CN1070129C - 用于制造碰撞缓冲气垫的无涂层织物及其制造方法 - Google Patents

用于制造碰撞缓冲气垫的无涂层织物及其制造方法 Download PDF

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CN1070129C
CN1070129C CN95193791A CN95193791A CN1070129C CN 1070129 C CN1070129 C CN 1070129C CN 95193791 A CN95193791 A CN 95193791A CN 95193791 A CN95193791 A CN 95193791A CN 1070129 C CN1070129 C CN 1070129C
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fabric
tex
air
uncoated
polyamide filaments
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CN1151140A (zh
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E·伯根
R·拉龙德
B·兰
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Viscosuisse SA
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Rhone Poulenc Viscosuisse SA
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/16Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R21/00Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
    • B60R21/02Occupant safety arrangements or fittings, e.g. crash pads
    • B60R21/16Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
    • B60R21/23Inflatable members
    • B60R21/235Inflatable members characterised by their material
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/02Inflatable articles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3008Woven fabric has an elastic quality
    • Y10T442/3024Including elastic strand or strip

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Air Bags (AREA)

Abstract

由单丝纤度为1.5-7dtex、强度为50-80×10-2N/tex和伸长为15-30%的聚酰胺长丝纱制的平纹-或重平组织的无涂层空气袋织物,具有空气透过性少于3升/分米2/分钟、剩余沸水收缩<2%和经纱与纬纱的撕破强力>110N。在制造无涂层的空气袋织物时采用热空气收缩<6%和最小收缩力>0.2×10-2N/tex的聚酰胺长丝作为原料。该织物在一密闭的容器中、在温度为80-160℃和相对空气湿度为90-100%的条件下进行处理,并放在张力框上干燥和定形,或者用通常熟知的轧光整理或预缩整理的方法进行处理。

Description

用于制造碰撞缓冲气垫的无涂层织物及其制造方法
本发明涉及用于制造碰撞缓冲气垫(气袋)的单丝纤度为1.5-7dtex,纤度强度为(50-80)×10-2N/tex和伸长率为30%聚酰胺长丝纱制的平纹-或重平组织的无涂层织物以及它的制造方法。
由聚酰胺6.6制的无涂层织物是已知的(EP-A-0436950)。在此要达到微小的空气透过性,显然要求在织物中要采用在160℃测定的热空气收缩为6-15%的长丝。粗织物随即在一水浴中、在温度范围为60和140℃之间进行突然收缩。但是用此已知方法,平纹织物的空气透过性在500Pa只能达到3和大于3升/分米2/分钟,这本身是微小的,由气袋系统制造厂所要求的空气透过性对于许多用途已足够,所需的纱线由于高热收缩和因此造成的高卷绕张力而不能用或只能很困难用纺牵法制造。
在应用高收缩纱(超过60%)时,在制造中要注意采取特别的措施,即通过强烈而均匀的冷却来固定热收缩使之不产生张力差。牵伸或是通过带有丝条张力控制冷却的丝速牵伸来进行,或者往往在纱管成形中通过垂直的单丝牵伸进行。对这种纱线,在实践中要求从纱管倒筒成圆筒或要求带有张力控制的冷却进行丝束牵伸。
本发明的任务是提供一种织物,这种织物的空气透过性接近相当于涂层织物的空气透过性,并且可用简单的因而也是经济的方法制造。此空气袋织物应具有非常小的空气透过性,高尺寸稳定性和高断裂强度。
另一个任务是,寻找以不涂层织物作为涂层织物代用品,用于制造空气袋织物,涂层不仅是耗费大和昂贵的方法,而且得到的织物可折叠性低劣10-15%,且包装体积大。
本发明的任务是这样解决的,织物同时具有空气透过性<3升/分米2/分钟,剩余沸水收缩<2%和经纱和纬纱撕破强度>110N。适当的空气透过性为1-3升/分米2/分钟。
织物以5cm的织物条子形式测定的撕拉(断裂)力大于2500N是适当的,这样才能保证空气袋织物在碰撞时具有安全性。
一种用纺牵法制造的单丝纤度为1.5-1.7dtex的聚酰胺复丝纱表明特别适用于制造无涂织物的方法中。其中特别具有优点的是,在160℃的空气中和在0.5×10-2N/tex的预张力下测定聚酰胺长丝纱的热空气收缩为<6%。然后作为织物放在密闭的容器中,在温度从80-160℃和相对空气湿度为90-100%的条件下进行处理。
惊奇地发现,用低收缩的原料也可达到很小的空气透过性。空气透过性超过3升/分米2/分钟对具有较少的和较细粒子的解开系统只是在一定条件下是允许的;空气透过性在3升/分米2/分钟以下,优选在2.5升/分米2/分钟和更少时,证明对空气袋织物为最优。
织物的空气透过性按德国工业标准DIN 53887、在空气压力为500Pa下进行测定。
热收缩和沸水收缩按德国工业标准DIN 53866测定,其中热收缩的测定时,空气温度为160℃,预张力为0.5×10-2N/tex。撕裂强度是按德国工业标准DIN 53859T2测定,撕拉(断裂)力和断裂伸长按德国工业标准DIN 83835测定。
作为原料采用无松毛球的用纺牵法制造的聚酰胺长丝纱,它的单丝纤度范围为1.5-7dtex,特别是3dtex或更细。特别必要的是,聚酰胺长丝的热空气收缩为<6%,尤其是为<5.5%,这是在160℃和0.5×10-2N/tex的预张力下测得的。同时,按德国工业标准DIN 53866在160℃测得的最小收缩力为0.2×10-2N/tex。用这样的低收缩纱例如有可能制造和成功地加工5-15kg纺牵园形筒子的大卷装。用已知的方法制成平纹组织和重平织组的织物,然后将织物放在一个密封的容器中,在温度为80-160℃和相对空气湿度为90-100%时进行处理。
本发明借助于一些实例予以进一步说明
实施例1
纤度为dtex350 f104 z60的聚酰胺长丝,在160℃、预张力为0.5×10-2N/tex下测得它的热收缩为5.5%,在160℃和预张力为0.5×10-2N/tex时测得的热收缩力为90×10-2N和0.25×10-2N/tex,同时沸水收缩为6.7%,将此聚酰胺长丝制成平纹织物。此织物接着在一饱和蒸气室中、在温度超过100℃进行处理,接着在张力框上进行干燥和定形。
此织物性能如下:
                    经纱           纬纱
每厘米丝数          28             24
撕拉(断裂)力N/5cm   2900           2700
剩余沸水收缩(%)    1.4            1.5
撕裂强力(N)         115            110
断裂伸长(%)        37             28
织物重量            215g/m2
织物的空气透过性    2.55升/分米2/分钟
实施例2
在同样条件下,制造纤度为dtex470 f68 z60,此外与实施例1具有同样性能的聚酰胺6.6长丝。
此织物的性能如下:
                      经纱          纬纱
每厘米丝数            23            22
撕拉(断裂)力N/5cm     3400          3550
剩余沸水收缩(%)      1.7           1.7
撕裂强力(N)           174           177
断裂伸长(%)          41            28
织物重量              240g/m2
织物的空气透过性     2.45升/分米2/分钟
实施例3
在同样条件下,制造纤度为dtex470 f68 z0.00、其它性能如同实施例1的聚酰胺6.6长丝。
织物的性能如下:
                         经纱           纬纱
每厘米丝数               24             21
撕拉(断裂)力N/5cm        3500           3100
剩余沸水收缩(%)         1.5            0
撕裂强力(N)              171            171
断裂伸长(%)             35             34.5
织物重量                 245g/m2
织物的空气透过性         3.0升/分米2/分钟
从这些实施例中可见,用本发明的方法第一次获得成功,取得兼有热收缩<6%和收缩力>0.2×10-2N/tex、空气透过性小于3升/分米2/分钟的织物。

Claims (3)

1.用于制造碰撞缓冲气垫(空气袋)的无涂层织物,具有由单丝纤度为1.5-7dtex、强度为(50-80)×10-2N/tex和伸长为15-30%的聚酰胺长丝纱制的平纹-或重平组织,其特征在于,此织物同时具有以下性能指标:空气透过性<3升/分米2/分钟、剩余沸水收缩<2%和经纱和纬纱的撕裂强力>110N。
2.按权利要求1所述的无涂层织物,其特征在于,此织物的5cm织物试条具有的撕拉(断裂)力为>2500N。
3.用于制造碰撞缓冲气垫(空气袋)的无涂层织物的制造方法,它具有由纺牵法制造的单丝纤度为1.5-7dtex聚酰胺长丝纱制的平纹-或重平组织,其特征在于,在预张力为0.5×10-2N/tex和160℃热空气中测定的聚酰胺长丝的热空气收缩为<6%、最小收缩力为0.2×10-2N/tex,将此织物在一密闭的容器中、在温度为80-160℃和相对湿度为90-100%的条件下进行处理。
CN95193791A 1994-08-25 1995-08-15 用于制造碰撞缓冲气垫的无涂层织物及其制造方法 Expired - Fee Related CN1070129C (zh)

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US (1) US5693392A (zh)
EP (1) EP0776282B1 (zh)
JP (1) JP2997548B2 (zh)
KR (1) KR100356645B1 (zh)
CN (1) CN1070129C (zh)
AT (1) ATE171900T1 (zh)
CA (1) CA2198014A1 (zh)
DE (1) DE59503873D1 (zh)
ES (1) ES2123274T3 (zh)
RU (1) RU2125624C1 (zh)
WO (1) WO1996005985A1 (zh)

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US5704402A (en) * 1996-04-01 1998-01-06 Milliken Research Corporation Air bag fabric
US5858886A (en) * 1996-07-02 1999-01-12 Milliken Research Corporation Low permeability airbag fabric
US6022817A (en) * 1997-06-06 2000-02-08 E. I. Du Pont De Nemours And Company Fabric for airbag
DE29711904U1 (de) * 1997-07-07 1997-11-06 Trw Repa Gmbh Gassack für ein Rückhaltesystem in Fahrzeugen und Gewebe zu seiner Herstellung
WO2001048279A2 (de) * 1999-12-23 2001-07-05 Acordis Industrial Fibers Gmbh Verfahren zum spinnstrecken von polymeren
JP3733869B2 (ja) * 2001-04-19 2006-01-11 東洋紡績株式会社 エアバッグ用高密度織物
JP3797486B2 (ja) * 2003-07-29 2006-07-19 東洋紡績株式会社 織物およびその製造方法
CA2450103C (en) * 2003-10-22 2008-09-16 Hyosung Corporation Low shrinkage polyamide fiber and uncoated fabric for airbags made of the same
KR100451263B1 (ko) * 2003-12-30 2004-10-11 주식회사 효성 비피복 에어백용 폴리아미드 섬유
DE202005008939U1 (de) * 2005-06-07 2005-08-04 Trw Automotive Safety Systems Gmbh Gassack
WO2007118675A1 (de) * 2006-04-12 2007-10-25 Itg Automotive Safety Textiles Gmbh Airbaggewebe

Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0436950A2 (de) * 1990-01-12 1991-07-17 Akzo Nobel N.V. Verfahren zur Herstellung von unbeschichteten Technischen Geweben mit geringer Luftdurchlässigkeit
EP0442273A2 (en) * 1990-02-16 1991-08-21 Decisions Investments Corp. Pressure balancing a closed ecological system
EP0501295A1 (de) * 1991-02-26 1992-09-02 Akzo Nobel N.V. Unbeschichtetes Gewebe für die Herstellung von Airbags
EP0509399A1 (de) * 1991-04-15 1992-10-21 Hoechst Aktiengesellschaft Gewebe für einen Airbag

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DE59006012D1 (de) * 1989-09-07 1994-07-14 Akzo Nobel Nv Unbeschichtetes Gewebe für Airbags.
DE4004216A1 (de) * 1990-02-12 1991-08-14 Hoechst Ag Gewebe fuer einen airbag

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0436950A2 (de) * 1990-01-12 1991-07-17 Akzo Nobel N.V. Verfahren zur Herstellung von unbeschichteten Technischen Geweben mit geringer Luftdurchlässigkeit
EP0442273A2 (en) * 1990-02-16 1991-08-21 Decisions Investments Corp. Pressure balancing a closed ecological system
EP0501295A1 (de) * 1991-02-26 1992-09-02 Akzo Nobel N.V. Unbeschichtetes Gewebe für die Herstellung von Airbags
EP0509399A1 (de) * 1991-04-15 1992-10-21 Hoechst Aktiengesellschaft Gewebe für einen Airbag

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JP2997548B2 (ja) 2000-01-11
CA2198014A1 (en) 1996-02-29
KR970705485A (ko) 1997-10-09
ATE171900T1 (de) 1998-10-15
KR100356645B1 (ko) 2003-03-15
JPH10504612A (ja) 1998-05-06
EP0776282A1 (de) 1997-06-04
US5693392A (en) 1997-12-02
RU2125624C1 (ru) 1999-01-27
EP0776282B1 (de) 1998-10-07
ES2123274T3 (es) 1999-01-01
DE59503873D1 (de) 1998-11-12
CN1151140A (zh) 1997-06-04
WO1996005985A1 (de) 1996-02-29

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