CN106938898A - A kind of true mineral varnish suitable for airless spraying - Google Patents
A kind of true mineral varnish suitable for airless spraying Download PDFInfo
- Publication number
- CN106938898A CN106938898A CN201710114757.7A CN201710114757A CN106938898A CN 106938898 A CN106938898 A CN 106938898A CN 201710114757 A CN201710114757 A CN 201710114757A CN 106938898 A CN106938898 A CN 106938898A
- Authority
- CN
- China
- Prior art keywords
- mineral varnish
- true mineral
- water
- varnish according
- quartz sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims abstract description 38
- 239000011707 mineral Substances 0.000 title claims abstract description 38
- 239000002966 varnish Substances 0.000 title claims abstract description 38
- 238000005507 spraying Methods 0.000 title claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000006004 Quartz sand Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003755 preservative agent Substances 0.000 claims abstract description 12
- 230000002335 preservative effect Effects 0.000 claims abstract description 12
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 229920002522 Wood fibre Polymers 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 10
- 239000013008 thixotropic agent Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000004576 sand Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229920000896 Ethulose Polymers 0.000 claims description 4
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 4
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 4
- -1 methyl ethyl hydroxyethyl Chemical group 0.000 claims description 4
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 239000003002 pH adjusting agent Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 14
- 238000000576 coating method Methods 0.000 abstract description 11
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- 239000003973 paint Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 238000005336 cracking Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- VPJOGDPLXNTKAZ-UHFFFAOYSA-N 2-methylpropanoic acid;2,2,4-trimethylpentane-1,3-diol Chemical class CC(C)C(O)=O.CC(C)C(O)C(C)(C)CO VPJOGDPLXNTKAZ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- 238000001792 White test Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 230000003694 hair properties Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to technical field of coatings, a kind of true mineral varnish suitable for airless spraying is specifically disclosed, by weight percentage, it includes following components：Acrylic resin 13~18%, water-loss reducer 0.1~0.3%, defoamer 0.03~0.1%, thixotropic agent 0.02~0.05%, antifreezing agent 0.6~1%, coalescents 0.5~1%, pH value regulator 0.05~0.1%, wood fibre 0.2~0.3%, preservative 0.1~0.2%, quartz sand 65~76%, surplus is water.The true mineral varnish of the present invention is applied to airless spraying, and with environmental protection, adhesion strength is high, dries and shrinks the features such as strong, the aobvious grittiness of small, water-proof breathable properties is protruded, and compared with common true mineral varnish, efficiency of construction is high, drop rate is few, it is possible to decrease construction cost.
Description
Technical field
The present invention relates to technical field of coatings, more particularly, to a kind of true mineral varnish.
Background technology
True mineral varnish is by aggregate, binding agent（Base-material）, various auxiliary agents and solvent composition, its coating possesses the abundant of lithotome
Texture, third dimension, and with the serious, aesthetic feeling of harmony.It is compared with facing tile, dry hanging granite, and cost performance is higher, and it is filled
Effect is adornd comparable to stone material, and is more suitable for than stone material moulding various designs, therefore is quite welcome by construction market, is current exterior wall
The preferred ornament materials of finishing.
At present, the construction of true mineral varnish is mainly aerial spraying, and less use airless spraying.Aerial spraying is to utilize compression
The air-flow of air, flows through spray tip hole and forms negative pressure, negative pressure makes paint vehicle be sucked from suction pipe, sprayed through nozzle, forms coating cloud, paint
Spray painting is mapped to and uniform paint film is formed on covering with paint substrate surface.Airless spraying is to be increased liquid coating using booster pump
Pressure, is then delivered to airless spray gun through high-pressure hose, finally without spraying to coated article after hydraulic pressure, instantaneous atomization are discharged at gas jets
Surface, forms film layer, due to not containing air in coating, so it is referred to as airless spraying, abbreviation airless spraying.
The pressure ratio aerial spraying of airless spraying is much bigger, and its emitted dose is far above aerial spraying, therefore efficiency of construction is more
Height, and because airless spraying principle is hydraulic atomizing, coating used is fewer than aerial spraying on the contrary when it sprays, therefore more saves
Material.However, because the jet velocity of airless spraying is fast, when spraying contains big particle, the true mineral varnish of fiber, with coating layer thickness
Increase, easily cracking phenomenon, and drop is more, coating quality is difficult to ensure that.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of true mineral varnish suitable for airless spraying, applied not open with thickness
Split, the advantage that drop rate is low, it is adaptable to airless spraying, it is possible to increase efficiency of construction, reduce construction cost.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of true stone suitable for airless spraying
Paint, by weight percentage, it is mixed by following components：
Acrylic resin 13~18%,
Water-loss reducer 0.1~0.3%,
Defoamer 0.03~0.1%,
Thixotropic agent 0.02~0.05%,
Antifreezing agent 0.6~1%,
Coalescents 0.5~1%,
PH value regulator 0.05~0.1%,
Wood fibre 0.2~0.3%,
Preservative 0.1~0.2%,
Quartz sand 65~76%,
Water surplus.
Wherein, the acrylic resin is self-crosslinking pure-acrylic emulsion, it is preferred that its solid content is 46~48%, minimum film forming
Temperature is 23 DEG C.
It is preferred that, the water-loss reducer is methyl ethyl hydroxyethyl cellulose ether, and the defoamer is mineral oil defoaming agent,
The thixotropic agent is organobentonite, and the coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates, the pH
Value conditioning agent is 2-amino-2-methyl-1-propanol, and the preservative is Kathon CG class preservative.
It is preferred that, the wood fibre length is 500um.
Further, the quartz sand is matched somebody with somebody for the natural crystal level of different-grain diameter and formed, different-grain diameter quartz sand mass ratio
For 20~40 mesh：40~80 mesh：80~120 mesh=1:7:7.
Instant component water is underground water or running water.
Further, the true mineral varnish is made as follows：
By the component proportion, water-loss reducer and thixotropic agent are dissolved in coalescents and antifreezing agent respectively, are then added into
Into the water accurately measured, stirring, then sequentially add into the aqueous solution acrylic resin, defoamer, preservative, wood fibre,
PH adjusting agent, stirring forms in emulsion form slurries, most backward emulsion form slurries and adds the quartz sand of different gradation, that is, institute is made
State true mineral varnish.
It is preferred that, when adding the quartz sand of different gradation, fine sand is first added, coarse sand is added afterwards.
It is using the beneficial effect produced by above-mentioned technical proposal：The true mineral varnish of the present invention using 100% pure acrylic latex as
Base-material, adds several functions additive, and its paint film flexibility reaches 50mm flawlesses, and adhesion strength reaches 1.3mpa, can
Constructed using airless spraying, compared with prior art aerial spraying, 6~8 times of improved efficiency, construction period shortens, manpower of constructing
Cost is significantly reduced, and drop phenomenon is significantly reduced, it is to avoid wasted.The present invention true mineral varnish production prepare it is simple and convenient, without waving
Hair property organic matter, safety and environmental protection can be used for exterior wall concrete, the surface such as old-wall renewing.
Embodiment
There is the high shortcoming of coating cracking, drop rate using airless spraying for the true mineral varnish of prior art, the present invention is provided
A kind of true mineral varnish suitable for airless spraying, by weight percentage, it is mixed by following components：Acrylic resin 13~
18%, water-loss reducer 0.1~0.3%, defoamer 0.03~0.1%, thixotropic agent 0.02~0.05%, antifreezing agent 0.6~1%, coalescents
0.5~1%, pH value regulator 0.05~0.1%, wood fibre 0.2~0.3%, preservative 0.1~0.2%, quartz sand 65~76%,
Surplus is water.
The present invention is made as follows suitable for the true mineral varnish of airless spraying：
By the component proportion, water-loss reducer and thixotropic agent are dissolved in coalescents and antifreezing agent respectively, are then added into
Into the water accurately measured, stirring, then sequentially add into the aqueous solution acrylic resin, defoamer, preservative, wood fibre,
PH adjusting agent, stirring forms in emulsion form slurries, most backward emulsion form slurries and adds the quartz sand of different gradation, it is preferred that first
Fine sand is added, coarse sand is added afterwards, that is, the true mineral varnish is made.
Illustrate below and the present invention is described in further detail.
The true mineral varnish embodiment suitable for airless spraying that proportioning component is constituted as shown in Table 1 below is prepared by preceding method
1-3。
In embodiment 1-3, acrylic resin used is LG-DOW（Dow）Self-crosslinking pure-acrylic emulsion TX100, its solid content is
46~48%, MFT is 23 DEG C.Water-loss reducer used is methyl ethyl hydroxyethyl cellulose ether, such as Akzo Nobel
（AkzoNobel）100K2.Defoamer used is mineral oil defoaming agent, such as Hai Chuan F111.Thixotropic agent used is organic bentonite
Profit soil, such as BP-188B of Zhejiang Ward.Used film forming auxiliary agent is 2,2,4- trimethyl -1,3- pentanediol mono isobutyrates, such as her
The graceful texanol of scholar.PH value regulator used is 2-amino-2-methyl-1-propanol, and the AMP-95 of lattice is pacified in such as U.S..It is used anti-
Rotten agent is Kathon CG class preservative, such as RS of Britain's Sol.Wood fibre used is Xing Meiya HB300, and its length is 500um.
Water used is running water.
In embodiment 1-3, quartz sand used is matched somebody with somebody for the natural crystal level of different-grain diameter to be formed, different-grain diameter quartz sand quality
Than for 20~40 mesh：40~80 mesh：80~120 mesh=1:7:7.
By true mineral varnish obtained by embodiment of the present invention 1-3 and the true mineral varnish of prior art（Competing product）Performance detection is carried out, is measured
All technical be shown in Table 2.
In table 2, detection project 1-13 is is detected according to national standard, and detection project 14-18 is to combine practice of construction automatic control
Project, wherein embodiment 1-3 products are airless spraying, and competing product are aerial spraying.
In table 2, initial stage water-whitening resistance be air drying 4h after do the resistance to water-white test of coating；Drop rate be spraying process in fall
Knockout grain accounts for the percentage of consumption；How long efficiency of construction refers to 1 square meter of spraying.
As can be seen from Table 2, the true mineral varnish of the embodiment of the present invention has environmental protection, adhesion strength height, dries and shrink small, anti-
The features such as strong, the aobvious grittiness of water gas permeability is protruded, not only meets true mineral varnish traditional performance, causes out after more solving once construction
The generation split, meanwhile, thixotropy is 6.0 or so, it is adaptable to airless spraying, and efficiency of construction is high（Equivalent to the 6-8 of usual spray
Times）, drop rate is low（＜ 2%）, cost of labor and construction period can be reduced, solves that existing market coating price is higher, drop
The problems such as many, low construction efficiency.
Compared with prior art, the embodiment of the present invention has the following advantages that：
（1）Using 100% acrylic emulsion there is provided the excellent adhesion strength of true mineral varnish, ageing-resistant performance, contaminated resistance and just
Phase water-whitening resistance.
（2）Using methyl ethyl hydroxyethyl cellulose as water-loss reducer, make system that there is bleed and the foam stability of brilliance,
The spray efficiency of true mineral varnish is greatly improved.
（3）High thixotroping bentonite is employed, association network structure is hydrated to form rapidly after meeting water, the list with smooth performance
Body microprocessing chip is embedded between the particles of material such as sand grains in order, reduces intergranular friction resistance, forms smooth effect, improves spraying
Smoothness.
（4）Use wood-fibred to be dried for true mineral varnish and moisture evaporation passage is provided, it is to avoid cracking phenomenon in drying process.
The present invention is described in detail above, embodiments of the present invention carried out using specific case in the present invention
Illustrate, the explanation of above example is only intended to help and understands the present invention, it is noted that for the technology people of the art
For member, under the premise without departing from the principles of the invention, some improvement can be also carried out to the present invention, these improvement also fall into this hair
In bright scope of the claims.
Claims (10)
1. a kind of true mineral varnish suitable for airless spraying, it is characterised in that：By weight percentage, it is mixed by following components and made
Into：
Acrylic resin 13~18%,
Water-loss reducer 0.1~0.3%,
Defoamer 0.03~0.1%,
Thixotropic agent 0.02~0.05%,
Antifreezing agent 0.6~1%,
Coalescents 0.5~1%,
PH value regulator 0.05~0.1%,
Wood fibre 0.2~0.3%,
Preservative 0.1~0.2%,
Quartz sand 65~76%,
Water surplus.
2. true mineral varnish according to claim 1, it is characterised in that the acrylic resin is self-crosslinking pure-acrylic emulsion, it is consolidated
Content is 46~48%, and MFT is 23 DEG C.
3. true mineral varnish according to claim 1, it is characterised in that the water-loss reducer is methyl ethyl hydroxyethyl cellulose ether.
4. true mineral varnish according to claim 1, it is characterised in that the defoamer is mineral oil defoaming agent.
5. true mineral varnish according to claim 1, it is characterised in that the thixotropic agent is organobentonite.
6. true mineral varnish according to claim 1, it is characterised in that the coalescents are 2,2,4- trimethyls -1,3- penta 2
Alcohol mono isobutyrate, the pH value regulator is 2-amino-2-methyl-1-propanol, and the preservative is Kathon CG class preservative.
7. true mineral varnish according to claim 1, it is characterised in that the wood fibre length is 500um.
8. true mineral varnish according to claim 1, it is characterised in that the quartz sand is matched somebody with somebody for the natural crystal level of different-grain diameter
Form, different-grain diameter quartz sand mass ratio is 20~40 mesh：40~80 mesh：80~120 mesh=1:7:7.
9. true mineral varnish according to claim 1, it is characterised in that the true mineral varnish is made as follows：
By the component proportion, water-loss reducer and thixotropic agent are dissolved in coalescents and antifreezing agent respectively, are then added into
Into the water accurately measured, stirring, then sequentially add into the aqueous solution acrylic resin, defoamer, preservative, wood fibre,
PH adjusting agent, stirring forms in emulsion form slurries, most backward emulsion form slurries and adds the quartz sand of different gradation, that is, institute is made
State true mineral varnish.
10. true mineral varnish according to claim 9, it is characterised in that when adding the quartz sand of different gradation, first add fine sand,
After add coarse sand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114757.7A CN106938898B (en) | 2017-02-28 | 2017-02-28 | A kind of lacquer suitable for airless spraying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710114757.7A CN106938898B (en) | 2017-02-28 | 2017-02-28 | A kind of lacquer suitable for airless spraying |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106938898A true CN106938898A (en) | 2017-07-11 |
| CN106938898B CN106938898B (en) | 2019-06-14 |
Family
ID=59468722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710114757.7A Active CN106938898B (en) | 2017-02-28 | 2017-02-28 | A kind of lacquer suitable for airless spraying |
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| Country | Link |
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| CN (1) | CN106938898B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073415A (en) * | 2019-12-17 | 2020-04-28 | 四川嘉宝莉涂料有限公司 | Light stone-like paint without color sand |
| CN114618703A (en) * | 2022-03-16 | 2022-06-14 | 河北晨阳工贸集团有限公司 | Real stone paint quality identification device and identification method thereof |
| CN114989685A (en) * | 2022-06-14 | 2022-09-02 | 亚士创能科技(石家庄)有限公司 | Texture paint and preparation method thereof |
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| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
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2017
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|---|---|---|---|---|
| CN104609772A (en) * | 2014-12-26 | 2015-05-13 | 三棵树涂料股份有限公司 | Really stone paint and preparation method thereof |
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Non-Patent Citations (1)
| Title |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073415A (en) * | 2019-12-17 | 2020-04-28 | 四川嘉宝莉涂料有限公司 | Light stone-like paint without color sand |
| CN111073415B (en) * | 2019-12-17 | 2022-02-08 | 四川嘉宝莉涂料有限公司 | Light stone-like paint without color sand |
| CN114618703A (en) * | 2022-03-16 | 2022-06-14 | 河北晨阳工贸集团有限公司 | Real stone paint quality identification device and identification method thereof |
| CN114618703B (en) * | 2022-03-16 | 2023-09-01 | 河北晨阳工贸集团有限公司 | Real stone paint quality identification device and identification method thereof |
| CN114989685A (en) * | 2022-06-14 | 2022-09-02 | 亚士创能科技(石家庄)有限公司 | Texture paint and preparation method thereof |
| CN114989685B (en) * | 2022-06-14 | 2023-08-11 | 亚士创能科技(石家庄)有限公司 | Texture paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106938898B (en) | 2019-06-14 |
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