CN106883896A - Terahertz emission material and its preparation method and application - Google Patents
Terahertz emission material and its preparation method and application Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
Abstract
The present invention relates to energy and environment field, specifically, the invention discloses a kind of terahertz emission material and its preparation method and application.The terahertz emission material is made up of plurality of raw materials, plurality of raw materials count by weight including：0.01 0.1 parts of 30 85 parts of silicon dioxide powder, 5 30 parts of aluminium oxide powder, 1 20 parts of ferric oxide powder, 1 15 parts of zirconium compounds powder, 1 10 parts of potassium oxide powder and rare earth oxide.Specifically preparation method is：After plurality of raw materials powder is mixed, at 500 1800 DEG C, sintering is obtained.The radiative material has terahertz emission high, can send THz wave, causes the resonance of the molecule in fuel molecule or hydrone, reduces activation energy, promotes the generation of reaction.It is applied to fuel oil, it is possible to increase efficiency of combustion；Running water is applied to, can be purified water.
Description
Technical field
The present invention relates to energy and environment field, in particular to a kind of terahertz emission material and preparation method thereof
And application.
Background technology
Today's society occurs in that many energy and environment problems.For example, energy-saving and emission-reduction are exactly world today's energy scarcity
One of task of top priority.And the efficiency of combustion of fuel oil directly affects the effect of energy-saving and emission-reduction.The efficiency of combustion of fuel oil exists with fuel oil
Combustion process in internal combustion engine is closely related, either gasoline or diesel oil, and fuel oil atomization quality before combustion determines it
Whether burning is abundant, so as to have impact on efficiency of combustion.It is that fuel thing occurs the chemical reaction of some row with oxygen during fuel combustion.
According to gas molecule motion theory, chemical reaction is caused because the molecule of reactive material is mutually collided, but
It is that within the unit interval, each molecule is many with the chance of the collision of other molecules, can be reached tens times per second.Such as
The collision each time of fruit molecule can react, then even if in the case of low temperature, no matter what reaction can be
Complete in a flash.But true really not so, chemical reaction is carried out with limited rate chemistry, i.e., not every point
Son can be collided and chemically reacted.And only have the collision between " activation " molecule could to chemically react.
In the prior art, burnt to improve or strengthen using some reaction units that can produce electronics, ion or neutral particle,
Enable that fuel oil fully burns, so as to reduce the discharge of nuisance, reach the purpose of energy-saving and emission-reduction.But these apparatus structures
Complexity, it is expensive, and the effect for obtaining is poor, so that fuel oil cannot fully burn, energy-saving and emission-reduction turn into one always
Hang-up.
Other problems on the energy and environment, such as water pollution problems causes running water severe contamination, when the mankind need
When wanting drinking water, it has to carry out purified treatment to running water.And the equipment and technique that existing purification running water is spent
It is numerous and diverse and costly, and the effect for obtaining is unsatisfactory.How environmental protection and effectively purified water, also as a great problem.
The content of the invention
It is an object of the invention to provide a kind of terahertz emission material, the radiative material has terahertz emission high
Property, THz wave can be sent, cause the resonance of fuel molecule or hydrone, activation energy is reduced, promote the generation of reaction.
Another object of the present invention is to provide a kind of preparation method of terahertz emission material, the method is simple to operate,
Obtained terahertz emission material, terahertz emission is high, can be resonated with fuel molecule or hydrone, reduces activation
Energy.
Another object of the present invention is to provide a kind of terahertz emission material in activation of fuel oil molecule or hydrone
Using.
In order to realize above-mentioned purpose of the invention, spy uses following technical scheme：
A kind of terahertz emission material, the terahertz emission material is made up of plurality of raw materials, counts by weight, Duo Zhongyuan
Material includes：Silicon dioxide powder 30-85 parts, aluminium oxide powder 5-30 parts, ferric oxide powder 1-20 parts, zirconium compounds powder 1-15
Part, 1-10 parts and rare earth oxide 0.01-0.1 parts of potassium oxide powder.
A kind of preparation method of terahertz emission material：
Plurality of raw materials is mixed, mixture of powders is obtained, plurality of raw materials includes silicon dioxide powder 30-85 parts, three oxidations two
Aluminium powder 5-30 parts, ferric oxide powder 1-20 parts, 1-15 parts of zirconium compounds powder, 1-10 parts of potassium oxide powder and rare earth oxide
0.01-0.1 parts；
Under anaerobic state, mixture of powders is sintered.
Application of the above-mentioned terahertz emission material in activation of fuel oil molecule or hydrone.
Compared with prior art, beneficial effects of the present invention are：
A kind of terahertz emission material that the present invention is provided and preparation method thereof, the terahertz emission material is by plurality of raw materials
Be made, plurality of raw materials count by weight including：Silicon dioxide powder 30-85 parts, aluminium oxide powder 5-30 parts, di-iron trioxide
Powder 1-20 parts, 1-15 parts of zirconium compounds powder, 1-10 parts and rare earth oxide 0.01-0.1 parts of potassium oxide powder.Specific preparation side
Method is：After plurality of raw materials powder is mixed, under anaerobic state, sintering.The terahertz emission material can send THz wave,
It can cause fuel molecule to resonate, and reduce activation energy, so as to break up the macromolecular reunited in fuel oil, reduce viscosity and surface
Power, makes it be converted into smaller liquid particle consequently facilitating uniformly mixing with oxygen.Improve efficiency of combustion, reach cleaning of off-gas,
The purpose of energy-conservation, lifting power.The THz wave that the terahertz emission material is produced can occur altogether with the particle in running water
Shake, form H3O+Bioactive molecule, so that impurity, dirt in having adsorbed running water, have purified water quality.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the present invention.It is unreceipted specific in embodiment
Condition person, the condition advised according to normal condition or manufacturer is carried out.Agents useful for same or the unreceipted production firm person of instrument, are
The conventional products that can be obtained by commercially available purchase.
The present embodiment provides a kind of terahertz emission material：
The terahertz emission material is made up of plurality of raw materials, counts by weight, and plurality of raw materials includes：Silicon dioxide powder
30-85 parts, aluminium oxide powder 5-30 parts, ferric oxide powder 1-20 parts, 1-15 parts of zirconium compounds powder, 1-10 parts of potassium oxide powder
And rare earth oxide 0.01-0.1 parts.
Terahertz emission refers to frequency from 0.1 Terahertz to 10 Terahertzs, and wavelength is between millimeter wave and infrared ray
Electromagnetic radiation region.THz wave is a kind of electromagnetic wave, is a kind of particle for being called quantum in quantum physics.THz wave
There is corpuscular property and fluctuation simultaneously, it is the root of profound influence material and life entity.Fluctuation brings material and life entity
Energy of electromagnetic field, makes molecule, atom produce covibration, thus changes the property of material or it is generated heat；THz wave
Corpuscular property makes the quantum such as free electron, the cation in metal and semiconductor produce conflict, and produces electron waves, forms micro- electricity
, influence the characteristic of material.All substances all with constitute it molecule, atom grid vibration, and with identical frequency occur
Resonance, absorbs and radiates THz wave.The various Terahertzs such as tellurian rock, microorganism or planet and the moon are put
Beam is all radiating THz wave.
According to the theory of quantum physics, in general, the Wave energy such as electromagnetic wave and molecule, atom, electronics or atom
The intrinsic frequency that the movement of core, revolution, the flexible, intrinsic frequency of expansion and the grid between atom or molecule vibrate occurs altogether
Absorbed after shaking and radiated again.
Fluent material, the adhesion between its molecule or atom is weaker, and grid vibration is easier to hair with the side of molecular vibration two
Raw resonance, is conducive to preferably absorbing, preserves and radiate THz wave again.
Therefore, terahertz emission material is used for the fuel oil of automobile, terahertz emission material can to send THz wave, its
Fuel molecule can be caused to resonate, reduce activation energy, so as to break up the macromolecular reunited in fuel oil, reduce viscosity and surface
Power, makes it be converted into smaller liquid particle consequently facilitating uniformly mixing with oxygen.Improve efficiency of combustion, reach cleaning of off-gas,
The purpose of energy-conservation, lifting power.
Terahertz emission material is used for running water, similarly, terahertz emission material can send THz wave so that
Hydrone resonates with terahertz emission material, forms H3O+Bioactive molecule, so that impurity, dirt in adsorbing running water,
Water quality is purified, and then has been beneficial to health.
Further, the THz wave that terahertz emission material sends also can act on solid material.Solid is due to it
Atom is stronger with the adhesion of molecule, and can be vibrated by grid carries out RESONANCE ABSORPTION.For example by terahertz emission materials application
In soil, now, THz wave also can act on the lattice of other molecules in soil, be resonated with it such that it is able to
Activation energy is reduced, the effect that can improve soil property is reached, and then be conducive to environmental protection.
This that a large amount of THz waves are absorbed because of covibration, the solid matter of concurrent biomass denaturation has can make confusion
Crystal structure become regular so that the effect of enhancing material script property.In addition, occurring in the case of material is liquefied
Carbon adhesion is slowed by, and gasification then occurs that the polarity and reactivity of molecule become strong tendency.When terahertz emission material is made
For automobile fuel oil when, enable to automobile fuel molecule be in " stimulated radiation " state, the fuel oil in excited state
Molecule can transit to lower level, and then cause that the collision between fuel molecule is more violent so that the combustion reaction of fuel oil
More fully, and then the utilization rate of fuel oil is improve, has saved the energy.
In preferred embodiments of the present invention, by weight, above-mentioned silicon dioxide powder is 50-80 parts, alundum (Al2O3)
Powder is 10-20 parts, ferric oxide powder is 3-10 parts, zirconium compounds powder is 2-8 parts, potassium oxide powder is 1-7 parts and rare earth oxygen
Compound 0.06-0.1 parts.
Silicon dioxide powder, aluminium oxide powder, ferric oxide powder, the zirconium powder used in above-mentioned terahertz emission material
And potassium oxide powder is oxide, wherein silicon dioxide powder is nonmetal oxide, and remaining several raw material is metallic element oxygen
Compound, when these metal oxides are fired together, can effectively discharge terahertz emission higher.Above-mentioned choosing
Several oxides, also as prove that above-mentioned several materials mutually can produce synergy by compatibility by substantial amounts of experiment,
Work in coordination, strengthen the terahertz emission performance of terahertz emission material.Meanwhile, above-mentioned several oxide raw materials only exist
Synergy can be produced with other raw materials in scope described in the present invention, if recorded higher or lower than the present invention
Scope, then can not produce synergy, can only play each raw material individually original performance, it is impossible to enough strengthen terahertz emission
The terahertz emission performance of material.
It should be noted that above-mentioned zirconium compounds powder includes zirconium oxide, zirconium carbide or zirconium boride.Above-mentioned rare-earth oxidation
Thing include ytterbium oxide, luteium oxide, neodymia, erbium oxide, thulium oxide, samarium oxide, oxidation roll, europium oxide or terbium oxide.
Preferably, the raw material of above-mentioned ore powder selects the silicate mineral of natural deep layer, such as basalt, andesite, stone
English diabase etc..
Andesite, basalt, quartz diorite etc. can send THz wave, and its emissivity is about 0.8 or so, in belonging to
Etc. degree.
Basaltic Main Ingredients and Appearance is silica, alundum (Al2O3), iron oxide, calcium oxide, magnesia, wherein titanium dioxide
Silicone content at most, accounts for 45 to 50 or so percent.
SiO in andesite2Changes of contents is larger (52~63%), and average content is 58.17%.98.5% andesite
SiO2, there is normative mineral quartz in supersaturation (more less than 15%).Andesite presses SiO2Content can be divided into two kinds：Containing 52~57%
Be basaltic andesite；It is andesite containing 57~63%, belongs to calc-alkaline.
The mineral composition of Ban Zhuanyan mainly has pyroxene, quartz, hornblend, biotite.Main chemical compositions are SiO265~
71%, Al2O315.5~18.6%, next Fe2O3, CaO below 3~5%, separately have Na2O、K2O is 1~3%, and on a small quantity
TiO2、P2O5、Mn2O3Below 1%.Walked back and forth with the chequered with black and white outward appearance of its texture and gained the name such as rice grain.Proportion 2.60~
2.66, hardness 5~6, its outward appearance is beautiful, and typically with black, red, grey foundation stone, surface distribution the white plagioclase such as the grain of rice
Stone grain point.Through long-time weathering, the variable formation into spongiosa porous material of rock matter has strong adsorption, and in water easily
It is molten to disengage the characteristics such as micro mineral matter element.
The silicate mineral of above-mentioned these natural deep layers, itself can radiate terahertz emission, when above-mentioned these originals
During material synergy, the terahertz emission performance of overall terahertz emission material can be more excited.
Preferably, the raw materials by weight portion meter of terahertz emission material also includes：1-5 parts of activated carbon powder.
Activated carbon is a kind of porous solid carbonaceous of black, by coal by crush, shaping or with uniform coal grain through carbonize,
Activation production.Main component is carbon, and containing elements such as a small amount of oxygen, hydrogen, sulphur, nitrogen, chlorine.The specific surface area of normal activated carbon is 500
~1700m2Between/g.It is a kind of extremely wide industrial adsorbents of purposes with very strong absorption property；It is also urging in chemical industry
Agent and catalyst carrier.In the present embodiment, activated carbon can further improve above-mentioned ore powder as catalyst carrier
Reaction in melting process, further enhances the terahertz emission performance of terahertz emission material.
It is highly preferred that the raw materials by weight portion meter of terahertz emission material also includes：Powder 1-5 parts of radiative material.
Further, it is preferable to ground, radiative material is tourmaline or spinelle.
Tourmaline has a radiance, piezoelectricity, induces the characteristics such as anionic property and pyroelectric, is a kind of healthy ring
The multifunctional material of guarantor.Tourmaline is a kind of boracic, the mineral of fluorine ring silicate type, and its chemical composition is more complicated.
Tourmaline exists and there is electrostatic field phenomenon around spontaneous electrode phenomenon and tourmaline, with very strong radiativity.In addition, China stores up
There is abundant tourmaline resource so that the cost for being used as radiative material using tourmaline is relatively low.
Due to silicate mineral, the THz wave that andesite, such as basalt, quartz diorite send, its emissivity is about
It is 0.8 or so, belongs to moderate, and mineral tourmaline material can prepare the raw material of radiative material after crushing processing,
Its compound preparation with other materials can effectively excitation material radiativity so that after further improving melting mixing too
The radiance of Hertzion radiation material.Adding spinelle can make emissivity reach 9.5.
Similarly, the radiance stabilization of spinelle, especially good to Ferrite Material infrared radiation property, often application
In energy-conserving and environment-protective field.In terahertz emission material, add spinelle as radiative material, can effectively excite it to radiate
Terahertz emission ripple, and then effect of the terahertz emission material to fuel molecule is improved, so as to reach the effect of energy-saving and emission-reduction.
The present embodiment also provides a kind of preparation method of terahertz emission material, including：
S1, by above-mentioned silicon dioxide powder 30-85 parts, aluminium oxide powder 5-30 parts, ferric oxide powder 1-20 parts, zirconium
1-15 parts of compound powder, the 1-10 parts and rare earth oxide 0.01-0.1 parts mixing of potassium oxide powder, obtain mixture of powders.
Further, powder 1-5 parts, 1-5 parts of activated carbon powder of radiative material are added in above-mentioned mixture of powders.And
Mixture of powders is sieved, the mesh number of sieving is 100-200 mesh.Particle diameter enables to this several between 100-200 mesh
The mixing of raw material is more uniform, so that for follow-up preparation technology flow provides effective guarantee.
S2, under anaerobic state, mixture of powders is sintered, obtain sintered body.
Preferably, sintering temperature is 500-1800 degrees Celsius, it is highly preferred that sintering temperature is 1600 degrees Celsius.
The selection of sintering temperature should guarantee all to melt raw material, and make it fully anti-in the molten state
Should.Too low sintering temperature, it is impossible to enough reach the melting point of raw material, it is impossible to so that raw material carries out frit reaction, and too high burning
Junction temperature, easily causes the waste of resource so that manufacturing cost increases.When sintering temperature is 500-1800 degrees Celsius, Neng Gouyou
Effect ground ensures the melting of raw material, it is fully reacted, and reaches and good founds effect.It is highly preferred that when sintering temperature is 1600
Degree Celsius when, can reach and preferably found effect, and saving energy consumption.
Further, in this embodiment, it is preferred that, sintering time be 10-20 hours.It is highly preferred that sintering time is
16 hours.Sintering time ensure that the abundant reaction of raw material and the clarification of follow-up fused solution, therefore ensure enough burnings
The knot time is very necessary.But sintering time too long not only results in the volatilization of raw material, and waste of resource, increase production
Cost.When sintering time is 10-20 hours, ensure that raw materials melt reaction is abundant, and the time foot that fused solution is clarified
It is enough；It is highly preferred that when sintering time is 16 hours, raw material reaction can not only be caused fully, the fused solution of clarification is obtained, and
Being capable of further saving energy consumption, reduces cost.
It should be noted that the form of sintered body obtained above is unfixed, can process according to the actual needs
Into powder, sheet and other irregular solid shapes, so as to be used in conjunction with each other with corresponding treatment place.
Above-mentioned terahertz emission material and preparation method thereof, using silica, alundum (Al2O3), di-iron trioxide,
Zirconium compounds, potassium oxide and rare earth oxide are used as raw material, and preparation method is simple and easy to apply, cooperate mutual 5 between each raw material,
So that the terahertz emission performance enhancement of above-mentioned terahertz emission material, preferably can resonate with fuel molecule, make
Obtain fuel oil fully to burn, reach the effect of energy-saving and emission-reduction.
The present embodiment also provides a kind of application of terahertz emission material in activation of fuel oil molecule or hydrone.
Specifically, the pipeline or container for terahertz emission materials application being passed through in fuel oil, activation of fuel oil molecule are improved
Fuel efficiency；In the pipeline or container that terahertz emission materials application is passed through in running water, hydrone and terahertz emission
Material resonates, and forms H3O+Bioactive molecule, so that impurity, dirt in adsorbing running water, have purified water quality.
Further, when by above-mentioned terahertz emission materials application in automobile so oil, it is preferable that by terahertz emission material
Material is made sheet or powder, is installed on the pipeline or container of fuel oil process, and it preferably can occur altogether with fuel molecule
Shake, so as to reduce the activation energy of fuel molecule, and then break up the macromolecular reunited in fuel oil, reach reduction viscosity and surface tension
Effect so that fuel molecule is converted into smaller liquid particle, consequently facilitating uniformly mix with oxygen, improves efficiency of combustion.
It should be understood that it is above-mentioned by terahertz emission materials application in fuel oil or water, should be not limited to it is above-mentioned both, herein only
It is for easy, the exemplary description made of description.The terahertz emission material that the present invention is provided, acts on all materials.
All materials mentioned here refer to, its composition is that, by molecule or atomic building, and its molecule or atom can be sent out
Raw vibration.When the terahertz emission material for providing the present invention, when acting on this material, molecule, the original of this material are constituted
Son can absorb the THz wave of terahertz emission material release provided by the present invention, and make the molecule or original of this material
The lattice of son is resonated with identical frequency, so that original activation energy between reducing particle, promotes the generation of reaction.
Embodiment 1
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 50g, aluminium oxide powder 10g, ferric oxide powder 3g, carbonization zirconium powder 2g, potassium oxide powder 1g, work
Property powdered carbon material 1g, tourmaline 1g, neodymia 0.01g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 100 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 500 DEG C, sinter 10 hours.Terahertz emission material is obtained.
Embodiment 2
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 80g, aluminium oxide powder 20g, ferric oxide powder 10g, titanium dioxide zirconium powder 8g, potassium oxide powder
7g, tourmaline 5g and ytterbium oxide 0.1g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1800 DEG C, sinter 20 hours.Terahertz emission material is obtained.
Embodiment 3
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 55g, aluminium oxide powder 12g, ferric oxide powder 4g, boronation zirconium powder 3g, potassium oxide powder 2g, point
Spar 1g, luteium oxide 0.06g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1600 DEG C, sinter 16 hours.Terahertz emission material is obtained.
Embodiment 4
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 75g, aluminium oxide powder 18g, ferric oxide powder 8g, boronation zirconium powder 7g, potassium oxide powder 6g, point
Spar 5g, erbium oxide 0.01g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1600 DEG C, sinter 16 hours.Terahertz emission material is obtained.
Embodiment 5
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 60g, aluminium oxide powder 15g, ferric oxide powder 5g, titanium dioxide zirconium powder 5g, potassium oxide powder 5g,
Tourmaline 4g, terbium oxide 0.01g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1200 DEG C, sinter 15 hours.Terahertz emission material is obtained.
Embodiment 6
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 56g, aluminium oxide powder 13g, ferric oxide powder 6g, carbonization zirconium powder 6g, potassium oxide powder 1g, point
0.02g is rolled in spar 3g, oxidation.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1500 DEG C, sinter 10 hours.Terahertz emission material is obtained.
Embodiment 7
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 57g, aluminium oxide powder 14g, ferric oxide powder 6g, titanium dioxide zirconium powder 6g, potassium oxide powder 4g,
Tourmaline 3g, europium oxide 0.03g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 200 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1500 DEG C, sinter 20 hours.Terahertz emission material is obtained.
Embodiment 8
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 56g, aluminium oxide powder 15g, ferric oxide powder 6g, titanium dioxide zirconium powder 6g, potassium oxide powder 1g,
Spinelle 3g, samarium oxide 0.04g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 100 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1600 DEG C, sinter 10 hours.Terahertz emission material is obtained.
Embodiment 9
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 30g, aluminium oxide powder 5g, ferric oxide powder 1g, titanium dioxide zirconium powder 1g, potassium oxide powder 1g,
Spinelle 3g, thulium oxide 0.06g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 100 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 500 DEG C, sinter 10 hours.Terahertz emission material is obtained.
Embodiment 10
The present embodiment provides a kind of terahertz emission material, and the raw materials by weight portion meter of the radiative material mainly includes：
Silicon dioxide powder 85g, aluminium oxide powder 30g, ferric oxide powder 20g, titanium dioxide zirconium powder 15g, potassium oxide powder
10g, spinelle 3g, rubidium oxide 0.1g.
The preparation method of the radiative material is：Above-mentioned raw materials are ground, 100 mesh sieves are crossed, after being then well mixed, in anaerobic
Under state, at 1800 DEG C, sinter 10 hours.Terahertz emission material is obtained.
Experimental example 1
The terahertz emission material provided the embodiment of the present invention 1 with reference to automobile emission gas analyzer experiment is improving vapour
The effect for using in the efficiency of combustion of car fuel is evaluated.
Testing program
Terahertz emission material provided in an embodiment of the present invention is used in the oil burning installation of automobile.To Terahertz is not used
The vehicle fuel waste gas of radiative material and it is collected respectively using the vehicle fuel waste gas after terahertz emission material, and point
It is other that detection contrast is carried out to two groups of concentration of waste gas.It should be noted that the data in upper table, wherein test for the first time is in peace
Tested after 1 month after dress, second test is the various waste gas in 20 days vehicle exhausts of test after first time tests
Concentration value.Specific result see the table below：
Table 1 adds concentrations versus' table (mg/m of discharge waste gas before and after terahertz emission material3)
As can be seen that after being mounted with terahertz emission material, after one month, the concentration of CO reduces 4.6%-6.5%,
CO2Concentration slightly have growth, but increasing value only only has 0.15%-1.51%, the concentration of THC reduces 7.41%-16%,
And NOXConcentration greatly reduced, be 63-81%；CH4Concentration reduce 11-50%, the concentration reduction of NMHC
2.1%-6.67%, PM values slightly increase, but only increase 12.71%-21.5%.
Further, second detection for being carried out after being separated by 20 days with first time test, the concentration of CO is reduced
25.87%-27%, CO2Concentration reduce 1.68%-2.01%, the concentration of THC reduces 24.07%-61%, and NOX
Concentration reduce 72.53%-84.61%；CH4Concentration reduce 22.22%-55.56%, the concentration of NMHC is reduced
The concentration of 24.44%-46.67%, PM reduces 17.98%-18.34%.
As can be seen that after having used terahertz emission material, the concentration of automotive exhaust is substantially reduced, i.e. Terahertz spoke
Penetrating material can effectively improve the efficiency of combustion of fuel.
Experimental example 2
The terahertz emission material provided the embodiment of the present invention 2 with reference to purification water test is improving activation moisture
Son, the using effect in purification running water is evaluated.
Testing program
Terahertz emission material provided in an embodiment of the present invention is used in water supplying unit.To terahertz emission material is not used
Running water and be collected detection respectively using the running water after terahertz emission material, and respectively to the grain in two groups of running water
Son carries out detection contrast.It should be noted that the data in upper table, wherein test for the first time is to be tested after 1 month after mounting, the
Second test is the mass percent of the various particles in 20 days running water of test after first time tests.Specific result see the table below：
Particle contrast table (%) in running water before and after the addition terahertz emission material of table 2
As can be seen that after being mounted with terahertz emission material, after one month, the content of impurity and dirt is occurred in that substantially
Reduction, wherein, H3O+The content of bioactive molecule increases more than 99%, and impurity reduces 34%-64%, and dirt is reduced
58%-66%.The particle in the THz wave and running water of the generation of terahertz emission material is primarily due to, is resonated, shape
Into H3O+Bioactive molecule, so that impurity, dirt in having adsorbed running water, have purified water quality.
Further, second detection for being carried out after being separated by 20 days with first time test, impurity reduces 97%-
99.3%, dirt reduces 98%-99%.
As can be seen that after having used terahertz emission material, H in running water3O+The content showed increased of bioactive molecule, it is miscellaneous
Matter and sludge content are significantly reduced, i.e., terahertz emission material can effectively purify water.
In sum, a kind of terahertz emission material that the present invention is provided and preparation method thereof, the terahertz emission material
By silicon dioxide powder, aluminium oxide powder, ferric oxide powder, zirconium compounds, potassium oxide and rare earth oxide, after mixing,
Under anaerobic state, sintering obtains sintered body, and sintered body is clayed into power prepared terahertz emission material.The terahertz emission
Material can send THz wave, and it can cause fuel molecule to resonate, and reduce activation energy, so as to break up reunite in fuel oil big
Molecule, reduces viscosity and surface tension, it is converted into smaller liquid particle consequently facilitating uniformly mixing with oxygen.Improve combustion
Efficiency is burnt, cleaning of off-gas, energy-conservation, the purpose of lifting power is reached.The THz wave that the terahertz emission material is produced can be with
Particle in running water, resonates, and forms H3O+Bioactive molecule, so that impurity, dirt in having adsorbed running water, purification
Water quality.
Although it should be understood that being illustrated with specific embodiment and describing the present invention, but will be appreciated that without departing substantially from this hair
Many other changes and modification can be made in the case of bright spirit and scope.It is, therefore, intended that will in appended right
Ask including belonging to all such changes and modifications in the scope of the invention.
Claims (10)
1. a kind of terahertz emission material, it is characterised in that the terahertz emission material is made up of plurality of raw materials, by weight
Number meter, the plurality of raw materials includes：Silicon dioxide powder 30-85 parts, aluminium oxide powder 5-30 parts, ferric oxide powder 1-20
Part, 1-15 parts of zirconium compounds powder, 1-10 parts and rareearth oxidate powder 0.01-0.1 parts of potassium oxide powder.
2. terahertz emission material according to claim 1, it is characterised in that count by weight, the silica
Powder is 50-80 parts, the aluminium oxide powder is 10-20 parts, the ferric oxide powder is 3-10 parts, the zirconium compounds powder
For 2-8 parts, the potassium oxide powder are for 1-7 parts and described rareearth oxidate powder 0.06-0.1 parts.
3. terahertz emission material according to claim 1 and 2, it is characterised in that count by weight, various originals
Material also includes：1-5 parts of activated carbon powder.
4. terahertz emission material according to claim 3, it is characterised in that count by weight, the plurality of raw materials
Also include：Powder 1-5 parts of radiative material.
5. terahertz emission material according to claim 4, it is characterised in that the radiative material is tourmaline or point
Spar.
6. a kind of preparation method of terahertz emission material, it is characterised in that including：
Plurality of raw materials is mixed, mixture of powders is obtained, the plurality of raw materials includes silicon dioxide powder 30-85 parts, three oxidations two
Aluminium powder 5-30 parts, ferric oxide powder 1-20 parts, 1-15 parts of zirconium compounds powder, 1-10 parts of potassium oxide powder and rareearth oxidate powder
0.01-0.1 parts；
Under anaerobic state, the mixture of powders is sintered.
7. the preparation method of terahertz emission material according to claim 6, it is characterised in that the plurality of raw materials is also wrapped
Include powder 1-5 parts, 1-5 parts of activated carbon powder of radiative material.
8. the preparation method of terahertz emission material according to claim 7, it is characterised in that to the mixture of powders
Sieved before being sintered, the mesh number of sieving is 100-200 mesh.
9. the preparation method of terahertz emission material according to claim 6, it is characterised in that sintering temperature is 500-
1800 degrees Celsius, sintering time is 10-20 hours.
10. application of a kind of terahertz emission material as claimed in claim 1 in activation of fuel oil molecule or hydrone.
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