CN106893645A - 一种电解生产小分子团水的方法及在家居洗涤剂应用 - Google Patents
一种电解生产小分子团水的方法及在家居洗涤剂应用 Download PDFInfo
- Publication number
- CN106893645A CN106893645A CN201611226275.2A CN201611226275A CN106893645A CN 106893645 A CN106893645 A CN 106893645A CN 201611226275 A CN201611226275 A CN 201611226275A CN 106893645 A CN106893645 A CN 106893645A
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- China
- Prior art keywords
- phases
- water
- small
- micelle water
- tourmaline
- Prior art date
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000000693 micelle Substances 0.000 title claims abstract description 27
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- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
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- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical class OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims 1
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- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
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- MLNKXLRYCLKJSS-RMKNXTFCSA-N (2e)-2-hydroxyimino-1-phenylethanone Chemical compound O\N=C\C(=O)C1=CC=CC=C1 MLNKXLRYCLKJSS-RMKNXTFCSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
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- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 101710093543 Probable non-specific lipid-transfer protein Proteins 0.000 description 1
- 101710180319 Protease 1 Proteins 0.000 description 1
- 101710180316 Protease 2 Proteins 0.000 description 1
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 101710137710 Thioesterase 1/protease 1/lysophospholipase L1 Proteins 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
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- 238000009835 boiling Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
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- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
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- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
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- 239000002304 perfume Substances 0.000 description 1
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Classifications
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
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- C11D3/201—Monohydric alcohols linear
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- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
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Abstract
本发明提供一种电解生产小分子团水的方法及在家居洗涤剂应用。包括以下几个步骤：步骤A：将电气石、铅球和去离子水按一定质量比混合均匀，在球磨机中球磨；步骤B：将所得原料干燥，研磨备用；步骤C：将球磨后的电气石添加到去离子水中，过滤静置取上清液得到小分子团水。本发明利用小分子团水的特点，通过电解方法所获得的小分子团水是呈弱碱性的，并且其溶解能力和渗透性都有所增强，因此，本发明采用小分子团水和碱性蛋白酶的复配性，增加碱性蛋白酶在水中的溶解度，在弱碱性条件下，碱性蛋白酶的水解能力得到充分发挥，增加其渗透能力，从而提高家居洗涤剂的洗涤能力。
Description
技术领域
本发明属于家居洗涤剂领域，具体涉及通过水处理产生小分子团水的生产工艺应用含碱性蛋白酶的家居洗涤剂中。
背景技术
水除了以单分子形式存在，还可以由若干分子形成由氢键连起来的团簇，水的这种团簇结构会引起其粘度，表面张力，熔点，沸点，溶解能力以及酸碱值等水性质的变化。通过一种方式将水分子点解，使水的酸碱值改变，从而提高水的界面活性，增强水的渗透力和溶解力，得到先分子团水，具有广泛的应用前景。
常用家居用品，使用多次后通常都会附着大量油污以及其他污渍，因此，发明提供一种洗涤剂来解决日常油污问题尤为关键。
国内专利查阅结果发现：各种家居清洗剂有很多专利。但是，暂时没发现有将小分子团水应用于这两个方面。
发明内容
为此，本发明提供一种水处理方法得到小分子团水，应用于含碱性但北美家居洗涤剂中。
一种以电解方式生产小分子团水的方法，包括以下几个步骤：
步骤A：将电气石、铅球和去离子水按一定质量比混合均匀，在球磨机中球磨；
步骤B：将所得原料干燥，研磨备用；
步骤C：将球磨后的电气石添加到去离子水中，过滤取上清液得到小分子团水。
小分子团水暂时没有测量标准，一般都是通过氧17核磁共振的半高幅宽的Hz来检测水分子团的大小。本发明小分子团水通过氧17核磁共振发测定，所得的半高幅宽的Hz数可反映小分子团水的大小，小分子团水越小，Hz数越小，反之越大。测试结果见表1。
表1
优选的，所述步骤A中，所述电气石、铅球和去离子水的质量比为2:47:10-4:47:10；球磨时间为1.5-2.5小时。
优选的，所述步骤B中，干燥时间为78-82℃，时间为7.5-8.5小时。
优选的，所述步骤C中，电气石以质量分数为2.5-3.5％添加到去离子水中，静置时间为8-10分钟。
本发明还提供一种家居洗涤剂，按质量浓度，包括：表面活性剂15％-40％，增稠剂1.0％-8％，螯合剂0％-0.15％，多元醇2-8％，香精0.2-0.6％，碱性蛋白酶1.0％-5％，防腐剂0.05％-0.5％，余量为小分子团水。
优选的，所述表面活性剂采用十二烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、十二烷基硫酸钠、癸基葡萄糖、月桂酰基氨酸钠、椰油酰胺丙基甜菜碱中的至少一种；所述增稠剂为氯化钠、椰油酰单乙醇胺、氨基酸增稠剂中的至少一种；所述螯合剂为乙二胺四乙酸二钠；所述多元醇采用乙醇、甘油、1,3丙二醇、1，2己二醇中的至少一种；所述防腐剂采用对羟基苯乙酮、DMDM乙内酰脲、甲基异噻唑啉酮、苯氧乙醇中的至少一种。
优选的，所制得的洗涤剂的酸碱值为9-11。
本发明还提供一种制备家居洗涤剂的制备方法，包括以下步骤：
步骤(1)：将A相加热至82-85℃，保温搅拌20-40分钟，搅拌至溶解完全。
步骤(2)：降温至35-45℃。
步骤(3)：加入B相、C相、D相、E相搅拌溶解完全，出料。
其中A相为表面活性剂、增稠剂、螯合剂，B相为多元醇，C相为碱性蛋白酶，D相为香精，E相为防腐剂。
优选的，所述步骤(1)中加热温度为82-85℃，搅拌时间为25-30分钟。
优选的，所述步骤(1)和步骤(3)中搅拌速度为150-200r/min。
上述步骤为本发明的优选投料方案，本发明不限于上述投料顺序。
本发明的有益效果：本发明利用小分子团水的特点，通过电解方法所获得的小分子团水是呈弱碱性的，并且其溶解能力和渗透性都有所增强，因此，本发明采用小分子团水和碱性蛋白酶的复配性，增加碱性蛋白酶在水中的溶解度，在弱碱性条件下，碱性蛋白酶的水解能力得到充分发挥，增加其渗透能力，从而提高家居洗涤剂的洗涤能力。
具体实施方式
下面对本发明的较优的实施例作进一步的详细说明：
实施例1：A组分：按质量分数，小分子团水59％，脂肪醇聚氧乙烯醚硫酸钠15％，椰油酰胺丙基甜菜碱15％，椰油酰单乙醇胺1.5％，氯化钠0.8％，乙二胺四乙酸二钠0.1％。B组分：乙醇3.0％，甘油3.0％，1,2己二醇0.5％，C组分：碱性蛋白酶1％。D组分：香精0.6％。E组分：对羟基苯乙酮0.5％。
具体步骤如下：1)分别将A相搅拌加热至82℃，保温搅拌(搅拌速度为200r/min)30分钟直至溶解完全。2)确认溶解完全后降温。3)当温度降至35℃时加入B相、C相、D相、E相，搅拌(搅拌速度为200r/min)分散均匀后出料。
对比例1：一种家居洗涤剂，与实施例1基本相同区别在于：所采用的水为去离子水。
实施例2：A组分：按质量分数，小分子团水64.1％，十二烷基苯磺酸钠20％，脂肪醇聚氧乙烯醚硫酸钠5％，椰油酰单乙醇胺1.5％，氯化钠0.6％，乙二胺四乙酸二钠0.1％。B组分：乙醇3.0％，甘油3.0％，C组分：碱性蛋白酶2％。D组分：香精0.6％。E组分：苯氧乙醇0.1％。
具体步骤如下：1)分别将A相搅拌加热至85℃，保温搅拌(搅拌速度为200r/min)30分钟直至溶解完全。2)确认溶解完全后降温。3)当温度降至45℃时加入B相、C相、D相、E相，搅拌(搅拌速度为200r/min)分散均匀后出料。
对比例2：一种家居洗涤剂，与实施例2基本相同区别在于：所采用的水为去离子水。
实施例3：A组分：按质量分数，小分子团水71.5％，脂肪醇聚氧乙烯醚硫酸钠10％，十二烷基磺酸钠5％，椰油酰单乙醇胺1.5％，氯化钠0.6％，乙二胺四乙酸二钠0.15％。B组分：甘油8.0％，C组分：碱性蛋白酶3％。D组分：香精0.2％。E组分：甲基异噻唑啉酮0.05％。
具体步骤如下：1)分别将A相搅拌加热至83℃，保温搅拌(搅拌速度为200r/min)30分钟直至溶解完全。2)确认溶解完全后降温。3)当温度降至38℃时加入B相、C相、D相、E相，搅拌(搅拌速度为200r/min)分散均匀后出料。
对比例3：一种家居洗涤剂，与实施例3基本相同区别在于：所采用的水为去离子水。
实施例4：A组分：按质量分数，小分子团水52.2％，癸基葡萄糖20％，椰油酰胺丙基甜菜碱20％，椰油酰单乙醇胺1.0％。B组分：1，3丙二醇1.0％，甘油1.0％，C组分：碱性蛋白酶4％。D组分：香精0.6％。E组分：DMDM乙内酰脲0.2％。
具体步骤如下：1)分别将A相搅拌加热至84℃，保温搅拌(搅拌速度为200r/min)30分钟直至溶解完全。2)确认溶解完全后降温。3)当温度降至40℃时加入B相、C相、D相、E相，搅拌(搅拌速度为200r/min)分散均匀后出料。
对比例4：一种家居洗涤剂，与实施例4基本相同区别在于：所采用的水为去离子水。
实施例5：A组分：按质量分数，小分子团水48.4％，月桂酰基氨酸钠20％，椰油酰胺丙基甜菜碱15％，氨基酸增稠剂8.0％。B组分：1，3丙二醇2.0％，1,2己二醇0.5％。C组分：碱性蛋白酶5％。D组分：香精0.6％。E组分：对羟基苯乙酮0.5％。
具体步骤如下：1)分别将A相搅拌加热至83℃，保温搅拌(搅拌速度为200r/min)30分钟直至溶解完全。2)确认溶解完全后降温。3)当温度降至42℃时加入B相、C相、D相、E相，搅拌(搅拌速度为200r/min)分散均匀后出料。
对比例5：一种家居洗涤剂，与实施例5基本相同区别在于：所采用的水为去离子水
分别对本发明实施例1-5所得的家居洗涤剂以及对比例1-5所得的家居清洗剂进行性能测试，测试名称为人工洗涤破片法。具体的测试方法如下：
准备50片直径50mm的小圆玻片，每片上用微量移液管移取0.8ml加有红色色素熔融状态下的猪油，稍移转动，便成均匀薄层，搁置过夜加以老化。选两大小适宜的玻璃容器作为洗玻片容器，分别盛清水和备用洗涤液(洗涤液配制1000ml含餐洗0.25％)。控制温度在30±1℃时洗涤，用一块泡沫塑料迅速地洗涤小玻片，在薰一下清水，以三块玻片为一组，排列观察。当你无论如何用力也洗不清这一组玻片时，即为终点。通过洗涤的组数来判断洗涤剂的洗涤能力，洗涤组数越少，说明洗涤能力越好。具体实验结果见下表2：
表2
由结果可见使用小分子团水作为溶剂，洗涤能力比使用去离子水作为溶剂要普遍较好。
表3实施例1-3和对比例1-3的配方组成
表4实施例4-5和对比例4-5的配方组成
以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明，不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干简单推演或替换，都应当视为属于本发明的保护范围。
Claims (10)
1.一种以电解方式生产小分子团水的方法，其特征在于，包括以下几个步骤：
步骤A：将电气石、铅球和去离子水按一定质量比混合均匀，在球磨机中球磨；
步骤B：将所得原料干燥，研磨备用；
步骤C：将球磨后的电气石添加到去离子水中，过滤静置取上清液得到小分子团水。
2.如权利要求1所述的方法，其特征在于，所述步骤A中，所述电气石、铅球和去离子水的质量比为2:47:10-4:47:10；球磨时间为1.5-2.5小时。
3.如权利要求1所述的方法，其特征在于，所述步骤B中，干燥时间为78-82℃，时间为7.5-8.5小时。
4.如权利要求1所述的方法，其特征在于，所述步骤C中，电气石以质量分数为2.5-3.5％添加到去离子水中，静置时间为8-10分钟。
5.一种家居洗涤剂，其特征在于，按质量浓度包括：表面活性剂15％-40％，增稠剂1.0％-8％，螯合剂0％-0.15％，多元醇2-8％，香精0.2-0.6％，碱性蛋白酶1.0％-5％，防腐剂0.05％-0.5％，余量为如权利要求1所制得的小分子团水。
6.如权利要求5所述的家居洗涤剂，其特征在于，所述表面活性剂采用十二烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、十二烷基硫酸钠、癸基葡萄糖、月桂酰基氨酸钠、椰油酰胺丙基甜菜碱中的至少一种；所述增稠剂为氯化钠、椰油酰单乙醇胺、氨基酸增稠剂中的至少一种；所述螯合剂为乙二胺四乙酸二钠；所述多元醇采用乙醇、甘油、1,3丙二醇、1，2己二醇中的至少一种；所述防腐剂采用对羟基苯乙酮、DMDM乙内酰脲、甲基异噻唑啉酮、苯氧乙醇中的至少一种。
7.如权利要求5所述的家居洗涤剂，其特征在于，所制得的洗涤剂的酸碱值为9-11。
8.一种制备如权利要求5所述的家居洗涤剂的制备方法，包括以下步骤：
步骤(1)：将A相加热至82-85℃，保温搅拌20-40分钟，搅拌至溶解完全。
步骤(2)：降温至35-45℃。
步骤(3)：加入B相、C相、D相、E相搅拌溶解完全，出料；
其中A相为表面活性剂、增稠剂、螯合剂，B相为多元醇，C相为碱性蛋白酶，D相为香精，E相为防腐剂。
9.如权利要求8所述的方法，其特征在于，所述步骤(1)中加热温度为82-85℃，搅拌时间为25-30分钟。
10.如权利要求8所述的方法，其特征在于，所述步骤(1)和步骤(3)中搅拌速度为150-200r/min。
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