KR102145932B1 - Exaust gas abatement materials for internal combustion engine - Google Patents

Abstract

The present invention relates to a composition for reducing exhaust gas for an internal combustion engine, and more particularly, it is possible to increase explosive power by inducing complete combustion by promoting digestion by injecting it together with the air of the engine of the internal combustion engine. It relates to a composition for reducing emissions for internal combustion engines with significantly lowered emissions.
According to the exhaust emission reduction composition for an internal combustion engine formed as a preferred sealing example of the present invention, since the amount of catalyst gas produced by the polyvinyl liquid is controlled, a large amount of catalyst gas does not escape and can be used for a long time. It is very effective because it can be supplied as a gas through a fine hole (about 1mm~3mm) before the pit.

Description

Emission Reduction Composition for Internal Combustion Engine {EXAUST GAS ABATEMENT MATERIALS FOR INTERNAL COMBUSTION ENGINE}

The present invention relates to a composition for reducing exhaust gas for an internal combustion engine, and more particularly, it is possible to increase explosive power by inducing complete combustion by promoting digestion by injecting it together with the air of the engine of the internal combustion engine. It relates to a composition for reducing emissions for internal combustion engines with significantly lowered emissions.

In general, the gas emitted by the internal combustion engine is referred to as exhaust gas, and contains numerous harmful substances such as carbon dioxide, carbon monoxide, hydrocarbons, sulfur oxides, hydrogen sulfide, nitrogen oxides, and ammonia. Since carbon monoxide is generated from lack of oxygen during combustion, it does not occur when the mixer is diluted to more than 148%, which is the theoretical air fuel ratio of a gasoline engine (the ratio of air and gasoline that the mixer completely burns). The generation of hydrocarbons is the least, but when it is diluted beyond the theoretical air fuel ratio, the propagation of the flame stops, causing incomplete combustion, and carbon monoxide increases.

Nitrogen oxide is produced by reacting oxygen and nitrogen in the air at high temperatures, so it becomes the maximum before and after the theoretical air ratio.

The internal combustion engine confines a mixture of fuel and air in a closed cylinder, compresses and ignites it to rapidly burn carbon in the fuel.

After combustion, the gas is discharged to the outside, and a fresh mixer is introduced again, and the gas thrown out to the outside is exhaust gas.

Among the internal combustion engines, exhaust gas burned and discharged from engines such as gasoline or diesel used in automobiles occupies most.

The exhaust gas emitted from the automobile pollutes the atmosphere and contains harmful components in the body, which has become a social problem due to new pollution.

As the problems of environmental pollution and resource depletion emerge as described above, fuel efficiency improvement agents such as smoke reduction agents or smoke reduction devices are continuously being developed.

However, the recently developed soot reduction composition also has a soot reduction level of 30 to 40%, and the fuel efficiency improvement effect is only 5 to 10%. Fuel economy improvement vehicles are being developed, but, compared to this, the progress of environmental pollution and resource depletion is remarkably fast, and thus, a lot of development of a composition having an excellent smoke reduction effect is in progress.

Conventionally, techniques related to combustion promotion and emission reduction compositions have been disclosed in Korean Patent Office Registration Nos. 0690553, 1716174, or Korean Patent Publication No. 2017-0110137.

However, the conventional combustion promotion and emission reduction composition has the following problems.

(1) Since the amount of the supplied catalyst composition is consumed a lot, it must be changed frequently.

(2) It is very difficult and complicated to install because it must be installed on the exhaust side.

In order to solve the above problems, the present invention includes a basic powder obtained by mixing white clay, chili stone, illite, noble stone, biotite, tourmaline, zeolite and pozzolan at the same weight ratio;

Citric acid water formed by adding 5 to 120 g of clay and 5 to 120 g of biotite to 1 liter of citric acid water in which 50 to 100 g of citric acid is dissolved per 1 liter of natural water, and then stirring with a drop;

Platinum chloride water in which 1 to 5 g of platinum chloride is dissolved per 2.5 liters of natural water;

Ruthenium water in which 1-5 g of ruthenium is dissolved per 2.5 liters of natural water;

Germanium water in which 2 to 10 g of germanium is dissolved per 1 liter of natural water;

Tannic acid water obtained by dissolving 1 to 20 g of tannic acid per liter of natural water;

Lanthanum water in which 1-50g of lanthanum is dissolved per 1 liter of natural water;

Zirconium water in which 1 to 20 g of zirconium is dissolved per liter of natural water;

Magnesium hydroxide water in which 1-50 g of magnesium hydroxide per liter of natural water is dissolved;

Vanadium water in which 8-50 g of vanadium is dissolved per 1 liter of natural water;

Titanium water in which 1-50g of titanium is dissolved per 1 liter of natural water;

Germanium water in which 1-50 g of germanium is dissolved per 1 liter of natural water;

A wood herb liquor made by mixing 2 liters of an EMT agent in which ethyl alcohol and methyl alcohol are mixed at 6:4 per 1 liter of wood vinegar, followed by stirring 40-160% by weight of the basic powder, and leaving it for 15 days at room temperature;

Per 1 liter of polyvinyl solution, 10 ml of EMT agent, 10 ml of activated white clay, 10 ml of platinum chloride, 10 ml of ruthenium water, and 100 g of basic powder are stirred and placed at room temperature for 15 days to prepare the main material.

Basic powder per 1 liter of the above main ingredient 20-800g, EMT 20-200ml, lanthanum water 20-300ml, zirconium water 20-300ml, magnesium hydroxide water 20-600ml, vanadium water 20-600ml, germanium water 20-600ml, citric acid water After stirring 20-300ml, wood herb liquid 20-500ml, activated white soil water 20-400ml, platinum chloride water 20-400ml, and ruthenium water 20-800ml, and then aging at room temperature for 15 days to form a prepared primary material,

For each liter of the main material, 20 to 1 liter of basic powder, 200 to 2 liters of EMT, 20 to 1 liter of activated white soil, 20 to 1 liter of citric acid water, 20 to 1 liter of wood herb liquid, 20 to 1 liter of germanium water, and platinum chloride water After stirring 20 to 1 liter, it is aged at room temperature for 15 days to form a prepared secondary material,

After stirring the basic powder 20-400g per 1 liter of the main material, 20-400 ml of the EMT agent, 20 to 1 liter of the primary material, and 20 to 1 liter of the secondary material, a tertiary material prepared by aging at room temperature for 15 days was formed. after

It characterized in that it is prepared by stirring at room temperature for 15 days after stirring the basic powder 150g, the primary material 5 ~ 500ml, the secondary material 5 ~ 500ml and the tertiary material 5 ~ 2500ml per 1 liter of the platinum chloride water.

According to the exhaust emission reduction composition for an internal combustion engine formed by the preferred sealing example of the present invention, the following effects occur.

(1) Since the amount of catalyst gas produced by the polyvinyl liquid is controlled, a large amount of catalyst gas does not escape at once, so it can be used for a long time.

(2) It is very effective because it can be supplied as a gas through a fine hole (about 1mm~3mm) before the intake air pit.

1 is a photograph of an installation state of an exhaust emission reduction composition for an internal combustion engine formed in a preferred embodiment of the present invention.
Figure 2 is a vehicle inspection table before installing the exhaust emission reduction composition for an internal combustion engine formed in a preferred embodiment of the present invention (emission inadequate)
Figure 3 is a vehicle inspection table after 15 days of operation by installing the smoke reduction composition for an internal combustion engine formed in a preferred embodiment of the present invention in the same vehicle that produced the result of Figure 2 (emission suitable)

The present invention is a basic powder obtained by mixing white clay, cloisonne, illite, noble stone, biotite, tourmaline, zeolite and pozzolan at the same weight ratio; Citric acid water formed by adding 5 to 120 g of clay and 5 to 120 g of biotite to 1 liter of citric acid water in which 50 to 100 g of citric acid is dissolved per 1 liter of natural water, and then stirring with a drop; Platinum chloride water in which 1 to 5 g of platinum chloride is dissolved per 2.5 liters of natural water; Ruthenium water in which 1-5 g of ruthenium is dissolved per 2.5 liters of natural water; Germanium water in which 2 to 10 g of germanium is dissolved per 1 liter of natural water; Tannic acid water obtained by dissolving 1 to 20 g of tannic acid per liter of natural water; Lanthanum water in which 1-50g of lanthanum is dissolved per 1 liter of natural water; Zirconium water in which 1 to 20 g of zirconium is dissolved per liter of natural water; Magnesium hydroxide water in which 1-50 g of magnesium hydroxide per liter of natural water is dissolved; Vanadium water in which 8-50 g of vanadium is dissolved per 1 liter of natural water; Titanium water in which 1-50g of titanium is dissolved per 1 liter of natural water; Germanium water in which 1-50 g of germanium is dissolved per 1 liter of natural water; A wood herb liquid made by mixing 2 liters of an EMT agent mixed with ethyl alcohol and methyl alcohol at a ratio of 6:4 per 1 liter of wood vinegar, and then stirring 40-160% by weight of the basic powder, and leaving it for 15 days at room temperature; Per 1 liter of polyvinyl solution, 10 ml of EMT agent, 10 ml of activated white soil water, 10 ml of platinum chloride water, 10 ml of ruthenium water, and 100 g of basic powder are stirred and left at room temperature for 15 days to prepare the main material.

Basic powder per 1 liter of the above main ingredient 20-800g, EMT 20-200ml, lanthanum water 20-300ml, zirconium water 20-300ml, magnesium hydroxide water 20-600ml, vanadium water 20-600ml, germanium water 20-600ml, citric acid water After stirring 20-300ml, wood herb liquid 20-500ml, activated white soil water 20-400ml, platinum chloride water 20-400ml, and ruthenium water 20-800ml, and then aging at room temperature for 15 days to form a prepared primary material,

For each liter of the main material, 20 to 1 liter of basic powder, 200 to 2 liters of EMT, 20 to 1 liter of activated white soil, 20 to 1 liter of citric acid water, 20 to 1 liter of wood herb liquid, 20 to 1 liter of germanium water, and platinum chloride water After stirring 20 to 1 liter, it is aged at room temperature for 15 days to form a prepared secondary material,

After stirring the basic powder 20-400g per 1 liter of the main material, 20-400 ml of the EMT agent, 20 to 1 liter of the primary material, and 20 to 1 liter of the secondary material, a tertiary material prepared by aging at room temperature for 15 days was formed. after

It is formed by stirring the basic powder 150g per 1 liter of the platinum chloride water, 5 to 500 ml of the primary material, 5 to 500 ml of the secondary material and 5 to 2500 ml of the tertiary material, and then aging at room temperature for 15 days.

The basic powder is formed by crossing white clay, cloisonne, illite, noble stone, biotite, tourmaline, zeolite and pozzolan at the same weight ratio.

The basic powder is suitable to be pulverized very finely, even to a nano-type powder, and is used by completely removing foreign substances.

The citric acid water and tannic acid water are administered to control the acidity, that is, to maintain the pH of 3.5 to 4.5.

The platinum chloride water, ruthenium water, germanium water, lanthanum water, zirconium water, magnesium hydroxide water, vanadium water, titanium water, germanium water, and wood herb liquid are all formed by diluting with purified water.

The EMT agent is formed by mixing ethyl alcohol and methyl alcohol at 6:4.

As the main material, a polyvinyl liquid is used as the main raw material, and the polyvinyl liquid is formed to prevent the catalyst gas from rapidly exiting.
The polyvinyl liquid is a liquid polyvinyl resin, and is composed of a liquid polyvinyl resin.

The primary material, secondary material, and tertiary material are prepared to make the final material of the present invention and each requires a 15-day aging period.

In the final step of the present invention, 5 to 500 ml of the primary material, 5 to 500 ml of the secondary material, and 5 to 2500 ml of the tertiary material are stirred to form.

Lanthanum is a chemical element with a symbol La (←Latin: Lanthanum lanthanum [*]) and an atomic number of 57.

The wood vinegar liquid is a by-product obtained by cooling and drying smoke in the process of making charcoal. To make wood vinegar at all, wood is dried and charcoal is obtained as a by-product.

The tannin (tannin) acid is a kind of polyphenol that gives off a very astringent taste, is synthesized by plants, and binds to proteins to precipitate.

Germanium is a chemical element, the symbol Ge and the atomic number 32. A semiconductor material discovered in 1886 by the German chemist Vinkler, obtained in the process of refining ores such as copper, lead, and zinc.

The ruthenium is a chemical element and the symbol Ru has an atomic number of 44. It is a rare transition metal belonging to the platinum group. It is produced together from platinum ore, and is used as a catalyst in platinum alloys.

The chloroplatinic acid is a strongly acidic substance consisting of a combination of hydrogen and platinum chloride. It is well soluble in water and alcohol.

The citric acid is a weak organic acid mainly found in citrus fruits, and the chemical formula is C6H8O7. In biochemistry, citric acid is an intermediate product of the citric acid cycle that occurs in the metabolic processes of all organisms that breathe oxygen.

Hereinafter, the effect of the exhaust emission reduction composition for an internal combustion engine formed according to a preferred sealing example of the present invention will be described as follows.

1 is a photograph showing a state of being attached to the engine intake side of an automobile because it is appropriate to attach it to the intake side because the exhaust reducing composition is discharged as a catalyst gas.

As shown in Fig. 1, it can be installed very simply and neatly, and once installed, it can be used for a long time (about 6 months or more) because it is discharged only through a small hole.

FIG. 2 is a table showing the results of testing the vehicle in the picture shown in FIG. 1 at an inspection station, and receiving rejection in smoke.

However, looking at FIG. 3, it is possible to confirm the result of receiving a pass in the soot that failed in FIG. 2.

In other words, it was confirmed that the smoke reduction and complete combustion were achieved by the smoke reduction composition of the present invention because the result was passed as a result of using and using the smoke reduction composition of the present invention for 15 days in the same vehicle that failed.

According to the exhaust emission reduction composition for an internal combustion engine formed as a preferred sealing example of the present invention, since the amount of the catalyst gas produced by the polyvinyl liquid is controlled, a large amount of catalyst gas does not escape and can be used for a long time. Since it can be supplied in a gaseous state through a fine hole (about 1mm~3mm) before the air pit, the effect is very excellent.

Although the present invention has been described based on a preferred embodiment with reference to the accompanying drawings, it is apparent that a person skilled in the art can make various modifications without departing from the scope of the present invention covered by the claims to be described later from this description.

Claims (3)

delete Basic powder obtained by mixing white clay, cloisonne, illite, noble stone, biotite, tourmaline, zeolite, and pozzolan at the same weight ratio;
Citric acid water formed by adding 5 to 120 g of clay and 5 to 120 g of biotite to 1 liter of citric acid water in which 50 to 100 g of citric acid is dissolved per 1 liter of natural water, and then stirring with a drop;
Platinum chloride water in which 1 to 5 g of platinum chloride is dissolved per 2.5 liters of natural water;
Ruthenium water in which 1-5 g of ruthenium is dissolved per 2.5 liters of natural water;
Germanium water in which 2 to 10 g of germanium is dissolved per 1 liter of natural water;
Tannic acid water obtained by dissolving 1 to 20 g of tannic acid per liter of natural water;
Lanthanum water in which 1-50g of lanthanum is dissolved per 1 liter of natural water;
Zirconium water in which 1 to 20 g of zirconium is dissolved per liter of natural water;
Magnesium hydroxide water in which 1-50 g of magnesium hydroxide per liter of natural water is dissolved;
Vanadium water in which 8-50 g of vanadium is dissolved per 1 liter of natural water;
Titanium water in which 1-50g of titanium is dissolved per 1 liter of natural water;
Germanium water in which 1-50 g of germanium is dissolved per 1 liter of natural water;
A wood herb liquor made by mixing 2 liters of an EMT agent in which ethyl alcohol and methyl alcohol are mixed at 6:4 per 1 liter of wood vinegar, followed by stirring 40-160% by weight of the basic powder, and leaving it for 15 days at room temperature;
Per 1 liter of polyvinyl solution, 10 ml of EMT agent, 10 ml of activated white clay, 10 ml of platinum chloride, 10 ml of ruthenium water, and 100 g of basic powder are stirred and placed at room temperature for 15 days to prepare the main material.
Basic powder per 1 liter of the above main ingredient 20-800g, EMT 20-200ml, lanthanum water 20-300ml, zirconium water 20-300ml, magnesium hydroxide water 20-600ml, vanadium water 20-600ml, germanium water 20-600ml, citric acid water After stirring 20-300ml, wood herb liquid 20-500ml, activated white soil water 20-400ml, platinum chloride water 20-400ml, and ruthenium water 20-800ml, and then aging at room temperature for 15 days to form a prepared primary material,
For each liter of the main material, 20 to 1 liter of basic powder, 200 to 2 liters of EMT, 20 to 1 liter of activated white soil, 20 to 1 liter of citric acid water, 20 to 1 liter of wood herb liquid, 20 to 1 liter of germanium water, and platinum chloride water After stirring 20 to 1 liter, it is aged at room temperature for 15 days to form a prepared secondary material,
After stirring the basic powder 20-400g per 1 liter of the main material, 20-400 ml of the EMT agent, 20 to 1 liter of the primary material, and 20 to 1 liter of the secondary material, a tertiary material prepared by aging at room temperature for 15 days was formed. after,
Smoke reduction composition for an internal combustion engine, characterized in that the basic powder 150g per 1 liter of platinum chloride water, the primary material 5 ~ 500ml, the secondary material 5 ~ 500ml and the tertiary material 5 ~ 2500ml are stirred and then aged for 15 days at room temperature. . delete

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