CN107029789B - 一种电解水制氢电极材料的制备方法 - Google Patents
一种电解水制氢电极材料的制备方法 Download PDFInfo
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- CN107029789B CN107029789B CN201710225541.8A CN201710225541A CN107029789B CN 107029789 B CN107029789 B CN 107029789B CN 201710225541 A CN201710225541 A CN 201710225541A CN 107029789 B CN107029789 B CN 107029789B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000001257 hydrogen Substances 0.000 title claims abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910001868 water Inorganic materials 0.000 title claims abstract description 8
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000007772 electrode material Substances 0.000 title claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 18
- 239000012621 metal-organic framework Substances 0.000 claims abstract description 18
- 239000013078 crystal Substances 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006230 acetylene black Substances 0.000 claims abstract description 8
- BSUSEPIPTZNHMN-UHFFFAOYSA-L cobalt(2+);diperchlorate Chemical compound [Co+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O BSUSEPIPTZNHMN-UHFFFAOYSA-L 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 6
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001273 butane Substances 0.000 claims abstract description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000047 product Substances 0.000 claims description 7
- 150000002460 imidazoles Chemical class 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000011259 mixed solution Substances 0.000 claims description 5
- 238000010583 slow cooling Methods 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract description 7
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000010189 synthetic method Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 239000012921 cobalt-based metal-organic framework Substances 0.000 description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000013495 cobalt Nutrition 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000002604 ultrasonography Methods 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 1
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical compound S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009396 hybridization Methods 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 230000005291 magnetic effect Effects 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108997587B (zh) * | 2018-06-21 | 2020-11-06 | 三峡大学 | 一种用于电解水制氢反应的金属有机框架材料及其纳米片材料的制备方法 |
CN111790453A (zh) * | 2019-04-08 | 2020-10-20 | 湖北大学 | 一种钴/钨双金属有机框架阴极析氢复合材料及其制备方法 |
CN109970988B (zh) * | 2019-04-22 | 2021-06-18 | 三峡大学 | 钴基配位聚合物及其作为电催化产氢催化剂的用途 |
CN110172709B (zh) * | 2019-06-05 | 2021-03-05 | 中南大学 | 基于金属离子与有机物吸附的MOFs碳化材料电化学阴极的制备方法及应用 |
CN110343257B (zh) * | 2019-07-16 | 2021-11-09 | 三峡大学 | 一种多氯代钴基复合材料,制备方法及其应用 |
CN111905827B (zh) * | 2020-08-21 | 2022-03-08 | 三峡大学 | 镍基异质复合材料的制备方法及在催化甲醇氧化上的应用 |
CN114957688B (zh) * | 2022-05-20 | 2023-10-20 | 昆明理工大学 | 一种多功能Co基金属-有机骨架材料和制备方法及其应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
CN104131309A (zh) * | 2014-08-01 | 2014-11-05 | 太原理工大学 | 一种mof复合电极催化水分裂制氢储氢方法 |
CN105107536A (zh) * | 2015-10-09 | 2015-12-02 | 清华大学 | 一种多面体形磷化钴电解水制氢催化剂的制备方法 |
CN105289733A (zh) * | 2015-10-28 | 2016-02-03 | 西南大学 | 基于金属有机框架化合物析氢电催化剂的制备方法 |
CN105977467A (zh) * | 2016-07-01 | 2016-09-28 | 北京工业大学 | 一种基于MOF模板制备Co3O4@CoP复合电极的制备方法 |
-
2017
- 2017-04-07 CN CN201710225541.8A patent/CN107029789B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
CN104131309A (zh) * | 2014-08-01 | 2014-11-05 | 太原理工大学 | 一种mof复合电极催化水分裂制氢储氢方法 |
CN105107536A (zh) * | 2015-10-09 | 2015-12-02 | 清华大学 | 一种多面体形磷化钴电解水制氢催化剂的制备方法 |
CN105289733A (zh) * | 2015-10-28 | 2016-02-03 | 西南大学 | 基于金属有机框架化合物析氢电催化剂的制备方法 |
CN105977467A (zh) * | 2016-07-01 | 2016-09-28 | 北京工业大学 | 一种基于MOF模板制备Co3O4@CoP复合电极的制备方法 |
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