CN106912494A - A kind of plant vaccine of phosphorous worm prestige and sandworm toxin insecticide and preparation method thereof - Google Patents

A kind of plant vaccine of phosphorous worm prestige and sandworm toxin insecticide and preparation method thereof Download PDF

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Publication number
CN106912494A
CN106912494A CN201710150009.4A CN201710150009A CN106912494A CN 106912494 A CN106912494 A CN 106912494A CN 201710150009 A CN201710150009 A CN 201710150009A CN 106912494 A CN106912494 A CN 106912494A
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China
Prior art keywords
parts
worm prestige
sandworm toxin
toxin insecticide
phosphorous
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CN201710150009.4A
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Inventor
唐剑峰
潘光民
刘振邦
刘杰
乔思佳
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SHANDONG UNITED PESTICIDE INDUSTRY Co Ltd
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SHANDONG UNITED PESTICIDE INDUSTRY Co Ltd
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Priority to CN201710150009.4A priority Critical patent/CN106912494A/en
Publication of CN106912494A publication Critical patent/CN106912494A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/08Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of plant vaccine the invention discloses phosphorous worm prestige and sandworm toxin insecticide includes 1 ~ 10 part of phosphorus worm prestige, 1 ~ 10 part of sandworm toxin insecticide, 1 ~ 2 part of sodium lignin sulfonate, 5 ~ 10 parts of 0.2 ~ 1 part of galacturonic acid and sodium alginate etc.;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or thiocyclam;The plant vaccine of phosphorous worm prestige of the invention and sandworm toxin insecticide, the immune system of crop can be improved, balance the nutrition of each side, make robust plant vibrant, so as to resist pathogen and attack and harm of some insects to crop, the quality and quality of crop are improved, the effect of increase harvest is reached;Plant vaccine of the invention, contain various natural polymerses, energy activating soil, recover and improve the natural vigor of soil, directly for plant growth provides nutrition crop root can be promoted flourishing, enhancing crop leaf photosynthesis and crop disease-resistant, anti-adversity ability, strong sprout, healthy tree, increase yield, improving quality.

Description

A kind of plant vaccine of phosphorous worm prestige and sandworm toxin insecticide and preparation method thereof
Technical field
The present invention relates to plant vaccine technical field, the plant of specifically a kind of phosphorous worm prestige and sandworm toxin insecticide Thing vaccine and preparation method thereof.
Background technology
Droop, is the plant disease being led to by fungi or bacterium, and general morbidity is unexpected, grows rapid tender tissue normal Standby invasion and attack, can cause the death of leaf, flower, fruit, stem or the whole plant of plant, not have preferable prevention and controls at present, typically It is that, using chemical fertilizer and chemical pesticide, long-term use brings many side effects:Such as to the pollution of environment, excessive use chemical pesticide Different degrees of pollution is produced to underground water by the infiltration of rainwater, and has caused soil hardening, destroyed the ventilative of soil Property, making the activity of soil cannot recover for a long time, and crop is also easy to produce resistance, and such as cucumber fusarium axysporum is caused by Botrytis cinerea , to be fallen ill successively after cucumber blooms more, killed strain is manifested initially by partial blade or the side blade noon of plant wilts It is sagging, it is later gradually throughout complete stool and dead quickly like water shortage shape, cause the cucumber underproduction at least 30%;Tomato wilt into Strain phase harm rhizome portion, early stage blade is wilted sagging at noon, and is from bottom to top turned yellow, and rear browning withers vertical, recovers sooner or later Normally, leaf color is thin out, and like water shortage shape, the state of an illness develops from bottom to top, and repeatedly after a couple of days, throughout whole plant, blade no longer restores, Complete stool is withered, causes tomato to have no harvest, and cross-sectional sick stem, sick portion's vascular bundle is brown.When humidity is high, the normal cloth of basal part of stem of dead strain is pink The mould layer of color, both the conidiophore and conidium of germ, there is the farmland of disease plant, such as carried out crop rotation, also had the state of an illness Second stubble crop is transmitted to, is endangered and its serious.
The treatment of droop is mainly at present uses agricultural chemicals, in the market also occurs in that treatment droop miscellaneous Agricultural chemicals, but the use of agricultural chemicals will until occurring Disease symptoms on crop could symptomatic treatment, now, droop to make Thing causes infringement, can only mitigation using these agricultural chemicals, it is impossible to makes up loss, and because droop outburst is fast, holds very much It is easily extensive to occur, then spray insecticide and do not have effect.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of phosphorous worm prestige and the plant of sandworm toxin insecticide Vaccine and preparation method thereof.
The present invention to achieve the above object, is achieved through the following technical solutions:
A kind of plant vaccine of phosphorous worm prestige and sandworm toxin insecticide, in parts by weight, including 1 ~ 10 part of phosphorus worm prestige, clam worm 1 ~ 10 part of toxin insecticides, 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 5 ~ 10 parts of sodium alginate, sweet dew is few 100 ~ 110 parts of 1 ~ 2 part of sugar, 1 ~ 3 part of abscisic acid, 0.1 ~ 0.5 part of neopelex and water;Described neires toxin is killed Worm agent is cartap, dimehypo, Cupric sulfate, bensultap or thiocyclam.
Preferred plant vaccine, also including 2 ~ 5 parts of 5 ~ 10 parts of lentinan and wood oligose.
Preferred plant vaccine, in parts by weight, including 5 parts of phosphorus worm prestige, 5 parts of sandworm toxin insecticide, sulfomethylated lignin 1.5 parts of sour sodium, 0.6 part of galacturonic acid, 8 parts of sodium alginate, 1.5 parts of manna oligosacchride, 2 parts of abscisic acid, DBSA 105 parts of 0.4 part of sodium, 8 parts of lentinan, 4 parts of wood oligose and water;Described sandworm toxin insecticide is cartap.
Present invention additionally comprises phosphorous worm prestige and the preparation method of the plant vaccine of sandworm toxin insecticide, including following step Suddenly:
1. in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
2. by step, 1. gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
3. in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid and the mixing of 0.1 ~ 0.5 part of neopelex, is stirring evenly and then adding into step 2. in gained sphere matrix, obtains The plant vaccine of phosphorous worm prestige and sandworm toxin insecticide.
Preferred preparation method, comprises the following steps:
(1), in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
(3) in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid, 0.1 ~ 0.5 part of neopelex, and 5 ~ 10 parts of lentinans and 2 ~ 5 parts of wood oligoses mix, and are stirring evenly and then adding into To in step (2) gained sphere matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
Further preferred preparation method, comprises the following steps:
(1), in parts by weight, by 8 parts of sodium alginates, 5 parts of phosphorus worm prestige and 5 parts of sandworm toxin insecticides are added in 105 parts of water, Stirred 2.5 hours with the speed of 500r/min, stand 2.5 hours, then mixed within 1.5 hours with the speed stirring of 300r/min Close liquid;Described sandworm toxin insecticide is cartap;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 40 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 20%;
(3) in parts by weight, by 1.5 parts of sodium lignin sulfonates, 0.6 part of galacturonic acid, 1.5 parts of manna oligosacchrides, 2 parts of abscisic acids, 0.4 part of neopelex, 8 parts of lentinans and 4 parts of wood oligose mixing, are stirring evenly and then adding into step (2) gained ball In shape matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
The present invention has advantages below compared to existing technology:
The plant vaccine of phosphorous worm prestige of the invention and sandworm toxin insecticide, can improve the immune system of crop, and balance is each The nutrition of aspect, makes robust plant vibrant, so as to resist the attack and harm of pathogen and insect to crop, improves crop Quality and quality, reach the effect of increase harvest.
The plant vaccine of phosphorous worm prestige of the invention and sandworm toxin insecticide, contains the polymerization of various natural polymers Thing, energy activating soil, recovers and improves the natural vigor of soil, reduces the pollution to environment, and crop easily absorbs, and can be directly plant Thing growth provides nutrition, promotes crop root flourishing, enhancing crop leaf photosynthesis and crop disease-resistant, anti-adversity ability, strong sprout, Healthy tree, increases yield, improving quality;Galacturonic acid, manna oligosacchride and abscisic acid in plant vaccine of the invention etc. are matched somebody with somebody Closing use can activate, induce plant to produce the disease-resistant factors such as substantial amounts of biology enzyme, organic acid, alkaloid, stimulate plant growth, reach To the effect of increasing both production and income;
The active ingredient of the plant vaccine of phosphorous worm prestige of the invention and sandworm toxin insecticide, can be transported by flora conduit All parts of a plant is transported to, there is good prevention and treatment effect to the droop of various crops;Each component of the invention Use cooperatively, content is moderate, it is scientific and reasonable, plant vaccine can be played a part of, crop can be stimulated to produce the life of similar protective plant protecting agent The resistant factor of thing, promotes the root growth of plant, promotes cell elongation and division, increases yield, improves fruit development, improves The metabolism of plant, increases the anti-adversity of crop disease-resistant insect prevention;
Phosphorus worm prestige, sandworm toxin insecticide in phosphorous worm prestige of the invention and the plant vaccine of sandworm toxin insecticide into Divide and sodium alginate is prepared into sphere matrix, it is ensured that phosphorus worm prestige and sandworm toxin insecticide can be equal with other compositions mixing Even, without additionally being disperseed using other auxiliary agents, it is in water and organic molten to solve phosphorus worm prestige and sandworm toxin insecticide Solubility is minimum in agent, is difficult to be prepared into the problem of the formulations such as conventional missible oil, aqua and soluble concentrate;And use the party Medicine can be sustained on blade after method is sprayed on crop, long action time, good absorbing, and can hold plant growth is interim Supervention waves drug effect, plays the effect of preferably prevention or treatment droop.
Specific embodiment
It is an object of the invention to provide a kind of phosphorous worm prestige and plant vaccine and its preparation side of sandworm toxin insecticide Method, is achieved through the following technical solutions:
A kind of plant vaccine of phosphorous worm prestige and sandworm toxin insecticide, in parts by weight, including 1 ~ 10 part of phosphorus worm prestige, clam worm 1 ~ 10 part of toxin insecticides, 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 5 ~ 10 parts of sodium alginate, sweet dew is few 100 ~ 110 parts of 1 ~ 2 part of sugar, 1 ~ 3 part of abscisic acid, 0.1 ~ 0.5 part of neopelex and water;Described neires toxin is killed Worm agent be cartap, dimehypo, Cupric sulfate, bensultap or thiocyclam, and with S-C-C (N)-C-S, S-C-C (- SR ,- OR ,-R)-C-S structures nereistoxin similar thing and derivative.
Preferred plant vaccine, also including 2 ~ 5 parts of 5 ~ 10 parts of lentinan and wood oligose.
Preferred plant vaccine, in parts by weight, including 5 parts of phosphorus worm prestige, 5 parts of sandworm toxin insecticide, sulfomethylated lignin 1.5 parts of sour sodium, 0.6 part of galacturonic acid, 8 parts of sodium alginate, 1.5 parts of manna oligosacchride, 2 parts of abscisic acid, DBSA 105 parts of 0.4 part of sodium, 8 parts of lentinan, 4 parts of wood oligose and water;Described sandworm toxin insecticide is cartap.
Present invention additionally comprises phosphorous worm prestige and the preparation method of the plant vaccine of sandworm toxin insecticide, including following step Suddenly:
1. in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
2. by step, 1. gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
3. in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid and the mixing of 0.1 ~ 0.5 part of neopelex, is stirring evenly and then adding into step 2. in gained sphere matrix, obtains The plant vaccine of phosphorous worm prestige and sandworm toxin insecticide.
Preferred preparation method, comprises the following steps:
(1), in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
(3) in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid, 0.1 ~ 0.5 part of neopelex, and 5 ~ 10 parts of lentinans and 2 ~ 5 parts of wood oligoses mix, and are stirring evenly and then adding into To in step (2) gained sphere matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
Further preferred preparation method, comprises the following steps:
(1), in parts by weight, by 8 parts of sodium alginates, 5 parts of phosphorus worm prestige and 5 parts of sandworm toxin insecticides are added in 105 parts of water, Stirred 2.5 hours with the speed of 500r/min, stand 2.5 hours, then mixed within 1.5 hours with the speed stirring of 300r/min Close liquid;Described sandworm toxin insecticide is cartap;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 40 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 20%;
(3) in parts by weight, by 1.5 parts of sodium lignin sulfonates, 0.6 part of galacturonic acid, 1.5 parts of manna oligosacchrides, 2 parts of abscisic acids, 0.4 part of neopelex, 8 parts of lentinans and 4 parts of wood oligose mixing, are stirring evenly and then adding into step (2) gained ball In shape matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 1kg, cartap 1kg, sulfomethylated lignin Sour sodium 1kg, galacturonic acid 0.2kg, sodium alginate 5kg, manna oligosacchride 1kg, abscisic acid 1kg, neopelex 0.1kg and water 100kg.
Embodiment 2
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 10kg, Cupric sulfate 10kg, lignin Sodium sulfonate 2kg, galacturonic acid 1kg, sodium alginate 10kg, manna oligosacchride 2kg, abscisic acid 3kg, neopelex 0.5kg and water 110kg.
Embodiment 3
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 7kg, dimehypo 4kg, sulfomethylated lignin Sour sodium 1.5kg, galacturonic acid 0.4kg, sodium alginate 6kg, manna oligosacchride 1.4kg, abscisic acid 2.5kg, detergent alkylate sulphur Sour sodium 0.2kg and water 102kg.
Embodiment 4
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 1kg, bensultap 10kg, lignin Sodium sulfonate 2kg, galacturonic acid 0.2kg, sodium alginate 5kg, manna oligosacchride 2kg, abscisic acid 1kg, neopelex 0.5kg, lentinan 10kg, wood oligose 2kg and water 110kg.
Embodiment 5
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 10kg, thiocyclam 1kg, lignin Sodium sulfonate 1kg, galacturonic acid 1kg, sodium alginate 10kg, manna oligosacchride 1kg, abscisic acid 3kg, neopelex 0.1kg, water 100kg, lentinan 5kg and wood oligose 5kg.
Embodiment 6
The plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, including phosphorus worm prestige 5kg, cartap 5kg, sulfomethylated lignin Sour sodium 1.5kg, galacturonic acid 0.6kg, sodium alginate 8kg, manna oligosacchride 1.5kg, abscisic acid 2kg, DBSA Sodium 0.4kg, lentinan 8kg, wood oligose 4kg and water 105kg.
Embodiment 7
The preparation method of the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide described in embodiment 1, comprises the following steps:
1. by 5kg sodium alginates, 1kg phosphorus worm prestige and 1kg cartaps are added in 100kg water, and 2 are stirred with the speed of 500r/min Hour, 2 hours are stood, mixed liquor is then obtained in 1 hour with the speed stirring of 300r/min;
2. by step, 1. gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 30 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 20%;Tested through particle diameter, the average grain diameter of sphere matrix is 315 μm;
3. by 1kg sodium lignin sulfonates, 0.2kg galacturonic acids, 1kg manna oligosacchrides, 1kg abscisic acids and 0.1kg dodecyls Benzene sulfonic acid sodium salt mix, be stirring evenly and then adding into step 2. gained sphere matrix in, obtain phosphorous worm prestige and neires toxin killed The plant vaccine of worm agent.
Equally, after the quality of each component in embodiment 2 ~ 3 is replaced, can obtain phosphorous worm prestige and neires toxin is killed The plant vaccine of worm agent.
Embodiment 8
The preparation method of the plant vaccine of the phosphorous worm prestige and sandworm toxin insecticide of embodiment 4, comprises the following steps:
(1) by 5kg sodium alginates, 1kg phosphorus worm prestige and 10kg bensultaps are added in 110 parts of water, are stirred with the speed of 500r/min 3 hours, 3 hours are stood, mixed liquor is then obtained in 2 hours with the speed stirring of 300r/min;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 45 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 25%;Tested through particle diameter, the average grain diameter of sphere matrix is 308 μm;
(3) by 2kg sodium lignin sulfonates, 0.2kg galacturonic acids, 2kg manna oligosacchrides, 1kg abscisic acids, 0.5kg detergent alkylates Sodium sulfonate, 10kg lentinans and 2kg wood oligoses mix, and are stirring evenly and then adding into step (2) in gained sphere matrix, obtain The plant vaccine of phosphorous worm prestige and sandworm toxin insecticide.
Equally, after the quality of each component in embodiment 5 is replaced, phosphorous worm prestige and neires toxin desinsection be can obtain The plant vaccine of agent.
Embodiment 9
The preparation method of the plant vaccine of the phosphorous worm prestige and sandworm toxin insecticide of embodiment 6, comprises the following steps:
(1) by 8kg sodium alginates, 5kg phosphorus worm prestige and 5kg cartaps are added in 105kg water, are stirred with the speed of 500r/min 2.5 hours, 2.5 hours are stood, mixed liquor is then obtained in 1.5 hours with the speed stirring of 300r/min;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 40 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 20%;Tested through particle diameter, the average grain diameter of sphere matrix is 302 μm;
(3) by 1.5kg sodium lignin sulfonates, 0.6kg galacturonic acids, 1.5kg manna oligosacchrides, 2kg abscisic acids, 0.4kg dodecanes Base benzene sulfonic acid sodium salt, 8kg lentinans and 4kg wood oligoses mix, and are stirring evenly and then adding into step (2) in gained sphere matrix, obtain To phosphorous worm prestige and the plant vaccine of sandworm toxin insecticide.
To the result of autumn outdoor cucumber
Take the phosphorous worm prestige of the gained of 10g embodiments 1 and the plant vaccine of sandworm toxin insecticide, plus 1kg water logging infused cucumber kinds 12 hours, then carry out seeding and seedling raising, and the leaf of cucumber 6 wholeheartedly when every sprinkling in 20 days once, the dosage for using is converted for 10g 50kg water, does not use other drugs;Comparative example then conventionally carries out nursery culture cucumber, uses the foliar fertilizer of in the market The insect on cucumber is killed with insecticide, it is as a result as follows:
The cucumber cultivated using conventional method, melon seedling height is uneven, and branches and leaves are sparse, and blade is small and thin, and cane and holder fine hair are dilute Dredge and uneven, the cucumber bending fruit that bears fruit is more, the later stage bears fruit generally major part or sharp mouth, 10440 jin of per mu yield;And use this The cucumber of the plant vaccine of invention, whole growth period disease-free spot and insect pest;Robust plant is neat, and melon seedling is dense, vigorous, leaf Piece is big and abundant, and cane and holder fine hair are uniform neat closely knit, cucumber bear fruit it is long and straight, it is glossy, the later stage bear fruit also almost without The lopsided cucumber of major part or sharp mouth, 15540 jin of per mu yield, than conventional method volume increase 48.85%.
Using conventional method plant cucumber 10 leaves wholeheartedly when there is the plant of droop, by time sprinkling medicine enter Row treatment, it is specific as follows using medicine and dosage:Blue or green withered Garrick 50-100ml+ garlic oils 7ml is watered 30 jin of even spray 2-3 times, 3-5 It is 1 time.
Prevention and treatment to outdoor tomato wilt
Tomato is planted in adjacent two panels farmland a plot and b plot, is managed collectively, wherein the tomato planting in a plot Afterwards before pregnant flower bud to fruit picking, the mixed liquor of the plant vaccine for once, altogether applying three L.P.K bio-fertilizers and embodiment 4 in every 10 days, its The amount of application of middle L.P.K bio-fertilizers is 3 kilograms every mu every time, is watered 1:200 times of pouring are applied, the administration of the plant vaccine of embodiment 4 It is 0.5 kilogram every mu every time to measure, and is watered 1:200 times of pouring are applied;After the tomato planting in b plot before pregnant flower bud to fruit picking, every 10 days one It is secondary, three L.P.K bio-fertilizers are applied altogether, amount of application is 3 kilograms every mu every time, is watered 1:200 times of pouring are applied;Comparing result is as follows:
The tomato melon seedling height in b plot is uneven, and branches and leaves are sparse, and blade is small and thin, and cane and holder fine hair are sparse and uneven, Tomato bear fruit it is sparse and small, the later stage bear fruit appearance deformity, there is droop in the later stage yielded positive results, early stage is sprayed in time 1000 times of liquid of thiophanate methyl, and it is watered 25kg pouring roots with the Mei Bangzhi 25g that wither, every plant of medication 100ml is spaced 7 days, even fills 3 times, Although having checked the non-large-scale outbreak of the state of an illness, the yield of tomato is also have impact on, final per mu yield is 4125 kilograms.And on a ground The tomato plant of block is healthy and strong neat, and melon seedling is dense, vigorous, and blade is big and abundant, and cane and holder fine hair are uniform neat close Real, tomato is justified and big, glossy, and the later stage bears fruit also without lopsided tomato, and the whole plant strain growth phase is without droop and other diseases Occur, per mu yield is 7150 kilograms, than the volume increase 73.3% in b plot.
Phosphorus worm prestige and neires toxin compound compounding use can also prevent and treat insect in multiple kinds of crops, and crops include water Rice, corn, vegetables, sugarcane, fruit tree etc., insect include the various pests of Lepidoptera, Diptera and coleoptera.
The synergy shown by two mixture of active principles can make in one or both of these active components While amount of application declines, it is ensured that good prevention effect.There is certain lasting effect more than expected effect after application, so that Be conducive to quickly killing insect, improve the death rate.The reduction of active component amount of application, reduces the cost of agricultural producer, and And the chemically reactive substance for reducing residual in the environment, mitigate environmental pressure, improve foodsafety.
The presence of cooperative effect between two kinds of active components is can determine that by means of Colby publicities:
P=A+B-AB/100;
Using Colby methods, by being primarily based on be administered alone two kinds of activity of component, the prediction activity P of mixture is calculated, The presence of cooperative interaction between to determine two kinds of active components.
In above-mentioned formula, A is that a kind of component being administered alone with amount of application x is lived with the biology that degree of preventing and treating percentage is represented Property.B is the bioactivity that the second component applied with amount of application y is represented with degree of preventing and treating percentage.If their effect is strict On see it is adduction, and in the absence of interaction, then the A that the formula is applied with amount of application x is with the B's applied with amount of application y The expected bioactivity of mixture calculates P.If the effect of the mixture set up in experiment exists more than expected activity, P Synergistic function.In order to the active component for applying Colby formula, mixture is administered alone and is administered in combination in testing.
It is below biology test example, the content displaying tested composition of the invention is prevented specific insect Control effect." prevention effect " represents the suppression to pest development(It is dead including insect), described " suppression ", including cause insect Food ration is substantially reduced.It will be understood by those skilled in the art that being not limited to by the control of insect protection that the compound is provided These species.
To evaluate the prevention effect to diamondback moth (Plutella xylostella), test unit has 12-14 days ages by interior The small open container of radish plants is constituted.Using the inoculator with auger conveyor, test sheet is dispersed in via corn cob grits About 50 newborn larvaes in unit infect it in advance.After being distributed in test unit, the larva moves on test plant It is dynamic.
Test-compound and composition are prepared using the solution comprising nonionic surfactant.The compound of preparation and Composition is by sprayer in each test unit applied on top 1mL liquid.To test in triplicate.Will prepare number testedization After compound or composition spray, each test unit is dried 1 hour, black square is then placed on top.Make test sheet Unit holding 6 days in the growth room of 25 DEG C and 70% relative humidity.Ingested leaf visual assessment plant is then based on to ingest damage Evil.
Calculate the average value of result in triplicate and will calculate that the results are shown in Table 1.Phosphorus worm prestige is dense with 5.0mg/L Degree is applied.Neires toxin compound is applied with the dosage being shown in Table 1.
The phosphorus worm prestige of table 1 and neires toxin compound compound the prevention effect table to diamondback moth
* desired value using Colby formula based on being calculated.
Prevention effect that phosphorus worm prestige and neires toxin compound be applied in combination can be seen that more than pre- by the result of table 1 Time value, can be inferred that phosphorus worm prestige and neires toxin compound are applied in combination with synergistic function.
Field conditions are increasingly complex than laboratory environment, are the important use environments for testing drug effect.Following field tests Embodiment, the content displaying tested prevention effect of the composition of the invention to specific insect." prevention effect " represents right The suppression of pest development, including insect is dead, described suppression, including causes substantially reducing for insect food ration.This area skill Art personnel by the control of insect protection that the compound is provided it is to be appreciated that be not limited to these species.
To evaluate phosphorus worm prestige and neires toxin compound to paddy rice borer (Chilo suppressalis Walker) Prevention effect, in borer early period of origination, phosphorus worm prestige and neires toxin compound are configured to suspending agent, used by different Dosage is converted into liquid point cell and is uniformly sprayed on rice plant, drug effect is observed on time and is counted.Test of pesticide effectiveness result is as follows Shown in table 2-6.
The prevention effect table of the phosphorus worm prestige of table 2 and cartap to paddy rice borer
Treatment Phosphorus worm prestige dosage Cartap dosage Average disease refers to Average preventive effect %
1 10 grams/acre 15 grams/acre 1.53 78.92
2 15 grams/acre 20 grams/acre 1.30 82.50
3 20 grams/acre 25 grams/acre 1.12 88.25
Phosphorus worm prestige suspending agent 50 grams/acre 3.28 45.52
Cartap suspending agent 50 grams/acre 4.68 35.90
Blank 8.53
The prevention effect table of the phosphorus worm prestige of table 3 and Cupric sulfate to paddy rice borer
Treatment Phosphorus worm prestige dosage Cupric sulfate dosage Average disease refers to Average preventive effect %
1 10 grams/acre 15 grams/acre 1.32 80.25
2 15 grams/acre 20 grams/acre 1.28 78.56
3 20 grams/acre 25 grams/acre 1.05 85.35
Phosphorus worm prestige suspending agent 50 grams/acre 2.95 32.55
Cupric sulfate suspending agent 50 grams/acre 5.67 52.68
Blank 9.63
The prevention effect table of the phosphorus worm prestige of table 4 and dimehypo to paddy rice borer
Treatment Phosphorus worm prestige dosage Dimehypo dosage Average disease refers to Average preventive effect %
1 10 grams/acre 15 grams/acre 1.53 76.58
2 15 grams/acre 20 grams/acre 1.25 86.29
3 20 grams/acre 25 grams/acre 1.05 89.53
Phosphorus worm prestige suspending agent 50 grams/acre 3.56 25.56
Dimehypo suspending agent 50 grams/acre 5.67 32.59
Blank 8.96
The prevention effect table of the phosphorus worm prestige of table 5 and thiocyclam to paddy rice borer
Treatment Phosphorus worm prestige dosage Thiocyclam dosage Average disease refers to Average preventive effect %
1 10 grams/acre 15 grams/acre 1.42 69.58
2 15 grams/acre 20 grams/acre 1.37 82.54
3 20 grams/acre 25 grams/acre 1.18 78.98
Phosphorus worm prestige suspending agent 50 grams/acre 5.96 42.53
Thiocyclam suspending agent 50 grams/acre 6.87 28.29
Blank 9.85
The prevention effect table of the phosphorus worm prestige of table 6 and bensultap to paddy rice borer
Treatment Phosphorus worm prestige dosage Bensultap dosage Average disease refers to Average preventive effect %
1 10 grams/acre 15 grams/acre 1.08 87.52
2 15 grams/acre 20 grams/acre 1.27 95.68
3 20 grams/acre 25 grams/acre 1.15 98.32
Phosphorus worm prestige suspending agent 50 grams/acre 5.65 40.55
Bensultap suspending agent 50 grams/acre 7.98 32.58
Blank 8.99
Phosphorus worm prestige and sandworm toxin insecticide can be seen that by the experimental data of table 2 ~ 6, dosage is big when being administered alone, Preventive effect to paddy rice borer is also unsatisfactory, and after the two compounding, dosage declines at least 50%, but preventive effect is greatly improved.

Claims (6)

1. the plant vaccine of a kind of phosphorous worm prestige and sandworm toxin insecticide, it is characterised in that:In parts by weight, including phosphorus worm 1 ~ 10 part of prestige, 1 ~ 10 part of sandworm toxin insecticide, 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, sodium alginate 5 ~ 10 parts, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part of abscisic acid, 100 ~ 110 parts of 0.1 ~ 0.5 part of neopelex and water;Described Sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or thiocyclam.
2. the plant vaccine of phosphorous worm prestige according to claim 1 and sandworm toxin insecticide, it is characterised in that:Also wrap Include 2 ~ 5 parts of 5 ~ 10 parts of lentinan and wood oligose.
3. the plant vaccine of phosphorous worm prestige according to claim 2 and sandworm toxin insecticide, it is characterised in that:With weight Amount part meter, including 5 parts of phosphorus worm prestige, 5 parts of sandworm toxin insecticide, 1.5 parts of sodium lignin sulfonate, 0.6 part of galacturonic acid, sea 8 parts of mosanom, 1.5 parts of manna oligosacchride, 2 parts of abscisic acid, 0.4 part of neopelex, 8 parts of lentinan, 4 parts of wood oligose With 105 parts of water;Described sandworm toxin insecticide is cartap.
4. phosphorous worm prestige and the preparation method of the plant vaccine of sandworm toxin insecticide described in claim 1, its feature exist In:Comprise the following steps:
1. in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
2. by step, 1. gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
3. in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid and the mixing of 0.1 ~ 0.5 part of neopelex, is stirring evenly and then adding into step 2. in gained sphere matrix, obtains The plant vaccine of phosphorous worm prestige and sandworm toxin insecticide.
5. phosphorous worm prestige and the preparation method of the plant vaccine of sandworm toxin insecticide described in claim 2, its feature exist In:Comprise the following steps:
(1), in parts by weight, by 5 ~ 10 parts of sodium alginates, 1 ~ 10 part of phosphorus worm prestige and 1 ~ 10 part of sandworm toxin insecticide are added to In 100 ~ 110 parts of water, stirred 2 ~ 3 hours with the speed of 500r/min, stand 2 ~ 3 hours, then stirred with the speed of 300r/min Mix 1 ~ 2 hour and obtain mixed liquor;Described sandworm toxin insecticide is cartap, dimehypo, Cupric sulfate, bensultap or desinsection Ring;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, step 1. gained mixing after instilling 30 ~ 45 minutes Liquid forms Spherical pellets in calcium chloride solution, gained Spherical pellets clear water is rinsed well and obtains sphere matrix;The chlorine The mass fraction for changing calcium solution is 20 ~ 25%;
(3) in parts by weight, by 1 ~ 2 part of sodium lignin sulfonate, 0.2 ~ 1 part of galacturonic acid, 1 ~ 2 part of manna oligosacchride, 1 ~ 3 part takes off Fall acid, 0.1 ~ 0.5 part of neopelex, and 5 ~ 10 parts of lentinans and 2 ~ 5 parts of wood oligoses mix, and are stirring evenly and then adding into To in step (2) gained sphere matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
6. the preparation method of the plant vaccine of phosphorous worm prestige according to claim 5 and sandworm toxin insecticide, it is special Levy and be:Comprise the following steps:
(1), in parts by weight, by 8 parts of sodium alginates, 5 parts of phosphorus worm prestige and 5 parts of sandworm toxin insecticides are added in 105 parts of water, Stirred 2.5 hours with the speed of 500r/min, stand 2.5 hours, then mixed within 1.5 hours with the speed stirring of 300r/min Close liquid;Described sandworm toxin insecticide is cartap;
(2) by step, (1) gained mixed liquor is added dropwise in calcium chloride solution, and 1. gained mixed liquor exists step after instilling 40 minutes Spherical pellets are formed in calcium chloride solution, gained Spherical pellets clear water is rinsed well and is obtained sphere matrix;The calcium chloride The mass fraction of solution is 20%;
(3) in parts by weight, by 1.5 parts of sodium lignin sulfonates, 0.6 part of galacturonic acid, 1.5 parts of manna oligosacchrides, 2 parts of abscisic acids, 0.4 part of neopelex, 8 parts of lentinans and 4 parts of wood oligose mixing, are stirring evenly and then adding into step (2) gained ball In shape matrix, the plant vaccine of phosphorous worm prestige and sandworm toxin insecticide is obtained.
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Cited By (1)

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CN116138257A (en) * 2022-06-20 2023-05-23 广西壮族自治区农业科学院 Nematicide composition containing lentinan for preventing and treating taro root knot nematode disease

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CN102771511A (en) * 2012-08-31 2012-11-14 陕西上格之路生物科学有限公司 Insecticidal composition containing fosthiazate
CN103651546A (en) * 2013-12-10 2014-03-26 济南凯因生物科技有限公司 Composition for preventing and treating injurious insects such as snout moth of paddy

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US4855140A (en) * 1987-09-26 1989-08-08 Basf Aktiengesellschaft O-(O-ethyl-S-alkylphosphoryl)-O-(carbamyl)-pyrocatechol derivatives
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CN116138257A (en) * 2022-06-20 2023-05-23 广西壮族自治区农业科学院 Nematicide composition containing lentinan for preventing and treating taro root knot nematode disease
CN116138257B (en) * 2022-06-20 2024-05-03 广西壮族自治区农业科学院 Nematicide composition containing lentinan for preventing and treating taro root knot nematode disease

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