CN106953091A - 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池 - Google Patents

贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池 Download PDF

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Publication number
CN106953091A
CN106953091A CN201710091948.6A CN201710091948A CN106953091A CN 106953091 A CN106953091 A CN 106953091A CN 201710091948 A CN201710091948 A CN 201710091948A CN 106953091 A CN106953091 A CN 106953091A
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CN
China
Prior art keywords
hydrogen
alloy
storage
capacity
phase
Prior art date
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Pending
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CN201710091948.6A
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English (en)
Chinese (zh)
Inventor
K-H·杨
T·乌奇
J·内
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BASF Battery Materials Ovonic
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BASF Battery Materials Ovonic
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Publication date
Application filed by BASF Battery Materials Ovonic filed Critical BASF Battery Materials Ovonic
Publication of CN106953091A publication Critical patent/CN106953091A/zh
Pending legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383—Hydrogen absorbing alloys
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C16/00—Alloys based on zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/242—Hydrogen storage electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/34—Gastight accumulators
    • H01M10/345—Gastight metal hydride accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacturing & Machinery (AREA)
CN201710091948.6A 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池 Pending CN106953091A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/694,299 US20140140885A1 (en) 2012-11-16 2012-11-16 Hydrogen storage alloy and negative electrode and Ni-metal hydride battery employing same
US13/694,299 2012-11-16
CN201380059787.2A CN104903479A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201380059787.2A Division CN104903479A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池

Publications (1)

Publication Number Publication Date
CN106953091A true CN106953091A (zh) 2017-07-14

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
CN201710091948.6A Pending CN106953091A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni‑金属氢化物电池
CN201380059787.2A Pending CN104903479A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池

Family Applications After (1)

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CN201380059787.2A Pending CN104903479A (zh) 2012-11-16 2013-11-13 贮氢合金和阴电极以及采用它们的ni-金属氢化物电池

Country Status (5)

Country Link
US (2) US20140140885A1 (https=)
EP (1) EP2920333A4 (https=)
JP (1) JP6312692B2 (https=)
CN (2) CN106953091A (https=)
WO (1) WO2014078351A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3256615A4 (en) * 2015-02-11 2018-12-05 BASF Corporation Hydrogen storage alloys

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020037454A1 (en) * 1994-07-22 2002-03-28 Kabushiki Kaisha Toshiba Hydrogen-absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery
CN1385911A (zh) * 2001-05-11 2002-12-18 浙江大学 镍－金属氢化物(Ni－MH)二次电池

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0650633B2 (ja) * 1987-07-30 1994-06-29 松下電器産業株式会社 水素吸蔵電極
KR920010422B1 (ko) * 1987-05-15 1992-11-27 마쯔시다덴기산교 가부시기가이샤 수소흡수저장전극 및 그 제조법
US5002730A (en) * 1989-07-24 1991-03-26 Energy Conversion Devices Preparation of vanadium rich hydrogen storage alloy materials
JPH05287422A (ja) * 1992-04-13 1993-11-02 Matsushita Electric Ind Co Ltd 水素吸蔵合金電極
JPH073365A (ja) * 1993-04-20 1995-01-06 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
JPH09199121A (ja) * 1996-01-22 1997-07-31 Toshiba Corp 水素吸蔵合金及び二次電池
US5560752A (en) * 1994-08-17 1996-10-01 Lucent Technologies Inc. Process for activation of metal hydrides
JPH08134567A (ja) * 1994-11-11 1996-05-28 Shin Kobe Electric Mach Co Ltd 水素吸蔵合金及びアルカリ蓄電池用水素吸蔵合金電極
JPH08319529A (ja) * 1995-05-22 1996-12-03 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
CN1279637C (zh) * 1996-01-22 2006-10-11 东芝株式会社 储氢合金
JP3528599B2 (ja) * 1998-05-21 2004-05-17 トヨタ自動車株式会社 水素吸蔵合金
US6270719B1 (en) * 1999-04-12 2001-08-07 Ovonic Battery Company, Inc. Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity
JP3931518B2 (ja) * 1999-07-08 2007-06-20 松下電器産業株式会社 ニッケル−水素二次電池
CN102683653A (zh) * 2011-03-09 2012-09-19 中国科学院长春应用化学研究所 复合贮氢合金及镍氢蓄电池
CN102738520B (zh) * 2011-04-14 2017-02-15 中国科学院长春应用化学研究所 镍氢蓄电池

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020037454A1 (en) * 1994-07-22 2002-03-28 Kabushiki Kaisha Toshiba Hydrogen-absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery
CN1385911A (zh) * 2001-05-11 2002-12-18 浙江大学 镍－金属氢化物(Ni－MH)二次电池

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
M.BOUOUDINA等: "Structural investigation by neutron diffraction of equi-atomic Zr-Ti(V)-Ni(Co) compounds and their related hydrides", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *

Also Published As

Publication number Publication date
JP2015537119A (ja) 2015-12-24
US20160204429A1 (en) 2016-07-14
EP2920333A4 (en) 2016-11-16
JP6312692B2 (ja) 2018-04-18
CN104903479A (zh) 2015-09-09
EP2920333A1 (en) 2015-09-23
US20140140885A1 (en) 2014-05-22
WO2014078351A1 (en) 2014-05-22

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