired - Fee Related CN107914353B (en) | 2017-12-13 | 2017-12-13 | Release agent for acrylic production |
Country Status (1)
| Country | Link |
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| CN (1) | CN107914353B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112387923A (en) * | 2020-10-21 | 2021-02-23 | 重庆市宇红轨道车辆配件有限公司 | Heat-resistant release agent for brake shoe manufacturing and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925273A (en) * | 2012-10-26 | 2013-02-13 | 苏州市德莱尔建材科技有限公司 | Concrete releasing agent |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102615747A (en) * | 2011-02-01 | 2012-08-01 | 汉高股份有限及两合公司 | Mould release agent, its preparation method and its purpose |
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2017
- 2017-12-13 CN CN201711324434.7A patent/CN107914353B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925273A (en) * | 2012-10-26 | 2013-02-13 | 苏州市德莱尔建材科技有限公司 | Concrete releasing agent |
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| Publication number | Publication date |
|---|---|
| CN107914353A (en) | 2018-04-17 |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Release agent for acrylic production Effective date of registration: 20200612 Granted publication date: 20200428 Pledgee: Zongyang sub branch of Huishang Bank Co.,Ltd. (Zongyang sub branch of Huishang bank) Pledgor: ANHUI XINSHENG PLASTIC TECHNOLOGY Co.,Ltd. Registration number: Y2020980003045 |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200428 |
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| CF01 | Termination of patent right due to non-payment of annual fee |