CN106906359B - 从硅酸盐矿物收取锂 - Google Patents
从硅酸盐矿物收取锂 Download PDFInfo
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- CN106906359B CN106906359B CN201610154532.XA CN201610154532A CN106906359B CN 106906359 B CN106906359 B CN 106906359B CN 201610154532 A CN201610154532 A CN 201610154532A CN 106906359 B CN106906359 B CN 106906359B
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- Prior art keywords
- lithium
- nitric acid
- stage
- solution
- nitrate
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 119
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 229910052604 silicate mineral Inorganic materials 0.000 title claims abstract description 69
- 238000003306 harvesting Methods 0.000 title abstract description 5
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 290
- 238000000034 method Methods 0.000 claims abstract description 192
- 230000008569 process Effects 0.000 claims abstract description 108
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 76
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 76
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 31
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 30
- 239000003546 flue gas Substances 0.000 claims abstract description 30
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 28
- 239000011707 mineral Substances 0.000 claims abstract description 28
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 14
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 286
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 156
- 229910017604 nitric acid Inorganic materials 0.000 claims description 152
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 83
- 239000007787 solid Substances 0.000 claims description 75
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 62
- 239000002002 slurry Substances 0.000 claims description 60
- 239000013078 crystal Substances 0.000 claims description 56
- 238000002386 leaching Methods 0.000 claims description 52
- 239000000047 product Substances 0.000 claims description 49
- 238000006243 chemical reaction Methods 0.000 claims description 46
- 238000010438 heat treatment Methods 0.000 claims description 46
- 238000002425 crystallisation Methods 0.000 claims description 44
- 230000008025 crystallization Effects 0.000 claims description 42
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 38
- 238000004519 manufacturing process Methods 0.000 claims description 38
- 238000000926 separation method Methods 0.000 claims description 38
- 239000007789 gas Substances 0.000 claims description 33
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 28
- 238000001035 drying Methods 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 22
- 239000008346 aqueous phase Substances 0.000 claims description 21
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 20
- 238000006386 neutralization reaction Methods 0.000 claims description 19
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims description 18
- 229910021529 ammonia Inorganic materials 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
- 229910052760 oxygen Inorganic materials 0.000 claims description 17
- 239000001301 oxygen Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 16
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 claims description 15
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 claims description 15
- 239000012071 phase Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 8
- 150000002642 lithium compounds Chemical class 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- 229910013553 LiNO Inorganic materials 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 230000035800 maturation Effects 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 238000007781 pre-processing Methods 0.000 claims description 2
- 230000002829 reductive effect Effects 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 claims description 2
- 229960004424 carbon dioxide Drugs 0.000 claims 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 238000005191 phase separation Methods 0.000 claims 2
- 229910002090 carbon oxide Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 238000001256 steam distillation Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 13
- 239000011435 rock Substances 0.000 abstract description 10
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052912 lithium silicate Inorganic materials 0.000 abstract description 6
- 229910052618 mica group Inorganic materials 0.000 abstract description 3
- 239000004927 clay Substances 0.000 abstract description 2
- 229910052570 clay Inorganic materials 0.000 abstract description 2
- 239000010445 mica Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 129
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 39
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 30
- 239000003570 air Substances 0.000 description 26
- 235000010755 mineral Nutrition 0.000 description 24
- 230000029087 digestion Effects 0.000 description 21
- 229910052642 spodumene Inorganic materials 0.000 description 19
- 229910052782 aluminium Inorganic materials 0.000 description 17
- 238000002485 combustion reaction Methods 0.000 description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 238000001914 filtration Methods 0.000 description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 15
- 239000000706 filtrate Substances 0.000 description 15
- 229910052742 iron Inorganic materials 0.000 description 15
- 238000003860 storage Methods 0.000 description 15
- 239000012065 filter cake Substances 0.000 description 14
- 239000000446 fuel Substances 0.000 description 14
- 229910052644 β-spodumene Inorganic materials 0.000 description 14
- 238000000354 decomposition reaction Methods 0.000 description 13
- 238000012545 processing Methods 0.000 description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 238000005201 scrubbing Methods 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 238000011282 treatment Methods 0.000 description 12
- 238000001354 calcination Methods 0.000 description 11
- 239000012141 concentrate Substances 0.000 description 11
- 239000012535 impurity Substances 0.000 description 10
- 239000000543 intermediate Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 9
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000011575 calcium Substances 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 8
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 8
- 229910052723 transition metal Inorganic materials 0.000 description 8
- 150000003624 transition metals Chemical class 0.000 description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 7
- 150000001342 alkaline earth metals Chemical class 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 229910052791 calcium Inorganic materials 0.000 description 7
- -1 cobalt Chemical class 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- 150000004679 hydroxides Chemical class 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 description 7
- 235000017550 sodium carbonate Nutrition 0.000 description 7
- 235000010344 sodium nitrate Nutrition 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 150000002823 nitrates Chemical class 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 229910052643 α-spodumene Inorganic materials 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- QTJOIXXDCCFVFV-UHFFFAOYSA-N [Li].[O] Chemical compound [Li].[O] QTJOIXXDCCFVFV-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 239000012452 mother liquor Substances 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 235000010333 potassium nitrate Nutrition 0.000 description 5
- 239000004317 sodium nitrate Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- 238000009997 thermal pre-treatment Methods 0.000 description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000001099 ammonium carbonate Substances 0.000 description 4
- 235000012501 ammonium carbonate Nutrition 0.000 description 4
- 230000005587 bubbling Effects 0.000 description 4
- 239000000567 combustion gas Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 229910001414 potassium ion Inorganic materials 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 238000007669 thermal treatment Methods 0.000 description 4
- 239000002918 waste heat Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 3
- 239000004323 potassium nitrate Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229910010100 LiAlSi Inorganic materials 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007084 catalytic combustion reaction Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- SXGDIBYXFSKCRM-UHFFFAOYSA-L dilithium hydrogen carbonate hydroxide Chemical compound [OH-].[Li+].C([O-])(O)=O.[Li+] SXGDIBYXFSKCRM-UHFFFAOYSA-L 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 229910052629 lepidolite Inorganic materials 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 229910002001 transition metal nitrate Inorganic materials 0.000 description 2
- 238000010977 unit operation Methods 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical class [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 1
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910052822 amblygonite Inorganic materials 0.000 description 1
- 229910052908 analcime Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- PNEFIWYZWIQKEK-UHFFFAOYSA-N carbonic acid;lithium Chemical compound [Li].OC(O)=O PNEFIWYZWIQKEK-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910000174 eucryptite Inorganic materials 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229910052598 goethite Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- AEIXRCIKZIZYPM-UHFFFAOYSA-M hydroxy(oxo)iron Chemical compound [O][Fe]O AEIXRCIKZIZYPM-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910001608 iron mineral Inorganic materials 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- APIQKPDPYIHQIU-UHFFFAOYSA-N lithium nitric acid nitrate Chemical compound [Li+].O[N+]([O-])=O.[O-][N+]([O-])=O APIQKPDPYIHQIU-UHFFFAOYSA-N 0.000 description 1
- VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/02—Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/065—Nitric acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/10—Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2015905317A AU2015905317A0 (en) | 2015-12-22 | Process and System for Recovering Lithium from Silicate Minerals | |
| AU2015905317 | 2015-12-22 | ||
| AU2016900774A AU2016900774A0 (en) | 2016-03-02 | Recovery of Lithium from Silicate Minerals | |
| AU2016900774 | 2016-03-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106906359A CN106906359A (zh) | 2017-06-30 |
| CN106906359B true CN106906359B (zh) | 2018-12-11 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610154532.XA Active CN106906359B (zh) | 2015-12-22 | 2016-03-17 | 从硅酸盐矿物收取锂 |
| CN202311112578.1A Pending CN117265263A (zh) | 2015-12-22 | 2016-12-22 | 从硅酸盐矿物收取锂 |
| CN201680075103.1A Pending CN108431253A (zh) | 2015-12-22 | 2016-12-22 | 从硅酸盐矿物收取锂 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202311112578.1A Pending CN117265263A (zh) | 2015-12-22 | 2016-12-22 | 从硅酸盐矿物收取锂 |
| CN201680075103.1A Pending CN108431253A (zh) | 2015-12-22 | 2016-12-22 | 从硅酸盐矿物收取锂 |
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| Country | Link |
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| US (2) | US10131968B2 (https=) |
| EP (2) | EP3859020A1 (https=) |
| JP (2) | JP6946302B2 (https=) |
| KR (3) | KR20240149908A (https=) |
| CN (3) | CN106906359B (https=) |
| AU (4) | AU2016374661B2 (https=) |
| CA (1) | CA3009374C (https=) |
| CL (1) | CL2018001689A1 (https=) |
| DK (1) | DK3394302T3 (https=) |
| ES (1) | ES2884254T3 (https=) |
| PT (1) | PT3394302T (https=) |
| SG (2) | SG11201804573XA (https=) |
| WO (1) | WO2017106925A1 (https=) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2840723T3 (es) * | 2015-12-22 | 2021-07-07 | ICSIP Pty Ltd | Procedimiento de captura de dióxido de carbono de una corriente de gas |
| EP4438749A3 (en) | 2016-11-14 | 2025-01-08 | Lilac Solutions, Inc. | Lithium extraction with coated ion exchange particles |
| US10604414B2 (en) | 2017-06-15 | 2020-03-31 | Energysource Minerals Llc | System and process for recovery of lithium from a geothermal brine |
| AR112663A1 (es) | 2017-08-02 | 2019-11-27 | Lilac Solutions Inc | Extracción de litio con perlas porosas de intercambio iónico |
| US10439200B2 (en) | 2017-08-02 | 2019-10-08 | Lilac Solutions, Inc. | Ion exchange system for lithium extraction |
| US10961126B2 (en) * | 2017-08-03 | 2021-03-30 | Veolia Water Technologies, Inc. | Process for reducing fouling in evaporators in lithium hydroxide recovery |
| DE102017125707A1 (de) * | 2017-11-03 | 2019-05-09 | Thyssenkrupp Ag | Verfahren und Anlage zur thermischen Behandlung eines Lithiumerzes |
| KR20200116526A (ko) | 2018-02-28 | 2020-10-12 | 리락 솔루션즈, 인크. | 리튬 추출을 위한 입자 트랩을 가진 이온 교환 반응기 |
| MX2018003804A (es) * | 2018-03-27 | 2019-09-30 | Centro De Investig Y De Estudios Avanzados Del I P N | Proceso para la lixiviacion de litio contenido en arcillas con moscovita y sanidina. |
| CN108193045A (zh) * | 2018-04-03 | 2018-06-22 | 湖北汇锂新能源科技有限公司 | 一种锂矿石机械化焙烧窑及其焙烧方法 |
| CN108439439A (zh) * | 2018-06-12 | 2018-08-24 | 佛山市灏金赢科技有限公司 | 一种电池级碳酸锂的制备方法 |
| EP3827105A4 (en) * | 2018-07-24 | 2022-04-27 | Lithium Australia NL | CAUSTIC CONVERSION PROCESS |
| JP6533859B1 (ja) * | 2018-10-29 | 2019-06-19 | 株式会社アサカ理研 | 炭酸リチウムの製造装置 |
| CN113365947A (zh) | 2018-11-29 | 2021-09-07 | 伊希普私人有限公司 | 锂化学品和金属锂的制备 |
| CA3126962A1 (en) | 2019-01-18 | 2020-07-23 | St-Georges Eco-Mining Corp. | Method of mineral recovery |
| CA3134664A1 (en) | 2019-03-29 | 2020-10-08 | Lithium Americas Corporation | Method of lithium extraction from sedimentary clay |
| US20200318219A1 (en) * | 2019-04-04 | 2020-10-08 | Iowa State University Research Foundation, Inc. | Mechanochemical recovery of Co, Li and other constituents from spent lithium-ion batteries |
| KR102278372B1 (ko) | 2019-04-29 | 2021-07-19 | 고등기술연구원연구조합 | 리튬 함유 물질로부터 리튬 회수방법 |
| CN110358934B (zh) * | 2019-08-26 | 2020-05-12 | 中国科学院地球化学研究所 | 离子交换法提取碳酸盐粘土型锂矿中锂的方法 |
| CN111057850B (zh) * | 2020-01-03 | 2020-12-25 | 四川万邦胜辉新能源科技有限公司 | 一种真空热还原法制备高纯金属锂的方法 |
| KR20220119166A (ko) | 2020-01-09 | 2022-08-26 | 리락 솔루션즈, 인크. | 바람직하지 않은 금속의 분리 방법 |
| WO2021148267A1 (de) * | 2020-01-20 | 2021-07-29 | Thyssenkrupp Industrial Solutions Ag | Thermische behandlung von mineralischen rohstoffen mit einem mechanischen wirbelbettreaktor |
| AU2021222020A1 (en) * | 2020-02-20 | 2022-09-15 | North Carolina State University | Process for extraction of lithium |
| CA3178825A1 (en) | 2020-06-09 | 2021-12-16 | David Henry SNYDACKER | Lithium extraction in the presence of scalants |
| CN111893318A (zh) * | 2020-07-16 | 2020-11-06 | 江西赣锋锂业股份有限公司 | 一种含锂黏土提锂的方法 |
| BR112023002448A2 (pt) * | 2020-08-12 | 2023-03-21 | Calix Ltd | Método para o piroprocessamento de pós |
| WO2022109156A1 (en) * | 2020-11-20 | 2022-05-27 | Lilac Solutions, Inc. | Lithium production with volatile acid |
| CA3199218A1 (en) | 2020-11-20 | 2022-05-27 | David Henry SNYDACKER | Lithium production with volatile acid |
| JP2022128097A (ja) * | 2021-02-22 | 2022-09-01 | 太平洋セメント株式会社 | 炭酸リチウムの製造方法 |
| KR20240014047A (ko) | 2021-04-23 | 2024-01-31 | 리락 솔루션즈, 인크. | 리튬 추출을 위한 이온 교환 장치 |
| US20230032153A1 (en) * | 2021-07-30 | 2023-02-02 | Schlumberger Technology Corporation | Lithium purification and conversion |
| US11931701B2 (en) | 2021-08-06 | 2024-03-19 | Lithium Ark Holding B.V. | Production of lithium hydroxide and lithium carbonate |
| CN113651342A (zh) * | 2021-09-06 | 2021-11-16 | 四川顺应动力电池材料有限公司 | 一种采用硝酸常压法处理锂云母生产锂产品的方法 |
| CN113772696A (zh) * | 2021-09-09 | 2021-12-10 | 四川顺应动力电池材料有限公司 | 一种采用硝酸加压法处理锂云母生产多种锂产品的方法 |
| CN114105171B (zh) * | 2021-11-04 | 2023-10-31 | 四川顺应锂材料科技有限公司 | 一种锂云母资源化综合利用的方法及制备的氢氧化锂 |
| KR20240101569A (ko) * | 2021-11-04 | 2024-07-02 | 메트소 핀란드 오이 | 리튬-함유 미네랄의 하소 및 침출을 위한 프로세스에서의 용액 순환 |
| CN114318008B (zh) * | 2021-12-27 | 2022-09-23 | 四川顺应锂材料科技有限公司 | 一种硝酸二次逆向浸出锂辉石提锂的方法 |
| CA3248339A1 (en) * | 2022-01-17 | 2023-07-20 | ICSIP Pty Ltd | PROCESS AND SYSTEM FOR THE PRODUCTION OF LITHIUM |
| CN114477243B (zh) * | 2022-02-11 | 2024-03-22 | 武汉工程大学 | 一种硝酸锂热解的方法 |
| US12590539B2 (en) | 2022-03-14 | 2026-03-31 | Schlumberger Technology Corporation | Systems and methods for analysis of drilling fluid |
| EP4499260A4 (en) | 2022-03-28 | 2026-04-01 | Lilac Solutions Inc | DEVICES FOR THE EFFICIENT USE OF SORBANTS IN LITHIUM EXTRACTION |
| AR128953A1 (es) | 2022-04-01 | 2024-06-26 | Lilac Solutions Inc | Extracción de litio con aditivos químicos |
| EP4519471A1 (en) | 2022-05-04 | 2025-03-12 | Services Pétroliers Schlumberger | Lithium recovery using aqueous sources |
| CN114875250B (zh) * | 2022-05-18 | 2023-08-01 | 北京机械力化学研究院有限公司 | 含锂粘土提纯锂的方法 |
| CA3255566A1 (en) * | 2022-05-25 | 2023-11-30 | Albemarle Corporation | PROCESS FOR THE PRODUCTION OF LITHIUM HYDROXIDE MONOHYDRATE |
| CN115321562B (zh) * | 2022-07-21 | 2023-10-17 | 四川顺应锂材料科技有限公司 | 一种锂矿硝酸浸出液膜法生产碳酸锂的方法 |
| DE102022121918B4 (de) * | 2022-08-30 | 2025-04-24 | cylib GmbH | Verfahren zum Aufarbeiten von lithiumhaltigen Energiespeichern |
| US12091727B2 (en) | 2022-09-30 | 2024-09-17 | James G. Blencoe | Process for extracting lithium, aluminum, and silicon materials from a hard rock source |
| CN115466854B (zh) * | 2022-10-13 | 2024-01-16 | 江西闪凝科技有限公司 | 一种锂矿石综合提取方法 |
| GB2623593B (en) * | 2022-10-21 | 2025-07-16 | Imerys British Lithium Ltd | Impurity removal and leaching of lithium material |
| DE102022130083A1 (de) * | 2022-11-14 | 2024-05-16 | EnBW Energie Baden-Württemberg AG | Verfahren und Vorrichtung zur Gewinnung von Lithiumcarbonat aus Sole |
| AU2024218169A1 (en) * | 2023-02-10 | 2025-09-25 | St-Georges Eco-Mining Corp. | Method of lithium recovery from hard rock resources |
| AU2024230147A1 (en) * | 2023-02-27 | 2025-09-18 | ICSIP Pty Ltd | Lithium recovery from sedimentary silicates |
| WO2024190768A1 (ja) * | 2023-03-14 | 2024-09-19 | 国立研究開発法人量子科学技術研究開発機構 | 無機物溶液の製造方法及び無機物溶液の製造装置 |
| AU2024245966A1 (en) * | 2023-03-28 | 2025-11-06 | Spodumene-Sourced Lithium, Llc | PROCESS FOR CO-PRODUCING LITHIUM, ALUMINUM, AND SILICON-OXYGEN (Si-O) MATERIALS |
| EP4491577A1 (en) | 2023-05-23 | 2025-01-15 | Lithium Ark Holding B.V. | Production of lithium hydroxide and lithium carbonate |
| CN116786078B (zh) * | 2023-05-25 | 2024-08-30 | 苏州博睿特环保科技有限公司 | 硅酸锂铁改性锂辉石矿渣锂离子筛、其前驱体及制备方法 |
| CN116768250A (zh) * | 2023-05-31 | 2023-09-19 | 广西中伟新材料科技有限公司 | 锂辉石的处理方法及装置 |
| KR102908776B1 (ko) * | 2023-08-22 | 2026-01-07 | 주식회사 씨아이에스케미칼 | 반도체 공정 부산물을 활용한 양극재 원료물질 제조방법 |
| US20260015288A1 (en) * | 2024-07-15 | 2026-01-15 | Schlumberger Technology Corporation | Geopolymer precursor preparation |
| CN120381809B (zh) * | 2025-06-30 | 2025-09-16 | 安徽天铁锂电新能源有限公司 | 一种正丁基锂废液中回收锂盐的装置及回收方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102765734A (zh) * | 2012-07-13 | 2012-11-07 | 江西赣锋锂业股份有限公司 | 一种从锂辉石提取锂制备锂盐的方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1531336A (en) * | 1924-04-10 | 1925-03-31 | Norsk Hydro Elektrisk | Process for the treatment of leucite |
| US1863986A (en) * | 1928-04-18 | 1932-06-21 | Jourdan Felix | Process for the treatment of leucitic rocks with nitrous vapors in a continuous cycle |
| US1976564A (en) * | 1932-03-18 | 1934-10-09 | Jourdan Felix | Process for the treatment of silicates with acids in order to obtain their soluble salts |
| GB402977A (en) * | 1932-03-18 | 1933-12-14 | Felix Jourdan | Improvements in process for the treatment of silicates with acids in order to obtaintheir soluble salts |
| US2024026A (en) * | 1933-11-17 | 1935-12-10 | Warner Chemical Company | Recovering lithium compounds |
| US2021988A (en) * | 1934-01-20 | 1935-11-26 | Grasselli Chemical Co | Production of lithium compounds |
| US3965239A (en) * | 1973-11-16 | 1976-06-22 | International Ore Technology, Inc. | Recovery of nitric acid soluble transition metals from sulfur and iron containing ores of the same |
| US4200264A (en) | 1976-08-16 | 1980-04-29 | Fumio Hori | Apparatus for obtaining Mg and Ca through carbon reduction |
| JPS5322810A (en) | 1976-08-16 | 1978-03-02 | Fumio Hori | Method and apparatus for producing metal mg or ca by carbon reduction |
| IL77081A (en) | 1984-12-04 | 1999-10-28 | Genetics Inst | Dna sequence encoding human erythropoietin process for the preparation thereof and a pharmaceutical composition of human erythropoietin |
| JPH024442A (ja) | 1988-06-21 | 1990-01-09 | Agency Of Ind Science & Technol | 高性能リチウム吸着剤およびその製造方法 |
| US5350717A (en) * | 1993-06-04 | 1994-09-27 | Corning Incorporated | Method for treating beta-spodumene ceramics |
| JP3676926B2 (ja) * | 1997-06-04 | 2005-07-27 | 株式会社日鉱マテリアルズ | 電池正極廃材からコバルト、ニッケルもしくはマンガンおよびリチウムを回収および再生する方法ならびに電池正極材原料 |
| CN1117164C (zh) * | 1999-12-10 | 2003-08-06 | 中国科学院青海盐湖研究所 | 金属锂的热还原制备及提纯工艺和设备 |
| WO2009157620A1 (en) * | 2008-06-25 | 2009-12-30 | Dongbu Fine Chemicals Co., Ltd. | Method of recovering a compound comprising manganese from dust of electronic furnace |
| CN102131942B (zh) | 2008-07-31 | 2013-06-05 | 澳大利亚联邦科学与工业研究组织 | 用于生产金属的方法 |
| CN102892708B (zh) | 2010-01-07 | 2015-04-22 | 银河锂业国际有限公司 | 用于制造碳酸锂的方法 |
| FI122831B (fi) | 2010-05-25 | 2012-07-31 | Outotec Oyj | Menetelmä spodumeenin käsittelemiseksi |
| JP2012112027A (ja) * | 2010-11-25 | 2012-06-14 | Kangen Yoyu Gijutsu Kenkyusho:Kk | リチウム並びにコバルトやその他メタルの回収方法 |
| JP2014508863A (ja) * | 2011-03-18 | 2014-04-10 | オーバイト アルミナ インコーポレイテッド | アルミニウム含有材料から希土類元素を回収する方法 |
| JP2012246519A (ja) * | 2011-05-26 | 2012-12-13 | Nippon Telegr & Teleph Corp <Ntt> | 金属の浸出方法 |
| JP2013095951A (ja) * | 2011-10-31 | 2013-05-20 | Nippon Telegr & Teleph Corp <Ntt> | リチウム回収方法 |
| EA201491632A1 (ru) | 2012-03-19 | 2015-03-31 | Оутотек (Финлэнд) Ой | Способ извлечения карбоната лития |
| AU2013201833B2 (en) * | 2012-08-13 | 2014-07-17 | Reed Advanced Materials Pty Ltd | Processing of Lithium Containing Ore |
| CN103667723A (zh) * | 2013-12-29 | 2014-03-26 | 四川师范大学 | 钴酸锂废电池正极材料的浸出方法 |
| CA3275949A1 (en) | 2014-02-24 | 2025-10-31 | Nemaska Lithium Inc. | Methods for treating lithium-containing materials |
| AR095821A1 (es) | 2014-04-09 | 2015-11-11 | Consejo Nac De Investig Científicas Y Técnicas (Conicet) | Procedimiento de obtención de compuestos de litio |
| CN105039699B (zh) | 2015-06-03 | 2018-01-02 | 江西合纵锂业科技有限公司 | 锂云母固氟重构提取碱金属渣处理与资源化利用方法 |
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