CN101270276A - Additive for cooling water and antifreeze, antifreeze added with the same - Google Patents
Additive for cooling water and antifreeze, antifreeze added with the same Download PDFInfo
- Publication number
- CN101270276A CN101270276A CNA2007101525280A CN200710152528A CN101270276A CN 101270276 A CN101270276 A CN 101270276A CN A2007101525280 A CNA2007101525280 A CN A2007101525280A CN 200710152528 A CN200710152528 A CN 200710152528A CN 101270276 A CN101270276 A CN 101270276A
- Authority
- CN
- China
- Prior art keywords
- additive
- deicing fluid
- weight
- hydrogen
- scatterer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
Abstract
The invention provides an additive for cooling water and antifreeze of a radiator for improving performance of conveying equipment, and antifreeze prepared by adding the additive. The additive contains tourmaline powder, medical stone, germanium and rare earth metals such as lanthanum, cerium, neodymium etc., hydrogen is produced via lanthanum (La), cerium (Ce) and neodymium (Nd) with hot water in cooled one, the produced hydrogen is stored in iron-titanium alloy, and the stored hydrogen is dispersed again with a function of power storage by the circulation. The invention is capable of saving fuels and reducing purged gas. Furthermore, the invention makes for cleaning up environment, decreasing noises, improving effect of combustion ratio and implementing the performances for maintaining electrostatic pressure and reducing static electricity, having a function of cleaning internal air of vehicles during a process of oxidizing and restoring repeatedly.
Description
Technical field
The present invention relates to be used to improve the additive of the scatterer water coolant of transportation equipment performance and deicing fluid and add the deicing fluid that this additive is made, relate in particular to the additive of the scatterer water coolant that is used to improve the transportation equipment performance and deicing fluid and add the deicing fluid that this additive is made, it is applicable to LPG (liquefied petroleum gas (LPG)), LNG (natural gas liquids) etc. to be the water cooling formula engine of various transportation equipments such as the automobile of medium and boats and ships weight equipment when the situation that the automobile motivating force is produced by mineral liquefied fuel-gasoline.
Background technology
Water cooling formula engine is divided into 2 cycles (cycle) mode and 4 cycles (cycle) mode substantially.
Wherein, find when observing the engine composition of 4 cycles (cycle) mode, form by suction-compression-blast-deflated 4 strokes, have cylinder head (cylinder head), cylinder body (block), piston, be used for carrying to the heat that produces when primary carburetor and combustion chamber and the engine carry out the refrigerative water coolant water jacket (water jacket), be used to make water coolant at scatterer round-robin water pump (water pump) and temperature control equipment (thermostat).In general, the function of water coolant mainly is to reduce the cooling function of engine thermal, but in addition also has other function.
Gasoline with 14.7: 1 mixed is inhaled into, by compression, during outburst, compression heat energy is released the piston of top dead center, forms kinetic energy (mechanical energy), makes crankshaft rotation, wheels thus, automobile is moved, but the heat that produces in this process is too much the time, the major parts of engine will be crooked or distortion and damaging.Therefore, prevent that this phenomenon and maintenance proper temperature from being the main effect of scatterer water coolant.Engine oil also has some refrigerating functions, but its effect is very little.
For this reason, developed and be used for the antifreeze multiple compositions such as deicing fluid that contain additives such as ethylene glycol, these compositions all are suitable for throughout the year.As an example, can enumerate the product that is mixed with phosphoric acid salt, silicate.
In addition, in engine material, change used in the past material-iron into aluminium alloy,, therefore be starved of the composition of developing the new ideas of coordinating mutually with the engine performance that changes in addition from beginning to change into iron-aluminum-titanium alloy several years ago.
The energy that use produces in the combustion chamber is 100% fuel, wherein 30% energy is with being used as power, but the friction of piston and cylinder and lose 5% loses 30% in hot process of cooling, and 35% remaining energy is by carbon monoxide (CO), hydrocarbon polymer (HC) or oxynitride (NO
x) discharge gas and lose, so power loss is very big.In addition, because the swelling pressure height in the cylinder, the exhaust velocity of discharging menifold (manifold) reaches the velocity of sound (mach one).
Summary of the invention
For addressing the above problem the present invention is proposed.The purpose of this invention is to provide the additive of the scatterer water coolant that is used to improve the transportation equipment performance and deicing fluid and add the deicing fluid that this additive is made, the carbon monoxide that produces in the minimizing burning, hydrocarbon polymer, oxynitride etc. are discharged the amount of gas, help environmental purification.
Another object of the present invention provides the additive of the scatterer water coolant that is used to improve the transportation equipment performance and deicing fluid and adds the deicing fluid that this additive is made, and uses the silicate (SiO of special preparation
4-3) the result, confirm to have very good result at first, but behind certain hour, confirm to produce to hurtful gel phenomenon and freeization phenomenons such as engines, so at prepare silicon hydrochlorate (SiO
4-3) state under, interpolation can replace the isotopic element-rare earth element of palladium catalyst (Pd), platinum (Pt), rhodium (Rh), improves fuel efficiency, and ratio of combustion is risen, and by the energy that moiety had, makes output improve more than 10%.
Other purpose of the present invention provides the additive of the scatterer water coolant that is used to improve the transportation equipment performance and deicing fluid and adds the deicing fluid that this additive is made, and has the function of purifying vehicle inner air in repeating oxidation and reductive process.
For achieving the above object, of the present inventionly be used to improve the scatterer water coolant of transportation equipment performance and the additive of deicing fluid contains tourmaline powder, medical stone and rare earth metal.
In addition, it is characterized in that with respect to the tourmalinite of 100 weight parts, described additive contains the medical stone of 50-1000 weight part and the rare earth metal of 14-30 weight part.
Above-mentioned medical stone is characterized in that, contains the SiO of 53.1-80.00 weight %
20.59-14.18 the MgO of weight %; 2.806-8.55 the Fe of weight %
2O
313.3-16.20 the Al of weight %
2O
31.63-6.85 the CaO of weight %; 1.88-4.28 the K of weight %
2O; 0.20-0.30 the TiO of weight %
2And the Na of 0.62-4.31 weight %
2O.
In addition, above-mentioned additive is characterized in that, contains the germanium of 0.001-0.07ppm.
In addition, above-mentioned additive is characterized in that, contains the selenium of 0.001-0.05ppm.
Above-mentioned rare earth metal is characterized in that, is selected from a kind of or two or more mixture in the group of being made up of lanthanum, cerium, neodymium.
In addition, above-mentioned additive is characterized in that, contains zeolite (zeolite).
In addition, above-mentioned additive is characterized in that, contains purity and be 99.99% SiO
2Nanoscale powder.
In addition, above-mentioned additive is characterized in that, contains TiO
2
In addition, for achieving the above object, add above-mentioned additive and make deicing fluid.
Above-mentioned deicing fluid is characterized in that, is benchmark with the whole deicing fluid of 100 weight parts, contains the above-mentioned additive of 0.1-2 weight part.
The present invention contains rare earth elements such as tourmalinite, medical stone, germanium and lanthanum as component.Below these materials are described in detail respectively.
Embodiment
* tourmalinite
Tourmalinite (Tourmaline) is unique mineral with permanent electric characteristic in the mineral that exist on the earth.Therefore, also be called the polarity xln.Negatively charged ion, weak current and the far infrared rays that this ore produces be to healthy and environmentally advantageous, so be the hot topic research of university and institute in the world.
Tourmalinite chemistry composition is magnesium (Mg), basic metal etc. and the borosilicate of the complexity of Al, forms hexagonal, nine jiaos, triangle, column.Two ends have (+), when being impacted and rub, produce electricity (0.6mA), and two ends are charged to be respectively positive and negative.In addition, tourmalinite obtains from grouan matter pegmatite, has the important associativity of hydroxyl ion.
Dielectric medium is meant and causes electropolarization when being placed on electric field and the material of surface charging lotus.But, not applying electric field from the outside and begin to have electropolarized crystallization at first yet even have yet, this crystallization is called the polarity xln.
In the polarity xln, some breaks away from original position the center of positive charge of this crystalline unit cell and center of negative charge.Therefore, the crystalline two ends become electrode.The positive electrode of tourmalinite and negative potential are unstable, but play pendulum always, and electronics ceaselessly flows to anodal from negative pole.Here it is static.
It is owing to constantly attract electronics from the sun that tourmalinite continues to produce dc static.Have positively charged ion and negatively charged ion during these electron synchrotrons, but the positively charged ion that is called proton can not only pass through negatively charged ion by the atmospheric sphere of the earth.
Be absorbed in the positive pole of tourmalinite from the negatively charged ion of the sun, and be transported to negative pole.Naturally, release a negatively charged ion electronics from negative electrode side, this negatively charged ion electronics ejects along the power line of positive electrode, forms permanent electric current.This electric current is the weak current of 0.06mA, is best suited for the electric current of human body.Add the capel-tourmalinite of both sides property electricity among the present invention with 0.6mA for additional electric exchangeability.
* medical stone
Medical stone belongs to granodiorite, and principal constituent is anhydrous silicic acid, aluminum oxide, and contains ferric oxide on a small quantity.Milky medical stone is as filtering medium, antiphlogistic etc., so be called remedies, it is releasing far infrared, is used for vaporium, feeder, medicine equipment etc.
As the known milky medical stone of remedies, the past is as the antiphlogistic of dermatosis such as pimple on the filtering medium made from extra care pill, the treatment back of the body etc. or useless fellow.According to Dong-eui-bo-gam, its character is sweet, gentle, nontoxic.
Every cubic centimetre medical stone has ten thousand holes of 3-15, so adsorptivity is strong, contains the 25000 kinds of inorganic salts of having an appointment.Since have exchange heavy metal and ionic effect, thus also can be used as the poisonous metal remover, when this rock of heating, will be releasing far infrared.
Medical stone has objectionable impurities elimination effect and heavy metal Decomposition, constitute by every cubic centimetre of multi-layer porous matter with ten thousand holes of 3-15, specific surface area is big, effect with absorption and decomposing pollutant matter and heavy metal etc., and in having and effects such as cement toxicity, antibiotic, insect protected and strong deodorizing power.Recently, also be used for the Dioxins technology for eliminating.Medical stone has water quality regulation and water purification effect, and acidity or strong alkaline water are adjusted to weakly alkaline (pH7.2-7.4), with the water quality sensitization, plays the water purification effect.The enriched oxygen content of medical stone is so when immersing medical stone in the water, COD (chemical oxygen demand (COD)) and BOD (biological oxygen demand) will reduce, and not only can play preservative activity, and can give vigor to organism by sensitization.In addition, medical stone has the far infrared radiation effect, and the resonance by far infrared radiation, resonance, sorption etc. are to the freshness that keeps food, improve sense of taste, stimulate circulation and remarkable effect is played in metabolism etc.
* Ge32,132 (inorganic, organic)
When the quantity of negatron (-) and proton (+) is identical, have electronics, separate at certain intervals with other cell at the cell and the skin of normal activity.But the unbalanced cell of negatron and proton just can not normal activity, unsettled cytotaxis normal cell.Therefore, the balance of negatron and proton is destroyed, can not normal activity, and mutagenesis.Produce disease when therefore, with the human body being the example explanation.
At this moment, germanium (Ge) electronics has 32 negatrons and 32 protons, and when feeling that periphery is uneven, in order to reach balance, germanium may become negatron (-) or positron (+).
Since electronics from-flow to+, germanium has the performance that can adjust unbalanced electronic number.
* also can add the feldspar-zeolite that uses alkaline earth series.
Zeolite found by the mineralogist of Sweden in 1756, with the ore of the meaning name of " ebullient stone ".
Zeolite has filled up water molecules in the fine pores of nano-order sizes of portion within it usually, and when this ore of heating, inner water molecules will evaporate, and produces water vapour.According to the above-mentioned fact with zeolite called after ebullient stone.The day of reflecting of Korea S has completely been buried natural zeolite near (transliteration) in a large number.
The skeleton of the zeolite three-D inorganic polymer that to be silicon be connected by 4 crosslinked oxygen respectively with aluminium, this moment, aluminium combined with 4 oxygen, so had anionic charge.In order to offset these anionic charges, there is multiple positively charged ion.
* can add and use purity is SiO more than 99.99%
2
Add with the nanometer powder form that purity is very high, ion stabilized with water coolant reduces static voltage and static, plays the vibration that reduces transportation equipments such as vehicle and the effect of noise thus.
* rare earth metal
The hydrogen occlusion characteristic of rare earth class series alloy be the seventies Holland Philip institute serendipitous in the magnetic force property research of SmCo5, and taking this as an opportunity has begun rare earth class series hydrogen absorbing alloy and study.The typical hydrogen absorbing alloy of rare earth class series is lanthanum-nickel series alloy and Mm series alloy.Particularly, the Mm series alloy is cheap, and characteristic is identical with LaNi5, so application meeting from now on is a lot.Using the MmNi5 alloy of hydrogen occlusion also researchs and develops as battery use in Korea S.Utilize in the pottery in the field of rare earth class, as the LaCrO of high-temperature electric conduction body
3Expect as MHD generating electrode materials, but the present shortcoming that does not also have to solve easy and alkali reaction.BaTiO
3Be perovskite compound, be widely used in strong dielectric-electrical condenser, posistor etc.This material adds rare earth class in order to change characteristic, control group thus, and shows the positive temperature profile that resistance sharply rises near Curie temperature.
Also developed recently with SrTiO
3BL electrical condenser, complex function solid component for base material.In order to be used for electrical condenser, at the domestic part of also producing of Korea S, the annual La that uses about 1 ton
2O
3, used the Nd about 200kg in every month
2O
3La
2O
3As the photoelectron material that obtains the photoswitch etc. of crystalline ceramics by hot pressing.In addition the purposes of using in the pottery also has high Tc superconduction pottery, as Si
3N
4Or the sintering aid of AlN can use the rare earth metal oxide compound.Rare earth metal also can be applied to laser generation, and wherein Nd attracts most attention.In addition, comprise that nearly all opticinstrument of camera is with all being added with La in the glass
2O
3, Y
2O
3, Yb
2O
3Deng.From now on, camera lens can continue high performance, densification, and the rare earth class usage quantity in high refraction, the low dispersion camera lens is estimated and will be increased gradually.
* cerium group (element of the cerium group)
Cerium group is 6 kinds of elements of La, Ce, Pr, Nd, Pm, Sm (also comprising Eu), and rare earth element is divided into cerium family and yttrium family, 6-7 kind element before cerium family is meant in the lanthanide.Have main the composition such as monazite, hamartite etc., and wherein the title of the Ce that exists is at most named.The alkalescence of oxyhydroxide is slightly strong in the rare earth element, and the double salt solubleness of its vitriol and NaSO is lower than yttrium family, utilizes the poor of this solubleness, can separate to a certain degree with yttrium family.
The hydrogen that stores rises along with temperature and disperses, and by the element of interpolation, hydrogen also can produce naturally in addition, Ge32 is the carbon series of elements, have negatively charged ion and cationic exchangeability, and far infrared rays and electric exchangeability are good, have the structure of the medium that hydrogen is moved to the combustion chamber.
In the moiety of the present invention, Ce, the La of rare earth class group of the lanthanides row, Nd etc. are nanoscale powder, have the effect as the essential substance of pedesis.
* storing hydrogen metal
The storing hydrogen metal is metal purpose, that can absorb hydrogen in a large number that is used for storing hydrogen, transportation.Only generate water during hydrogen burning, do not produce obnoxious flavour fully, so attract attention as clear energy sources (clean energy).When titanium, zirconium, lanthanum nickel alloy absorption hydrogen, form hydride TiH, ZrH, LaNiH, the hydrogen of this hydride is identical with the gaseous hydrogen of the equal volume of compressing with 1000atm, and can store the about 2 times hydrogen that is equivalent to liquid hydrogen.Metal with above-mentioned character has the alloy of magnesium, niobium, vanadium, manganese and these metals.Even the hydride of these metals only improves some temperature, also can the release hydrogen body, and also the purity of the hydrogen that discharges this moment is very high.
* hydrogen occlusion metal
Hydrogen occlusion metal is that the hydride formation reaction is used in the storage of hydrogen, the metal of storage of heat.The hydrogen that enters into the crystallization of carbon steel becomes of major reason of steel tearing failure, so broad research is carried out in the reaction to metal and hydrogen aspect hydrogen embrittlement.Recently, the storage of the hydrogen that the hydride formation reaction is used to get most of the attention as secondary energy, the heat absorption in the time of perhaps will reacting, heat release are used for the storage of heat, and these aspects that are used for energy system are much studied.
The reaction of metal and hydrogen is divided into 3 kinds substantially.
(1) hydrogen is as the saloid type hydride of the anionic class of 1 valency
Alkalimetal hydride (LiH, NaH, KH etc.), alkaline earth metal hydride (MgH, CaH etc.) generate by thermopositive reaction, show certain hydrogen dissociation pressure at a certain temperature.At high temperature, its dissociation pressure will rise.
(2) hydrogen has the hydride of the metalloid of metallic element effect
Hydrogen and Ti, Zr, Pd, Ta, La, rare earth element etc. carry out thermopositive reaction, form intermetallic compound-hydride.On the thermodynamics, identical with (1) kind, show certain dissociation pressure by the temperature decision.In general, compare with (1) kind, its dissociation temperature is low.
(3) hydrogen is dissolved in the metallographic phase hydride that forms sosoloid in the solid metal crystallization
Universal metal major parts such as Al, Fe, Ni, Cu are with the hydrogen solutionizing by thermo-negative reaction.Owing to be thermo-negative reaction, different with the situation of compound, under certain hydrogen pressure, along with the rising of temperature, the meltage of hydrogen will increase.In addition, balance meltage at a certain temperature is the function that becomes hydrogen pressure.When hydride was used as the storage thing of hydrogen, only with the hydride of the pure metal of investigation so far, its practicality was insufficient.
Recently, find the alloy that practicality increases substantially in the alloy of the solid solution build element in the intermetallic compound type element in (2) and (3).Typical example is Ti-Fe, La-Ni etc.Based on the material of Ti-Fe alloy, near room temperature, also show the dissociation pressure of vapour pressure, so approach practicability on the price of material, but hydrogen occlusion reaction is subjected to the influence of the trace impurity (particularly oxygen) in the hydrogen easily, is difficult to surface activation.In addition, based on the alloy of La-Ni, also show the dissociation pressure that 10atm is above at normal temperatures.Use the hybrid alloys-Mm of rare earth element to replace the Mm-Ni of lanthanum also can obtain sufficient characteristic.As the alloy that heat storage technology is used, proposed based on the reaction heat size, be the alloy of (1) of the high Mg of dissociation temperature etc. the metal of planting.
The storing hydrogen alloy comprises the alloy (Fe+Ti) of alloy (Mg+Ni), iron and titanium of alloy (La+Ni5), magnesium and the nickel of lanthanum and nickel, wherein selects to use the optimal material of component with engine cylinder.
In addition, consider this point, among the present invention, with the tourmaline powder more than 1200 sieve meshes is medium, uses 800 sieve mesh powder of biotite series medical stone, the alloy of above-mentioned tourmaline powder and iron and titanium (Fe+Ti), Al reaction, repeat oxidation and reduction, and high more heat and electricity and the electronic action under the large impact is active more, the release of far infrared rays is active, forms the ionic covalent linkage and discharges hydroxyl ion.
In addition, interpolation as a kind of to the nano level rare earth column element of 15000 sieve meshes and with the material-lanthanum (La) of reaction such as hydrogen, cerium (Ce), neodymium (Nd) etc., interpolation is as the selenium (Se) of photoreceptor element, to Fe, the TiO as the steam jacket thickness of the 2mm-3mm of cylinder component
2Alloy film and the H in the cylinder and C implement catalytic performance, according to the constant in energy rule of mass conservation rule,, obtain the performance of identical kinetic energy with few fuel, these are by discarded (CO, HC, NO
x) reduction confirm.
It is relevant with all elements of interpolation that the maintenance of static voltage and static reduce performance, particularly the SiO of the quartzy character with quartzose silicon of Tian Jiaing
2Composition produces with the driving process and the wheel turns of the tourmalinite with 0.6mA weak current by cylinder, piston and engine, and by the energy that utilizes natural light sun power to produce the electromotive force that the negative current that covers car body pulls to the ignition energy side in the cylinder is produced.
In addition, the element that uses among the present invention all has the feature that can be used for refrigerant, so also have the performance that prevents engine overheat.
Describe the present invention in detail below with reference to embodiment.
Embodiment
For example, be the vehicle of 2000cc during with the total amount of water coolant as benchmark, heat sink size is about 8L-12L, and when osculant 10L was benchmark, weight was 940g/L, so scatterer water coolant total amount is 9400g (9.4kg) (=940 * 10L).
Under said reference, the content of medical stone, Ge32, tourmalinite, lanthanum (La), cerium (Ce), neodymium rare earth metals such as (Nd) and other additive is as follows.
1, the content of tourmalinite in the amount of each element that contains in the scatterer water coolant of different vehicle (from 3000 sieve meshes to 12000 sieve meshes) is as shown in table 1.
Table 1
The cooling water inflow of different vehicle | Unit | Minimum content (every g) | High-content (every g) |
1500cc-2000cc= 7500ml-10000ml | Weight is every 1L940g | Contain 0.00074468085g | Contain 0.0014893617g |
2.5 tons of 18L-20L of 2300cc-6000cc | - | Contain 0.00088652482g | Contain 0.00177304964g |
4.5-11 tons=38L-42L of ton | - | Contain 0.00085106382g | Contain 0.00132978723g |
42-75L such as motorbus, heavy goods vehicles, dumper, boats and ships | - | Contain 0.00059574468g | Contain 0.0009929078g |
2, the element that contains of medical stone (800 sieve meshes-1200 sieve mesh) is as shown in table 2.
Table 2
SiO 253.1% | Fe 2O 38.55% | Al 2O 313.3% | CaO 6.85% |
MgO14.18% | K 2O 1.88% | Na 2O 0.62% | Other is 1.0% years old |
3, every g content of medical stone is as shown in table 3.
Table 3
The cooling water inflow of different vehicle | Unit | Minimum content (every g) | High-content (every g) |
1500cc-2000cc= 7500ml-10000ml | Weight is every 1L940g | Contain 0.00031914893g | Contain 0.00159574468g |
2.5 tons of 18L-20L of 2300cc-6000cc | - | Contain 0.00088652482g | Contain 0.00170212765g |
4.5-11 tons=38L-42L of ton | - | Contain 0.00085106382g | Contain 0.00127659574g |
42-75L such as motorbus, heavy goods vehicles, dumper, boats and ships | - | Contain 0.00043971631g | Contain 0.00113475177g |
4, the addition of lanthanum and neodymium (powder is 15000 sieve meshes-100 nanometers) is as shown in table 4 in the rare earth element.
Table 4
The cooling water inflow of different vehicle | Unit | Minimum content (every g) | High-content (every g) |
1500cc-2000cc= 7500m1-10000ml | Weight is every 1L 940g | Contain 0.00002127659g | Contain 0.00007092198g |
2.5 tons of 18L-20L of 2300cc-6000cc | - | The same | The same |
4.5-11 tons=38L-42L of ton | - | The same | The same |
42-75L such as motorbus, heavy goods vehicles, dumper, boats and ships | - | The same | Contain 0.00015957446g |
5, the addition of cerium (powder is 15000 sieve meshes-100 nanometers) is as shown in table 5 in the rare earth element.
Table 5
The cooling water inflow of different vehicle | Unit | Minimum content (every g) | High-content (every g) |
1500cc-2000cc= 7500ml-10000ml | Weight is every 1L 940g | Contain 0.00004255319g | Contain 0.00014184397g |
2.5 tons of 18L-20L of 2300cc-6000cc | - | The same | The same |
4.5-11 tons=38L-42L of ton | - | The same | The same |
42-75L such as motorbus, heavy goods vehicles, dumper, boats and ships | - | The same | Contain 0.00021276595g |
6, contain overall weight respectively than being the Ge32 of 0.001ppm-0.07ppm.
7, contain overall weight respectively than being the Se of 0.01ppm-0.05ppm (selenium).
Selenium is sensitive materials, when having heat absorption and performance such as heat release, participates in the conduction of electricity, electronics and moving of far infrared rays, improves all elements effect directly or indirectly.
In the time of will carrying out the nanometer combination as the germanium (Ge) of semiconductor substance and silicon (Si), will increase substantially the character of thermal conversion for electricity.
Be injected into Prey base of a fruit Austria (automobile name in 1997 as the described deicing fluid that is mixed with additive of embodiment, transliteration) (2957cc, 236240km travels), Mo Suo (automobile name in 1994, transliteration) (2874cc, 203812km travels), miniature diesel vehicle and small gasoline vehicle, before measure injecting and the discharge gas after injecting etc., its result as table 6 to shown in the table 9.
Table 6
Table 7
Table 8
Table 9
As table 6 to shown in the table 9, from additive of the present invention is injected into before the deicing fluid and afterwards vent gas body measurement result as can be seen, the vent gas scale of construction significantly reduces, and confirms that CO has on average reduced more than 90%, HC has minimumly reduced more than 30%, NO
xBe reduced to below half.
From here as can be seen, lanthanum (La), cerium (Ce), neodymium (Nd) lead to the superheated water temperature and produce hydrogen in water coolant, the storing hydrogen of this generation is at the iron-titanium alloy of cylinder film, the hydrogen of this storage disperses once more, by above-mentioned circulation, function with storage power shows fuel economy, reduces the effect of discharging gas, strengthening output and reducing noise, realizes that static voltage keeps and static reduces performance.
As mentioned above, according to the additive of scatterer water coolant that is used to improve the transportation equipment performance of the present invention and deicing fluid and add the deicing fluid that this additive is made, reduce the vent gas scale of construction that produces in the burning, help environmental purification, and at prepare silicon hydrochlorate (SiO
4-3) state under, interpolation can replace the isotopic element-rare earth element of palladium catalyst (Pd), platinum (Pt), rhodium (Rh), improves fuel efficiency, and ratio of combustion is risen, and by the energy that moiety had, output has been improved more than 10%.
In addition, the function that has purifying vehicle inner air in repeating oxidation and reductive process.
Claims (11)
1, a kind of being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, and this additive contains tourmaline powder, medical stone and rare earth metal.
2, according to claim 1ly be used to improve the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that, with respect to the tourmalinite of 100 weight parts, described additive contains the medical stone of 50-1000 weight part and the rare earth metal of 14-30 weight part.
3, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that described medical stone contains the SiO of 53.1-80.00 weight %
2, the MgO of 0.59-14.18 weight %, the Fe of 2.806-8.55 weight %
2O
3, 13.3-16.20 weight % Al
2O
3, the CaO of 1.63-6.85 weight %, the K of 1.88-4.28 weight %
2The TiO of O, 0.20-0.30 weight %
2, and the Na of 0.62-4.31 weight %
2O.
4, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that described additive contains the germanium of 0.001-0.07ppm.
5, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that described additive contains the selenium of 0.001-0.05ppm.
6, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that, described rare earth metal is a kind of or two or more mixture that is selected from the group of being made up of lanthanum, cerium and neodymium.
7, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that described additive contains zeolite.
8, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that described additive contains TiO
2
9, according to claim 1 being used to improved the scatterer water coolant of transportation equipment performance and the additive of deicing fluid, it is characterized in that, it is 99.99% SiO that described additive contains purity
2Nanoscale powder.
10, a kind of deicing fluid, this deicing fluid are to prepare by any one additive that adds in the claim 1 to 9.
11, deicing fluid according to claim 10 is characterized in that, is benchmark with the whole deicing fluid of 100 weight parts, and described deicing fluid contains the described additive of 0.1-2 weight part.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020070026521A KR100866919B1 (en) | 2007-03-19 | 2007-03-19 | Additives of antifreezing solution and antifreezing solution produced using the additives |
KR10-2007-0026521 | 2007-03-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101270276A true CN101270276A (en) | 2008-09-24 |
CN101270276B CN101270276B (en) | 2011-05-18 |
Family
ID=40004510
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007101525280A Active CN101270276B (en) | 2007-03-19 | 2007-09-27 | Additive for cooling water and antifreeze, antifreeze added with the same |
Country Status (2)
Country | Link |
---|---|
KR (1) | KR100866919B1 (en) |
CN (1) | CN101270276B (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102757770A (en) * | 2012-08-06 | 2012-10-31 | 何秋生 | Replacement-free non-aqueous nano coolant for central air-conditioning and industrial cycle heat exchange system |
CN103922490A (en) * | 2013-01-14 | 2014-07-16 | 沈善通 | Formula of oil saving type cooling water additive |
CN104861940A (en) * | 2014-02-27 | 2015-08-26 | 北京富兴华工贸集团 | Eco-friendly energy-saving antifreeze fluid of internal combustion engine |
CN105107844A (en) * | 2015-07-31 | 2015-12-02 | 铜陵市大明玛钢有限责任公司 | Method for preparing steel cast roller cooling water |
CN106010471A (en) * | 2016-06-07 | 2016-10-12 | 深圳千跑龙能源科技有限公司 | Nanometer cooling water additive and preparation method thereof |
CN106190356A (en) * | 2016-07-12 | 2016-12-07 | 黑龙江金源仑特种纤维有限公司 | A kind of cracking hydrocarbon oil gas saver |
CN106220165A (en) * | 2016-07-12 | 2016-12-14 | 无锡市华东电力设备有限公司 | A kind of preparation method and applications of electric shock/piezoelectric |
CN107189770A (en) * | 2016-03-15 | 2017-09-22 | 新高丽绿色有限公司 | For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously |
CN108314971A (en) * | 2018-02-07 | 2018-07-24 | 浙江微米能环境科技有限公司 | Reduce air cleaner surface sticker, production and the application method of the discharge of benzene class |
CN108361131A (en) * | 2018-02-07 | 2018-08-03 | 浙江微米能环境科技有限公司 | Reduce the lossless installation suit of automobile of benzene class discharge |
CN109749719A (en) * | 2017-11-03 | 2019-05-14 | 北京万成天泰科技发展有限责任公司 | It is a kind of that can to keep radiator temperature be 85 degrees Celsius of water tank coolant liquid |
CN109868120A (en) * | 2017-12-01 | 2019-06-11 | 北京万成天泰科技发展有限责任公司 | One kind can make radiator in subzero 45 degrees Celsius of non-icing anti-icing fluid |
CN110325616A (en) * | 2017-02-23 | 2019-10-11 | 金载洙 | Reduce coal smoke composition |
CN111542588A (en) * | 2018-01-17 | 2020-08-14 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100911940B1 (en) * | 2008-12-09 | 2009-08-13 | 유종선 | Additive compositon for automotive cooling water |
KR101130606B1 (en) * | 2009-01-20 | 2012-04-02 | 송희용 | Additives improving of vehicle using Bio-ceramic carrier and method for production thereof |
KR101010935B1 (en) * | 2010-03-23 | 2011-01-25 | 신충교 | Additives of antifreeze for decreasing greenhouse gases and antifreeze produced using thereof |
KR101252571B1 (en) * | 2012-05-21 | 2013-04-09 | 주식회사 에스지코리아 | Active composition for cooling water and method for manufacturing the same |
WO2014077553A1 (en) * | 2012-11-14 | 2014-05-22 | 주식회사 에스지코리아 | Coolant activating agent, and method for producing same |
KR101457657B1 (en) | 2012-12-05 | 2014-11-07 | 이수정 | Coolant additives for radiator of vehicles |
JP6487382B2 (en) * | 2016-06-24 | 2019-03-20 | トヨタ自動車株式会社 | Automotive engine coolant composition, automotive engine concentrated coolant composition, and internal combustion engine operating method |
KR101915766B1 (en) * | 2016-12-30 | 2018-11-06 | 주식회사 포월드코리아 | Manufacturing method of coolant additive composition for vehicle and coolant additive composition for vehicle |
KR102476566B1 (en) * | 2020-08-21 | 2022-12-13 | 김교훈 | Composition for adding vehicle coolant |
CN115160994B (en) * | 2022-09-09 | 2022-12-02 | 纯牌科技股份有限公司 | Preparation method of automobile engine cooling liquid containing nano titanium |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1133606C (en) * | 2001-05-18 | 2004-01-07 | 李献 | Functional tourmaline fertilizer and its preparing process |
JP2003161152A (en) * | 2001-11-28 | 2003-06-06 | Koike:Kk | Radiator cooling water for vehicle or the like |
CN1226237C (en) * | 2002-03-20 | 2005-11-09 | 孙志峰 | Multiple functional denatured haycites and its manufacturing methods |
KR20040005492A (en) * | 2002-07-10 | 2004-01-16 | 양승민 | Antifreezing solution composite for high fuel efficiency |
CN1413921A (en) * | 2002-09-26 | 2003-04-30 | 北京雅润泽科技有限公司 | Anion ceramic material for water purifying |
CN1413737A (en) * | 2002-09-26 | 2003-04-30 | 北京雅润泽科技有限公司 | Passive (hydroxide) anion generation material for indoor air purifying and its application |
CN100384492C (en) * | 2004-01-15 | 2008-04-30 | 陈民全 | Multifunctional healthy cushion capable of producing far infrared ray and anion |
JP2005291006A (en) | 2004-03-31 | 2005-10-20 | Santeeru:Kk | Cooling liquid of water-cooled engine |
KR100555984B1 (en) * | 2004-07-27 | 2006-03-03 | 김병훈 | composition for elevation of fuel ratio and cooling water in radiator utilizing the same |
KR100638692B1 (en) * | 2005-04-20 | 2006-10-27 | (주)미라노이멕스 | Method of manufacturing coolant for reducing exhaust fumes and improving fuel efficiency of internal-combustion engine |
CN1865187A (en) * | 2005-05-20 | 2006-11-22 | 天津市赛远保健品有限公司 | Composite function ceramic mass and its production method thereof |
KR100771190B1 (en) | 2006-04-28 | 2007-10-29 | 주식회사 에스엘티테크놀리지 | Addition matter for cooling water of engine |
CN100378009C (en) * | 2006-05-31 | 2008-04-02 | 北京水宜生科技发展有限公司 | Micro electrolytic energy water treatment element and its preparation method |
-
2007
- 2007-03-19 KR KR1020070026521A patent/KR100866919B1/en active IP Right Grant
- 2007-09-27 CN CN2007101525280A patent/CN101270276B/en active Active
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102757770A (en) * | 2012-08-06 | 2012-10-31 | 何秋生 | Replacement-free non-aqueous nano coolant for central air-conditioning and industrial cycle heat exchange system |
CN103922490A (en) * | 2013-01-14 | 2014-07-16 | 沈善通 | Formula of oil saving type cooling water additive |
CN104861940A (en) * | 2014-02-27 | 2015-08-26 | 北京富兴华工贸集团 | Eco-friendly energy-saving antifreeze fluid of internal combustion engine |
CN105107844A (en) * | 2015-07-31 | 2015-12-02 | 铜陵市大明玛钢有限责任公司 | Method for preparing steel cast roller cooling water |
CN107189770A (en) * | 2016-03-15 | 2017-09-22 | 新高丽绿色有限公司 | For removing the antifreeze solution additive of denitrification and particulate matter and anti-icing fluid containing the additive simultaneously |
CN106010471A (en) * | 2016-06-07 | 2016-10-12 | 深圳千跑龙能源科技有限公司 | Nanometer cooling water additive and preparation method thereof |
CN106220165A (en) * | 2016-07-12 | 2016-12-14 | 无锡市华东电力设备有限公司 | A kind of preparation method and applications of electric shock/piezoelectric |
CN106190356A (en) * | 2016-07-12 | 2016-12-07 | 黑龙江金源仑特种纤维有限公司 | A kind of cracking hydrocarbon oil gas saver |
CN110325616A (en) * | 2017-02-23 | 2019-10-11 | 金载洙 | Reduce coal smoke composition |
CN109749719A (en) * | 2017-11-03 | 2019-05-14 | 北京万成天泰科技发展有限责任公司 | It is a kind of that can to keep radiator temperature be 85 degrees Celsius of water tank coolant liquid |
CN109868120A (en) * | 2017-12-01 | 2019-06-11 | 北京万成天泰科技发展有限责任公司 | One kind can make radiator in subzero 45 degrees Celsius of non-icing anti-icing fluid |
CN111542588A (en) * | 2018-01-17 | 2020-08-14 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
CN111542588B (en) * | 2018-01-17 | 2021-09-28 | 比奥能源株式会社 | Engine oil additive for enhancing engine function and improving fuel efficiency |
CN108314971A (en) * | 2018-02-07 | 2018-07-24 | 浙江微米能环境科技有限公司 | Reduce air cleaner surface sticker, production and the application method of the discharge of benzene class |
CN108361131A (en) * | 2018-02-07 | 2018-08-03 | 浙江微米能环境科技有限公司 | Reduce the lossless installation suit of automobile of benzene class discharge |
Also Published As
Publication number | Publication date |
---|---|
KR100866919B1 (en) | 2008-11-04 |
CN101270276B (en) | 2011-05-18 |
KR20080085281A (en) | 2008-09-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101270276B (en) | Additive for cooling water and antifreeze, antifreeze added with the same | |
CN1420940A (en) | High storage capacity alloys enabling hydrogen-based ecosystem | |
Wang et al. | The recent research, development and industrial applications of metal hydrides in the People's Republic of China | |
KR20040022222A (en) | Single stage metal hydride compressor | |
EP1476693A1 (en) | Vane heat transfer structure | |
EP1243041B1 (en) | Modified magnesium based hydrogen storage alloys | |
CN108193107B (en) | Preparation method of organic coated core-shell nano composite hydrogen storage material | |
EP1404578B1 (en) | Atomically engineered hydrogen storage alloys having extended storage capacity at high pressures and high pressure hydrogen storage units containing variable amounts thereof | |
TW527425B (en) | High storage capacity, fast kinetics, long cycle-life, hydrogen storage alloys | |
EP1082469A1 (en) | Magnesium mechanical alloys for thermal hydrogen storage | |
Cao et al. | Development of (Ti–Zr) 1.02 (Cr–Mn–Fe) 2-based alloys toward excellent hydrogen compression performance in water-bath environments | |
TWI245803B (en) | High storage capacity alloys having excellent kinetics and a long cycle life | |
JP2004138217A (en) | Hydrogen storage tank | |
Chao et al. | Hydrogen storage in interstitial metal hydrides | |
Bouaziz et al. | Advanced interpretation of hydrogen absorption process in LaMgNi3. 6M0. 4 (M= Ni, Mn, Al, Co, Cu) alloys using statistical physics treatment | |
CN100391827C (en) | Field-assisted gas storage materials and fuel cells comprising same | |
US6616891B1 (en) | High capacity transition metal based hydrogen storage materials for the reversible storage of hydrogen | |
Heung | On-board hydrogen storage system using metal hydride | |
Dragassi et al. | Hydrogen Storage as a Key Energy Vector for Car Transportation: A Tutorial Review | |
Wei et al. | Catalytic effect of multi-wall carbon nanotubes supported nickel on hydrogen storage properties of Mg99Ni prepared by hydriding combustion synthesis | |
EP0220678A1 (en) | Hydrogen storage materials useful for heat pump applications | |
Rusman | Performance Analysis of Metal Hydride-Based Hydrogen Storage System | |
JP2004316621A (en) | Turbo stainless steel engine | |
VN | USE OF METAL HYDRIDES AS SOURCES OF HYDROGEN FOR VARIOUS PRACTICAL APPLICATIONS | |
CN101787455B (en) | High capacity Mg-ZrMn2 composite hydrogen storage alloy preparation method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20090821 Address after: South Korea Applicant after: Xin Zhongjiao Address before: Daejeon, Korea Applicant before: Religious loyalty Co-applicant before: Shen Mingche |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |