CN109089905A - A kind of multifunctional graphite vinyl-bentonite cat litter and preparation method thereof - Google Patents

A kind of multifunctional graphite vinyl-bentonite cat litter and preparation method thereof Download PDF

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Publication number
CN109089905A
CN109089905A CN201810791240.6A CN201810791240A CN109089905A CN 109089905 A CN109089905 A CN 109089905A CN 201810791240 A CN201810791240 A CN 201810791240A CN 109089905 A CN109089905 A CN 109089905A
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China
Prior art keywords
graphene
cat litter
bentonite
preparation
graphite vinyl
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CN201810791240.6A
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CN109089905B (en
Inventor
韩燚
陈琛
高超
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Hangzhou Gaoxi Technology Co Ltd
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Hangzhou Gaoxi Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00Housing animals; Equipment therefor
    • A01K1/015Floor coverings, e.g. bedding-down sheets ; Stable floors
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/40Clays

Abstract

The present invention relates to a kind of multifunctional graphite vinyl-bentonite cat litters, belong to pet supplies areas.Graphene-the bentonite cat litter is made of bentonite in powder, coagulating agent, graphene.The graphene-bentonite cat litter soaking effect is strong, and no dust, especially antibacterial, anti-mite and deodorizing effect are splendid, and cake strength is big after chance water, convenient for cleaning.

Description

A kind of multifunctional graphite vinyl-bentonite cat litter and preparation method thereof
Technical field
The invention belongs to pet supplies areas, and in particular to a kind of multifunctional graphite vinyl-bentonite cat litter and its preparation side Method.
Background technique
Cat litter is the object raised the main cat for its raising and be used to bury excrement and urine, there is preferable water imbibition, general meeting It uses, suitable cat litter is fallen in cat litter box, trained cat ought need to drain together with cat litter box (or cat lavatory) When will come into cat litter box excretion face thereon.General cat litter is to break into fine granularity using paper pulp to simulate sandy soil and provide Water imbibition also has the particle using the physical drynesses agent such as silica gel.Cat litter is mostly conglomeration cat litter at present, and main component is swelling Soil can form one after being absorbed into urine or excrement, and cooperation cat litter shovel can be cleared up easily.Since conglomeration cat litter generally will not Integral replacing, so the antibacterial and deodouring function to cat litter proposes high requirement.Common product can be by adding antibacterial agent, deodorization The chemical products such as agent and preservative realize this function, however the antibacterial deodorant of chemistry itself be possible to it is just flavoursome and There is the risk that skin irritatin is caused to pet, furthermore antibacterial deodorant will also result in certain pollution to environment.Because of the invention one kind The cat litter of antibiosis and deodorization effects and safety and environmental protection has great market potential.
The two-dimension single layer stratified material that graphene is made of carbon atom.Scientific investigations showed that graphene is cut by machinery The mechanism such as effect, package cell, activated cell chemical reaction are cut, bacterium can be efficiently killed and will not develop drug resistance, be A kind of outstanding antibacterial agent.Graphene essence is carbon material, not can cause environmental pollution, and will not cause to hurt to animal skin Evil, is a kind of ideal antibacterial additives.Graphene single layer two-dimensional structure also makes it have great specific surface area, reaches as high as 2600m2/ g can be very good absorption peculiar smell.Furthermore graphene high-specific surface area cooperate its extremely strong adsorption capacity that can adsorb, Acarid is wrapped up and killed, there is that acarid is significantly inhibited to grow.Therefore graphene can achieve " a kind of addition, realization The marvellous effect of multiple functions ".However graphene various functions and structure again there is and its complicated relationship, such as graphene Piece diameter size influences adsorption capacity, and graphene oxygen-containing functional group type and ratio influence antibacterial ability and cat litter knot to bacterium The intensity of block, there is the relationships for the restriction that influences each other again between these factors.Therefore to obtain cost performance height, functional Graphene-bentonite cat litter can not be blended by simple to realize, but need certain theory support and complexity To verify, especially current Graphene antibiosis mechanism there is no final conclusion in academia for experiment, and innovation difficulty is very big.
Summary of the invention
Present invention aims to overcome that the prior art is insufficient, provide a kind of environmentally friendly, safety with antibacterial, deodorization, inhibition Graphene-bentonite cat litter preparation method of acarid multi-functional.
The present invention is achieved by the following technical solutions: a kind of multifunctional graphite vinyl-bentonite cat litter, feature exist In being granulated by bentonite clay particle and coagulating agent group, wherein the bentonite clay particle outer surface has attached graphene film, institute The lateral dimension for stating graphene film is 4-8um, and carbon-to-oxygen ratio is 5~7;The quality of graphene is with bentonitic mass ratio 0.05-1.5:100。
A kind of preparation method of multifunctional graphite vinyl-bentonite cat litter, sequentially includes the following steps:
(1) bentonite powder is uniformly mixed with graphene dispersing solution.
(2) the dry, crushing by the resulting mixed dispersion liquid of step 1, obtains graphene-supported bentonite powder, graphene Piece is attached in bentonite clay particle outer surface.
(3) bentonite powder and coagulating agent graphene-supported obtained by step 2 are placed in pelletizer and cat litter is made.
Further, the quality of the graphene and bentonitic mass ratio are 0.01-3:100.
Further, the graphene lateral dimension is greater than 1 micron, and carbon-to-oxygen ratio is 2.5~10.
Further, obtained cat litter 4~6mm of diameter, 6~8mm of length.
The beneficial effects of the present invention are: (1) since graphene have both antibacterial, anti-mite, antibacterial multiple functions, pass through addition A kind of additive makes common cat litter have the function of to save cumbersome antimicrobial formulation, products obtained therefrom urgently needed for a variety of high-end cat litters The great market competitiveness.(2) graphene does not have irritation to animal skin, and no pollution to the environment, the multi-functional cat litter of gained is not only Effect is obvious, friendly to animal and Environmental security.(3) since graphene used contains certain oxygen-containing functional group, after meeting water It acts synergistically with coagulating agent, so that the cat litter bulk strength of condensation is obviously improved, so that when cleaning cat litter condensation is fast It is not easily damaged, the comfort level of cleaning pollution cat litter is greatly improved, this is unexpected effect.
Detailed description of the invention
Fig. 1 is cat litter grain structure schematic diagram.
Specific embodiment
(1) bentonite powder is uniformly mixed with graphene dispersing solution.Wherein, graphene and swelling in graphene dispersing solution The mass ratio of soil is as shown in table 1, and size, the carbon-to-oxygen ratio of graphene film are as shown in table 1;
(2) the dry, crushing by the resulting mixed dispersion liquid of step 1, obtains graphene-supported bentonite powder, graphene Piece is attached in bentonite clay particle outer surface.
(3) bentonite powder and coagulating agent graphene-supported obtained by step 2 are placed in pelletizer and cat litter is made, it is made Cat litter 4~the 6mm of diameter, 6~8mm of length obtained.
Table 1
As can be seen from the above table, after meeting water, graphene acts synergistically with coagulating agent, so that the cat litter block of condensation is strong Degree is obviously improved, not easily damaged when clearing up cat litter and condensing fast, greatly improves the comfort level of cleaning pollution cat litter, This is unexpected effect.And said effect be based on suitable graphene size, carbon-to-oxygen ratio and its with bentonitic proportion Come what is realized.

Claims (5)

1. a kind of multifunctional graphite vinyl-bentonite cat litter, which is characterized in that it is granulated by bentonite clay particle and coagulating agent group, Wherein, the bentonite clay particle outer surface has attached graphene film, and the lateral dimension of the graphene film is 4-8um, carbon-to-oxygen ratio It is 5~7;The quality of graphene and bentonitic mass ratio are 0.05-1.5:100.
2. a kind of preparation method of multifunctional graphite vinyl-bentonite cat litter, which is characterized in that sequentially include the following steps:
(1) bentonite powder is uniformly mixed with graphene dispersing solution.
(2) the dry, crushing by the resulting mixed dispersion liquid of step 1 obtains graphene-supported bentonite powder, graphene film patch It pays in bentonite clay particle outer surface.
(3) bentonite powder and coagulating agent graphene-supported obtained by step 2 are placed in pelletizer and cat litter is made.
3. preparation method according to claim 2, which is characterized in that the quality of the graphene and bentonitic quality it Than for 0.01-3:100.
4. preparation method according to claim 3, which is characterized in that the graphene lateral dimension is greater than 1 micron, carbon oxygen Than being 2.5~10.
5. preparation method according to claim 3, which is characterized in that obtained cat litter 4~6mm of diameter, length 6~ 8mm。
CN201810791240.6A 2018-07-18 2018-07-18 Multifunctional graphene-bentonite cat litter and preparation method thereof Active CN109089905B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810791240.6A CN109089905B (en) 2018-07-18 2018-07-18 Multifunctional graphene-bentonite cat litter and preparation method thereof

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Application Number Priority Date Filing Date Title
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CN109089905A true CN109089905A (en) 2018-12-28
CN109089905B CN109089905B (en) 2020-07-14

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3167125U (en) * 2011-01-25 2011-04-07 アイリスオーヤマ株式会社 Excretion treatment material for pets
US20160362607A1 (en) * 2015-03-08 2016-12-15 Proton Power, Inc. Biochar products and production
CN106718976A (en) * 2016-12-07 2017-05-31 长兴三山炭素有限公司 A kind of preparation method of activated carbon cat litter
CN106922549A (en) * 2017-04-11 2017-07-07 安徽省明美矿物化工有限公司 A kind of bentonite cat litter and preparation method thereof
CN107876027A (en) * 2017-11-27 2018-04-06 清远初曲智能科技有限公司 One kind porous water-absorbing material for air purification and method made of animal wastes
CN107897009A (en) * 2017-11-22 2018-04-13 陈燕蓉 A kind of bentonite cat litter and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3167125U (en) * 2011-01-25 2011-04-07 アイリスオーヤマ株式会社 Excretion treatment material for pets
US20160362607A1 (en) * 2015-03-08 2016-12-15 Proton Power, Inc. Biochar products and production
CN106718976A (en) * 2016-12-07 2017-05-31 长兴三山炭素有限公司 A kind of preparation method of activated carbon cat litter
CN106922549A (en) * 2017-04-11 2017-07-07 安徽省明美矿物化工有限公司 A kind of bentonite cat litter and preparation method thereof
CN107897009A (en) * 2017-11-22 2018-04-13 陈燕蓉 A kind of bentonite cat litter and preparation method thereof
CN107876027A (en) * 2017-11-27 2018-04-06 清远初曲智能科技有限公司 One kind porous water-absorbing material for air purification and method made of animal wastes

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