CN106942787A - A kind of cigarette microemulsion capsule and preparation method thereof - Google Patents
A kind of cigarette microemulsion capsule and preparation method thereof Download PDFInfo
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- CN106942787A CN106942787A CN201710174145.7A CN201710174145A CN106942787A CN 106942787 A CN106942787 A CN 106942787A CN 201710174145 A CN201710174145 A CN 201710174145A CN 106942787 A CN106942787 A CN 106942787A
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- capsule
- oil
- water
- cigarette
- core
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
- B01J13/043—Drying and spraying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention relates to a kind of cigarette microemulsion capsule and preparation method thereof, the capsule is used as core using water-in-oil inverse microemulsion, capsule wall material is used as using biomass glue or synthetic resin, capsule appearance is the transparent or semitransparent elastomeric spherical bodies of the 4mm of particle diameter 2, wall material thickness is 0.1 0.5mm, and pop strength is 0.5 2.5kg.Methods described prepares the cigarette to be formed and can be good at being wrapped up soluble perfume, alcohol-soluble essence and oil soluble perfume with capsule, and gained capsule core is stable in properties, and wall material water lock is good, and pressure value is moderate.The capsule can significantly enrich the fragrance of cigarette capsule and increase flue gas moisture feeling to a certain extent, lift cigarette smoking quality；And preparation is simple, material safety and environmental protection is adapted to continuous industrial production.
Description
Technical field
The invention belongs to cigarette products production technical field, it is related to a kind of Novel tobacco capsule using microemulsion as core
Preparation method.
Background technology
Perfuming cigarette is an important topic in cigarette process, and the suction taste for improving cigarette covers miscellaneous gas, increases rich
The product of consumer are inhaled impression with direct relation by Fu Xing, mellow and full flue gas, raising comfortableness and pleasant impression etc..Existing perfuming skill
Art mainly has tobacco perfuming, cigarette auxiliary materials perfuming etc., but both perfuming technologies have more obvious shortcoming, such as fragrance meeting
Gradually weaken over time, cause cigarette quality to decline.Cigarette auxiliary materials perfuming mainly carries fragrant by being added in filter stick
Cored wire, particle, capsule (quick-fried pearl) etc..Cigarette is the popular a kind of perfuming cigarette mode of industry in recent years with soft capsule, and it will be certain
The flavouring essence for tobacco of amount is sealed in spherical soft capsule by certain means, then cigarette is added in filter stick for cigarettes with capsule,
Consumer can pinch brokenly capsule in good time in aspiration procedure and discharge fragrance component, play improvement and inhale the works such as taste, increase property pondered
With.
In current market, be used as capsule wall material be generally hydroaropic substance, core liquid also almost without exception with
Oil soluble perfume is aided with lipid solvent as essence diluent.Therefore, a kind of skill for being capable of coated water-soluble essence capsule is developed
Art becomes a focus for research, such as：The A of CN 104305521 disclose one kind wax and flocculation aid passes through as wall material
Cooling condensation mode carries out aqueous solution parcel, and pulvis and hydrophilic film are then wrapped up successively, makes capsule circular；Cigarette in Hubei
The CN 201410059720 of industrial Co., Ltd's application discloses a kind of three layers of capsule with diuresis promoting function；The limited duty of cigarette industry in Yunnan
The CN 201510352940 of Ren companies application discloses a kind of preparation method of composite package capsule, and this method uses amphipathic
Natural macromolecular material directly wraps up water or the aqueous solution prepares internal layer bag water soft capsule.
However, in the above prior art, though Contained oil capsule has formd more ripe technology, its capsule wall material
Limitation, which result in it, can not wrap up the core liquid with water soluble ingredient；And never had out in industry and be now able to form industrialization
Reliable bag capsule with diuresis promoting function technology.The present invention by Contained oil capsule with bag capsule with diuresis promoting function the characteristics of be combined together, overcome simultaneously
The defect of Contained oil capsule and bag capsule with diuresis promoting function, adds while realizing oil soluble perfume, soluble perfume, greatly widens
The selection range of essence, enriches the blending of cigarette capsule and application.
Microemulsion is being increasingly becoming every profession and trade focus of attention in recent years, CN101167706 A, CN101811014 A,
CN102601833 A, EP1021085 A1 are used to prepare each type nano granular or microcapsules using emulsion as dispersion,
CN201310123729, CN201610070603, CN201610070602 are disclosed in cosmetic field with the shape of microemulsion
Aqueous substance and oily matter are combined together by formula, CN201510495025, CN201510408249, CN201310163543
Disclosed microemulsion is used for food service industry, but microemulsion not yet realizes related application in cigarette industry, and the invention discloses one kind
Using water-in-oil microemulsion as the preparation method of the cigarette capsule of core liquid, application of the microemulsion in cigarette industry is realized.
The content of the invention
In order to solve the above technical problems, the invention provides a kind of simultaneously new containing oil soluble perfume and soluble perfume
Type cigarette capsule and preparation method thereof.
The present invention by Contained oil capsule with bag capsule with diuresis promoting function the characteristics of be combined together, it is achievable oil soluble perfume, water-soluble
Added while property essence, greatly widened the selection range of essence, enriched the blending of cigarette capsule and application.
In one aspect of the invention there is provided a kind of Novel tobacco capsule, described Novel tobacco capsule is by 10-30 weight
Part capsule wall material is constituted with 30-70 parts by weight core, and capsule appearance is the transparent or semitransparent elastomeric spherical bodies of particle diameter 2.5-4mm.
The pop strength of the capsule is preferably 0.5-2.5kg, and the wall thickness of the capsule is preferably 0.1-0.5mm.
A preferred embodiment of the invention, the capsule is using water-in-oil inverse microemulsion as core, with life
Material glue or synthetic resin are used as capsule wall material.The density of the Water-In-Oil reverse micelle microemulsion core is preferably 0.8-1.1g/
cm3, and containing compound surfactant, cosurfactant, oil phase, oil soluble perfume, water, soluble perfume/alcohol-soluble is fragrant
Essence.
Preferably, water, soluble perfume/alcohol-soluble are contained in the aqueous phase of the capsule core water-in oil microemulsion
Essence.
Preferably, oil and oil soluble perfume are contained in the oil phase of the capsule core water-in oil microemulsion.
In another aspect of this invention, the preparation method of above-mentioned capsule is additionally provided, the preparation method includes preparing
Core and wall material proportionally add in dripping pill device, formed wall material wrap up micro emulsion wick-containing liquid capsule.
A preferred embodiment of the invention, the preparation process of described water-in-oil inverse microemulsion core can be with
For：By oily components, uniformly mixing constitutes oil phase in proportion for oil soluble perfume, compound surfactant；By cosurfactant,
Aqueous phase is constituted after water and soluble perfume or alcohol-soluble essence are well mixed, aqueous phase is added dropwise to the oil phase of positive ultrasonic disperse
In, continue the transparent or semitransparent shape water-in-oil inverse microemulsion of scattered (preferably from about 10min) formation after being well mixed.
A preferred embodiment of the invention, the water-in-oil inverse microemulsion core includes following quality percentage
The component of ratio：Oil phase:Aqueous phase=30-70%:70-30%, the oil phase includes oily components, oil soluble perfume, compounding surface
Activating agent；The aqueous phase includes water, soluble perfume or alcohol-soluble essence, cosurfactant.
A preferred embodiment of the invention, in described oil phase, oily components, oil soluble perfume, compounding
The mass percent of surfactant is 60-79%:0.01-1%:40-20%.
Described oily components can be hydrocarbon ils, laruyl alcohol glyceride, nutmeg beans isopropyl propionate, isopropyl palmitate fat, palm fibre
One or more in the different monooctyl ester of palmitic acid acid, caprylic/capric glyceride, vegetable and animals oils, silicone oil.
Described compound surfactant can be soybean lecithin, anhydro sorbitol sesquialter monoglyceride, isostearic acid/amber
One or more in two glyceride of amber acid, three ricinoleic acid esters, Tween80, Span80.
Described oil soluble perfume can be orange oil, lemon oil, peppermint oil, olive oil, refined jasmine oil, oil-soluble coffee
At least one in essence and all kinds of flavoring essences.
According to another preferred embodiment of the present invention, in described water phase components, water, soluble perfume or alcohol-soluble
Essence, the mass percent of cosurfactant are 40-60%:0.01-20%:40-20%.
Described soluble perfume can be that honey, sweetener, tobacco extract, extract of licorice root, jujube medicinal extract, fig are carried
Take one kind or several in thing, tea extract, lupulus extract, plum extract, blackcurrant extract, apple extract etc.
Kind.
Described alcohol-soluble essence can be furanone, damascenone, Megastigmatrienone, cis Jasmine ketone, solanone or first
Cyclopentene ketone, maltol or eugenol, dihydroactinidiolide or gamma-undecalactone, phenylacetaldehyde or vanillic aldehyde, 2,3- diformazans
At least one of base pyrazine or 2- acetylpyridines.
Described cosurfactant can be in propane diols, glycerine, ethanol, polyethylene glycol 400, benzyl carbinol etc. extremely
Few one kind.
According to another preferred embodiment of the present invention, described cigarette is with capsule biomass glue wall material preparation method：
Add in 60-80 DEG C of hot water, be stirred continuously simultaneously, 60-80 DEG C of water-bath after the biomass glue of heterogeneity is weighed in proportion
Insulation standing obtains the biomass glue wall material liquid after dissolving fully.
The cigarette capsule biomass glue wall material can be：Gelatin, locust bean gum, xanthans, carragheen, konjac glucomannan, melon
One or more in your glue, starch.
A preferred embodiment of the invention, the synthetic resin compound method that described cigarette capsule is used：
The synthetic resin, copolymer and ketone compounds of different component are modulated well mixed in proportion, then at 50-60 DEG C of temperature
Heating, stirring is fully mixed, then stands more than 2h, is cooled down and is removed bubble and keeps in dark place, and obtains described capsule wall material liquid.
According to another preferred embodiment of the present invention, the cigarette is bisphenol-A ring with capsule synthetic resin wall material component
Oxypropylene acid resin, other resins and/or assimilation compound.
Other described resins can include acrylic resin, PE, pinene resin, epoxy novolac acrylic resin, epoxidation
Oily acrylate, aromatic series and aliphatic polyurethane acrylic resin, polyester acrylate resin, amino acrylic resin, Malaysia
It is one or more in acid anhydride copolymer, ketone compounds.
Described ketone compounds can be 2- hydroxy-2-methyl -1- phenyl ketones, 1- hydroxycyclohexyl phenyl ketones, 2-
Methyl -2- (4- morpholinyls) -1- [4- (methyl mercapto) phenyl] -1- acetone, 2- hydroxy-2-methyls -1- [4- (2- hydroxyl-oxethyls)
Phenyl] one or more in -1- acetone.This kind of ketone compounds promote capsule to solidify as the crosslinking agent of synthetic resin
Shaping.
In a particularly preferred embodiment, the cigarette of the invention is carried out with capsule using capsule dripping method
(being preferably used as wall material using biomass glue), the capsule dripping method is as follows：By the core prepared and wall material liquid according to 70-
90% is respectively charged into core flow container and glue pot with 10-30% ratio, by constant displacement pump by dripping pill device concentric circles water dropper by glue
Cyst wall material liquid is added in 10-20 DEG C of cooling oil with micro emulsion wick-containing drop, and core liquid is punctured into ball-type, outer layer in the presence of cohesive force
Wall material liquid is wrapped up, both form a ball-type and slowly fallen in protection liquid, and capsule wall material liquid is gradually cold in its dropping process
But curing molding, sealed bundle wraps water-in-oil inverse micro emulsion wick-containing liquid, and then wet capsule is separated with protection liquid using screen cloth, is received
The wet capsule collected puts into rotating cage after surface oil is blotted using oil-Absorbing Sheets, 200-300rpm dries 4-10h, during which sent with fan
Wind accelerates drying, treats that rubber is dried completely, capsule is placed in ventilation 1-2h with absolute alcohol rinsing and treats wine afterwards twice after taking-up is dry
Biomass glue wall material-microemulsion core capsule is obtained after essence volatilization.
During described coolant can be water, propane diols, glycerine, sorbierite, silicone oil, rapeseed oil, paraffin oil, mineral oil
It is at least one.
According to another preferred embodiment of the present invention, the cigarette of the invention is carried out with capsule using capsule dripping method
(preferably matched somebody with somebody using synthetic resin and be used as wall material), the capsule dripping method is as follows：By the core prepared and wall material liquid according to
70-90% and 10-30% ratio is respectively charged into core flow container and glue pot, will by dripping pill device concentric circles water dropper by constant displacement pump
The capsule wall material liquid of preparation is added in protection liquid with the water-in-oil inverse micro emulsion wick-containing drop prepared, the core in the presence of cohesive force
Liquid is punctured into ball-type, outer layer covers wall material liquid, and both form a ball-type and slowly fallen in protection liquid, in its dropping process
Apply light source irradiation, synthetic resin wall material liquid gradually completes crosslinking solid under the single or common factor effect of illumination and cooling
Change environmental sealing core liquid formation capsule, the capsule for thereafter being separated and collected capsule with protection liquid using screen cloth, and concentration with
The ethanol solution of stereometer 90% is washed, and is air-dried, and obtains described synthetic resin wall material-microemulsion core capsule.
Described light source be power be 50-1000w fluorescent lamp, incandescent lamp, uviol lamp, LED or searchlight in extremely
Few one kind.
Compared with prior art, the present invention prepares the cigarette capsule formed and can be good at soluble perfume, alcohol-soluble
Essence is wrapped up with oil soluble perfume, and gained capsule core is stable in properties, and wall material water lock is good, and pressure value is moderate.The glue
Capsule can significantly enrich the fragrance of cigarette capsule and increase flue gas moisture feeling to a certain extent, lift cigarette smoking product
Matter；And preparation is simple, material safety and environmental protection is adapted to serialization industrial production.
Embodiment
The present invention is described in more detail below with reference to embodiment, but embodiments of the present invention are not
It is limited to following case study on implementation.
Embodiment 1
The cigarette of the present embodiment is 3.5-4.0mm with capsule diameter, peppermint-Kiwi berry taste capsule, and wall material is biomass glue.Its
Middle core accounts for capsule proportion 90%, it is necessary to which subsequently rubber is dried.
Preparation method is as follows：
Capsule core is prepared：Isopropyl palmitate, peppermint oil, soybean lecithin, ethanol are compared 100 according to weight:20:17:
13 are uniformly mixed to form solution A, water, dihydroactinidiolide, and n-butanol is according to mass ratio 10:1:6 preparations form solution B, will
Above-mentioned A, B solution press 5:3 well mixed form transparent or semitransparent water-in-oil inverse microemulsion.
Capsule wall material is prepared：By carragheen, locust bean gum, guar gum, starch in mass ratio 1:1:0.5:0.1 is made into mixing
Uniform powder, be stirred continuously it is rear it is dispersed in the hot water, the mass ratio 1 of powder and water:70, protected at 80 degrees celsius
Temperature.
Dripping is molded：By the core prepared and wall material liquid by quality 3:1 is respectively charged into the glue pot of pill dripping machine and core flow container,
The capsule wall material liquid of preparation is added to water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
In 10-20 DEG C of cooling oil, capsule gradually cools and solidifies shaping in its dropping process, and sealed bundle wraps water-in-oil inverse microemulsion
Core liquid simultaneously makes capsule grain diameter between 3.5-4.0mm by adjustment equipment parameter.
Dry：Wet capsule is separated with protection liquid using screen cloth, the wet capsule being collected into is inhaled surface oil using oil-Absorbing Sheets
Rotating cage is put into after dry, 200-300rpm dries 4-10h, during which accelerates drying with fan air-supply, treat that rubber is dried completely, take out dry
Dry rear capsule is placed in ventilation 1-2h with alcohol rinsing and obtains biomass glue wall material-microemulsion core after alcohol volatilizees afterwards twice
Capsule sample.
Embodiment 2
The cigarette of the present embodiment is 2.5-3.0mm with capsule diameter, sweet orange-honey flavour capsule, and wall material is synthetic resin, wherein
Core accounting about 85%.
Preparation method is as follows：
Capsule core is prepared：By hexamethylene, orange oil, Arlacel-83, n-butanol according to weight ratio
100:15:22:15 are uniformly mixed to form solution A, water, honey, and PEG-400 is according to mass ratio：12:1:8 preparations form solution B,
Above-mentioned A, B solution are pressed 3:2 well mixed form transparent or semitransparent water-in-oil inverse microemulsion.
Capsule wall material is prepared：By bisphenol A epoxide resin, acrylic resin mass ratio 1:1.5 are well mixed, and add quality hundred
Divide the 1- hydroxycyclohexyl phenyl ketones than 0.05%, then heated under temperature 50 C, and keep in dark place.
Dripping is molded：By the core prepared and wall material liquid by quality 6:1 is respectively charged into the glue pot of pill dripping machine and core flow container,
The capsule wall material liquid of preparation is added to water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
In 10-20 DEG C of cooling oil, capsule wall material is sealed by gradually cooling and solidifying is molded after the irradiation of additional light source in its dropping process
Water-in-oil inverse micro emulsion wick-containing liquid is wrapped, by adjustment equipment parameter regulation capsule size in the range of 2.5-3.0mm.Collect
Gained capsule is synthetic resin wall material-microemulsion core capsule sample.
Embodiment 3
Cigarette is 2.5-3.0mm with capsule diameter in the present embodiment, is lemon-mela capsule, and wall material is biomass glue,
Core accounts for capsule proportion 85%.
Preparation method is as follows：
Capsule core is prepared：Triacetyl glycerine, lemon oil, Tween80, Span80 are compared 98 according to weight:12:18:
16 are uniformly mixed to form solution A；Water, Herba Lysimachiae foenumgraeci extract, n-amyl alcohol is according to mass ratio：12:0.5:6 preparations form solution B, will
Above-mentioned A, B solution press 4:3 well mixed form transparent or semitransparent water-in-oil inverse microemulsion；
Capsule wall material is prepared：Gelatin, carragheen, guar gum, starch quality are compared 3:1:0.5:0.2 be made into it is well mixed
Powder, be stirred continuously it is rear it is dispersed in the hot water, the mass ratio 1 of powder and water:65, it is incubated at 80 degrees celsius.
Dripping is molded：By the core prepared and wall material liquid by quality 3.5:1 is respectively charged into the glue pot of pill dripping machine and core liquid
Tank, is added the capsule wall material liquid of preparation with water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
Into 10-20 DEG C of cooling oil, capsule gradually cools and solidifies shaping in its dropping process, and sealed bundle wraps water-in-oil inverse micro emulsion
Wick-containing liquid, and capsule grain diameter is made between 2.5-3.0mm by adjustment equipment parameter.
Dry：Wet capsule is separated with protection liquid using screen cloth, the wet capsule being collected into is inhaled surface oil using oil-Absorbing Sheets
Rotating cage is put into after dry, 200-300rpm dries 4-10h, during which accelerates drying with fan air-supply, treat that rubber is dried completely, take out dry
Dry rear capsule is placed in ventilation 1-2h with alcohol rinsing and obtains biomass glue wall material-microemulsion core after alcohol volatilizees afterwards twice
Capsule sample
Embodiment 4
Cigarette is 2.5-3.0mm with capsule diameter in the present embodiment, is jasmine-aloe taste capsule, and wall material is biomass glue, core
Material accounts for capsule proportion 85%.
Preparation method is as follows：
Capsule core is prepared：By laruyl alcohol glyceride, refined jasmine oil, three ricinoleic acid esters, ethanol according to weight ratio
96:15:18:12 are uniformly mixed to form solution A；Water, aloe extract, propane diols is according to mass ratio：12:1.5:5 prepare formation
Solution B, 4 are pressed by above-mentioned A, B solution:3 well mixed form transparent or semitransparent water-in-oil inverse microemulsion.
Capsule wall material is prepared：By konjac glucomannan, guar gum, starch in mass ratio 5:2:0.2 is made into well mixed powder, no
After disconnected stirring it is dispersed in the hot water, the mass ratio 1 of powder and water:70, it is incubated under the conditions of 80 DEG C.
Dripping is molded：By the core prepared and wall material liquid by quality 3.5:1 is respectively charged into the glue pot of pill dripping machine and core liquid
Tank, is added the capsule wall material liquid of preparation with water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
Into 10-20 DEG C of cooling oil, capsule gradually cools and solidifies shaping in its dropping process, and sealed bundle wraps water-in-oil inverse micro emulsion
Wick-containing liquid, and capsule grain diameter is made between 2.5-3.0mm by adjustment equipment parameter.
Dry：Wet capsule is separated with protection liquid using screen cloth, the wet capsule being collected into is inhaled surface oil using oil-Absorbing Sheets
Rotating cage is put into after dry, 200-300rpm dries 4-10h, during which accelerates drying with fan air-supply, treat that rubber is dried completely, take out dry
Dry rear capsule is placed in ventilation 1-2h with alcohol rinsing and obtains biomass glue wall material-microemulsion core after alcohol volatilizees afterwards twice
Capsule sample.
Embodiment 5
Cigarette is 3.5-4.0mm with capsule diameter in the present embodiment, is agalloch eaglewood-tea perfume capsule, and wall material is synthetic resin, core
Account for capsule proportion 90%.
Preparation method is as follows：
Capsule core is prepared：By isopropyl myristate, agalloch eaglewood essence, isopropyl isostearate, Span80 according to weight
Than 96:5:22:15 are uniformly mixed to form solution A；Water, tealeaves medicinal extract, isoamyl alcohol is according to mass ratio：12:1.5:5 preparations form molten
Liquid B, 4 are pressed by above-mentioned A, B solution:3 well mixed form transparent or semitransparent water-in-oil inverse microemulsion.
Capsule wall material is prepared：Epoxy novolac acrylic resin, epoxidized oil acrylate, LLDPE are pressed
Mass ratio 3:2:0.5 is made into well mixed well mixed and then is heated at 110 DEG C of temperature, and is incubated preservation.
Dripping is molded：By the core prepared and wall material liquid by quality 6:1 is respectively charged into the glue pot of pill dripping machine and core flow container,
The capsule wall material liquid of preparation is added to water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
In 10-20 DEG C of cooling oil, capsule wall material gradually cools and solidifies shaping in its dropping process, and it is micro- that sealed bundle wraps water-in-oil inverse
Emulsion core liquid, by adjustment equipment parameter regulation capsule size in the range of 2.5-3.0mm.Made capsule is collected to be synthesized
Resin wall material-microemulsion core capsule sample.
Embodiment 6
Cigarette is 3.5-40mm with capsule diameter in the present embodiment, is the stem of noble dendrobium-cigarette perfume capsule, and wall material is synthetic resin, core
Account for capsule proportion 90%.
Preparation method is as follows：
Capsule core is prepared：Caprylic/capric glyceryl ester, stem of noble dendrobium essence, oleate, Tween80 are compared 96 according to weight:
10:22:15 are uniformly mixed to form solution A；Water, tobacco extract, isoamyl alcohol is according to mass ratio：15:2:3 preparations form solution B, will
Above-mentioned A, B solution press 4:3 well mixed form transparent or semitransparent water-in-oil inverse microemulsion.
Capsule wall material is prepared：Aliphatic polyurethane acrylic resin, polyester acrylate resin, amino acrylic resin are pressed
Mass ratio 3:2:0.5 is well mixed, and then adds the 2- hydroxy-2-methyl -1- phenyl ketones that mass percent is 0.03%, and
The agitating heating under temperature 50 C, keeps in dark place.
Dripping is molded：By the core prepared and wall material liquid by quality 6:1 is respectively charged into the glue pot of pill dripping machine and core flow container,
The capsule wall material liquid of preparation is added to water-in-oil inverse micro emulsion wick-containing drop by dripping pill device concentric circles water dropper by constant displacement pump
In Medium Oil, in its dropping process capsule wall material add outside light source irradiate under gradually curing molding, sealed bundle wraps Water-In-Oil
Reverse microemulsion wick-containing liquid, by adjustment equipment parameter regulation capsule size in the range of 3.5-4.0mm.Made capsule is collected to produce
To synthetic resin wall material-microemulsion core capsule sample.
This written description discloses the present invention, including optimal mode using example, and can also allow those skilled in the art's energy
It is enough to manufacture and using the present invention.The present invention can patentable scope be defined by the claims but be not limited to this.If
This other examples have the structural element of literal language not different from claims, or if this other examples include
With the equivalent structure element of the literal language without substantial differences of claims, then this other example intentions will in right
Within the scope of seeking book.In the case where not resulting in inconsistent degree, by reference to by place of all references referred to herein simultaneously
Enter herein.
Claims (9)
1. a kind of cigarette capsule, it is characterised in that be made up of 10-30 parts by weight capsule wall materials with 30-70 parts by weight cores, capsule
Outward appearance is the transparent or semitransparent elastomeric spherical bodies of particle diameter 2.5-4mm.
2. cigarette capsule according to claim 1, the pop strength of the capsule is 0.5-2.5kg, the wall of the capsule
Thickness is 0.1-0.5mm.
3. cigarette capsule according to claim 1 or 2, it is characterised in that the capsule using water-in-oil inverse microemulsion as
Core, capsule wall material is used as using biomass glue or synthetic resin.
4. cigarette capsule according to claim 3, the Water-In-Oil reverse micelle microemulsion density of core material is 0.8-1.1g/
cm3, and also contain compound surfactant, cosurfactant, oil phase, oil soluble perfume, water, soluble perfume.
5. cigarette capsule according to claim 4, it is characterised in that the water-in-oil type reverse microemulsion in the capsule core
Liquid contains water and soluble perfume.
6. cigarette capsule according to claim 4, it is characterised in that the water-in-oil type reverse microemulsion in the capsule core
Liquid contains oil and oil soluble perfume.
7. the preparation method of cigarette capsule according to any one of the preceding claims, it is characterised in that by what is prepared
Core and wall material are proportionally added in dripping pill device, form the capsule that wall material wraps up microemulsion.
8. the preparation method of cigarette capsule according to claim 7, it is characterised in that water-in-oil inverse microemulsion core
Preparation process is：By oily components, and uniformly mixing constitutes oil phase in proportion for oil soluble perfume, compound surfactant；Will
Aqueous phase is constituted after cosurfactant, water and water-soluble essence are well mixed, aqueous phase is added dropwise to the oil of positive ultrasonic disperse
Xiang Zhong, continues to disperse to form transparent or semitransparent shape water-in-oil inverse microemulsion after being well mixed.
9. preparation method according to claim 7, it is characterised in that the preparation method causes water-in-oil inverse micro emulsion wick-containing
Material includes the component of following mass percent：Oil phase:Aqueous phase=30-70%:70-30%.
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