CN103418436A - Acidic catalyst solution for internal combustion engine, and method for preparing the same - Google Patents
Acidic catalyst solution for internal combustion engine, and method for preparing the same Download PDFInfo
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- CN103418436A CN103418436A CN2013101765881A CN201310176588A CN103418436A CN 103418436 A CN103418436 A CN 103418436A CN 2013101765881 A CN2013101765881 A CN 2013101765881A CN 201310176588 A CN201310176588 A CN 201310176588A CN 103418436 A CN103418436 A CN 103418436A
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- combustion engine
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 73
- 239000003054 catalyst Substances 0.000 title claims abstract description 68
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 24
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 113
- 239000011707 mineral Substances 0.000 claims abstract description 113
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 46
- 150000003624 transition metals Chemical class 0.000 claims abstract description 46
- 238000002360 preparation method Methods 0.000 claims abstract description 23
- 239000007788 liquid Substances 0.000 claims description 64
- 239000003795 chemical substances by application Substances 0.000 claims description 63
- 239000000203 mixture Substances 0.000 claims description 63
- 239000004575 stone Substances 0.000 claims description 54
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 49
- 229910052732 germanium Inorganic materials 0.000 claims description 48
- 229910052613 tourmaline Inorganic materials 0.000 claims description 23
- 229940070527 tourmaline Drugs 0.000 claims description 23
- 239000011032 tourmaline Substances 0.000 claims description 23
- 229910052626 biotite Inorganic materials 0.000 claims description 21
- 229910052900 illite Inorganic materials 0.000 claims description 21
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 15
- 230000005855 radiation Effects 0.000 claims description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 14
- 238000004061 bleaching Methods 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 239000010445 mica Substances 0.000 claims description 13
- 229910052618 mica group Inorganic materials 0.000 claims description 13
- 239000010457 zeolite Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 claims description 10
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052590 monazite Inorganic materials 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 9
- 230000035800 maturation Effects 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 7
- 229910052763 palladium Inorganic materials 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 238000010306 acid treatment Methods 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000779 smoke Substances 0.000 abstract description 39
- 239000000446 fuel Substances 0.000 abstract description 30
- 230000000694 effects Effects 0.000 abstract description 22
- 239000000126 substance Substances 0.000 abstract description 17
- 230000009467 reduction Effects 0.000 abstract description 11
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 abstract description 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 47
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 39
- 150000001450 anions Chemical class 0.000 description 35
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 15
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 229910002091 carbon monoxide Inorganic materials 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- 238000002156 mixing Methods 0.000 description 10
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 5
- 239000002912 waste gas Substances 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000008246 gaseous mixture Substances 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000002285 radioactive effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 235000011201 Ginkgo Nutrition 0.000 description 1
- 235000008100 Ginkgo biloba Nutrition 0.000 description 1
- 244000194101 Ginkgo biloba Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical class [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B01J35/27—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
The invention relates to an acidic catalyst solution for an internal combustion engine, and a method for preparing the same. The acidic catalyst solution for the internal combustion engine is composed of a mineral substance, a pyroligneous solution and a transition metal in optimum proportions. The method comprises a preparation step (S10), a stirring step (S20) and a curing step (S30). Therefore, according to the invention, harmful substances of the internal combustion engine are changed into harmless substances by anionic oxidation and reduction, so that the acidic catalyst solution has excellent effects for reducing dark smoke and increasing fuel efficiency.
Description
Technical field
The present invention relates to acidic catalyst agent solution and forming method thereof for a kind of internal combustion engine.Relate in more detail a kind of method of internal combustion engine with the acidic catalyst agent solution that form, this internal combustion engine by the feature of acidic catalyst agent solution is, comprise mineral matter that the exit dose of the anion in the far-infrared radiation mineral is many, comprise the pyrolkigneous liquid of organic germanium and inorganic matter (mineral) and for the transition metal of oxidation and reduction with best cooperation content, this solution reduces black smoke, thereby increase beyond example air-fuel ratio, there is the effect of thrifty fuel.
Background technology
In general, the gas that internal combustion engine is discharged is called waste gas, comprising countless harmful substances such as carbon dioxide, carbon monoxide, hydrocarbon, oxysulfide, hydrogen sulfide, nitrogen oxide, ammonia.Carbon monoxide is that the deficiency due to oxygen produces between main combustion period, therefore when the chemically correct fuel by air-fuel mixture enleanment being become to gasoline engine (making the ratio of air and the gasoline of gaseous mixture completing combustion)---14.8% when above, can not produce carbon monoxide, with regard to hydrocarbon, in the time of near gaseous mixture is chemically correct fuel, the generation of hydrocarbon is minimum, but when air-fuel mixture enleanment extremely surpasses chemically correct fuel, because the propagation of spark is interrupted, therefore can cause not exclusively whole burning, thereby increase carbon monoxide.Nitrogen oxide is that airborne oxygen and nitrogen at high temperature react and generate, therefore maximum near theoretical air-fuel ratio.
Internal combustion engine stops the gaseous mixture of fuel and air in the cylinder of sealing, and compressed and igniting is burnt rapidly the carbon in fuel.The backward outer Exhaust Gas that burns, and again suck fresh gaseous mixture, and the gas discharged is waste gas.What the gas flow of discharging was many is the gasoline engine of automobile.Contain contaminated air and harmful composition in the waste gas of automobile, therefore as new public hazards, become social concern.
Along with environmental pollution and resource exhaustion problem occurring, continue exploitation black smoke depressant or black smoke and reduce the combustion such as device than improver etc.Yet the black smoke that the composition of the black smoke of exploitation reduction recently brings reduces degree and also rests on 30% to 40%, and it is 5% to 10% only that fuel efficiency is improved effect.Although developing the vehicle that improves fuel efficiency, by comparison, environmental pollution and resource exhaustion speed are obviously fast, therefore are badly in need of the composition that a kind of black smoke of exploitation reduces the effect excellence.
Summary of the invention
So, the objective of the invention is to propose in order to solve problem in the past as above, its objective is a kind of internal combustion engine acidic catalyst agent solution is provided, this solution passes through with best cooperation mixed mineral matter, pyrolkigneous liquid and transition metal, make the radiation of far infrared and anion maximize, thus the effect brilliance of carrying out oxidation and reduction in internal combustion engine for the harmful substance produced.
Another object of the present invention is to provide the preparation method of a kind of internal combustion engine with the acidic catalyst agent solution, the method is passed through with best fit mixed mineral matter, pyrolkigneous liquid and transition metal, and stirred and slaking and make it the fermentation, with radioactive anion to greatest extent, therefore black smoke reduces the effect excellence, increase air-fuel ratio thereupon, thereby bring the thrifty effect of fuel.
In order to realize described purpose, internal combustion engine of the present invention is to comprise mineral matter, pyrolkigneous liquid and transition metal by the feature of acid solution catalyst.Feature of the present invention is, with respect to described mineral matter 100 weight portions, described pyrolkigneous liquid is 25 to 90 weight portions, and described transition metal is 0.01 to 40 weight portion.Feature of the present invention is, described mineral matter is the far-infrared radiation mineral, and described mineral matter is bleaching earth, illite, seven colored stones
Biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi
Yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, Hygerion
At least one in sericite, kaolin or bentonite.Feature of the present invention is, with respect to bleaching earth 100 weight portions, described mineral matter comprises illite 80 to 130 weight portions, seven colored stone 80 to 130 weight portions, biotite 40 to 70 weight portions, germanium 40 to 70 weight portions, tourmaline 120 to 200 weight portions, volcanic ash 80 to 130 weight portions, Kweiyang stone 120 to 200 weight portions and doctor Wang Shi 80 to 130 weight portions.Feature of the present invention is, described mineral matter is Powdered, and the mean size of described powder is 300 to 50,000 orders.The size of each mineral dust is as follows: described illite is 300 to 1, 000 order, described seven colored stones are 300 to 1, 000 order, described biotite is 300 to 1, 000 order, described germanium is 1, 000 to 4, 000 order, described tourmaline is 1, 500 to 6, 000 order, described volcanic ash is 300 to 1, 000 order, described Kweiyang stone is 15, 000 to 50, 000 order, described doctor Wang Shi is 300 to 1, 000 order, described yellow mica is 300 to 1, 000 order, described Qarnet stone is 300 to 1, 000 order, described lanthanite is 300 to 1, 000 order, described anatase is 300 to 1, 000 order, described monazite is 1, 000 to 4, 000 order, described zeolite is 300 to 1, 000 order.Further comprise any in organic germanium or inorganic matter (mineral) at described pyrolkigneous liquid.Feature of the present invention is that it is composed as follows: with respect to pyrolkigneous liquid 100 weight portions, described organic germanium is 50 to 75 weight portions, and described inorganic matter (mineral) is 50 to 75 weight portions.Described transition metal is at least one in platinum, vanadium, palladium or silver.Feature of the present invention is that it is composed as follows: with respect to chloroplatinic acid 100 weight portions, comprise vanadium pentoxide 150 to 250 weight portions, palladium 120 to 200 weight portions, nano silver particles 40 to 65 weight portions and form.
The formation method of acidic catalyst agent solution for internal combustion engine comprises the following steps: preparation process, prepare mineral mixture, pyrolkigneous liquid and transition metal mixture; Whipping step drops into described mineral mixture and described transition metal mixture and is stirred and prepare internal combustion engine acidic catalyst agent solution in described pyrolkigneous liquid; And maturation stage, make acidic catalyst agent solution slaking for described internal combustion engine.Feature of the present invention is, at mineral mixture described in described preparation process, by the far-infrared radiation mineral, formed, described mineral matter is bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi, yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, hygerion
At least one in sericite, kaolin or bentonite.Feature of the present invention is, described mineral mixture, with respect to bleaching earth 100 weight portions, comprises that illite 80 to 130 weight portions, seven colored stone 80 to 130 weight portions, biotite 40 to 70 weight portions, germanium 40 to 70 weight portions, tourmaline 120 to 200 weight portions, volcanic ash 80 to 130 weight portions, Kweiyang stone 120 to 200 weight portions, doctor Wang Shi 80 to 130 weight portions form.Feature of the present invention is further to comprise organic germanium or inorganic matter (mineral) at pyrolkigneous liquid described in described preparation process.The feature of its composition is that, with respect to described pyrolkigneous liquid 100 weight portions, described organic germanium is that 50 to 75 weight portions, described inorganic matter (mineral) are 50 to 75 weight portions.Feature of the present invention is, described pyrolkigneous liquid, described organic germanium and described inorganic matter (mineral) are mixed 2 to 20 hours under the temperature of 10 to 50 ℃, 2 to 5 pH condition.For at least one and the slaking dropped in distilled water in germanium, zeolite, illite, yellow mica, biotite, Qarnet stone or seven colored stones, within 1.5 to 7 days, prepared by described inorganic matter (mineral).Feature of the present invention is transition metal to be carried out dropping in distilled water after acid treatment in described preparation process.Feature of the present invention is that described acid is phosphoric acid.Feature of the present invention is that, in described whipping step, with respect to described mineral mixture 100 weight portions, described pyrolkigneous liquid is that 25 to 90 weight portions, described transition metal mixture are 0.01 to 40 weight portion.Feature of the present invention is that described whipping step comprises: the first whipping step drops into described mineral mixture and is stirred and prepare dilute solution in described pyrolkigneous liquid; And second whipping step, drop into described transition metal mixture in the described dilute solution in described the first whipping step and stirred.Feature of the present invention is, in described maturation stage, makes acidic catalyst agent solution slaking 7 to 15 days at the temperature of 30 to 60 ℃ for described internal combustion engine.
Acidic catalyst agent solution of the present invention is the acidic catalyst agent solution that has coordinated the transition metal of mineral matter, pyrolkigneous liquid and redox ability excellence, mineral matter prepared by the high mineral matter of exit dose that described mineral matter is anion in the cooperation mixing far-infrared radiation mineral with best, described pyrolkigneous liquid contains the inorganic matters (mineral) such as organic germanium and a large amount of boron, silicon.When described acidic catalyst agent solution is used for internal combustion engine, can reduce black smoke, especially significantly the generation of the nitrogen dioxide in the black smoke harmful substance.And anion becomes oxygen by the unburned gas ion-exchange in cylinder, thereby bring the effect of further minimizing black smoke, finally have black smoke is reduced to 60% to the effect more than 70%.By such black smoke, reduce, air-fuel ratio also significantly brings up to 30% to 40%., along with the increase of air-fuel ratio, correspondingly reduce fuel consumption, thereby can reduce fuel cost.Accordingly, reduce the use amount of coal fuel, to preserve resource.In addition, even use described acidic catalyst agent solution at internal combustion engine, also can increase water, carbon dioxide and oxygen, therefore can not produce any direct or indirect interference by combustion motor.
The accompanying drawing explanation
Fig. 1 shows the flow chart of internal combustion engine of the present invention by the formation method of acidic catalyst agent solution according to the order of sequence.
The specific embodiment
Below, acidic catalyst agent solution and preparation method thereof for the internal combustion engine that present invention will be described in detail with reference to the accompanying.
The present invention relates to a kind of internal combustion engine acidic catalyst agent solution, internal combustion engine comprises mineral matter, pyrolkigneous liquid and transition metal with the acidic catalyst agent solution and forms.This is that black smoke minimizing and the fuel efficiency in internal combustion engine, used are improved composition.
Preferably, in the composition at internal combustion engine with the acidic catalyst agent solution, with respect to mineral matter 100 weight portions, pyrolkigneous liquid is 25 to 90 weight portions, and transition metal is 0.01 to 40 weight portion.More preferably, with respect to mineral matter 100 weight portions, pyrolkigneous liquid is 45 to 80 weight portions, and transition metal is 2 to 15 weight portions.
When the content of pyrolkigneous liquid during lower than 45 weight portion, can not keep suitable pH, therefore there is the problem that redox ability reduces, when surpassing 80 weight portion, because too much hydrogen ion concentration can cause and the reacting of transition metal, therefore be not suitable for using in internal combustion engine.When the content of transition metal, during lower than 2 weight portion, may make the reducing degree of Ionized harmful substance reduce, when content surpasses 15 weight portion, and the concentration proportioning between the hydrogen ion of pyrolkigneous liquid is improper, the problem that may cause reduction efficiency to reduce.
Mineral matter is preferably the far-infrared radiation mineral.The far-infrared radiation mineral are the aluminium silicate salt mineral, the mineral of the far infrared of radiation 0.76 to 1,000 wave-length coverage in the mineral that especially in the layer silicate mineral group, contain mass crystallization water.When the far infrared of radiation and the molecule that forms a certain material or atom same frequency, this far infrared is by the atom of material or molecule absorption the phenomenon of striking a chord, and this motion is called as resonance motion.When producing resonance motion, produce molecular energy, the energy produced is by activate.
Described mineral matter, in the mineral matter that belongs to the far-infrared radiation mineral, is preferably bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi, yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, hygerion that the anion generation is high
At least one in sericite, kaolin or bentonite.Be more preferably tourmaline or Kweiyang stone.Anion be put in the burner of internal combustion engine and in and the harmful substances such as carbon monoxide, hydrocarbon, nitrogen oxide or oxysulfide, thereby reduce waste gas and black smoke.Compared with using a kind of mineral matter, use together as above mineral matter, thereby improve to greatest extent the exit dose of mineral matter and the exit dose of anion.
Particularly, tourmaline is the borosilicate with hexagonal column crystallization, belongs to the natural minerals of hexagonal crystal system, its radioactive anion, weak current and far infrared.Tourmaline is radioactive anion constantly in the following manner: when the former stone of tourmaline or powder contact wetting, moment can be discharged to moisture, and now water is ionized, and hydrone is separated into hydrogen ion and hydroxyl ion.The hydrogen ion separated attracted to negative electrode and be combined with electronics and neutralize and become hydrogen and evaporate, and hydroxyl ion and water molecules on every side, become the such surface reactive material of hydroxyl anion.In addition, the far infrared generation of tourmaline is rendered as high value, has powerful thermal effect and high penetration power.
Kweiyang stone produces a large amount of anion, and its amount is ten times of left and right of tourmaline, at room temperature has 96% high far infrared irradiation rate characteristic.
Described mineral matter is at least one in bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone or doctor Wang Shi, the content of described mineral matter is preferably as follows: with respect to bleaching earth 100 weight portions, illite is 80 to 130 weight portions, seven colored stones are 80 to 130 weight portions, biotite is 40 to 70 weight portions, germanium is 40 to 70 weight portions, tourmaline is 120 to 200 weight portions, volcanic ash is 80 to 130 weight portions, Kweiyang stone is 120 to 200 weight portions, and doctor Wang Shi is 80 to 130 weight portions.Find energy generation and anion generation that mineral matter mixing ratio as above can be brought into play to greatest extent the far infrared irradiation effect and bring thus through many experiments.
The state of preferably described mineral matter being clayed into power is used.The mean size of powder is preferably 300 to 50, 000 order (mesh), each mineral matter more specifically size is as follows: illite is 300 to 1, 000 order, seven colored stones are 300 to 1, 000 order, biotite is 300 to 1, 000 order, germanium is 1, 000 to 4, 000 order, tourmaline is 1, 500 to 6, 000 order, volcanic ash is 300 to 1, 000 order, Kweiyang stone is 15, 000 to 50, 000 order, doctor Wang Shi is 300 to 1, 000 order, yellow mica is 300 to 1, 000 order, Qarnet stone is 300 to 1, 000 order, lanthanite is 300 to 1, 000 order, anatase is 300 to 1, 000 order, monazite is 1, 000 to 4, 000 order, zeolite is 300 to 1, 000 order.If size of powder particles is less than 300 orders, because powder surface is long-pending, increase, powder easily carries out mutual reaction, while using in the high temperature internal combustion engine, have explosion danger, if size of powder particles is greater than 50,000 orders, the exit dose of far infrared and anion can be reduced, thereby the ability of the cation such as reduction black smoke etc. can be reduced.Various mineral matter sizes depend on the characteristic of mineral matter.
Described pyrolkigneous liquid, for having gathered the flue gas produced contact with extraneous air when timber is made to charcoal and the material that falls of liquefying forming, can be used multiple timber as timber, preferably includes bamboo pyrolkigneous liquid, Oak Tree pyrolkigneous liquid and ginkgo pyrolkigneous liquid.More preferably, through experiment, find, the most effectively the Oak Tree pyrolkigneous liquid.Pyrolkigneous liquid has the highly acid of about 3.5pH left and right, the hydrogen ion active ions of pyrolkigneous liquid middle and high concentration.
Can further comprise at least one in organic germanium or inorganic matter (mineral) in pyrolkigneous liquid.
Organic germanium is (GeCH
2CH
2COOH)
2O
3, the purity of germanium is preferably approximately 42.8%, and it is water-soluble.Organic germanium radiates a large amount of anion, plays the effect of neutralizing cation.
Contain the compositions such as boron or silicon in inorganic matter (mineral), produce anion, by the far-infrared radiation mineral matter is dropped in distilled water and prepares.To this, in the preparation method, illustrate.As for the composition of inorganic matter (mineral) pyrolkigneous liquid, organic germanium and inorganic matter (mineral), be preferably with respect to pyrolkigneous liquid 100 weight portions, organic germanium is 50 to 75 weight portions, inorganic matter (mineral) is 50 to 75 weight portions.More preferably, with respect to pyrolkigneous liquid 100 weight portions, organic germanium is 60 to 70 weight portions, and inorganic matter (mineral) is 60 to 70 weight portions.Through many experiments, find, when the mixing ratio of pyrolkigneous liquid, organic germanium and inorganic matter (mineral) as above the time, the generation maximum of anion.Compared with only using acid pyrolkigneous liquid, organic germanium or the inorganic matter (mineral) that comprises mineral matter are mixed to the effect that the exit dose that just can bring anion increases with pyrolkigneous liquid.
Described transition metal is preferably at least one in platinum, vanadium, palladium or silver, and more preferably, when platinum is chloroplatinic acid, vanadium is vanadic anhydride, more effective when silver is nano silver particles.By anion, the harmful substance ionization, Ionized atom becomes H by the reduction of the non-metal kind transition metal such as platinum, vanadium, palladium, silver
2O, CO
2.Therefore at internal combustion engine when in the acidic catalyst agent solution, comprising transition metal, Ionized atom is reduced and reduces the black smoke of internal combustion engine, thereby air-fuel ratio is brought to unprecedented raising effect.The composition of transition metal is preferably as follows: with respect to chloroplatinic acid 100 weight portions, vanadic anhydride is 150 to 250 weight portions, and palladium is 120 to 200 weight portions, and nano silver particles is 40 to 65 weight portions.Find that through many experiments this mixing ratio is the most effective to reducing Ionized atom.
Also be mixed with by using pyrolkigneous liquid and the transition metal that comprises organic germanium or inorganic matter (mineral) except mineral matter, thereby can bring into play to greatest extent the exit dose of far infrared and anion, and, by the anion of radiation, oxidation and the reduction of Ionized material brought to remarkable effect.
Secondly, as shown in the precedence diagram of Fig. 1, internal combustion engine of the present invention comprises preparation process S10, whipping step S20 and maturation stage S30 by the formation method of acidic catalyst agent solution and forms.
Preparation process S10 is for preparing the step of mineral mixture, pyrolkigneous liquid and transition metal mixture, for the preparation of the step of each material that produces far infrared or anion.
In preparation process S10, mineral mixture consists of the far infrared radiation mineral, and mineral matter is preferably bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi, yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, hygerion
At least one in sericite, kaolin or bentonite.Mineral mixture, with respect to bleaching earth 100 weight portions, preferably mixes illite 80 to 130 weight portions, seven colored stone 80 to 130 weight portions, biotite 40 to 70 weight portions, germanium 40 to 70 weight portions, tourmaline 120 to 200 weight portions, volcanic ash 80 to 130 weight portions, Kweiyang stone 120 to 200 weight portions and doctor Wang Shi 80 to 130 weight portion preparations.
In preparation process S10, pyrolkigneous liquid can further comprise at least one in organic germanium or inorganic matter (mineral) and prepare.With respect to pyrolkigneous liquid 100 weight portions, preferably mix organic germanium 50 to 75 weight portions, inorganic matter (mineral) 50 to 75 weight portions.
When mixing pyrolkigneous liquid and organic germanium and/or inorganic matter (mineral), be uniformly mixed 2 to 20 hours at the temperature of 10 to 50 ℃, the sour composition due to pyrolkigneous liquid, form 2 to 5 pH.When the temperature of inorganic matter (mineral), during lower than 10 ℃, the mixing of each composition is not too suitable, can reduce telling on of anion, and when temperature surpasses 60 ℃, the composition evaporation owing to comprising in pyrolkigneous liquid, can reduce significantly anion and tell on.Temperature is more preferably 10 to 35 ℃.Pyrolkigneous liquid has the strong acid composition, therefore in 2 to 5 pH, is stirred.When mixing time is shorter than 2 hours, each material mixes abundant not, can reduce telling on of anion, when mixing time surpasses 20 hours, produce and interact between organic germanium or inorganic matter (mineral) composition and pyrolkigneous liquid, thus the generation of minimizing anion.Be more preferably 3 to 12 hours.
The present invention includes following steps: described inorganic matter (mineral) by dropping at least one in germanium, zeolite, illite, yellow mica, biotite, Qarnet stone or seven colored stones and being within 1.5th to 7, prepared by its slaking in distilled water.Contain the compositions such as boron or silicon in germanium, zeolite, illite, yellow mica, biotite, Qarnet stone or seven colored stones, the anion that therefore more improves mineral mixture tells on.Through 1.5 to 7 days, be more preferably slaking 2 to 5 days to carry out fermentation step.
In preparation process S10, transition metal mixture can drop in distilled water after acid treatment by carrying out.The acid of using in acid treatment is mainly phosphoric acid, can regulate pH concentration with phosphoric acid.Phosphoric acid has the character of attack metal intensely and oxide thereof, and it has when using phosphoric acid to process transition metal mixture can make oxidation and the maximized advantage of reduction effect.Due to harmful substance carbon monoxide (CO), hydrocarbon (HC), nitrogen oxide (NO
X) be ionized and reduced by transition metal mixture and become innocuous substance, therefore by acid-treated pH, regulating is important step.
After preparation process S10, whipping step S20 is by mineral mixture, pyrolkigneous liquid or contains organic germanium or the step of the pyrolkigneous liquid of inorganic matter (mineral) and transition metal mixture stirring.In whipping step, mix with best match ratio the material that contains in a large number far infrared, anion and tell on to make it bringing into play to greatest extent anion, thereby prepare internal combustion engine acidic catalyst agent solution.
Composition in whipping step S20 is preferably as follows: with respect to mineral mixture 100 weight portions, pyrolkigneous liquid is 25 to 90 weight portions, and transition metal is 0.01 to 40 weight portion.
Whipping step S20 comprises the first whipping step S21 and the second whipping step S22 and forms.The first whipping step S21 for dropping into mineral mixture and being stirred the step for preparing dilute solution in pyrolkigneous liquid, and the second whipping step S22 is the step that drops into transition metal mixture and stirred in dilute solution.Contain sour composition in pyrolkigneous liquid, therefore at first mix again after mixed mineral matter mixture with sour hyperergic transition metal mixture to suitable mix effective.While mixing in the ban pyrolkigneous liquid and transition metal mixture, due to the larger reactivity of transition metal, can there is the possibility of being reacted with the sour composition of pyrolkigneous liquid, therefore there is safe not problem.Therefore, preferably at mixed mineral matter mixture and pyrolkigneous liquid with after being diluted, hybrid transition metal.
Secondly, maturation stage S30 makes the internal combustion engine the prepared step of acidic catalyst agent solution slaking, and it is the step for the preparation of the solution that fully contains far infrared and anion.In maturation stage S30, the internal combustion engine acidic catalyst agent solution that at the temperature of 30 to 60 ℃ prepared by slaking.More preferably, the temperature of 35 to 50 ℃ is more effective.During lower than 30 ℃, can't obtain fully the anion of mineral mixture when curing temperature, when curing temperature, during higher than 60 ℃, the anion produced breaks away from outside solution, can produce the problem that anion quantity reduces.Curing time is 7 to 15, and preferably, 9 to 12 effective to the generation of anion.Now, between the maturation period, for the internal combustion engine that makes to have prepared is not subject to external action with the acidic catalyst agent solution, preferably slaking in rustless steel container.
When the burning of cylinder, the air sucked and acidic catalyst agent solution gas can produce harmful substance carbon monoxide, hydrocarbon, nitrogen oxide or oxysulfide etc. in the combustion process of burning volatile oil or light oil.Carbon monoxide, hydrocarbon oxidation that acidic catalyst agent solution gas produces low temperature when outburst, and make it to become ion, the atom that becomes ion reduces by transition metal innocuous substances such as becoming water, carbon dioxide.In addition, the nitrogen oxide, the oxysulfide that when high temperature breaks out, form are reduced into nitrogen (N by transition metal
2), sulfur monoxide (SO), therefore reduce black smoke.
In addition, the anion of mineral matter carries out ion-exchange to the unburned gas in cylinder makes it to be transformed into oxygen, thereby more reduces black smoke.Due to the generation of oxygen, air capacity increases in car, harmful substance ionization and the reduction such as carbon monoxide, hydrocarbon, nitrogen oxide and oxysulfide, thus black smoke is reduced approximately to 60% to 70%.The minimizing of black smoke finally can bring the raising effect of air-fuel ratio.
Below, the acidic catalyst agent solution prepare by said method is installed at vehicle, and the end value of the minimizing effect of the harmful substance produced during to the burning of the volatile oil at vehicle is tested.The experimental subjects vehicle, for using the grandeurXG (Hyundai Motor Co. manufacture) of volatile oil, is released market November calendar year 2001, and the accumulative total running distance is 223.045km.
Table 1
The discharge rate of the known carbon monoxide of discharge rate, hydrocarbon and the nitrogen oxide of the harmful substance of the vehicle of the installation acidic catalyst agent solution from described table 1 all reduces.Carbon monoxide and hydrocarbon reduce 3 to 4 times than discharging standard value, and the reduction of black smoke reduces.In addition, take while discharging standard value as benchmark, nitrogen oxide reduces approximately 12 times significantly, and hence one can see that, and described acidic catalyst agent solution has remarkable effect to the discharge rate minimizing of nitrogen oxide.Below that the black smoke that uses internal combustion engine to represent by pH with the acidic catalyst agent solution detects the experimental example that reduces effect.The acidic catalyst agent solution prepared is arranged in bonnet, under the heat of engine or normal temperature, becomes gaseous state, and when air cleaner sucks extraneous air, the gas in extraneous air and solution mixes and passes through the interior combustion process of cylinder.
Experimental example 1
Bleaching earth, Kweiyang stone, monazite, biotite, tourmaline, seven colored stones, illite and anatase mixing are prepared to mineral matter.In order wherein to mix prepared by organic germanium (Ge-132) and inorganic matter (mineral) for pyrolkigneous liquid, platinum chloride, vanadic anhydride, silver nitrate and NaOH magnesium are carried out to acid treatment with the preparation transition metal mixture, and carry out this experiment.Prepared internal combustion engine is 1000ml with the acidic catalyst agent solution, and the pH value is approximately 3.8.(the experimental subjects vehicle, for using the grandeurXG (Hyundai Motor Co. manufacture) of volatile oil, is released market November calendar year 2001, and the accumulative total running distance is 223.045km.)
Table 2
The black smoke standard value that ※ is generally acknowledged is 25%.
Experimental example 2
Identical with experimental example 1, but the internal combustion engine acidic catalyst agent solution of 1000ml prepared by the pH0.4 phosphoric acid dilution of use 200lml.Now the pH value is approximately 3.0.
Table 3
The black smoke standard value that ※ is generally acknowledged is 25%.
Experimental example 3
Identical with experimental example 1, but the internal combustion engine acidic catalyst agent solution of 1000ml prepared by the pH0.4 phosphoric acid dilution of use 300lml.Now the pH value is approximately 2.2.
Table 4
The black smoke standard value that ※ is generally acknowledged is 25%.
From above-mentioned table 2 to table 4, the black smoke density % of nitric oxide (NO), far below generally acknowledged black smoke standard value 25%, reduces effectively black smoke.The acidic catalyst agent solution prepared through slaking radiates a large amount of anion and far infrared and is invested in the burner of internal combustion engine, and is that carbon monoxide, nitrogen oxide, oxysulfide etc. carry out the nertralizer oxidation and reduce to reduce waste gas and black smoke degree to harmful substance.Table 2 is being used phosphoric acid to carry out having difference in acid treatment to table 4, and pH is lower, on black smoke reduces, more has remarkable effect, in table 4 black smoke density % be only lower than generally acknowledged black smoke standard value 25% half 11%.When the pH value, regulate into about 2.2 the time, black smoke density % significantly reduces.The concentration of pH is lower, and black smoke density % is just lower, thereby this situation means Ionized activate degree, becomes large oxidation and reducing power grow.
When black smoke density % is 20% to 29%, air-fuel ratio is 10km/L, and when black smoke density is 14% to 16%, air-fuel ratio is 11km/L, and black smoke density % brings the thrifty effect of fuel when low.It is 60% to 70% that the average black smoke of acidic catalyst agent solution reduces effect, therefore equally effectively improves air-fuel ratio.The raising of air-fuel ratio reduces fuel consumption, thereby reduces fuel efficiency, so it becomes the scheme that can solve resource exhaustion problem or problem of environmental pollution.
Interest field of the present invention is not limited to above-described embodiment, but is embodied as the embodiment of various ways in the appending claims scope.In the scope that does not break away from claims the present invention for required protection spirit those skilled in the art all flexible multiple scope also be considered as including in the scope of claims record of the present invention.
Claims (23)
1. an internal combustion engine acidic catalyst agent solution, is characterized in that, comprises mineral matter, pyrolkigneous liquid and transition metal.
2. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
With respect to described mineral matter 100 weight portions, described pyrolkigneous liquid is 25 to 90 weight portions, and described transition metal is 0.01 to 40 weight portion.
3. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
Described mineral matter is the far-infrared radiation mineral.
4. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
Described mineral matter is at least one in bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi, yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, Hygerion, sericite, kaolin or bentonite.
5. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
With respect to bleaching earth 100 weight portions of described mineral matter, comprise illite 80 to 130 weight portions, seven colored stone 80 to 130 weight portions, biotite 40 to 70 weight portions, germanium 40 to 70 weight portions, tourmaline 120 to 200 weight portions, volcanic ash 80 to 130 weight portions, Kweiyang stone 120 to 200 weight portions and doctor Wang Shi 80 to 130 weight portions.
6. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
Described mineral matter is Powdered, and the mean size of described powder is 300 to 50000 orders.
7. internal combustion engine according to claim 4 acidic catalyst agent solution, is characterized in that,
Described illite is 300 to 1000 orders, described seven colored stones are 300 to 1000 orders, described biotite is 300 to 1000 orders, described germanium is 1000 to 4000 orders, described tourmaline is 1,500 to 6000 orders, described volcanic ash is 300 to 1000 orders, described Kweiyang stone is 15000 to 50000 orders, and described doctor Wang Shi is that 300 to 1000 orders, described yellow mica are 300 to 1000 orders, and described Qarnet stone is 300 to 1000 orders, described lanthanite is 300 to 1000 orders, described anatase is 300 to 1000 orders, and described monazite is 1000 to 4000 orders, and described zeolite is 300 to 1000 orders.
8. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
Further comprise any in organic germanium or inorganic matter (mineral) at described pyrolkigneous liquid.
9. internal combustion engine according to claim 8 acidic catalyst agent solution, is characterized in that,
With respect to described pyrolkigneous liquid 100 weight portions, described organic germanium is 50 to 75 weight portions, and described inorganic matter (mineral) is 50 to 75 weight portions.
10. internal combustion engine according to claim 1 acidic catalyst agent solution, is characterized in that,
Described transition metal is at least one in platinum, vanadium, palladium or silver.
11. according to the described internal combustion engine of claim 1 or 10 acidic catalyst agent solution, it is characterized in that,
Described transition metal, with respect to chloroplatinic acid 100 weight portions, comprises vanadium pentoxide 150 to 250 weight portions, palladium 120 to 200 weight portions and nano silver particles 40 to 65 weight portions and forms.
12. the internal combustion engine formation method of acidic catalyst agent solution, is characterized in that, comprising:
Preparation process, prepare mineral mixture, pyrolkigneous liquid and transition metal mixture;
Whipping step drops into described mineral mixture and described transition metal mixture and is stirred and prepare internal combustion engine acidic catalyst agent solution in described pyrolkigneous liquid; And
Maturation stage, make acidic catalyst agent solution slaking for described internal combustion engine.
13. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
At mineral mixture described in described preparation process, by the far-infrared radiation mineral, formed, described mineral matter is at least one in bleaching earth, illite, seven colored stones, biotite, germanium, tourmaline, volcanic ash, Kweiyang stone, doctor Wang Shi, yellow mica, Qarnet stone, lanthanite, anatase, monazite, zeolite, titanium, Hygerion, sericite, kaolin or bentonite.
14. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
Described mineral mixture is with respect to bleaching earth 100 weight portions, comprises illite 80 to 130 weight portions, seven colored stone 80 to 130 weight portions, biotite 40 to 70 weight portions, germanium 40 to 70 weight portions, tourmaline 120 to 200 weight portions, volcanic ash 80 to 130 weight portions, Kweiyang stone 120 to 200 weight portions and doctor's Wang Shi's 80 to 130 weight portions and forms.
15. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
At pyrolkigneous liquid described in described preparation process, by further comprising organic germanium or inorganic matter (mineral), prepare.
16. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 15, is characterized in that,
With respect to described pyrolkigneous liquid 100 weight portions, described organic germanium is 50 to 75 weight portions, and described inorganic matter (mineral) is 50 to 75 weight portions.
17. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
In described preparation process, under the temperature of 10 to 50 ℃, 2 to 5 pH condition, described pyrolkigneous liquid, described organic germanium and described inorganic matter (mineral) are mixed 2 to 20 hours.
18. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 15, is characterized in that,
By dropping at least one in germanium, zeolite, illite, yellow mica, biotite, Qarnet stone or seven colored stones and make it slaking in distilled water, within 1.5 to 7 days, prepared by described mineral (mineral).
19. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
In described preparation process, transition metal is carried out after acid treatment, it being dropped in distilled water.
20. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 19 is characterized in that described acid is phosphoric acid.
21. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
In described whipping step, with respect to described mineral mixture 100 weight portions, described pyrolkigneous liquid is 25 to 90 weight portions, and described transition metal mixture is 0.01 to 40 weight portion.
22. the formation method according to the described internal combustion engine of claim 12 or 21 with the acidic catalyst agent solution, is characterized in that, described whipping step comprises:
The first whipping step drops into described mineral mixture and is stirred and prepare dilute solution in described pyrolkigneous liquid; And
The second whipping step, drop into described transition metal mixture and stirred in the described dilute solution in described the first whipping step.
23. the formation method of acidic catalyst agent solution for internal combustion engine according to claim 12, is characterized in that,
Described maturation stage is to make acidic catalyst agent solution slaking 7 to 15 days in the temperature of 30 to 60 ℃ for described internal combustion engine.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104140856B (en) * | 2014-08-06 | 2016-05-18 | 青岛创恩康环保设备有限公司 | A kind of engine exhaust gas liquid charging stock and preparation method thereof that reduces |
| CN105482510A (en) * | 2015-12-20 | 2016-04-13 | 高大元 | Preparing method for nanometer illite platinum-loaded plastic antibacterial agent |
| CN107189770A (en) * | 2016-03-15 | 2017-09-22 | 新高丽绿色有限公司 | For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously |
Also Published As
| Publication number | Publication date |
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| KR101475782B1 (en) | 2014-12-24 |
| KR20130127797A (en) | 2013-11-25 |
| CN103418436B (en) | 2016-04-27 |
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