CN106922549A - A kind of bentonite cat litter and preparation method thereof - Google Patents

A kind of bentonite cat litter and preparation method thereof Download PDF

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Publication number
CN106922549A
CN106922549A CN201710232824.5A CN201710232824A CN106922549A CN 106922549 A CN106922549 A CN 106922549A CN 201710232824 A CN201710232824 A CN 201710232824A CN 106922549 A CN106922549 A CN 106922549A
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China
Prior art keywords
parts
cat litter
bentonite
cloves
camellia
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Pending
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CN201710232824.5A
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Chinese (zh)
Inventor
扈卫珍
周慧堂
刘玉梅
石娟
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ANHUI MINGMEI MINCHEM Co Ltd
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ANHUI MINGMEI MINCHEM Co Ltd
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Priority to CN201710232824.5A priority Critical patent/CN106922549A/en
Publication of CN106922549A publication Critical patent/CN106922549A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • A01K1/0154Litter comprising inorganic material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A01K1/0152Litter
    • A01K1/0155Litter comprising organic material

Abstract

The invention discloses a kind of bentonite cat litter, including following weight portion component:40~50 parts of bentonite, 20~30 parts of blast furnace slag, 5~10 parts of Iron Ore Powder, 4~5 parts of binding agent, 1.8~2.2 parts of cloves, 2.4~3.6 parts of peppermint, 2.4~3.6 parts of golden cypress, 3.4~3.6 parts of thyme, 0.8~1.2 part of camellia, 30~40 parts of agricultural crop straw, the component sequentially pass through grinding immersion, ultrasonication, pelletize, dry the techniques such as ultraviolet sterilization and can be prepared by the bentonite cat litter.Using bentonite as raw material, the bentonite cat litter for preparing has the advantages that adsorption rate is high, it is strong to de-taste ability to the present invention, and its chemical stability is strong, nontoxic;The bentonite cat litter adds the Chinese herbal medicines such as cloves, peppermint, golden cypress, thyme, camellia, increased the sterilizing ability of the bentonite cat litter;The preparation process is simple, easy to operate, suitable popularization.

Description

A kind of bentonite cat litter and preparation method thereof
Technical field
The invention belongs to bentonite clay material field, and in particular to a kind of bentonite cat litter and preparation method thereof.
Background technology
Cat litter is the object for raising the main cat for its raising for burying excrement and urine, and the feeding of big tripe pig is also used in sometimes Support.The object has preferable water imbibition, typically can in the lump be used with cat litter box (or cat lavatory), and appropriate cat litter fallen into cat In sand basin, trained cat will come into cat litter box when excretion is needed and drain face thereon;The use of cat litter is the sheet of cat Energy, most cats can learn to use cat litter easily.Cat litter on the market is mostly granular, and conventional includes soil sand, paper sand, crystal Sand, bean curd sand, wooden sand, wheat sand etc..Cat litter can be divided into two major classes, conglomeration and not conglomeration.Conglomeration cat litter it is main into It is divided into bentonite, one can be formed after being absorbed to urine or excrement, coordinates cat litter shovel both can easily clear up.The cat litter of not conglomeration Run into urine will not conglomeration, cat defecate after shoveled out, integral replacing is needed after use.
Wherein, conglomeration cat litter is unfavorable for growing up healthy and sound for cat after conglomeration to cause the growth of bacterium, the cat of not conglomeration Sand is replaced the great waste for causing cat litter due to needing entirety.On this basis, current someone is by conglomeration cat Increase antiseptic in sand and improve the antibiotic property of cat litter, but can so reduce the conglomeration effect of cat litter;Someone is not by yet Binding agent and antiseptic are added in the cat litter of conglomeration, but result is still to be difficult to simultaneously so that cat litter has excellent conglomeration effect And antibiotic property.
Bentonite is a kind of clay based on smectite type mineral, and each bentonite particle is by thousands of micro- Small Montmorillonite Crystal nano flake composition.Montmorillonite Crystal is by one layer of aluminium (magnesium) oxygen (hydrogen-oxygen) eight of folder in the middle of two-layer silicon-oxy tetrahedron Face body composition.Due to there is a small amount of silicon to be replaced by aluminium in Montmorillonite Crystal tetrahedron, there is a small amount of aluminium to be replaced by magnesium in octahedron, Crystal interlayer is set to produce permanent negative electrical charge, thus in a large amount of tradable cations of brilliant Inter layer adsorption.It is tradable between crystal layer Cation turns into hydrated cation after meeting water, greatly increases the distance between Montmorillonite Crystal nano flake, then montmorillonite Construction unit --- the space between nano flake just can accommodate substantial amounts of hydrone, and this is that bentonite has excellent water imbibition The reason for.
Bentonite cat litter is the smell that pet excrement is removed with bentonitic adsorptivity, and special bentonite is by special Cat litter prepared by technique has the good ability that de-tastes, therefore, strong bentonite cat litter of a kind of ability of de-tasting and preparation method thereof It is necessary.
The content of the invention
The invention provides a kind of bentonite cat litter and preparation method thereof, the bentonite cat litter de-tastes ability by force, antibacterial Property it is good, its preparation process is simple, be adapted to promote.
In order to solve the problems, such as prior art, adopt the following technical scheme that:
A kind of bentonite cat litter of the invention, including following weight portion component:40~50 parts of bentonite, blast furnace slag 20~30 Part, 5~10 parts of Iron Ore Powder, 4~5 parts of binding agent, 1.8~2.2 parts of cloves, 2.4~3.6 parts of peppermint, 2.4~3.6 parts of golden cypress, hundred In fragrant 3.4~3.6 parts, 0.8~1.2 part of camellia, 30~40 parts of agricultural crop straw.
Preferably, the bentonite cat litter includes the component of following weight portion:42~48 parts of bentonite, blast furnace slag 21~27 Part, 5~7 parts of Iron Ore Powder, 4.3~4.9 parts of binding agent, 1.9~2.1 parts of cloves, 2.6~3.3 parts of peppermint, golden cypress 2.6~3.3 Part, 3.5~3.6 parts of thyme, 1.1~1.2 parts of camellia, 33~37 parts of agricultural crop straw.
Preferably, the bentonite cat litter includes the component of following weight portion:47 parts of bentonite, 23 parts of blast furnace slag, iron ore 6 parts of powder, 4.5 parts of binding agent, 2 parts of cloves, 2.73 parts of peppermint, 2.7 parts of golden cypress, 3.53 parts of thyme, 1.1 parts of camellia, crops 35 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, warm water is soaked 10~15 hours, 80~90 DEG C are then heated to, at this temperature, with the 20~40min of ultrasonication of 350~380W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component It is even, add the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 30~35 minutes, the high speed dispersor Speed be 2200~2800r/min, cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle is obtained;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, until the content of water is less than 5%, so After be placed in UV environment sterilized, the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
Preferably, the step(1)Middle heating water is 10~30 times of bentonite weight, and warm water temperature is 40~50 ℃。
Preferably, the step(1)With the step(2)Middle powder crosses 100 mesh sieves.
Preferably, the step(2)A diameter of 2~5mm of middle cat litter particle.
Preferably, the step(3)The temperature of middle drying machine is 200~450 DEG C, 3~8 hours drying times.
Compared with prior art, it has the advantages that the present invention:
Bentonite cat litter of the present invention, de-tastes ability by force, and antibiotic property is good, its preparation process is simple, suitable popularization, specifically such as Under:
(1)Using bentonite as raw material, the bentonite cat litter for preparing has that adsorption rate is high, it is strong to de-taste ability to the present invention Advantage, and its chemical stability is strong, nontoxic;
(2)The Chinese herbal medicines such as cloves, peppermint, golden cypress, thyme, camellia are added in bentonite cat litter of the present invention, institute is increased The sterilizing ability of bentonite cat litter is stated, antibiotic property is strong, has and is easy to the healthy of pet cat;
(3)Bentonite cat litter preparation process is simple of the present invention, easy to operate, suitable popularization.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.
Embodiment 1
Bentonite cat litter described in the present embodiment, including following weight portion component:40 parts of bentonite, 20 parts of blast furnace slag, iron ore 5 parts of powder, 4 parts of binding agent, 1.8 parts of cloves, 2.4 parts of peppermint, 2.4 parts of golden cypress, 3.4 parts of thyme, 0.8 part of camellia, crops straw 30 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, 100 mesh sieves, warm water immersion are crossed 10 hours, warm water weight was 10 times of bentonite weight, and the temperature of warm water is 40 DEG C, is then heated to 80 DEG C, at this temperature, With the ultrasonication 20min of 350W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component Even, the powder crosses 100 mesh sieves, adds the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 30 minutes, The speed of the high speed dispersor is 2200r/min, and cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle, the cat litter is obtained A diameter of 2~5mm of particle;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, and the temperature of drying machine is 200 DEG C, is done 3 hours dry time, until the content of water is less than 5%, sterilization in UV environment is subsequently placed in, the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
The bentonite cat litter water absorbing capacity of preparation is strong in the present embodiment, go peculiar smell ability strong, and has sterilized well effect Really.
Embodiment 2
Bentonite cat litter described in the present embodiment, including following weight portion component:50 parts of bentonite, 30 parts of blast furnace slag, iron ore 10 parts of powder, 5 parts of binding agent, 2.2 parts of cloves, 3.6 parts of peppermint, 3.6 parts of golden cypress, 3.6 parts of thyme, 1.2 parts of camellia, crops straw 40 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, 100 mesh sieves, warm water immersion are crossed 15 hours, the warm water amount was 30 times of bentonite weight, and the temperature of warm water is 50 DEG C, 90 DEG C is then heated to, in this temperature Under, with the ultrasonication 40min of 380W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component Even, the powder crosses 100 mesh sieves, adds the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 35 minutes, The speed of the high speed dispersor is 2800r/min, and cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle, cat litter particle is obtained A diameter of 2~5mm;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, and the temperature of drying machine is 450 DEG C, is done 8 hours dry time, until the content of water is less than 5%, sterilization in UV environment is subsequently placed in, the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
The bentonite cat litter water absorbing capacity of preparation is strong in the present embodiment, go peculiar smell ability strong, and has sterilized well effect Really.
Embodiment 3
Bentonite cat litter described in the present embodiment, including following weight portion component:42 parts of bentonite, 21 parts of blast furnace slag, iron ore 5 parts of powder, 4.3 parts of binding agent, 1.9 parts of cloves, 2.6 parts of peppermint, 2.6 parts of golden cypress, 3.5 parts of thyme, 1.1 parts of camellia, crops 33 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, 100 mesh sieves, warm water immersion are crossed 12 hours, institute's warm water amount was 15 times of bentonite weight, and the warm water temperature is 45 DEG C, is then heated to 85 DEG C, herein temperature Under degree, with the ultrasonication 30min of 360W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component Even, the powder crosses 100 mesh sieves, adds the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 32 minutes, The speed of the high speed dispersor is 2500r/min, and cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle, cat litter particle is obtained A diameter of 2~5mm;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, until the content of water is less than 5%, does The temperature of dry machine is 225 DEG C, 5 hours drying times, is subsequently placed in sterilization in UV environment, and the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
The bentonite cat litter water absorbing capacity of preparation is strong in the present embodiment, go peculiar smell ability strong, and has sterilized well effect Really.
Embodiment 4
Bentonite cat litter described in the present embodiment, including following weight portion component:48 parts of bentonite, 27 parts of blast furnace slag, iron ore 7 parts of powder, 4.9 parts of binding agent, 2.1 parts of cloves, 3.3 parts of peppermint, 3.3 parts of golden cypress, 3.6 parts of thyme, 1.2 parts of camellia, crops 37 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, 100 mesh sieves, warm water immersion are crossed 12 hours, institute's warm water amount was 15 times of bentonite weight, and the warm water temperature is 45 DEG C, is then heated to 85 DEG C, herein temperature Under degree, with the ultrasonication 30min of 360W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component Even, the powder crosses 100 mesh sieves, adds the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 32 minutes, The speed of the high speed dispersor is 2500r/min, and cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle, cat litter particle is obtained A diameter of 2~5mm;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, until the content of water is less than 5%, does The temperature of dry machine is 225 DEG C, 5 hours drying times, is subsequently placed in sterilization in UV environment, and the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
The bentonite cat litter water absorbing capacity of preparation is strong in the present embodiment, go peculiar smell ability strong, and has sterilized well effect Really.
Embodiment 5
Bentonite cat litter described in the present embodiment, including following weight portion component:47 parts of bentonite, 23 parts of blast furnace slag, iron ore 6 parts of powder, 4.5 parts of binding agent, 2 parts of cloves, 2.73 parts of peppermint, 2.7 parts of golden cypress, 3.53 parts of thyme, 1.1 parts of camellia, crops 35 parts of stalk.
A kind of method for preparing the bentonite cat litter, comprises the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, 100 mesh sieves, warm water immersion are crossed 12 hours, institute's warm water amount was 15 times of bentonite weight, and the warm water temperature is 45 DEG C, is then heated to 85 DEG C, herein temperature Under degree, with the ultrasonication 30min of 360W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component Even, the powder crosses 100 mesh sieves, adds the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 32 minutes, The speed of the high speed dispersor is 2500r/min, and cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle, cat litter particle is obtained A diameter of 2~5mm;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, until the content of water is less than 5%, does The temperature of dry machine is 225 DEG C, 5 hours drying times, is subsequently placed in sterilization in UV environment, and the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
The bentonite cat litter water absorbing capacity of preparation is strong in the present embodiment, go peculiar smell ability strong, and has sterilized well effect Really.
Be can be seen that from above-described embodiment, the present invention is using bentonite as raw material, the bentonite cat litter tool for preparing Have the advantages that adsorption rate is high, it is strong to de-taste ability, and its chemical stability is strong, nontoxic;The bentonite cat litter adds cloves, thin The Chinese herbal medicines such as lotus, golden cypress, thyme, camellia, increased the sterilizing ability of the bentonite cat litter;The preparation process is simple, It is easy to operate, it is adapted to promote.
Specific embodiment of the invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can within the scope of the claims make various deformations or amendments, this not shadow Sound substance of the invention.

Claims (8)

1. a kind of bentonite cat litter, it is characterised in that the component including following weight portion:40~50 parts of bentonite, blast furnace slag 20 ~30 parts, 5~10 parts of Iron Ore Powder, 4~5 parts of binding agent, 1.8~2.2 parts of cloves, 2.4~3.6 parts of peppermint, golden cypress 2.4~3.6 Part, 3.4~3.6 parts of thyme, 0.8~1.2 part of camellia, 30~40 parts of agricultural crop straw.
2. bentonite cat litter according to claim 1, it is characterised in that the component including following weight portion:Bentonite 42 ~48 parts, 21~27 parts of blast furnace slag, 5~7 parts of Iron Ore Powder, 4.3~4.9 parts of binding agent, 1.9~2.1 parts of cloves, peppermint 2.6~ 3.3 parts, 2.6~3.3 parts of golden cypress, 3.5~3.6 parts of thyme, 1.1~1.2 parts of camellia, 33~37 parts of agricultural crop straw.
3. bentonite cat litter according to claim 1, it is characterised in that the component including following weight portion:Bentonite 47 Part, 23 parts of blast furnace slag, 6 parts of Iron Ore Powder, 4.5 parts of binding agent, 2 parts of cloves, 2.73 parts of peppermint, 2.7 parts of golden cypress, thyme 3.53 Part, 1.1 parts of camellia, 35 parts of agricultural crop straw.
4. a kind of method for preparing bentonite cat litter described in any one of claims 1 to 3, it is characterised in that comprise the following steps:
(1)Cloves, peppermint, golden cypress, thyme, camellia grind into powder are taken by the component, warm water is soaked 10~15 hours, 80~90 DEG C are then heated to, at this temperature, with the 20~40min of ultrasonication of 350~380W, centrifugation obtains filtrate;
(2)Bentonite, blast furnace slag, Iron Ore Powder, agricultural crop straw, binding agent are pulverized into last mixing by the component It is even, add the step(1)In the filtrate for obtaining, it is put into high speed dispersor and disperses 30~35 minutes, the high speed dispersor Speed be 2200~2800r/min, cat litter slurry is obtained;
(3)By step(2)The cat litter slurry for preparing is placed in extruder grain in comminutor, and cat litter particle is obtained;
(4)By the step(3)The cat litter particle for obtaining is dried in being put into drying machine, until the content of water is less than 5%, so After be placed in UV environment sterilized, the wavelength of the ultraviolet is 253.7nm, you can obtain the bentonite cat litter.
5. preparation method according to claim 4, it is characterised in that the step(1)Middle heating water is bentonite weight 10~30 times of amount, warm water temperature is 40~50 DEG C.
6. preparation method according to claim 4, it is characterised in that the step(1)With the step(2)Middle powder is equal Cross 100 mesh sieves.
7. preparation method according to claim 4, it is characterised in that the step(2)A diameter of the 2 of middle cat litter particle~ 5mm。
8. preparation method according to claim 4, it is characterised in that the step(3)The temperature of middle drying machine be 200~ 450 DEG C, 3~8 hours drying times.
CN201710232824.5A 2017-04-11 2017-04-11 A kind of bentonite cat litter and preparation method thereof Pending CN106922549A (en)

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CN109089905A (en) * 2018-07-18 2018-12-28 杭州高烯科技有限公司 A kind of multifunctional graphite vinyl-bentonite cat litter and preparation method thereof
CN109089907A (en) * 2018-08-14 2018-12-28 洛南县盛大农副产品发展有限公司 A kind of non-agglomerated type cat litter and preparation method thereof
CN109247246A (en) * 2018-09-26 2019-01-22 芜湖市鹏磊新材料有限公司 A kind of bentonitic processing method of cat litter
CN109329078A (en) * 2018-09-28 2019-02-15 淮阴工学院 A kind of cat litter and preparation method thereof
CN109479733A (en) * 2018-11-21 2019-03-19 周权立 A kind of environment-friendly antibacterial pet fragrant sand and preparation method thereof

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CN105684916A (en) * 2015-07-03 2016-06-22 怀宁县宝友工贸有限公司 Bentonite cat litter having great destinking capability and a preparation method therefor
CN106386534A (en) * 2016-12-05 2017-02-15 郑州丽福爱生物技术有限公司 Agglomerate type cat litter with antibacterial and deodorant effects, and preparation method and application thereof

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CN104521768A (en) * 2014-12-04 2015-04-22 芜湖倍思科创园有限公司 Low-density light-scented particulate cat litter and preparation method thereof
CN104489424A (en) * 2014-12-16 2015-04-08 繁昌县奥科包装有限公司 Modified bentonite cat litter and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN108739427A (en) * 2018-04-27 2018-11-06 铜陵市华佳矿产品技术开发有限公司 A kind of bentonite cat litter and preparation method thereof
CN109089905A (en) * 2018-07-18 2018-12-28 杭州高烯科技有限公司 A kind of multifunctional graphite vinyl-bentonite cat litter and preparation method thereof
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CN109089907B (en) * 2018-08-14 2021-11-09 洛南县盛大农副产品发展有限公司 Non-caking cat litter and preparation method thereof
CN109247246A (en) * 2018-09-26 2019-01-22 芜湖市鹏磊新材料有限公司 A kind of bentonitic processing method of cat litter
CN109329078A (en) * 2018-09-28 2019-02-15 淮阴工学院 A kind of cat litter and preparation method thereof
CN109479733A (en) * 2018-11-21 2019-03-19 周权立 A kind of environment-friendly antibacterial pet fragrant sand and preparation method thereof

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Application publication date: 20170707