CN107189770A - For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously - Google Patents
For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously Download PDFInfo
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- CN107189770A CN107189770A CN201610518872.6A CN201610518872A CN107189770A CN 107189770 A CN107189770 A CN 107189770A CN 201610518872 A CN201610518872 A CN 201610518872A CN 107189770 A CN107189770 A CN 107189770A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
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Abstract
The present invention relates to a kind of antifreeze solution additive for removing denitrification and particulate matter simultaneously and the anti-icing fluid containing the additive.It is of the invention to be used to go denitrification and the antifreeze solution additive of particulate matter and the anti-icing fluid containing the additive to include tourmaline, medical stone, rare earth metal, generation electromagnetic wave fortifier, generation far infrared fortifier and produce hydrogen fortifier simultaneously.The present invention can not only improve fuel firing rate and power, and can also effectively remove denitrification and particulate matter.
Description
Technical field
The present invention relates to a kind of antifreeze solution additive for removing denitrification and particulate matter simultaneously and containing the addition
The anti-icing fluid of agent, it is more particularly to a kind of effectively to remove denitrification and particle using the additive that directly make an addition to anti-icing fluid
The antifreeze solution additive for removing denitrification and particulate matter simultaneously and the anti-icing fluid containing the additive of thing.
Background technology
The pollutant of diesel emission has carbon monoxide, hydrocarbon, nitrogen oxides（NOx）And particulate matter（PM）Deng.
The diesel engine is run in the state of air is sufficient, therefore, carbon monoxide and hydrocarbon and vapour in the pollutant
Without too big problem when petrol car is compared, still, the nitrogen oxides and particulate matter severe contamination environment of diesel automobile exhaust, because
This is, it is necessary to be effectively treated.The nitrogen oxides discharged together with waste gas（Nox）And particulate matter（PM）Discharge rate be inversely proportional.
That is, when the discharge rate of nitrogen oxides is reduced, the discharge rate increase of particulate matter, and during the reduction of the discharge rate of particulate matter, nitrogen oxides
Discharge rate then relative increase.
It is general to be followed again using improvement combustion chamber, improvement fuel injection, improvement suction apparatus and exhaust in order to handle pollutant
The methods such as ring, still, not yet get the nod because the above method is also immature.In recent years, due to light caused by nitrogen oxides
The severe contamination environment such as chemical fumes, therefore can reduce the technology of nitrogen oxides in automobile exhaust gas in continuous research and development.Nitrogen oxides
Processing method mainly have to remove using catalyst and subtract in the fuel denitration method of nitrogen compound being contained in fuel, combustion process
The firing optimization method of few nitrogen oxides and post treatment method of processing waste gas etc..Wherein, most study is utilization in post treatment method
The method of catalyst decomposing nitrogen oxide.
The particulate matter that diesel engine is largely discharged is main by that can melt organic matter（Soluble Organic Fraction:SOF）、
Carbon black and sulfide are constituted.Accordingly, it would be desirable to which remove major part in exhaust gas constituents melts organic matter, hydrocarbonization by what hydrocarbon was constituted
Compound, carbon monoxide and odour component.Waste gas purification technology mainly including diesel oil high-quality, engine performance improvement and
Setting of after-treatment device etc..
In the post-processing technology, have the advantages that filter efficiency is high using the method for strainer valve, but utilize strainer valve
Particulate matter removal device, its control device is complicated, poor durability, price are high.
Also, the catalyst of denitrification and particulate matter can be gone not come into operation so far simultaneously.
Accordingly, it would be desirable to the deficiencies in the prior art can be made up by researching and developing, function is good, the method that can reduce waste gas.
What the applicant applied " is used to improve the anti-hydrodynamic additive of haulage vehicle performance and containing the antifreeze of the additive
Liquid "（Korean granted patent publication the 10-0866919th, 2008.11.04）Although improving fuel firing rate and power,
Nitrogen oxides and particulate matter（Particulate Matters）Removal effect it is unobvious.
【Citation】
【Patent document】
The KR 10-0866919 B1 2008.11.04 of patent document 1.
The content of the invention
The purpose of the present invention is to make up the deficiencies in the prior art can not only improve fuel firing rate and work(there is provided a kind of
Rate, and can also effectively go being used for while going the anti-icing fluid of denitrification and particulate matter to add of denitrification and particulate matter
Agent and the anti-icing fluid containing the additive.
The technical solution adopted by the present invention is as follows in order to achieve the above object：
The present invention is used for the antifreeze solution additive for removing denitrification and particulate matter simultaneously, counts, contains by 100 parts by weight of tourmaline
There are 1,000~2,000 parts by weight medical stones, 7~14 parts by weight rare earth metals, 10~20 parts by weight to produce electromagnetic wave reinforcing
Thing, 10~20 parts by weight produce far infrared fortifier and 10~20 parts by weight produce hydrogen fortifier, the rare earth metal
For selected from by lanthanum（La）, cerium（Ce）And neodymium（Nd）At least one of group of composition.
The generation electromagnetic wave fortifier is by 40~60 percentage by weight germanium, 20~40 percentage by weight selenium, 5~15 weight
Percentage zeolite and 5~15 percentage by weight ferrites are mixed.
The generation far infrared fortifier is by 40~60 percentage by weight potassium feldspars, 10~30 percentage by weight Erie
Stone, 10~30 percentage by weight Chiba stones and 5~15 percentage by weight dolomites are mixed.
The generation hydrogen fortifier is by 40~60 percentage by weight zirconiums, 20~40 percentage by weight strontiums and 10~30 weights
Amount percentage yttrium is mixed.
Counted by 100 parts by weight of the tourmaline, also containing 1~5 parts by weight of silica（SiO2）And 1~5 parts by weight
Titanium dioxide（TiO2）.
Counted by 100 parts by weight of the tourmaline, also containing 5~10 parts by weight cooling water activators, the cooling water swashs
Being is mixed by 50~70 percentage by weight zirconium oxides, 20~40 percentage by weight carborundum and 5~15 percentage by weight sodium carbonate
Conjunction is formed.
Counted by 100 parts by weight of the tourmaline, also containing 5~10 parts by weight anion radiations, the anion is put
Thing is penetrated by 50~70 percentage by weight bentonites, 10~30 percentage by weight kaolinites, 5~15 percentage by weights jade and 5~15
Percentage by weight topaz is mixed.
Counted by 100 parts by weight of anti-icing fluid, include antifreeze solution additive described in 0.1~2 parts by weight claim 1
Anti-icing fluid.
The present invention is used to go the antifreeze solution additive of denitrification and particulate matter not only to improve fuel combustion simultaneously
Rate and power, and can also effectively remove denitrification and particulate matter.
Embodiment
The present invention is described in detail below.
The present invention is used to first to go the antifreeze solution additive of denitrification and particulate matter to illustrate simultaneously.
The present invention is used to go the antifreeze solution additive of denitrification and particulate matter to include tourmaline simultaneously, medical stone, dilute
Great soil group metal, generation electromagnetic wave fortifier, generation far infrared fortifier and generation hydrogen fortifier.
The present invention is used for the antifreeze solution additive for removing the nitrogen oxides and particulate matter simultaneously, using tourmaline as 100 weights
Part meter is measured, contains 1,000~2,000 parts by weight medical stone, 7~14 parts by weight rare earth metals, 10~20 parts by weight and produces electricity
Magnetic wave fortifier, 10~20 parts by weight produce far infrared fortifier and 10~20 parts by weight produce hydrogen fortifier.
The tourmaline（Tourmaline）Big energy is produced when heated.In the presence of the energy in radiator
Cooling water is ionized, and near maximum temperature cylinder, cooling water produces positive electricity.Also, make in the piston of high speed rotation
With producing negative charge in lower cylinder.Forming potential difference in the positive electricity and cylinder of cooling water between negative charge causes the stream of electronics
It is dynamic.The translational speed of the higher electronics of temperature is faster, therefore, and electromagnetic wave is produced because of electronics high-speed mobile near high-temperature cylinder.
The electromagnetic wave makes the fuel in combustion chamber attenuate, and makes it easier to burning, so as to ensure burning completely.The tourmaline used
Particle size is preferably 3,000~12,000 mesh（mesh）.
The medical stone can discharge far infrared when heated, the far infrared produces electric wave energy, to activate fuel.Vapour
Car fuel is half acid chain hydrocarbon, when radiating far infrared to hydrocarbon, in the vibration and rotation by far infrared
Under the energy effect of the change generation of dipole moment caused by turning, the electronics of hydrocarbon is with contrast to far infrared wave energy
Direction rotate, interconnection between molecule is disconnected and is become particulate.Exist to the fuel molecule transmitting of micronized
During the high frequency produced in the presence of far-infrared electric wave energy, the hyperlocomotion of the circumnuclear electronics of fuel molecule is centered around, makes combustion
Material is in optimal activation state.As a result, fuel molecule is stable in cylinder and equably spreads, increase with the adhesion of oxygen
Greatly, and then bigger engine power can be obtained with equal amount fuel.The particle size of the medical stone used is preferably 800
~1,200 mesh（mesh）.
The medical stone composition includes 54 percentage by weight SiO2, 14 percentage by weight MgO, 13 percentage by weight Al2O3、8
Percentage by weight Fe2O3, 7 percentage by weight CaO, 2 percentage by weight K2O and 2 percentage by weight Na2O。
The rare earth metal radiates tiny radioactive ray, reforms petroleum hydrocarbon system fuel, while in burning and empty
Gas anion produces OH bases, reduces the pernicious gases such as CO, HC.Also, the rare earth metal can effectively store substantial amounts of hydrogen, from
And hydrogen is produced in hot cooling water, combustion rate is improved by the recycling function of hydrogen.Particularly, rare earth metal preferably makes
With easy releasing hydrogen, the hydrogen purity released is high, can smoothly perform the terres rares group of the lanthanides row lanthanum that Bu Lang move basic role（La）、
Cerium（Ce）And neodymium（Nd）.The rare earth metal can be used alone, and be used after can also mixing at least two.Grain is preferred
Sub- size is 15,000 mesh~100 nanometer（nm）Rare earth metal.
The generation electromagnetic wave fortifier is preferably by 40~60 percentage by weight germanium, 20~40 percentage by weight selenium, 5~15
Percentage by weight zeolite and 5~15 percentage by weight ferrites are mixed.
The germanium（germanium）The uneven electron number for adjusting.If the germanium and silicon are carried out into nanometer combination, i.e.,
The property that heat is changed over to electricity can be greatly improved.
The selenium（selenium）For photoreceptor, conduction is intervened together with heat absorption and heat release function, helps other elements to increase
Big function.
The zeolite（zeolite）The three-D inorganic macromolecule that is connected respectively by four bridging oxygens for silicon and aluminium of skeleton,
Now, aluminium is combined and with negative charge with four oxygen.Contain various cations to offset the negative charge.
The ferrite（ferrite）Temperature coefficient is high, can be run near car combustion engine.Ferrite is permanent magnetic
Iron, mainly turns into BaO 6Fe2O3、 SrO․6Fe2O3。
The generation far infrared fortifier preferably by 40~60 percentage by weight potassium feldspars, 10~30 percentage by weights she
Sharp stone, 10~30 percentage by weight Chiba stones and 5~15 percentage by weight dolomites are mixed.
The potassium feldspar（Potassium Feldspar）For the feldspar race mineral using potassium as principal component, chemical composition is
KAlSi3O8.The radiation-curable beneficial far infrared of potassium feldspar, removing heavy metals effect is gone with excellent.
The illite（（K,H3O)Al2(Si,Al)4O10(H2O,OH)2）For the tiny hydrosilicate mineral of clayey, it is
With kaolinite（Montmorillonite）And dolomite（Muscovite）The rare mica clay mineral of middle corner structure
（Micalikeclay Minerals）.Illite discharges the far infrared that 89~92% wavelength are 2~25 at normal temperatures.It has
There is very strong deodorization power, and more than 3 times of dissolved oxygen can be ensured by activated water molecule, with very strong oxygen aggegation
Power.
The Chiba stone（Kiyoseki）To release substantial amounts of anion and radiating the new of optimal far infrared at normal temperatures
Material.The mine formed when the Chiba stone originates in diastrophism before about 6500 under warm water effect, is cohesion nature
The mysterious material of boundary's energy.The Chiba stone is natural stone, only originates in Gunma Prefecture, Japan.
The dolomite（dolomite）For trigonal system mineral, formed by the dolomitized of calcite, similar in appearance to
Calcite.Dolomite has the characteristic for radiating a large amount of far infrareds.
The generation hydrogen fortifier is preferably by 40~60 percentage by weight zirconiums, 20~40 percentage by weight strontiums and 10~30
Percentage by weight yttrium is mixed.
The zirconium and strontium are used to increase storing hydrogen function to greatest extent, and storing hydrogen rate is very high, can have in cooling water
Effect produces hydrogen.That is, storing hydrogen function is further strengthened together with existing rare earth metal, to cast iron/titanium alloy film of cylinder jacket
With hydrogen in cylinder（H）And carbon（C）Catalytic action is carried out, is executable and kinetic energy identical function with a small amount of fuel, so as to big
Width reduces the discharge of carbon dioxide.
The zirconium is one of transferable element, and generation metal hydride is combined with hydrogen.The hydride has ZrH2, ZrH
Deng, be hydrogen atom intrusion metal grill between structure.The zirconium is more rich environment-friendly materials in the Nature, it is easy to from natural ore deposit
Obtained in thing.
The strontium belongs to one of alkali earth metal of periodic table second family, and generation metal hydride is combined with hydrogen.Also,
It is better than calcium with the reactivity worth of water, therefore is also easy to produce hydrogen, so as to easily provides hydrogen.The strontium is main with day in nature
Green stone（celestite）And strontianite（strontianite）Shape is present.
It is powdered to nanosized that the zirconium or strontium are preferred micron, to smoothly complete storing hydrogen function and catalysis
Agent function.
The yttrium（Y）For the representative element of terres rares yttrium system, the storing hydrogen function of zirconium and strontium can be effectively made up.It is preferred
Particle size is 15,000 mesh~100 nanometer（nm）Yttrium.
The present invention is used to remove the antifreeze solution additive of denitrification and particulate matter using tourmaline as 100 parts by weight simultaneously
Meter, also containing 1~5 parts by weight of silica（SiO2）And 1~5 parts by weight of titanium dioxide（TiO2）.
Purity is more than 99.99% SiO2Nano-powder is used for the ion for stablizing cooling water, reduction voltage stabilizing and electrostatic, so that
Vehicular vibration and noise can be reduced.Particle size is preferred for 15,000 mesh~100 nanometer（nm）Silica.
Electronics, hydroxyl of the generation with strong oxdiative power are formed when the titanium dioxide is by ultraviolet（-OH）And peroxidating
Thing（O2）.Hydroxyl and the peroxide decomposing organic compounds, generation water and carbon dioxide.By in this principle decomposition water
Pollutant, generates the innocuous substance such as water and carbon dioxide.Particle size is preferred for 15,000 mesh~100 nanometer（nm）Two
Titanium oxide.
The present invention is used to remove the antifreeze solution additive of denitrification and particulate matter using tourmaline as 100 parts by weight simultaneously
Meter, also containing 5~10 parts by weight cooling water activators.
The cooling water activator activates the water for cooling down engine, induction burning completely.The cooling water performance is strong
Compound is contacted with water, will be synthesized by hydrone formed by soft water water cluster（cluster）Become small group, to activate cooling
Water.In engine environment circulation during the water burning of activation, combustion characteristics is influenceed, so as to can induce burning completely, waste gas is reduced
Produce.
The cooling water activator preferably by 50~70 percentage by weight zirconium oxides, 20~40 percentage by weight carborundum and
5~15 percentage by weight sodium carbonate are mixed.
When the zirconium oxide, carborundum and sodium carbonate mixture are heated, resistance rapidly diminishes, and electric conductivity rapidly increases,
So that water cluster becomes tuftlet, and then activate cooling water.
The present invention is used to remove the antifreeze solution additive of denitrification and particulate matter using tourmaline weight as 100 weight simultaneously
Part meter, also containing 5~10 parts by weight anion radiations.
Fuel in order to burn and with suction air in oxygen mix when, the anion activating oxygen makes fuel smoothly enter
Row oxidation, so as to improve efficiency of combustion.Also, the anion radiation can be with taste removal, purification air, so as to build
Comfortable driving environment.
The anion radiation is preferably by 50~70 percentage by weight bentonites, 10~30 percentage by weight kaolinites, 5
~15 percentage by weights are beautiful and 5~15 percentage by weight topazs are mixed.
The bentonite（bentonite）For clay, the monoclinic system mineral illiteracy such as mica crystalline texture is mainly contained
De- stone, color is white, grey, filbert, light green etc..
The kaolinite（kaolinite）Belong to monoclinic crystal mineral, chemical formula is Al2Si2O5(OH)4, crystallize as Si plates
The clay mineral alternateed with Al plates, with 1:1 type lattice.
The jade is the general name of nephrite and jadeite.Wherein nephrite refers to a kind of angle of the feltwork shape crystal with trickle
Amphibole, jadeite refers to a kind of alkali pyroxene to form hard monoclinic system.The topaz is orthorhombic system mineral, also referred to as Huang
It is beautiful（Topaz）, with olivine identical crystalline texture.The chemical constitution of the beautiful and topaz includes abundant anion
Group, can produce a large amount of anions.
In addition, its surface area very big, surface tension is strong for the particle relative volume of nanosized, therefore can between particle
Produce cohesion.When i.e., using the zirconium or strontium of nanosized, if the anti-icing fluid is packaged in institute's constant volume device, then just
The possibility of the phase inter coagulation between particle in narrow space can not be excluded.Therefore, in order to prevent between particle phase inter coagulation and
It is dispersed in solvent, preferably add at least one of surfactant, dispersant in the antifreeze solution additive.
The surfactant is used to prevent the nanometer powder mixed with solvent from condensing, not special to its species
Limitation.It is, for example, possible to use the existing surfactant used for the divided metallic powder in cylinder oil.But
Organic amino acid, polyoxyethylene, stearic acid is preferred（Stearic acid）, lauryl sodium sulfate（sodium
dodecyl sulfate）Deng.
The addition of the surfactant, is counted by 100 parts by weight of anti-icing fluid total amount, and preferably addition is 0.05~10
Parts by weight, optimum addition is 0.1~5 parts by weight.When addition is less than 0.05 parts by weight, it is difficult to obtain satisfaction prevent receive
Ground rice end flocculating result；And addition more than 10 parts by weight when, then the characteristic such as heat resistance of components of anti-icing liquor can decline.
While the dispersant is used to prevent that the nanometer powder mixed with solvent from condensing, it is additionally operable to improve dispersiveness, with
Suppress the precipitability of nanometer powder.Its species is had no particular limits, but epoxy resin, oleic acid is preferred（oleic
acid）, linoleic acid（linoleic acid）, Tamol NN8906, Tween20 etc..
In order to prevent nanometer powder from condensing, it can use and the material for constituting antifreeze solution additive of the invention is put into solvent
The method that ultrasonication is carried out while stirring.
The packaging of the anti-icing fluid can utilize the methods commonly used in the art such as plastic containers or glass container.Specifically
For, PE, PP or PET can be used in the material of the plastic containers, but is not limited to this.
The antifreeze solution additive can be packaged into capsule, injection shape, and graininess or strip can also be made.Will be certain dense
Spend solution or certain content solid（Particle）Small articles are made in antifreeze solution additive, to be used for consumer.For example, with glue
When cryptomere is packed, the capsule dissolves in high-temperature cooling water, antifreeze solution additive is scattered in automatically in cooling water.When with pin
Agent shape pack when it is easy to carry, it is necessary to when cut-out injection one end can make an addition at any time in cooling water.
Gelatin or collagen can be used in the material of the capsule, and glass or hard can be used in the outside material of the injection
Vinyl chloride, but it is not limited to this.
The anti-icing fluid that the present invention adds the antifreeze solution additive and manufactured, is counted, most by 100 parts by weight of anti-icing fluid total amount
Include antifreeze solution additive described in 0.1~2 parts by weight well.
1,500 parts by weight medical stones, 3 parts by weight lanthanums, 3 parts by weight neodymiums, 3 parts by weight are mixed in 100 parts by weight of tourmaline
Cerium, 20 parts by weight produce electromagnetic wave fortifier, 15 parts by weight and produce far infrared fortifier, the generation hydrogen reinforcing of 10 parts by weight
Thing, 10 parts by weight cooling water activators, 5 parts by weight anion radiations, 2 parts by weight of silica（SiO2）And 2 parts by weight two
Titanium oxide（TiO2）And manufacture antifreeze solution additive.The generation electromagnetic wave fortifier is by 50 percentage by weight germanium, 30 weight
Percentage selenium, 10 percentage by weight zeolites and 10 percentage by weight ferrites are mixed and are made.The generation far infrared reinforcing
Thing is by 50 percentage by weight potassium feldspars, 20 percentage by weight illites, 20 percentage by weight Chiba stones and 10 percentage by weights
Dolomite is mixed and is made.The generation hydrogen fortifier is by 50 percentage by weight zirconiums, 30 percentage by weight strontiums and 20 weight
Percentage yttrium is mixed and is made.The cooling water activator is by 60 percentage by weight zirconium oxides, 30 percentage by weight carborundum
And 10 percentage by weight sodium carbonate mixing and be made.The anion radiation is by 60 percentage by weight bentonites, 20 weight
Percentage kaolinite, 10 percentage by weights are beautiful and 10 percentage by weight topazs are mixed and are made.The used tourmaline
Particle size be that 12,000 mesh, the particle size of medical stone are that 1,200 mesh, the particle size of lanthanum are 100 nanometers, the particle of neodymium
The particle size that size is 100 nanometers, the particle size of cerium is 100 nanometers, produce electromagnetic wave fortifier is 12,000 mesh, generation
It is 100 nanometers that the particle size of far infrared fortifier, which is 1,200 mesh, produce the particle size of hydrogen fortifier, cooling water swashs
The particle size of being is that 1,200 mesh, the particle size of anion radiation are that 1,200 mesh, the particle size of silica are
100 nanometers, the particle size of titanium dioxide be 100 nanometers.
[test example 1]
In order to investigate the waste gas decrement of the antifreeze solution additive manufactured in embodiment 1, the longitude and latitude science and technology hair in Tianjin City, China
Exhibition Co., Ltd is tested using 5-gas detectors, and as shown in table 1, test vehicle is that KIA is old-fashioned to NOx measurement result
SPORTAGE diesel vehicles.
【Table 1】
Antifreeze solution additive of the invention can reduce by least 91% NOx as can be seen from Table 1.
[test example 2]
In order to investigate the waste gas decrement of the antifreeze solution additive manufactured in embodiment 1, in Chinese state-run detection institute（China is open to the traffic
Services Co., Ltd）And wasted nickel catalyst experiment has been carried out under the accompanying of public security officer, HC measurement result is as shown in table 2.Examination
Validate the car and used Chinese Tianjin Dafa micro-bus（Diesel oil）.
【Table 2】
Antifreeze solution additive of the invention can reduce HC at least 93% as can be seen from Table 2.
[test example 3]
For the minimizing effect of the particulate matter of investigating the antifreeze solution additive manufactured in embodiment 1, in South Korea SANGSIN
ENGINEERING Co., Ltd. has carried out flue gas detector and has accelerated model test, pull-in value and is not through the measurement result of rate such as
Shown in table 3.Test vehicle has used masses' PASSAT2.0TDI diesel vehicles in 2013.
【Table 3】
The antifreeze solution additive manufactured as can be seen from Table 3 in embodiment 1 will can be not through rate from 83.1% be obviously improved to
14.1%。
[test example 4]
For the minimizing effect of the particulate matter of investigating the antifreeze solution additive manufactured in embodiment 1, in the state-run inspection in Shenyang China city
Survey is tested, and the measurement result of coefficient of light absorption K value is as shown in table 4.Test vehicle has used Chinese lorry（Diesel oil）.
【Table 4】
As shown in table 4, to lorry（Diesel oil）The absorption coefficient of light exceedes base before the antifreeze solution additive manufactured in injection embodiment 1
Quasi- value, is defined as unqualified, and the absorption coefficient of light is significantly less than benchmark after injecting the antifreeze solution additive manufactured in embodiment 1
Value, it is qualified to be defined as.
It can thus be appreciated that particulate matter can be greatly decreased in antifreeze solution additive of the invention（PM）.
To sum up test, antifreeze solution additive of the invention can effectively remove denitrification and particulate matter.
[test example 5]
Commission chemical fusion Testing ＆ Research Institute of South Korea has carried out heavy metal to the antifreeze solution additive manufactured in embodiment 1 and harmful
The detection experiment of material, result of the test is as shown in table 5.
【Table 5】
The antifreeze solution additive manufactured as can be seen from Table 5 in embodiment 1 is environment-friendly products, not comprising heavy metal and harmful organic
Thing.
Claims (8)
1. a kind of antifreeze solution additive for being used to remove denitrification and particulate matter simultaneously, it is characterised in that：Using tourmaline as
100 parts by weight meters, contain 1,000~2,000 parts by weight medical stone, 7~14 parts by weight rare earth metals, the production of 10~20 parts by weight
Raw electromagnetic wave fortifier, 10~20 parts by weight produce far infrared fortifier and 10~20 parts by weight produce hydrogen fortifier, institute
It is selected from by lanthanum to state rare earth metal（La）, cerium（Ce）And neodymium（Nd）At least one of group of composition.
2. the antifreeze solution additive according to claim 1 for being used to remove denitrification and particulate matter simultaneously, its feature exists
In：The generation electromagnetic wave fortifier is by 40~60 percentage by weight germanium, 20~40 percentage by weight selenium, 5~15 weight percents
Mixed than zeolite and 5~15 percentage by weight ferrites.
3. the antifreeze solution additive according to claim 1 for being used to remove denitrification and particulate matter simultaneously, its feature exists
In：It is described generation far infrared fortifier by 40~60 percentage by weight potassium feldspars, 10~30 percentage by weight illites, 10~
30 percentage by weight Chiba stones and 5~15 percentage by weight dolomites are mixed.
4. the antifreeze solution additive according to claim 1 for being used to remove denitrification and particulate matter simultaneously, its feature exists
In：The generation hydrogen fortifier is by 40~60 percentage by weight zirconiums, 20~40 percentage by weight strontiums and 10~30 weight hundred
Divide and mixed than yttrium.
5. the antifreeze solution additive according to claim 1 for being used to remove denitrification and particulate matter simultaneously, its feature exists
In：Counted by 100 parts by weight of the tourmaline, also containing 1~5 parts by weight of silica（SiO2）And 1~5 parts by weight titanium dioxide
Titanium（TiO2）.
6. the antifreeze solution additive according to claim 1 for being used to remove denitrification and particulate matter simultaneously, its feature exists
In：Counted by 100 parts by weight of the tourmaline, also containing 5~10 parts by weight cooling water activators, the cooling water activator
By 50~70 percentage by weight zirconium oxides, 20~40 percentage by weight carborundum and 5~15 percentage by weight sodium carbonate mixing and
Into.
7. remove the antifreeze solution additive of denitrification and particulate matter simultaneously according to being used for described in claim 1, it is characterised in that：
Counted by 100 parts by weight of the tourmaline, also containing 5~10 parts by weight anion radiations, the anion radiation is by 50
~70 percentage by weight bentonites, 10~30 percentage by weight kaolinites, 5~15 percentage by weights jade and 5~15 weight percents
Mixed than topaz.
8. being counted by 100 parts by weight of anti-icing fluid, include preventing for the antifreeze solution additive described in 0.1~2 parts by weight claim 1
Freeze liquid.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2016-0030942 | 2016-03-15 | ||
| KR1020160030942A KR101735789B1 (en) | 2016-03-15 | 2016-03-15 | Additives of Antifreeze for removing Nitrogen Oxides and Particulate Matters and Antifreeze comprising thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107189770A true CN107189770A (en) | 2017-09-22 |
Family
ID=58739545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610518872.6A Withdrawn CN107189770A (en) | 2016-03-15 | 2016-07-05 | For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101735789B1 (en) |
| CN (1) | CN107189770A (en) |
| WO (1) | WO2017160040A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749719A (en) * | 2017-11-03 | 2019-05-14 | 北京万成天泰科技发展有限责任公司 | It is a kind of that can to keep radiator temperature be 85 degrees Celsius of water tank coolant liquid |
| CN109868120A (en) * | 2017-12-01 | 2019-06-11 | 北京万成天泰科技发展有限责任公司 | One kind can make radiator in subzero 45 degrees Celsius of non-icing anti-icing fluid |
| CN111542588A (en) * | 2018-01-17 | 2020-08-14 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102250132B1 (en) * | 2019-03-25 | 2021-05-11 | 김재수 | Composition for soot-particle and fuel reduction |
| KR102441192B1 (en) * | 2022-03-22 | 2022-09-08 | 주식회사 션킴모터스 | Composition for cooling water additive and manufacturing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100771190B1 (en) * | 2006-04-28 | 2007-10-29 | 주식회사 에스엘티테크놀리지 | Addition matter for cooling water of engine |
| KR20080083991A (en) * | 2007-03-14 | 2008-09-19 | 김운학 | Cooling water additive in car |
| CN101270276A (en) * | 2007-03-19 | 2008-09-24 | 辛忠教 | Additive for cooling water and antifreeze, antifreeze added with the same |
| KR20130058143A (en) * | 2011-11-25 | 2013-06-04 | 이한국 | Improved perfomance matterial for vehicle |
| CN103418436A (en) * | 2012-05-15 | 2013-12-04 | 全甲述 | Acidic catalyst solution for internal combustion engine, and method for preparing the same |
| WO2014077553A1 (en) * | 2012-11-14 | 2014-05-22 | 주식회사 에스지코리아 | Coolant activating agent, and method for producing same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2780096B1 (en) * | 1998-06-22 | 2000-09-08 | Rhodia Chimie Sa | PROCESS FOR THE COMBUSTION TREATMENT OF CARBON PARTICLES IN AN EXHAUST CIRCUIT OF AN INTERNAL COMBUSTION ENGINE |
| JP4175558B2 (en) * | 2002-07-23 | 2008-11-05 | 株式会社ファーベスト | Far-infrared radiation material |
| KR101010935B1 (en) * | 2010-03-23 | 2011-01-25 | 신충교 | Additives of antifreeze for decreasing greenhouse gases and antifreeze produced using thereof |
| KR101252571B1 (en) * | 2012-05-21 | 2013-04-09 | 주식회사 에스지코리아 | Active composition for cooling water and method for manufacturing the same |
-
2016
- 2016-03-15 KR KR1020160030942A patent/KR101735789B1/en active IP Right Grant
- 2016-07-05 CN CN201610518872.6A patent/CN107189770A/en not_active Withdrawn
-
2017
- 2017-03-13 WO PCT/KR2017/002687 patent/WO2017160040A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100771190B1 (en) * | 2006-04-28 | 2007-10-29 | 주식회사 에스엘티테크놀리지 | Addition matter for cooling water of engine |
| KR20080083991A (en) * | 2007-03-14 | 2008-09-19 | 김운학 | Cooling water additive in car |
| CN101270276A (en) * | 2007-03-19 | 2008-09-24 | 辛忠教 | Additive for cooling water and antifreeze, antifreeze added with the same |
| KR20130058143A (en) * | 2011-11-25 | 2013-06-04 | 이한국 | Improved perfomance matterial for vehicle |
| CN103418436A (en) * | 2012-05-15 | 2013-12-04 | 全甲述 | Acidic catalyst solution for internal combustion engine, and method for preparing the same |
| WO2014077553A1 (en) * | 2012-11-14 | 2014-05-22 | 주식회사 에스지코리아 | Coolant activating agent, and method for producing same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749719A (en) * | 2017-11-03 | 2019-05-14 | 北京万成天泰科技发展有限责任公司 | It is a kind of that can to keep radiator temperature be 85 degrees Celsius of water tank coolant liquid |
| CN109868120A (en) * | 2017-12-01 | 2019-06-11 | 北京万成天泰科技发展有限责任公司 | One kind can make radiator in subzero 45 degrees Celsius of non-icing anti-icing fluid |
| CN111542588A (en) * | 2018-01-17 | 2020-08-14 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
| CN111542588B (en) * | 2018-01-17 | 2021-09-28 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101735789B1 (en) | 2017-05-15 |
| WO2017160040A1 (en) | 2017-09-21 |
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Application publication date: 20170922 |