CN106938164A - A kind of anti-haze immunologic function film and preparation method and application - Google Patents
A kind of anti-haze immunologic function film and preparation method and application Download PDFInfo
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- CN106938164A CN106938164A CN201710186341.6A CN201710186341A CN106938164A CN 106938164 A CN106938164 A CN 106938164A CN 201710186341 A CN201710186341 A CN 201710186341A CN 106938164 A CN106938164 A CN 106938164A
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- haze
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/54—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms
- B01D46/543—Particle separators, e.g. dust precipitators, using ultra-fine filter sheets or diaphragms using membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2201/00—Details relating to filtering apparatus
- B01D2201/30—Filter housing constructions
- B01D2201/308—Use of foils, membranes or other means to protect the filter before its use or for protecting the environment, e.g. during removal of the filter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/04—Additives and treatments of the filtering material
- B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The invention provides a kind of anti-haze immunologic function film and preparation method and application.The anti-haze immunologic function film of the present invention is mainly prepared using adsorbent, photochemical catalyst, antiseptic, antioxidant, film forming agent and the immunopotentiator of specific consumption proportion, and preparation method technique is simple, low cost, efficiency high, suitable for large-scale production.The anti-haze immunologic function film of the present invention can be used in preparing filtration, purification equipment, can effectively obstruct PM2.5 haze particles, nontoxic, pollution-free, non-stimulated, while having excellent immunologic function concurrently, human body is effectively protected, is a kind of self-clean type functional membrane.
Description
Technical field
The present invention relates to functional film material technical field, in particular to a kind of anti-haze immunologic function film and its preparation
Method and application.
Background technology
Climate warming and urban development cause large-scale environmental pollution, vehicle exhaust produce substantial amounts of hydronitrogen,
Various heavy metal compounds and smokeshade, complicated photochemical pollution is produced in atmosphere.PM2.5 particles are inhaled as carrier
Attached a large amount of atmosphere poisonous substances, oral, nose, lung and brain path invasion human body, some smaller Aerosol Pollution haze ions are invaded
Enter alveolar, diffusion, deposition, cause neoplastic lesion, current haze produces serious harm to human health.
In correlation technique, it can be used to take precautions against above-mentioned pollutant using different methods, but often used a large amount of chemistry
Article, these products are directly abandoned after use will cause new pollution again；Carry out filtering net using the equipment of recyclable processing
Change, equipment cost and recycling cost are higher, it is difficult to promoted the use of to ordinary consumer.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of anti-haze immunologic function film, and described anti-haze immunologic function film can have
Effect barrier PM2.5 haze particles, it is nontoxic, pollution-free, non-stimulated, while having excellent immunologic function concurrently, human body is carried out effective
Protection, is a kind of self-clean type functional membrane.
The second object of the present invention is to provide a kind of preparation method of described anti-haze immunologic function film, this method technique
Simply, low cost, efficiency high, suitable for large-scale production.
The third object of the present invention is to provide a kind of application of described anti-haze immunologic function film, and described anti-haze is immunized
Functional membrane can be used in preparing filtration, purification equipment, can effectively obstruct PM2.5 haze particles, give full play to immune effect, right
Human body is effectively protected.
In order to realize the above-mentioned purpose of the present invention, spy uses following technical scheme：
A kind of anti-haze immunologic function film, is mainly prepared by the raw material of following mass fraction：
5-35 parts of adsorbent, 1.1-15 parts of photochemical catalyst, 0.2-10 parts of antiseptic, 0.3-15 parts of antioxidant, film forming agent
2-15 parts and 0.2-10 parts of immunopotentiator.
Preferably, the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
15-25 parts of adsorbent, 4-10 parts of photochemical catalyst, 3-6 parts of antiseptic, 6-12 parts of antioxidant, 6-12 parts of film forming agent
With 3-6 parts of immunopotentiator.
It is further preferred that the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
20 parts of adsorbent, 7 parts of photochemical catalyst, 4 parts of antiseptic, 9 parts of antioxidant, 9 parts of film forming agent and immunopotentiator 4
Part.
The anti-haze immunologic function film of the present invention is mainly using the adsorbent of specific consumption proportion, photochemical catalyst, antiseptic, antioxygen
Agent, film forming agent and immunopotentiator are prepared, and can effectively obstruct PM2.5 haze particles, nontoxic, pollution-free, non-stimulated,
Have excellent immunologic function concurrently simultaneously, human body is effectively protected, is a kind of self-clean type functional membrane.
Alternatively, the adsorbent includes porous adsorbing material, preferably includes inorganic porous material, further preferably includes
Aluminum oxide porous material.
Preferably, the particle diameter of the aluminum oxide porous material is below 500nm, preferably 100-500nm.
Alternatively, the photochemical catalyst includes the one or more in fluoro-silicone emulsion and titanium dioxide, preferably includes fluorine silicon
Emulsion and titanium dioxide.
Preferably, the titanium dioxide is Nano titanium dioxide, and preferably particle diameter is below 100nm nanoscale dioxy
Change titanium.
Preferably, the mass ratio of the fluoro-silicone emulsion and titanium dioxide is 1-10：0.1-5, preferably 3-7：1-3, enters one
Step is preferably 5：2.
Alternatively, the antiseptic includes the one or more in quaternary ammonium salt silane and cinnamic acid, preferably includes quaternary ammonium salt
Silane and cinnamic acid.
Preferably, the mass ratio of the quaternary ammonium salt silane and cinnamic acid is 0.1-5：0.1-5, preferably 1-2：1-2, enters one
Step is preferably 1：1.
Alternatively, the antioxidant preferably includes Tea Polyphenols, dimension including a kind of excessively a variety of in Tea Polyphenols and vitamin
One or more in raw element C and vitamin E, further preferably including Tea Polyphenols, vitamin C and vitamin E.
Preferably, the mass ratio of the Tea Polyphenols, vitamin C and vitamin E is 0.1-5：0.1-5：0.1-5, be preferably
1-2：1-2：1-2, more preferably 1：1：1.
Alternatively, the film forming agent include chitosan and sodium alginate in one or more, preferably include chitosan and
Sodium alginate.
Preferably, the mass ratio of the chitosan and sodium alginate is 1-5：1-10, preferably 1-2：2-4, it is further excellent
Elect 1 as：2.
Alternatively, the immunopotentiator includes the one or more in moringa seeds and dandelion, preferably includes moringa seeds
And dandelion.
Preferably, the moringa seeds and the mass ratio of dandelion are 0.1-5：0.1-5, preferably 1-2：1-2, it is further excellent
Elect 1 as：1.
A kind of preparation method of above-mentioned anti-haze immunologic function film, by adsorbent, photochemical catalyst, antiseptic, antioxidant,
Sustained release agent, binding agent and immunopotentiator and solvent are thoroughly mixed uniformly, and gained slurry is coated on base material, dried
To a kind of anti-haze immunologic function film.
The preparation method technique of the anti-haze immunologic function film of the present invention is simple, low cost, efficiency high, suitable for large-scale production.
Alternatively, the solvent includes the one or more in volatilizable liquid, preferably includes water.
Preferably, the base material includes the one or more in metal, timber, cloth, preferably string porous paper.
Preferably, the drying temperature is less than 90 DEG C, is preferably room temperature to 80 DEG C, more preferably 60-80 DEG C.
A kind of application of above-mentioned anti-haze immunologic function film, including the anti-haze immunologic function film is in filtration, purification field
Using.
The anti-haze immunologic function film of the present invention can be used in preparing filtration, purification equipment, can effectively obstruct PM2.5 hazes
Grain, gives full play to immune effect, human body is effectively protected.
Preferably, including the anti-haze immunologic function film air filtration field of purification application.
It is further preferred that including the anti-haze immunologic function film in filter, purifier, indoor and outdoor apparatus facility
On application.
Compared with prior art, beneficial effects of the present invention are：
The anti-haze immunologic function film of the present invention is mainly using the adsorbent of specific consumption proportion, photochemical catalyst, antiseptic, antioxygen
Agent, film forming agent and immunopotentiator are prepared, and preparation method technique is simple, low cost, efficiency high, suitable for extensive raw
Production.The anti-haze immunologic function film of the present invention can be used in preparing filtration, purification equipment, can effectively obstruct PM2.5 haze particles, nothing
It is malicious, pollution-free, non-stimulated, while having excellent immunologic function concurrently, human body is effectively protected, is a kind of self-clean type function
Film.
Embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment, but ability
Field technique personnel will be understood that, following described embodiment is a part of embodiment of the invention, rather than whole embodiments,
The present invention is merely to illustrate, and is not construed as limiting the scope of the present invention.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.Unreceipted actual conditions person in embodiment, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or instrument
Unreceipted production firm person, is the conventional products that can be obtained by commercially available purchase.
The invention provides a kind of anti-haze immunologic function film, mainly prepared by the raw material of following mass fraction：
5-35 parts of adsorbent, 1.1-15 parts of photochemical catalyst, 0.2-10 parts of antiseptic, 0.3-15 parts of antioxidant, film forming agent
2-15 parts and 0.2-10 parts of immunopotentiator.
Preferably, the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
15-25 parts of adsorbent, 4-10 parts of photochemical catalyst, 3-6 parts of antiseptic, 6-12 parts of antioxidant, 6-12 parts of film forming agent
With 3-6 parts of immunopotentiator.
It is further preferred that the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
20 parts of adsorbent, 7 parts of photochemical catalyst, 4 parts of antiseptic, 9 parts of antioxidant, 9 parts of film forming agent and immunopotentiator 4
Part.
The anti-haze immunologic function film of the present invention is mainly using the adsorbent of specific consumption proportion, photochemical catalyst, antiseptic, antioxygen
Agent, film forming agent and immunopotentiator are prepared, and can effectively obstruct PM2.5 haze particles, nontoxic, pollution-free, non-stimulated,
Have excellent immunologic function concurrently simultaneously, human body is effectively protected, is a kind of self-clean type functional membrane.
Alternatively, the adsorbent includes porous adsorbing material, preferably includes inorganic porous material, further preferably includes
Aluminum oxide porous material.
Aluminum oxide porous material is the excellent inorganic carrier of a class absorption property, can obstruct, adsorb PM2.5 particles and gas is molten
Glue, while other functions component distributing can be made into network-like, it is ensured that each function ingredients can play a role for a long time.It is preferred that adopting
With the aluminum oxide porous material of medical grade that purity is more than 99.9%.
Preferably, the particle diameter of the aluminum oxide porous material is below 500nm, preferably 100-500nm.
Nanoscale Lu porous material has higher specific surface area, can further improve its to PM2.5 particles and
The barrier of aerosol and absorption property, more uniformly spread, it is ensured that other functions component while also contributing to other functions component
Effect is given full play to, further extends effective time.
Alternatively, the photochemical catalyst includes the one or more in fluoro-silicone emulsion and titanium dioxide, preferably includes fluorine silicon
Emulsion and titanium dioxide.
Fluoro-silicone emulsion and titanium dioxide have excellent surface characteristic, and surface tension is low, with excellent Water-proof and oil-proof and
Anti-pollution function, can effectively obstruct PM2.5 photochemical pollutions particle and aerosol, at the same again can long acting antibiotic, except it is mould, sterilization,
Bacterial cell can be prevented to breathe to death, while also there is self-cleaning function, and excellent in stability.
Preferably, the titanium dioxide is Nano titanium dioxide, and preferably particle diameter is below 100nm nanoscale dioxy
Change titanium.
Nano titanium dioxide has higher specific surface area, can further improve photocatalysis effect, improves antibacterial, removes
Mould, Disinfection Effect.
Preferably, the mass ratio of the fluoro-silicone emulsion and titanium dioxide is 1-10：0.1-5, preferably 3-7：1-3, enters one
Step is preferably 5：2.
Using the fluoro-silicone emulsion and titanium dioxide of specific usage ratio, contribute to the full and uniform dispersion of titanium dioxide, enter
One step improves photocatalysis effect, improves antibacterial, except mould, Disinfection Effect, while improving the self-cleaning energy of the anti-haze immunologic function film of gained
Power, makes it keep stable for a long time.
Alternatively, the antiseptic includes the one or more in quaternary ammonium salt silane and cinnamic acid, preferably includes quaternary ammonium salt
Silane and cinnamic acid.
Quaternary ammonium salt silane security is good, has a broad antifungal spectrum, and effect is a class non-dissolving type antibacterial deodourizing product persistently.Quaternary ammonium
Salt silane can effectively suppress the infection of drug-resistant S. aureus (MRSA) etc., can kill gram and all kinds of skins
Mould, tinea bacterium, bacteriostasis rate is more than 99%.
Cinnamic acid is a kind of antimycotic active material, by destroying fungi rill wall, organelle, can kill a variety of causes
Characteristic of disease fungi, for carrying out transplantation treatment, deodorization and sterilization to various bacterium infections.Meanwhile, cinnamic acid can cheat influenza virus, resist
Mutagenesis, radioresistance suppresses tumour, improves immunity, maintains skin, stimulates circulation, and strengthens mental, improves memory.
Preferably, the mass ratio of the quaternary ammonium salt silane and cinnamic acid is 0.1-5：0.1-5, preferably 1-2：1-2, enters one
Step is preferably 1：1.
Using the quaternary ammonium salt silane and cinnamic acid of specific usage ratio, help further to improve the anti-haze immunologic function of gained
The antibacterial ability of film, is effectively protected to human body.
Alternatively, the antioxidant preferably includes Tea Polyphenols, dimension including a kind of excessively a variety of in Tea Polyphenols and vitamin
One or more in raw element C and vitamin E, further preferably including Tea Polyphenols, vitamin C and vitamin E.
Tea Polyphenols has excellent health oxidisability and triumph activity, is a kind of human free radical scavenger, with anti-cancer work(
Effect.Flavanol compound material in human body superoxide radical and hydroxy radical reaction meeting damage dna, Tea Polyphenols can terminate this kind of anti-
The progress answered.Tea Polyphenols can also induced tumor cell apoptosis, while have very strong metal ion-chelant function, detoxify,
Radioresistance, resists allergic effect notable.
Contain hydroxyl in vitamin C and vitamin E, with oxidation resistant effect, human body can be protected, immunity is improved,
Strengthen absorbability of the tissue to oxygen, strengthen blood circulation, anti-aging improves immunity.
Preferably, the mass ratio of the Tea Polyphenols, vitamin C and vitamin E is 0.1-5：0.1-5：0.1-5, be preferably
1-2：1-2：1-2, more preferably 1：1：1.
Using the Tea Polyphenols, vitamin C and vitamin E of specific usage ratio, the further anti-haze of gained that improves is contributed to exempt from
The oxidation resistance of epidemic disease functional membrane, improves immunocompetence, and to decline pigment, cutin-softening, suppressing sebum secretion also has well
Effect.
Alternatively, the film forming agent include chitosan and sodium alginate in one or more, preferably include chitosan and
Sodium alginate.
Chitosan is a class marine organisms flocculant, with good Immunity regulation activity, good film forming, logical
Permeability, fibre forming property, moisture retention, are a class natural polymeric chelants, can metal ion difficult to understand conspicuous, adsorb cholesterol, can be direct
Suppress tumour cell, promote cholesterol to be converted into bile acid, excrete.Chitosan can also improve immunity, liver detoxification,
It is anti-oxidant, it is antistatic, it is good with skin-friendliness, it is a kind of immunologic function activator.
Sodium alginate is a class marine biomass binding agent, can by types of functionality material it is scattered be bonded to it is network-like, into
It is good that film drinks biodegradability.
Preferably, the mass ratio of the chitosan and sodium alginate is 1-5：1-10, preferably 1-2：2-4, it is further excellent
Elect 1 as：2.
Using the chitosan and sodium alginate of specific usage ratio, absorption affinity and biocompatibility are favorably improved, is promoted
Degraded, improves infiltration, sustained release and the assimilation effect of other functions material.
Alternatively, the immunopotentiator includes the one or more in moringa seeds and dandelion, preferably includes moringa seeds
And dandelion.
Moringa seeds being capable of prevention disease, improvement sleep, enhancing memory, anti-aging, raising immunity, toxin expelling promotion generation
Thank, treat allergic, solution is baffled to itch, and solves the uncomfortable problem of skin contact stain particle.Moringa seeds contain a variety of dimensions
Raw element, trace element and several amino acids composition, being capable of effective activation cell, anti-inflammation, raising immunity.
Contain taraxol in dandelion, can anti-inflammation, it is clearing heat and detoxicating, multi-infection can be treated, it is anti-cure cold, gas
Guan Yan, whets the appetite, and strengthens body, prevents and treats all kinds of carninomatosis, effectively dredging pent-up irritability, and regulation spirit improves immunologic function.
Preferably, the moringa seeds and the mass ratio of dandelion are 0.1-5：0.1-5, preferably 1-2：1-2, it is further excellent
Elect 1 as：1.
Moringa seeds and dandelion using specific usage ratio, help further to improve the anti-haze immunologic function film of gained
Immunocompetence.
A kind of preparation method of above-mentioned anti-haze immunologic function film, by adsorbent, photochemical catalyst, antiseptic, antioxidant,
Sustained release agent, binding agent and immunopotentiator and solvent are thoroughly mixed uniformly, and gained slurry is coated on base material, dried
To a kind of anti-haze immunologic function film.
The preparation method technique of the anti-haze immunologic function film of the present invention is simple, low cost, efficiency high, suitable for large-scale production.
Alternatively, the solvent includes the one or more in volatilizable liquid, preferably includes water.
Solvent load is not required to excessively, to be sufficiently stirred for, and combines the water consumption requirement of specifically used equipment, prepares
Obtain the slurry for coating.
Preferably, the base material includes the one or more in metal, timber, cloth, preferably string porous paper.
String porous paper has appropriate intensity, while ensure that the air permeability of resulting product.
Alternatively, the coating is included by hand and machinery is coated with, or spraying.
Preferably, the drying temperature is less than 90 DEG C, is preferably room temperature to 80 DEG C, more preferably 60-80 DEG C.
Using specific drying temperature, drying efficiency is favorably improved, while keeping the anti-haze immunologic function film each component of gained
And the stabilization of membrane structure.
A kind of application of above-mentioned anti-haze immunologic function film, including the anti-haze immunologic function film is in filtration, purification field
Using.
The anti-haze immunologic function film of the present invention can be used in preparing filtration, purification equipment, can effectively obstruct PM2.5 hazes
Grain, gives full play to immune effect, human body is effectively protected.
Preferably, including the anti-haze immunologic function film air filtration field of purification application.
It is further preferred that including the anti-haze immunologic function film in filter, purifier, indoor and outdoor apparatus facility
On application.
Embodiment 1
A kind of preparation method of anti-haze immunologic function film, including：
(1) taking nano oxidized Lu porous material 5kg, fluoro-silicone emulsion respectively, (model AG710, manufacturer is Asahi Glass strain
Formula commercial firm) 1kg, nano titanium oxide 0.1kg, quaternary ammonium salt silane (model DC5700, manufacturer is DOW CORNING) 0.1kg, meat
Cinnamic aldehyde 0.1kg, Tea Polyphenols 0.1kg, vitamin C 0.1kg, vitamin E 0.1kg, chitosan 1kg, sodium alginate 1kg and Moringa
Seed 0.1kg and dandelion 0.1kg, it is standby；
(2) above-mentioned raw materials are sequentially added and be thoroughly mixed in water (consumption is not required to excessively, to be sufficiently stirred for)
Uniformly；
(3) using nick coating apparatus, (model TM750, manufacturer, which is that Dongguan City is strong, insults the scientific and technological limited public affairs of automation
Department), slurry obtained by step (2) is coated in into string porous paper, and (ST string porous papers, manufacturer is Zhejiang Kai Ente
Kind of material limited company) on (thousand grades of dustfree environments)；
(4) dried at 90 DEG C；
(5) winding obtains the product containing anti-haze immunologic function film after natural cooling.
Embodiment 2
A kind of preparation method of anti-haze immunologic function film, including：
(1) taking nano oxidized Lu porous material 35kg, fluoro-silicone emulsion respectively, (model AG710, manufacturer is Asahi Glass strain
Formula commercial firm) 10kg, nano titanium oxide 5kg, quaternary ammonium salt silane (model DC5700, manufacturer is DOW CORNING) 5kg, cinnamic acid
5kg, Tea Polyphenols 5kg, vitamin C 5kg, vitamin E 5kg, chitosan 1-5kg, sodium alginate 10kg and moringa seeds 5kg and Pu
Public English 5kg, it is standby；
(2) above-mentioned raw materials are sequentially added and be thoroughly mixed in water (consumption is not required to excessively, to be sufficiently stirred for)
Uniformly；
(3) using nick coating apparatus, (model TM750, manufacturer, which is that Dongguan City is strong, insults the scientific and technological limited public affairs of automation
Department), slurry obtained by step (2) is coated in string porous paper ST string porous papers, manufacturer is Zhejiang Kai Ente
Kind of material limited company) on (thousand grades of dustfree environments)；
(4) nature is carried out at room temperature to dry；
(5) winding obtains the product containing anti-haze immunologic function film after natural cooling.
Embodiment 3
A kind of preparation method of anti-haze immunologic function film, including：
(1) taking nano oxidized Lu porous material 15kg, fluoro-silicone emulsion respectively, (model AG710, manufacturer is Asahi Glass strain
Formula commercial firm) 3kg, nano titanium oxide 1kg, quaternary ammonium salt silane (model DC5700, manufacturer is DOW CORNING) 1kg, cinnamic acid
2kg, Tea Polyphenols 3kg, vitamin C 1.5kg, vitamin E 1.5kg, chitosan 2kg, sodium alginate 4kg and moringa seeds 1kg and
Dandelion 2kg, it is standby；
(2) above-mentioned raw materials are sequentially added and be thoroughly mixed in water (consumption is not required to excessively, to be sufficiently stirred for)
Uniformly；
(3) using nick coating apparatus, (model TM750, manufacturer, which is that Dongguan City is strong, insults the scientific and technological limited public affairs of automation
Department), slurry obtained by step (2) is coated in string porous paper ST string porous papers, manufacturer is Zhejiang Kai Ente
Kind of material limited company) on (thousand grades of dustfree environments)；
(4) dried at 80 DEG C；
(5) winding obtains the product containing anti-haze immunologic function film after natural cooling.
Embodiment 4
A kind of preparation method of anti-haze immunologic function film, including：
(1) taking nano oxidized Lu porous material 25kg, fluoro-silicone emulsion respectively, (model AG710, manufacturer is Asahi Glass strain
Formula commercial firm) 7kg, nano titanium oxide 3kg, quaternary ammonium salt silane (model DC5700, manufacturer is DOW CORNING) 4kg, cinnamic acid
2kg, Tea Polyphenols 3kg, vitamin C 6kg, vitamin E 3kg, chitosan 4kg, sodium alginate 8kg and moringa seeds 4kg and Pu are public
English 2kg, it is standby；
(2) above-mentioned raw materials are sequentially added and be thoroughly mixed in water (consumption is not required to excessively, to be sufficiently stirred for)
Uniformly；
(3) using nick coating apparatus, (model TM750, manufacturer, which is that Dongguan City is strong, insults the scientific and technological limited public affairs of automation
Department), slurry obtained by step (2) is coated in string porous paper ST string porous papers, manufacturer is Zhejiang Kai Ente
Kind of material limited company) on (thousand grades of dustfree environments)；
(4) dried at 60 DEG C；
(5) winding obtains the product containing anti-haze immunologic function film after natural cooling.
Embodiment 5
A kind of preparation method of anti-haze immunologic function film, including：
(1) taking nano oxidized Lu porous material 20kg, fluoro-silicone emulsion respectively, (model AG710, manufacturer is Asahi Glass strain
Formula commercial firm) 5kg, nano titanium oxide 2kg, quaternary ammonium salt silane (model DC5700, manufacturer is DOW CORNING) 2kg, cinnamic acid
2kg, Tea Polyphenols 3kg, vitamin C 3kg, vitamin E 3kg, chitosan 3kg, sodium alginate 6kg and moringa seeds 4kg and Pu are public
English 2kg, it is standby；
(2) above-mentioned raw materials are sequentially added and be thoroughly mixed in water (consumption is not required to excessively, to be sufficiently stirred for)
Uniformly；
(3) using nick coating apparatus, (model TM750, manufacturer, which is that Dongguan City is strong, insults the scientific and technological limited public affairs of automation
Department), slurry obtained by step (2) is coated in string porous paper ST string porous papers, manufacturer is Zhejiang Kai Ente
Kind of material limited company) on (thousand grades of dustfree environments)；
(4) dried at 70 DEG C；
(5) winding obtains the product containing anti-haze immunologic function film after natural cooling.
Experimental example 1
Barrier property detection, experimental method are carried out to the product containing anti-haze immunologic function film obtained by various embodiments of the present invention
For, in the suction inlet upper cover last layer non-woven fabrics disposable breathing mask of dust catcher, this hair of cover last layer respectively on the outside of disposable breathing mask
(the anti-haze immunologic function film of gained is respectively 4 μm or so to the product containing anti-haze immunologic function film, is used obtained by bright each embodiment
The thickness of string porous paper be respectively 12 μm or so), containing anti-haze immunologic function film obtained by various embodiments of the present invention
Product respectively coats non-woven fabrics disposable breathing mask completely, prevents it from directly contacting outside air, can only be with suction port of suction cleaner
It is in contact.As a comparison, comparative example 1 dust catcher suction inlet upper cover last layer non-woven fabrics disposable breathing mask, in disposable breathing mask
Outside is sequentially superimposed upper 3 layers of cover and inner side identical non-woven fabrics disposable breathing mask, 3 layers of non-woven fabrics disposable breathing mask being sequentially superimposed
The non-woven fabrics disposable breathing mask of inner side is coated completely, prevents it from directly contacting outside air, can only be with suction port of suction cleaner phase
Contact.Comparative example 2 is sequentially superimposed in the suction inlet upper cover last layer non-woven fabrics disposable breathing mask of dust catcher on the outside of disposable breathing mask
The string porous paper that 2 layers of embodiment 5 are used is covered, 2 layers of string porous paper being sequentially superimposed are by the non-woven fabrics of inner side
Disposable breathing mask is coated completely, prevents it from directly contacting outside air, can only be in contact with suction port of suction cleaner.Using above-mentioned reality
Experiment device adsorbs the cigarette that particle diameter is lighted for 40nm carbon black conductive agent, lithium hexafluoro phosphate carbonic ester, three binding end points respectively
(red plum board), by dust catcher (1500w) western entrance respectively just to the carbon black conductive agent equipped with 40nm, lithium hexafluoro phosphate carbonic ester, three
The surface tool target affinity thing about 15cm of the opening of the container for the cigarette that branch binding end points is lighted (starts burning point about away from cigarette
At 15cm) place adsorbed, and adsorption time is respectively 15mi n (the cigarette nature tail-off time is about 15mi n under this state), is adopted
The method weighed with assay balance is compared, and gained absorption result is as shown in table 1.
The barrier property of product of the present invention of table 1 containing anti-haze immunologic function film
It can be seen from Table 1 that, the mouth mask product obtained using anti-haze immunologic function film preparation of the invention can effectively be hindered
Every particulate matter, toxic chemical and the combustion product gases that particle diameter is 40nm；In above-mentioned test, containing anti-haze immunologic function of the invention
Non-woven fabrics disposable breathing mask on the inside of the mouth mask product of film does not increase weight, and represents above-mentioned pollutant not by containing the present invention
The mouth mask product of anti-haze immunologic function film, is effectively isolated；And the mouth mask product containing anti-haze immunologic function film of the invention is upper
State and do not increased weight in test, illustrate that the mouth mask product containing anti-haze immunologic function film of the invention has excellent surface property, energy
Above-mentioned pollutant is enough avoided in remained on surface, causes to influence filter effect or the eupnea of user；Contain anti-haze of the invention
The mouth mask product of immunologic function film does not interfere with the eupnea of user, at the same can effective block contaminants, with notable
Progress.
Experimental example 2
The product that embodiment 1-5 gained contains anti-haze immunologic function film is subjected to antibacterial experiment, wherein antibacterial experiment is (big
Enterobacteria and staphylococcus aureus) enter according to the requirement of GB15979-2002 Disposable Sanitary Accessory standards appendix C 5
OK, antimicrobial agent experiment (methicillin-resistant staphylococcus aureus) is tested according to AATCC 100-2012 antibacterial textiles
It is required that carrying out, acquired results are as shown in table 2：
The antibacterial effect of product of the present invention gained of table 3 containing anti-haze immunologic function film
It can be seen from Table 3 that product of the present invention gained containing anti-haze immunologic function film is to staphylococcus aureus, big
Antibacterial efficiency >=99% of enterobacteria, to antibacterial efficiency >=99% of methicillin-resistant staphylococcus aureus, with significant anti-
Bacterium effect, effectively can carry out immune protection to user.
The anti-haze immunologic function membrane material of gained of the invention has the following advantages that：
1st, anti-haze immunologic function film of the invention can effectively be obstructed, filtered, adsorbing PM2.5 particle diameters below 0.1 micron
The various suspended contaminants contained in ultra micro haze dust granules and Vehicular exhaust, effect is notable；
2nd, anti-haze immunologic function film of the invention has photo-catalysis function, can effectively adsorb, chelate, detoxify invasion mouth, nose,
The various toxic pollutants produced in the heavy metal ion and photochemistry poisonous substance and living environment of skin, effect is notable；
3rd, anti-haze immunologic function film of the invention can effectively suppress, kill in environmental pollution without hormone, without antibiotic
A variety of pathogenic funguses virus, effect is notable；
4th, anti-haze immunologic function film of the invention can effectively remove harmful free radicals, anti-oxidant, antifatigue, antiallergy, exhale
Inhale smooth comfortable, lung, brain vigor can be strengthened, body immunity is improved.
The anti-haze immunologic function film of the present invention can be widely applied for mouth mask, curtain, air-conditioning, clarifier, house ornamentation.Automotive trim
And the articles for daily use such as field tent.
Although illustrate and describing the present invention with specific embodiment, but it will be appreciated that various embodiments above is only used
To illustrate technical scheme, rather than its limitations；It will be understood by those within the art that：Without departing substantially from this hair
In the case of bright spirit and scope, the technical scheme described in foregoing embodiments can be modified, or to wherein
Some or all of technical characteristic carries out equivalent；And these modifications or replacement, do not make the essence of appropriate technical solution
Depart from the scope of various embodiments of the present invention technical scheme；It is, therefore, intended that including belonging to the present invention in the following claims
In the range of all these substitutions and modifications.
Claims (10)
1. a kind of anti-haze immunologic function film, it is characterised in that mainly prepared by the raw material of following mass fraction：
5-35 parts of adsorbent, 1.1-15 parts of photochemical catalyst, 0.2-10 parts of antiseptic, 0.3-15 parts of antioxidant, film forming agent 2-15
0.2-10 parts of part and immunopotentiator；
Preferably, the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
15-25 parts of adsorbent, 4-10 parts of photochemical catalyst, 3-6 parts of antiseptic, 6-12 parts of antioxidant, 6-12 parts of film forming agent and exempt from
3-6 parts of epidemic disease reinforcing agent；
It is further preferred that the anti-haze immunologic function film is mainly prepared by the raw material of following mass fraction：
4 parts of 20 parts of adsorbent, 7 parts of photochemical catalyst, 4 parts of antiseptic, 9 parts of antioxidant, 9 parts of film forming agent and immunopotentiator.
2. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the adsorbent includes porous absorption
Material, preferably includes inorganic porous material, further preferably including aluminum oxide porous material；
Preferably, the particle diameter of the aluminum oxide porous material is below 500nm, preferably 100-500nm.
3. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the photochemical catalyst includes fluorine silicon breast
One or more in liquid and titanium dioxide, preferably include fluoro-silicone emulsion and titanium dioxide；
Preferably, the titanium dioxide is Nano titanium dioxide, and preferably particle diameter is below 100nm nanoscale titanium dioxide
Titanium；
Preferably, the mass ratio of the fluoro-silicone emulsion and titanium dioxide is 1-10：0.1-5, preferably 3-7：1-3, it is further excellent
Elect 5 as：2.
4. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the antiseptic includes quaternary ammonium salt silicon
One or more in alkane and cinnamic acid, preferably include quaternary ammonium salt silane and cinnamic acid；
Preferably, the mass ratio of the quaternary ammonium salt silane and cinnamic acid is 0.1-5：0.1-5, preferably 1-2：1-2, it is further excellent
Elect 1 as：1.
5. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the antioxidant includes Tea Polyphenols
With it is a kind of excessively a variety of in vitamin, preferably include the one or more in Tea Polyphenols, vitamin C and vitamin E, further it is excellent
Choosing includes Tea Polyphenols, vitamin C and vitamin E；
Preferably, the mass ratio of the Tea Polyphenols, vitamin C and vitamin E is 0.1-5：0.1-5：0.1-5, preferably 1-2：
1-2：1-2, more preferably 1：1：1.
6. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the film forming agent include chitosan and
One or more in sodium alginate, preferably include chitosan and sodium alginate；
Preferably, the mass ratio of the chitosan and sodium alginate is 1-5：1-10, preferably 1-2：2-4, more preferably
1：2.
7. a kind of anti-haze immunologic function film according to claim 1, it is characterised in that the immunopotentiator includes Moringa
One or more in seed and dandelion, preferably include moringa seeds and dandelion；
Preferably, the moringa seeds and the mass ratio of dandelion are 0.1-5：0.1-5, preferably 1-2：1-2, more preferably
1：1.
8. the preparation method of a kind of anti-haze immunologic function film as described in claim 1-7 is any, it is characterised in that will adsorb
Agent, photochemical catalyst, antiseptic, antioxidant, sustained release agent, binding agent and immunopotentiator and solvent are thoroughly mixed uniformly,
Gained slurry is coated on base material, drying obtains a kind of anti-haze immunologic function film.
9. the preparation method of a kind of anti-haze immunologic function film according to claim 8, it is characterised in that the solvent includes
One or more in volatilizable liquid, preferably include water；
Preferably, the base material includes the one or more in metal, timber, cloth, preferably string porous paper；
Preferably, the drying temperature is less than 90 DEG C, is preferably room temperature to 80 DEG C, more preferably 60-80 DEG C.
10. the application of a kind of anti-haze immunologic function film as described in claim 1-7 is any, it is characterised in that including described anti-
Application of the haze immunologic function film in filtration, purification field；
Preferably, including the anti-haze immunologic function film air filtration field of purification application；
It is further preferred that including the anti-haze immunologic function film on filter, purifier, indoor and outdoor apparatus facility
Using.
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| CN110373076A (en) * | 2019-07-12 | 2019-10-25 | 成都新柯力化工科技有限公司 | A kind of environment protecting building paint and preparation method of photocatalytic degradation haze precursor |
| CN112704959A (en) * | 2020-11-23 | 2021-04-27 | 安徽元琛环保科技股份有限公司 | Preparation method of denitration and dedusting integrated filter material and prepared filter material |
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| CN110373076A (en) * | 2019-07-12 | 2019-10-25 | 成都新柯力化工科技有限公司 | A kind of environment protecting building paint and preparation method of photocatalytic degradation haze precursor |
| CN112704959A (en) * | 2020-11-23 | 2021-04-27 | 安徽元琛环保科技股份有限公司 | Preparation method of denitration and dedusting integrated filter material and prepared filter material |
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