CN109679246B - Terahertz coupling anion material energy-saving card sheet and production method thereof - Google Patents
Terahertz coupling anion material energy-saving card sheet and production method thereof Download PDFInfo
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- CN109679246B CN109679246B CN201811555623.XA CN201811555623A CN109679246B CN 109679246 B CN109679246 B CN 109679246B CN 201811555623 A CN201811555623 A CN 201811555623A CN 109679246 B CN109679246 B CN 109679246B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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Abstract
The invention belongs to the technical field of functional sheets, and particularly relates to a terahertz coupling anion material energy-saving card sheet and a production method thereof. The raw materials comprise the following components in percentage by mass: 25% -60% of functional powder material; 36% -70% of PVC polyvinyl chloride resin; 3% -5% of an auxiliary agent; 1 to 1.5 percent of pigment. The terahertz coupled anion material energy-saving card sheet has the advantages of water resistance, ultrathin property, flexibility, high energy and more scientific function, and is a high-efficiency, electricity-saving and oil-saving product. The production method of the terahertz coupled anion material energy-saving card sheet adopts a continuous and efficient environment-friendly production process, and has the advantages of stable quality, higher energy, convenience in installation and convenience in efficient industrialization.
Description
Technical Field
The invention belongs to the technical field of functional sheets, and particularly relates to a terahertz coupling anion material energy-saving card sheet and a production method thereof.
Background
Energy conservation and emission reduction are basic national policies and are the permanent subjects of human social development, automobile fuel saving and electric appliance power saving are the most intuitive, outstanding and important fields of energy conservation and emission reduction benefits, and as for automobile fuel saving, a plurality of technical products are provided, but the technical products are fewer and have convenient application, stable performance, practicability and reliability.
Patent CN201610085914.1 discloses a nano negative ion electricity/fuel saving card, which is prepared by mixing 80 parts of negative ion powder with the particle size of 200 nm, 5 parts of tourmaline powder with the particle size of 20 nm, 10 parts of far infrared powder with the particle size of 55 nm, 3 parts of starch adhesive and 2 parts of dicumyl oxide cross-linking agent, stirring at high speed to prepare negative ion slurry with stable viscosity, attaching the negative ion slurry between two layers of hard plastic plates, then hot pressing at high temperature of 120 ℃ for 5 minutes, cooling and preparing into a card.
In terms of the manufacturing process of the product of the above publication, 95 parts (80 parts of anion powder +5 parts of tourmaline +10 parts of infrared powder) of functional powder can ensure the generation of anions and far infrared rays, which should be realized, but the following problems are undoubtedly existed:
(1)3 parts of starch adhesive and 2 parts of cross-linking agent, especially the adhesive accounts for too little proportion in the solid film-forming material of the total composition to be formed or the adhesive strength can not be ensured after forming, just as if the cement is too little and the sand is too much.
(2) Starch is adopted to be bonded with two layers of plastic plates under hot pressing, the peeling strength is very low, common plastics are anti-sticking materials, the starch is difficult to obtain good adhesive force and is easy to crack, and the starch is a rewetting material and is easy to rewet when meeting water. The water in the pulping process cannot be volatilized but remains in the tabletting, so the water resistance is poor, and the application range of the product is limited.
(3) Because the intermittent working procedure of the hot press molding in the process of mixing the pulping and the two-layer plastic is adopted, a continuous and efficient production process is difficult to form in the production.
In view of the above, there is a need to develop an energy-saving card sheet made of terahertz coupled anion material to meet the above requirements.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides a terahertz coupling anion material energy-saving card sheet. The sheet is waterproof, ultrathin, flexible, high-energy, convenient to install and more scientific in function, and is a high-efficiency electricity-saving and oil-saving product; the invention also provides a preparation method thereof.
The terahertz coupling anion material energy-saving card sheet comprises the following raw materials in parts by mass:
wherein:
the functional powder material is composed of a terahertz crystal material and an anion inducing material.
The functional powder material comprises the following raw materials in parts by mass:
the auxiliary agent consists of a plasticizer, a heat stabilizer, an antioxidant, an anti-aging agent and calcium stearate.
The plasticizer is preferably ACS-186, the heat stabilizer is preferably YP-728, the antioxidant is preferably LG-70S, and the anti-aging agent is preferably W-16.
The pigment is one of titanium blue, carbon black or titanium green.
The particle size of the functional powder material powder is less than or equal to 3000 meshes, and the water content is less than or equal to 3 percent.
The production method of the terahertz coupled anion material energy-saving card sheet is characterized in that a functional powder material, PVC polyvinyl chloride resin, an auxiliary agent and pigment are prepared into a functional coiled material with the thickness of 0.3-1.2 mm and the width of 500-2000 mm for the energy-saving and oil-saving card by adopting a pressing-in method or an extrusion method.
The concrete process of the pressing method is as follows: a PVC four-roller pressing production line is adopted, the effective width is 2000mm, the prepared PVC polyvinyl chloride resin, the auxiliary agent, the pigment and the functional powder material are mixed according to the design proportion, the mixture is plasticized by an internal mixer, an open mill or a conveying mixing roll, the mixture is directly fed between rollers of the pressing machine after being combusted, the equipment operation temperature is 190-210 ℃, the mixture is calendered into a coiled material by a calender to carry out edge cutting and rolling, the material production thickness is selected from 0.3mm-1.2mm, the width is 500mm-2000mm, the length can be fixed according to the requirement, for example, the length is generally 100m-200m, and the slitting can be carried out within the width of 2000mm according to the requirement.
The extrusion method is realized on a plastic extrusion production line, and the specific process comprises the following steps: PVC polyvinyl chloride resin, an auxiliary agent, pigment and a functional powder material are mixed and then plasticized in an extruder, and the mixture is extruded into a blank plate from a slit machine head die by the extruder, and the blank plate is trimmed and rolled into a functional coiled material by a three-roll calender.
Although the two processing procedures are different, the performance of the functional coiled material is the same, compared with the processing yield of a calendering production line, the processing yield of the functional coiled material is higher, and 5-8 tons of functional coiled material can be produced by one single machine per work.
The production method of the terahertz coupled anion material energy-saving card sheet can realize high-efficiency automatic production such as printing of composite pressure-sensitive adhesive, automatic die cutting and the like on coiled materials.
If the produced functional coiled material has the thickness of 0.7mm and the width of 1200, a multicolor printer or a three-dimensional portrait printer can be used for continuous printing, then pressure-sensitive adhesive and release paper are coated on a pressure-sensitive adhesive coating compound machine (or the pressure-sensitive adhesive can not be coated for direct die cutting), then the die cutting is carried out on an automatic die cutting machine, the full-mechanization high-efficiency completion is realized, and the die cutting can be carried out by laser or mechanical die cutting.
The functional principle of the continuous production method of the terahertz coupled anion material energy-saving card sheet is explained as follows: the terahertz frequency is 100 GHz-10 THz, the wavelength is 0.03mm-3mm, the terahertz frequency is between microwave and infrared, the terahertz crystal functional powder has strong penetrability, THz radiation waves can be generated by terahertz crystal functional powder, THz radiation waves are coupled with electric fields emitted by negative ions to induce catalytic materials to act on fuel molecules, the negative polarization tendency and the like of the fuel molecules are caused, the principle of like polarity repulsion are adopted, the grouping changes the monopolymerization, the surface tension is reduced, the fuel molecules are better atomized, the surface area of the fuel is increased, the full combustion of the fuel is further achieved, the fuel efficiency is improved, the obvious fuel saving effect is achieved, the emission of harmful pollutants such as nitrogen oxides, hydrocarbons, carbon monoxide, PM2.5, TVOC and the like to the environment is reduced, and the fuel saving effect is about 10% -35%.
The electricity-saving principle is as follows: through the functional crystal material of the electricity-saving card, a negative ion electric field and a THz radiation field are formed around the electric wire of the electric appliance, so that the reactive loss caused by 'turbulent' harmful electromagnetic waves generated by the electric appliance is effectively eliminated, and the electricity-saving card has a remarkable electricity-saving effect particularly under the working condition that the electric load is unstable and fluctuates greatly.
Compared with the prior art, the invention has the following beneficial effects:
(1) the terahertz coupled anion material energy-saving card sheet has the advantages of water resistance, ultrathin property, flexibility, high energy and more scientific function, and is a high-efficiency, electricity-saving and oil-saving product.
(2) The production method of the terahertz coupled anion material energy-saving card sheet adopts a continuous and efficient environment-friendly production process, and has the advantages of stable quality, higher energy, convenience in installation and convenience in efficient industrialization.
Detailed Description
The present invention is further described below with reference to examples.
Example 1
The functional powder material described in this example 1 is composed of the following raw materials in parts by mass:
functional powder material: the grain diameter of the powder is less than or equal to 3000 meshes, and the water content is less than or equal to 3 percent.
The terahertz coupled anion material energy-saving card sheet described in this embodiment 1 comprises the following raw materials:
the functional sheet formula comprises: weight ratio (kg)
The functional sheet material of the invention with the color of the sapphire blue and the thickness of 0.8mm and the width of 1200mm is prepared by adopting a calendering production line, and the following technical indexes are measured:
releasing amount of negative ions: 45000.
② the infrared emissivity of 2-18um is 93%.
③ 0.03mm-2mm THz emissivity is 80%.
And oxygen index OI is more than or equal to 32.
And fifthly, no function change is caused after 24 hours of water soaking test.
Sixthly, the retention rate is more than or equal to 90 percent in 30000h functional test.
Example 2
The functional powder material described in this embodiment 2 is composed of the following raw materials in parts by mass:
functional powder material: the grain diameter of the powder is less than or equal to 3000 meshes, and the water content is less than or equal to 3 percent.
The terahertz coupled anion material energy-saving card sheet described in this embodiment 2 comprises the following raw materials:
the black functional sheet with the thickness of 0.5mm and the width of 1000mm is prepared by adopting an extrusion processing technology, and the following technical parameters are measured.
The release amount of negative ions is more than or equal to 36000.
② the infrared emissivity of 2-18um is 91%.
③ 0.03mm-2mm THz emissivity is 75%.
And oxygen index OI is more than or equal to 32.
And fifthly, no function change is caused after 24 hours of water soaking test.
Sixthly, the function retention rate is more than or equal to 90 percent when the test is carried out for 30000 h.
Example 3
The functional powder material described in this embodiment 3 is composed of the following raw materials in parts by mass:
functional powder material: the grain diameter of the powder is less than or equal to 3000 meshes, and the water content is less than or equal to 3 percent.
The terahertz coupling anion material energy-saving card sheet described in this embodiment 3 comprises the following raw materials:
preparing a green functional sheet with the thickness of 0.9mm and the width of 1000 by adopting a calendering production line, and measuring the following technical parameters:
the release amount of negative ions is more than or equal to 68000.
② 2.18 the infrared emissivity is 95.
③ the emissivity of 0.03mm-2mm THz is 92 percent.
And oxygen index OI is more than or equal to 32.
And fifthly, no function change is caused after 24 hours of water soaking test.
Sixthly, the retention rate is more than or equal to 90 percent in 30000h functional test.
Oil saving experiment:
according to the formula of the embodiment 1-3, the sapphire blue (titanium blue), black and titanium green functional sheets are respectively made into oil saving cards of 5.0 × 8.0cm, 5.0 × 9.0cm and 4.0 × 8.0cm, the cards are respectively stuck to the inner side of an oil tank or a km oil tank cover (door) according to the corresponding use amount of 1.6L, 2.0T, 3.0T, 4.0T and 5.0T gasoline cars and the discharge amount of 1, 2, 3, 4, 5 and 6 cards, and the actual test of 200 road test tests shows that the oil is saved by 15-35% compared with the average oil without sticking the cards and the emission is reduced by 45-55%.
The diesel vehicle test:
the three functional sheets of sapphire blue, black and green are respectively prepared: the fuel-saving cards with the length of 10 multiplied by 20cm, 15 multiplied by 20cm and 10 multiplied by 15cm respectively have 380 horsepower HOWO, European MANEST 6430 horsepower and 330 horsepower for Jinlong guests, 4, 5 and 4 cards are respectively stuck, the cards are stuck on a fuel tank to carry cargo and empty vehicles respectively to test for 1000km, and the average fuel saving is measured to be 18 to 31 percent.
And (3) power saving test:
the energy-saving cards 4.0 multiplied by 8.0cm, 5.0 multiplied by 1.0cm and 8 multiplied by 15cm prepared by the green functional sheet in the example 3 are respectively used for household and city application and factory application.
The household type air conditioner is pasted on 3 pieces of air conditioners, the pasting part of the lattice air conditioner in one circle (summer) is at the switch part, and the electricity is saved by 15 percent after the household type air conditioner is pasted with the card compared with the household type air conditioner without pasting the card.
The power of an elevator of an office building is 15kw, 2 cards are pasted on a switch contactor, and the electricity is saved by 21 percent compared with the average electricity of the elevator without sticking the cards after one month of operation.
5 welding machines are protected by 5kw of carbon dioxide in a welding workshop of a machinery factory, and 2 cards are pasted on each switch. The average power saving of the card sticking test is 26 percent after the card sticking test is carried out for one week under the same workload compared with the card not sticking test.
The terahertz coupled anion material energy-saving card is a novel high-tech subversive technology, can be widely applied to fuel saving and emission reduction in transportation and power saving in factories, cities and families, and becomes a novel global revolutionary energy-saving and emission-reducing most excellent technical product.
Claims (6)
1. The terahertz coupled anion material energy-saving card sheet is characterized in that: the raw materials comprise the following components in percentage by mass:
the functional powder material comprises the following raw materials in parts by mass:
2. the terahertz coupled anion material energy-saving card sheet as claimed in claim 1, wherein: the auxiliary agent consists of a plasticizer, a heat stabilizer, an antioxidant, an anti-aging agent and calcium stearate.
3. The terahertz coupled anion material energy-saving card sheet as claimed in claim 1, wherein: the pigment is one of titanium blue, carbon black or titanium green.
4. The production method of the terahertz coupled anion material energy-saving card sheet as claimed in claim 1, which is characterized in that: functional powder materials, PVC polyvinyl chloride resin, auxiliary agents and pigments are manufactured into functional coiled materials with the thickness of 0.3mm-1.2mm and the width of 500mm-2000mm for the electricity-saving and oil-saving card by adopting a pressing method or an extrusion method.
5. The production method of the terahertz coupled anion material energy-saving card sheet as claimed in claim 4, characterized in that: the concrete process of the pressing method is as follows: a PVC four-roller pressing production line is adopted, the effective width is 2000mm, the prepared PVC polyvinyl chloride resin, the auxiliary agent, the pigment and the functional powder material are mixed according to a design proportion, an internal mixer is used, an open mill or a conveying mixing roll is used for plasticizing, the plasticized PVC polyvinyl chloride resin, the auxiliary agent, the pigment and the functional powder material are directly fed between rollers of the pressing machine after being combusted, the equipment operation temperature is 190-210 ℃, the PVC polyvinyl chloride resin is rolled into a coiled material by a calender to be subjected to edge cutting and rolling, the material production thickness is selected from 0.3mm-1.2mm, the width is 2000mm, the length is fixed according to needs, and the PVC four-roller pressing production line is cut within the width of.
6. The production method of the terahertz coupled anion material energy-saving card sheet as claimed in claim 4, characterized in that: the extrusion method is realized on a plastic extrusion production line, and the specific process comprises the following steps: PVC polyvinyl chloride resin, an auxiliary agent, pigment and a functional powder material are mixed and then plasticized in an extruder, and the mixture is extruded into a blank plate from a slit machine head die by the extruder, and the blank plate is trimmed and rolled into a functional coiled material by a three-roll calender.
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| CN110344968B (en) * | 2019-06-03 | 2021-04-23 | 黑龙江睿雨能量子科技有限公司 | Manufacturing method of terahertz negative ion strong-magnetic oil-saving rod |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353253A (en) * | 2007-07-25 | 2009-01-28 | 北京联飞翔科技股份有限公司 | Functional ceramic powder material , preparation and use thereof |
| CN104479220A (en) * | 2014-12-02 | 2015-04-01 | 东莞市车宝节能科技有限公司 | Oil-saving combustion-supporting core and preparation method thereof |
| CN105482855A (en) * | 2016-01-26 | 2016-04-13 | 四川复力环保科技有限公司 | Fuel oil processing method and generator |
| CN106883896A (en) * | 2017-03-22 | 2017-06-23 | 四川复力环保科技有限公司 | Terahertz emission material and its preparation method and application |
| JP3212096U (en) * | 2017-06-02 | 2017-08-24 | 田中 一八 | Functional fuel oil tank |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101353253A (en) * | 2007-07-25 | 2009-01-28 | 北京联飞翔科技股份有限公司 | Functional ceramic powder material , preparation and use thereof |
| CN104479220A (en) * | 2014-12-02 | 2015-04-01 | 东莞市车宝节能科技有限公司 | Oil-saving combustion-supporting core and preparation method thereof |
| CN105482855A (en) * | 2016-01-26 | 2016-04-13 | 四川复力环保科技有限公司 | Fuel oil processing method and generator |
| CN106883896A (en) * | 2017-03-22 | 2017-06-23 | 四川复力环保科技有限公司 | Terahertz emission material and its preparation method and application |
| JP3212096U (en) * | 2017-06-02 | 2017-08-24 | 田中 一八 | Functional fuel oil tank |
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