CN106867380A - Breathable flame-retardant anti-immersion fabric and preparation method thereof - Google Patents
Breathable flame-retardant anti-immersion fabric and preparation method thereof Download PDFInfo
- Publication number
- CN106867380A CN106867380A CN201710096259.4A CN201710096259A CN106867380A CN 106867380 A CN106867380 A CN 106867380A CN 201710096259 A CN201710096259 A CN 201710096259A CN 106867380 A CN106867380 A CN 106867380A
- Authority
- CN
- China
- Prior art keywords
- parts
- fabric
- butanone
- toluene
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 134
- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 5
- 238000007654 immersion Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000576 coating method Methods 0.000 claims abstract description 72
- 239000011248 coating agent Substances 0.000 claims abstract description 71
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 49
- 230000001070 adhesive effect Effects 0.000 claims abstract description 48
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 48
- 239000000853 adhesive Substances 0.000 claims abstract description 47
- 229920002635 polyurethane Polymers 0.000 claims abstract description 44
- 239000004814 polyurethane Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000002131 composite material Substances 0.000 claims abstract description 33
- 239000012528 membrane Substances 0.000 claims abstract description 30
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003292 glue Substances 0.000 claims abstract description 26
- 230000002940 repellent Effects 0.000 claims abstract description 20
- 239000005871 repellent Substances 0.000 claims abstract description 20
- 238000003490 calendering Methods 0.000 claims abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 120
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 80
- 238000004132 cross linking Methods 0.000 claims description 59
- 239000004971 Cross linker Substances 0.000 claims description 32
- 229920000877 Melamine resin Polymers 0.000 claims description 32
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 32
- 229920005749 polyurethane resin Polymers 0.000 claims description 31
- 239000012948 isocyanate Substances 0.000 claims description 27
- 150000002513 isocyanates Chemical class 0.000 claims description 27
- 229920006231 aramid fiber Polymers 0.000 claims description 24
- 239000004831 Hot glue Substances 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 238000007711 solidification Methods 0.000 claims description 14
- 230000008023 solidification Effects 0.000 claims description 14
- 238000009940 knitting Methods 0.000 claims description 9
- 239000007921 spray Substances 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 238000013329 compounding Methods 0.000 abstract description 14
- 230000002706 hydrostatic effect Effects 0.000 abstract description 6
- 230000032683 aging Effects 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 5
- 239000011229 interlayer Substances 0.000 abstract description 3
- 239000010410 layer Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 18
- 238000006757 chemical reactions by type Methods 0.000 description 10
- 239000003431 cross linking reagent Substances 0.000 description 7
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 6
- 239000011527 polyurethane coating Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000014347 soups Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000003712 anti-aging effect Effects 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010008190 Cerebrovascular accident Diseases 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 208000006011 Stroke Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a breathable flame-retardant anti-immersion fabric and a preparation method thereof. The preparation method of the breathable flame-retardant immersion-resistant fabric comprises the following steps: 1) coating the coating adhesive on the outer-layer fabric which is subjected to water repellent finishing and calendering in sequence to obtain a windproof finished fabric; 2) carrying out glue point compounding on the surface of the windproof finished fabric coated with the coating glue and the polytetrafluoroethylene/polyurethane composite film; 3) and (3) carrying out glue point compounding on the surface of the composite polytetrafluoroethylene/polyurethane composite film of the fabric obtained in the step 2) and the lining fabric. The invention solves the problem that the interlayer peeling of the middle two-component PTFE membrane material occurs due to wind action in the use environment of the water-resistant fabric. And simultaneously, the comprehensive indexes of hydrostatic pressure, moisture permeability, flame retardance, ageing resistance and the like of the fabric are ensured, and the requirements of the fabric of the clothing for special industry operation are met.
Description
Technical field
The present invention relates to fire-retardant anti-dip facing material of a kind of vapor-permeable type and preparation method thereof, belong to textile processing field.
Background technology
With the raising and the progress of society of living standards of the people, functional fabric is more and more applied to people
Daily life and work, especially special trade tooling fabric and outdoor sport fabric feature are more and more stronger, and overall target is got over
Come higher.The garment material of simple function is easier to realize, but the comprehensive one of many indexes, due to the mutual system between index
About, difficulty of processing is larger, is often difficult all to reach expected requirement simultaneously.
In order to meet the index such as fire-retardant, moisture-inhibiting, anti-aging, water resistant leaching, existing method is all by the way of coating, that is, to exist
A kind of mode of flame-retardant coatings glue coating is taken on a kind of fibr tissue fabric, fire-retardant, moisture-inhibiting, water resistant leaching index, but this is realized
Fabric after kind arranging due to the influence of flame-retardant additive, often hydrothermal aging, soda boiling be aging and washing after hydrostatic drops compared with
Greatly, it is difficult to meet anti-aging index request.
The content of the invention
It is an object of the invention to provide fire-retardant anti-dip facing material of a kind of vapor-permeable type and preparation method thereof, by base material outer facing material
Arrangement is coated, makes fabric that there is fabulous wind-proof performance, due to the windproof iris action of outer facing material in operating environment, made
Wind-force cannot be applied directly in middle membrane material, will not be thus resulted in the interlayer slip of membrane material and be influenceed product to take effect,
And this coating to outer facing material is arranged except possessing the conditions such as low weightening, feel be soft, should not influence product penetrability, anti-flammability,
Water permeability resistance and ageing properties index request.
Present invention firstly provides a kind of coating adhesive, it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2~3 parts of isocyanate crosslinking；
0.2~0.5 part of melamine crosslinkers；
1.2~1.8 parts of crosslinking accelerator；
15~35 parts of organic solvent.
In above-mentioned coating adhesive, the organic solvent can be butanone and toluene；
The viscosity of the coating adhesive can be 10000~12000mPa.s, concretely 10500mPa.s, 11000mPa.s,
11500mPa.s or 12000mPa.s, the viscosity can ensure that coating starching amount is small, low weightening, make the fabric feel after coating soft
Soft, vapor transfer rate is high, and reduces to fire resistance, the influence of water vapour permeability index.
In above-mentioned coating adhesive, counted as 100 parts with the mass parts of the reactive polyurethane resin, the quality of the butanone
Addition can be 5~15 parts, and the quality addition of the toluene can be 10~20 parts.
The coating adhesive concretely following 1) -7) in any one：
1) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2~2.5 parts of isocyanate crosslinking；
0.2~0.3 part of melamine crosslinkers；
1.2~1.5 parts of crosslinking accelerator；
5~10 parts of butanone；
15~20 parts of toluene；
2) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.3~0.5 part of melamine crosslinkers；
1.5~1.8 parts of crosslinking accelerator；
5~8 parts of butanone；
17~20 parts of toluene；
3) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.4~0.5 part of melamine crosslinkers；
1.6~1.8 parts of crosslinking accelerator；
8~10 parts of butanone；
10~17 parts of toluene；
4) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2 parts of isocyanate crosslinking；
0.2 part of melamine crosslinkers；
1.2 parts of crosslinking accelerator；
10 parts of butanone；
15 parts of toluene；
5) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.3 part of melamine crosslinkers；
1.5 parts of crosslinking accelerator；
5 parts of butanone；
20 parts of toluene；
6) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
3 parts of isocyanate crosslinking；
0.5 part of melamine crosslinkers；
1.8 parts of crosslinking accelerator；
8 parts of butanone；
17 parts of toluene；
7) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.4 part of melamine crosslinkers；
1.6 parts of crosslinking accelerator；
10 parts of butanone；
10 parts of toluene.
The reactive polyurethane resin refers to the polyurethane resin of also hydroxyl reactive group, and hydroxyl therein can be with
Cross-linking reaction is carried out with the isocyanate crosslinking and melamine crosslinkers, cross-linked structure is formed, is improved and is combined jail
Degree.
It is D-ACE 2345 that the reactive polyurethane resin can use the code that new east station of Guangzhou is produced into Chemical Co., Ltd.
Product；
It is the product of D-ACE 555 that the isocyanate crosslinking can use the code that new east station of Guangzhou is produced into Chemical Co., Ltd.
Product；
It is the product of D-ACE 557 that the melamine crosslinkers can use the code that new east station of Guangzhou is produced into Chemical Co., Ltd.
Product；
It is the product of D-ACE 900 that the crosslinking accelerator can use the code that new east station of Guangzhou is produced into Chemical Co., Ltd..
The coating adhesive can be prepared according to the method for comprising the following steps：
The reactive polyurethane resin and the solvent are mixed to get mixed liquor；It is described to being added in the mixed liquor
Isocyanate crosslinking, the crosslinking accelerator and the melamine crosslinkers, stir and obtain final product.
The viscosity of the coating adhesive is adjusted to 10000~12000mPa.s using butanone or toluene.
Invention further provides a kind of preparation method of the fire-retardant anti-dip facing material of vapor-permeable type, comprise the following steps：
1) coating adhesive is coated on outer shell fabric successively through water repellent finish and calendering, obtains windproof arrangement face
Material；
2) surface of the windproof coating coating adhesive for arranging fabric is entered with polytetrafluoroethylene (PTFE)/polyurethane composite membrane
Row glue point is combined；
3) by step 2) surface of the compound described polytetrafluoroethylene (PTFE)/polyurethane composite membrane of fabric that obtains and nexine fabric
Carry out glue point to be combined, obtain final product the fire-retardant anti-dip facing material of the vapor-permeable type.
In above-mentioned preparation method, the outer shell fabric can be aramid fiber plain cloth；
The nexine fabric can be the knitting screen cloth of aramid fiber；
The aramid fiber plain cloth and the knitting screen cloth of the aramid fiber are respectively provided with good fire resistance, and without molten drop problem；
The polytetrafluoroethylene (PTFE)/polyurethane composite membrane refers to coating a strata urethane in PolytetrafluoroethylFilm Film
The composite membrane that film is obtained, its thickness can be 15~50 μm, and grammes per square metre can be 15~55g/m2, it is 30 μm, grams that can specifically use thickness
Weight is 35g/m2Polytetrafluoroethylene (PTFE)/polyurethane composite membrane.
Removed because it possesses certain hydrostatic pressing index while being also to ensure that whole using the polytetrafluoroethylene (PTFE)/polyurethane composite membrane
The fire-retardant index of body reaches standard requirement.
In above-mentioned preparation method, step 1) in, method conventional in the art can be used the step of the water repellent finish
Carry out；
The spray rating of the outer shell fabric is not less than 3 grades after the water repellent finish；
Step 1) in, the condition of the calendering is as follows：
Pressure can be 10~11Mpa, and concretely 10Mpa or 11Mpa, temperature can be 100~120 DEG C, concretely 110
DEG C or 120 DEG C, speed can be 20~30m/min, concretely 20m/min, 25m/min or 30m/min；
Step 1) in, the windproof arrangement fabric is dried 1~1.5 minute under conditions of 160~170 DEG C；
After through the coating step, the dry weightening of the outer shell fabric can be 7~10g/m2, concretely 7g/m2、8g/
m2、9g/m2Or 10g/m2。
By carrying out water repellent finish and calendering pretreatment to the outer shell fabric, web surface is set to reach water repellent, smooth cause
Close effect, to reduce slurry penetration in coating procedure, makes coating adhesive film forming continuity good and soft, is windproof coating
Finishing effect creates primary condition.
In above-mentioned preparation method, step 2) described in the compound condition of glue point it is as follows：
Compound binding agent can (through inquiry, this statement should be more accurate for mono-component polyurethane Reactive hot melt adhesive
's！), the code that can specifically use Fuller (China) adhesive Co., Ltd to produce is the product of TL-5201；
Spread can be 8~12g/m2, concretely 10g/m2；
Solidification temperature can be 25~35 DEG C, and solidification humidity can be 50~70%, and hardening time can be 1~7 day；
Step 3) described in the compound condition of glue point it is as follows：
Compound binding agent can be the mono-component polyurethane Reactive hot melt adhesive；
Spread can be 8~10g/m2, concretely 8g/m2；
Solidification temperature can be 25~35 DEG C, and solidification humidity can be 50~70%, and hardening time can be 1~7 day；
The fire-retardant anti-dip facing material of vapor-permeable type that the above method is prepared falls within protection scope of the present invention.
The present invention is coated by using the coating adhesive to fabric, that is, ensure that the fabric after arranging possesses anti-well
Wind performance, while having preferable water vapour permeability again, and ensure that (reaction type polyurethane is heated coat side with compound binding agent
Glue) there is good binding strength.Selection reaction type polyurethane hot-melt adhesive, it is possible to use hydrophilic non-porous reactive polyurethane resin
In moisture and other active hydrogen compoundses reacted with-NCO group, chain extension, crosslinking of the generation with stronger cohesive force
Network structure polymer, it is ensured that the binding strength of reaction type polyurethane hot-melt adhesive and coating adhesive；Meanwhile, it is different in coating adhesive formula
Isocyanate cross-linking agent contain-NCO group can further ensure that the combination of coating adhesive and fabric with the active hydrogen reaction in fabric
Fastness.
The present invention is coated on outer facing material by by a certain amount of hydrophilic non-porous type polyurethane resin, is reached windproof well
Effect (air penetrability norm controlling is under certain standard), makes wind-force to penetrate the double-component that fabric acts on composite material nexine
On fire-retardant PTFE film material, solve the problems, such as to make double-component PTFE produce splitting because of wind-force vibration, and improve cloth and film it
Between binding strength, while the laminating technology of three kinds of materials realizes fabric water permeability resistance, penetrability, anti-flammability, ageing resistance etc.
Overall target, meets the functional requirement of job that requires special skills environmental suits fabric.
The present invention solves water resistant dip facing material because middle double-component PTFE film material occurs in the effect of use environment apoplexy power
Splitting problem.And ensure the overall targets such as hydrostatic pressing, vapor transfer rate, anti-flammability, the anti-ageing property of fabric simultaneously, meet special type
Industry operation garment material needs.
Brief description of the drawings
Fig. 1 is the schematic diagram of the fire-retardant anti-dip facing material of vapor-permeable type of the present invention.
Each mark is as follows in figure：
1. outer shell fabric；2. coating glue surface；3. polytetrafluoroethylene (PTFE)/polyurethane composite membrane；4. nexine fabric (screen cloth)；
5. reaction type polyurethane hot-melt adhesive point.
Specific embodiment
Experimental technique used in following embodiments is conventional method unless otherwise specified.
Material used, reagent etc. in following embodiments, unless otherwise specified, commercially obtain.
The present invention solves in the middle of composite material bilayer film because of wind oscillation action by carrying out on outer fabric coating way
Produce intermembranous slippage.
Embodiment 1,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish is carried out to outer shell fabric：Using fluorine system waterproofing agent (TX-15) padding finishing, temperature is 160 DEG C,
Time 1min, drying, spray rating >=4 grade；
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure is 10Mpa, and temperature is 110
DEG C, speed is 20m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：10 parts
Toluene：15 parts
Isocyanate crosslinking D-ACE 555：2.0 parts
Crosslinking accelerator D-ACE 900：1.2 parts
Melamine crosslinkers D-ACE 557：0.2 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers, adjust viscosity to 10500mPa.s with toluene, obtain coating adhesive；
The toluene consumption of viscosity is adjusted to be not included in the toluene proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, staged temperature is 140 DEG C -140 DEG C -150 DEG C -160 DEG C dries 1 minute, does weightening 7g/m2。
(7) fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane are arranged on compounding machine with glue by windproof obtained in (6)
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature,
Solidify 3 days (72h) in the environment of humidity 50%.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2.In 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 1# of solidification.
Embodiment 2,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure is 11Mpa, and temperature is 110
DEG C, speed is 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：5 parts
Toluene：20 parts
Isocyanate crosslinking D-ACE 555：2.5 parts
Crosslinking accelerator D-ACE 900：1.5 parts
Melamine crosslinkers D-ACE557：0.3 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers, adjust viscosity to 11500mPa.s with butanone, obtain coating adhesive；
The butanone consumption of viscosity is adjusted to be not included in the butanone proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, -150 DEG C -160 DEG C of staged temperature 140 DEG C -140 DEG C is dried 1 minute, does weightening 8g/m2。
(7) fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane are arranged on compounding machine with glue by windproof obtained in (6)
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature,
Solidify 3 days (72h) in the environment of humidity 50%.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2.In 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 2# of solidification.
Embodiment 3,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure is 11Mpa, and temperature is 120
DEG C, speed is 30m/min；
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：8 parts
Toluene：17 parts
Isocyanate crosslinking D-ACE 555：3.0 parts
Crosslinking accelerator D-ACE 900：1.8 parts
Melamine crosslinkers D-ACE557：0.5 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers, adjust viscosity to 11000mPa.s with butanone, obtain coating adhesive；
The butanone consumption of viscosity is adjusted to be not included in the butanone proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, -150 DEG C -160 DEG C of staged temperature 140 DEG C -140 DEG C is dried 1 minute, does weightening 9g/m2。
(7) fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane are arranged on compounding machine with glue by windproof obtained in (6)
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature,
Solidify 3 days (72h) in the environment of humidity 50%.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2.In 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 3# of solidification.
Embodiment 4,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure is 11Mpa, and temperature is 110
DEG C, speed is 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：10 parts
Toluene：10 parts
Isocyanate crosslinking D-ACE 555：2.5 parts
Crosslinking accelerator D-ACE 900：1.6 parts
Melamine crosslinkers D-ACE 557：0.4 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers, viscosity number 12000mPa.s is adjusted with toluene, obtains coating adhesive；
The toluene consumption of viscosity is adjusted to be not included in the toluene proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, -150 DEG C -160 DEG C of staged temperature 140 DEG C -140 DEG C is dried 1 minute, does weightening 10g/m2。
(7) fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane are arranged on compounding machine with glue by windproof obtained in (6)
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature,
Solidify 3 days (72h) in the environment of humidity 50%.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2, in 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 4# of solidification.
Comparative example 1,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering, pressure 11Mpa, 110 DEG C of temperature, car are carried out with calender to carrying out the outer shell fabric after water repellent finish
Fast 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：5 parts
Toluene：10 parts
Isocyanate crosslinking D-ACE 555：2.5 parts
Crosslinking accelerator D-ACE 900：1.6 parts
Melamine crosslinkers D-ACE557：0.4 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator, melamine crosslinkers, viscosity 13000mPa.s is adjusted with toluene, obtains coating adhesive；
The toluene consumption of viscosity is adjusted to be not included in the toluene proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, -150 DEG C -160 DEG C of step temperature 140 DEG C -140 DEG C is dried 1 minute, does weightening 12g/m2。
It is (7) windproof arrangement fabric obtained in (6) is compound with glue point on compounding machine with the fire-retardant PTFE film of (2) double-component,
Composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature, humidity
Solidify 3 days (72h) in 50% environment.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2, in 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 5# of solidification.
Comparative example 2,
(1) fabric selection：Outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, nexine fabric is aramid fiber pin
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) membrane material is polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m in the middle of2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering, pressure 11Mpa, 110 DEG C of temperature, car are carried out with calender to carrying out the outer shell fabric after water repellent finish
Fast 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed：
Reactive polyurethane resin D-ACE 2345：100 parts
Butanone：10 parts
Toluene：20 parts
Isocyanate crosslinking D-ACE 555：2.5 parts
Crosslinking accelerator D-ACE 900：1.5 parts
Melamine crosslinkers D-ACE557：0.3 part
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, are stirred, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers, viscosity 9000mPa.s is adjusted with butanone, obtains coating adhesive；
The butanone consumption of viscosity is adjusted to be not included in the butanone proportional quantity of dispensing in the above method.
(6) coating：Coating adhesive obtained in above-mentioned steps (4) is coated in into above-mentioned steps (4) with floating blade coating machine to process
On fabric afterwards, -150 DEG C -160 DEG C of step temperature 140 DEG C -140 DEG C is dried 1 minute, does weightening 6g/m2。
(7) fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane are arranged on compounding machine with glue by windproof obtained in (6)
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, and spread is 10g/m2, in 25 DEG C of temperature,
Solidify 3 days (72h) in the environment of humidity 50%.
(8) (7) are obtained into fabric face to be combined with glue point on compounding machine with the nexine knitting screen cloth of fabric aramid fiber, are combined viscous
Agent is connect for mono-component polyurethane Reactive hot melt adhesive TL-5201, spread is 8g/m2.In 25 DEG C of temperature, in the environment of humidity 50%
3 days (72h) finished product 6# of solidification.
When the dry weightening of the windproof top finish of fabric is respectively in 7,8,9,10,12 and 6g/m2When, obtained finished product after being combined
1#-6# product all technical test results are as shown in table 1.
Be can be seen that with the increase of windproof top finish spread by the data in table 1, air penetrability (windproof index) by
Gradually improve, when windproof coating does weightening >=7g/m2, air penetrability index do not measure, it is ensured that wind-force cannot penetrate fabric be applied to it is poly-
On tetrafluoroethene/polyurethane compound film material, it is to avoid the interlayer slip problem of polytetrafluoroethylene (PTFE)/polyurethane composite film material.And with
Spread increase it is fire-retardant be gradually reduced with moisture-inhibiting index, (weightening is more than 10g/m when reaching certain amount2), it is fire-retardant with it is saturating
Wet index cannot meet standard requirement, and hydrostatic pressing increases with the increase of spread, and wash resistant and aging rear hydrostatic pressing refer to
Mark is more preferable.
Verified when glue-spread is in 7~10g/m by above-described embodiment2When, that is, defensive ability/resistance ability of the outer facing material to wind is can guarantee that,
Also ensure that and do not influence vapor transfer rate, anti-flammability, resistance to ag(e)ing index.Fabric prepared by the present invention meets fire-retardant, moisture-inhibiting, anti-ageing
Change, waterproof high-performance apparel fabric product standard is required.
The index test result of 1#-6# fabrics prepared by the embodiment of the present invention 1-4 of table 1 and comparative example 1-2
Claims (10)
1. a kind of coating adhesive, is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2~3 parts of isocyanate crosslinking；
0.2~0.5 part of melamine crosslinkers；
1.2~1.8 parts of crosslinking accelerator；
15~35 parts of organic solvent.
2. coating adhesive according to claim 1, it is characterised in that：The solvent is butanone and toluene；
The viscosity of the coating adhesive is 10000~12000mPa.s.
3. coating adhesive according to claim 2, it is characterised in that：Mass parts with the reactive polyurethane resin are
100 parts of meters, the quality addition of the butanone is 5~15 parts, and the quality addition of the toluene is 10~20 parts.
4. coating adhesive according to claim 2, it is characterised in that：The coating adhesive is following 1) -7) in any one：
1) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2~2.5 parts of isocyanate crosslinking；
0.2~0.3 part of melamine crosslinkers；
1.2~1.5 parts of crosslinking accelerator；
5~10 parts of butanone；
15~20 parts of toluene；
2) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.3~0.5 part of melamine crosslinkers；
1.5~1.8 parts of crosslinking accelerator；
5~8 parts of butanone；
17~20 parts of toluene；
3) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.4~0.5 part of melamine crosslinkers；
1.6~1.8 parts of crosslinking accelerator；
8~10 parts of butanone；
10~17 parts of toluene；
4) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2 parts of isocyanate crosslinking；
0.2 part of melamine crosslinkers；
1.2 parts of crosslinking accelerator；
10 parts of butanone；
15 parts of toluene；
5) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.3 part of melamine crosslinkers；
1.5 parts of crosslinking accelerator；
5 parts of butanone；
20 parts of toluene；
6) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
3 parts of isocyanate crosslinking；
0.5 part of melamine crosslinkers；
1.8 parts of crosslinking accelerator；
8 parts of butanone；
17 parts of toluene；
7) it is made up of the component of following mass parts：
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.4 part of melamine crosslinkers；
1.6 parts of crosslinking accelerator；
10 parts of butanone；
10 parts of toluene.
5. the preparation method of coating adhesive any one of claim 1-4, comprises the following steps：By the reactive polyurethane
Resin is mixed to get mixed liquor with the solvent；Promote to the isocyanate crosslinking, the crosslinking is added in the mixed liquor
Enter agent and the melamine crosslinkers, stir and obtain final product.
6. a kind of preparation method of the fire-retardant anti-dip facing material of vapor-permeable type, comprises the following steps：
1) coating adhesive any one of claim 1-4 is coated on outer shell fabric successively through water repellent finish and calendering,
Obtain windproof arrangement fabric；
2) surface of the windproof coating coating adhesive for arranging fabric is carried out into glue with polytetrafluoroethylene (PTFE)/polyurethane composite membrane
Point is compound；
3) by step 2) surface of the compound described polytetrafluoroethylene (PTFE)/polyurethane composite membrane of fabric that obtains carries out with nexine fabric
Glue point is combined, and obtains final product the fire-retardant anti-dip facing material of the vapor-permeable type.
7. preparation method according to claim 6, it is characterised in that：The outer shell fabric is aramid fiber plain cloth；
The nexine fabric is the knitting screen cloth of aramid fiber；
The thickness of the polytetrafluoroethylene (PTFE)/polyurethane composite membrane is 15~50 μm, and grammes per square metre is 15~55g/m2。
8. the preparation method according to claim 6 or 7, it is characterised in that：Step 1) in, it is described after the water repellent finish
The spray rating of outer shell fabric is not less than 3 grades；
Step 1) in, the condition of the calendering is as follows：
Pressure is 10~11Mpa, and temperature is 100~120 DEG C, and speed is 20~30m/min；
Step 1) in, the windproof arrangement fabric is dried 1~1.5 minute under conditions of 160~170 DEG C；
After through the coating step, the dry weightening of the outer shell fabric is 7~10g/m2。
9. the preparation method according to any one of claim 6-8, it is characterised in that：Step 2) described in glue point it is compound
Condition is as follows：
Compound binding agent is mono-component polyurethane Reactive hot melt adhesive；
Spread is 8~12g/m2；
Solidification temperature is 25~35 DEG C, and solidification humidity is 50~70%, and hardening time can be 1~7 day；
Step 3) described in the compound condition of glue point it is as follows：
Compound binding agent is the mono-component polyurethane Reactive hot melt adhesive；
Spread is 8~10g/m2；
Solidification temperature is 25~35 DEG C, and solidification humidity is 50~70%, and hardening time can be 1~7 day.
10. the fire-retardant anti-dip facing material of vapor-permeable type that prepared by method any one of claim 6-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096259.4A CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096259.4A CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106867380A true CN106867380A (en) | 2017-06-20 |
| CN106867380B CN106867380B (en) | 2019-07-19 |
Family
ID=59168954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710096259.4A Active CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106867380B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108528059A (en) * | 2018-03-08 | 2018-09-14 | 海宁天福经编涂层有限公司 | A kind of preparation method of fire-retardant banner fabric |
| CN109778545A (en) * | 2019-01-22 | 2019-05-21 | 乐清市雅格狮丹服饰有限公司 | A kind of finishing technique of waterproof casings |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201104309Y (en) * | 2007-08-29 | 2008-08-20 | 中国人民解放军总后勤部军需装备研究所 | Active nucleus ash protection facing material |
| WO2010057593A1 (en) * | 2008-11-21 | 2010-05-27 | Bayer Materialscience Ag | Multi-layered fire-resistant plastic material |
| CN103614922A (en) * | 2013-11-22 | 2014-03-05 | 丹东优耐特纺织品有限公司 | Down coat fabric treatment method for preventing down feather from escaping from needle holes |
| CN106049049A (en) * | 2016-08-02 | 2016-10-26 | 丹东优耐特纺织品有限公司 | Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric |
-
2017
- 2017-02-22 CN CN201710096259.4A patent/CN106867380B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201104309Y (en) * | 2007-08-29 | 2008-08-20 | 中国人民解放军总后勤部军需装备研究所 | Active nucleus ash protection facing material |
| WO2010057593A1 (en) * | 2008-11-21 | 2010-05-27 | Bayer Materialscience Ag | Multi-layered fire-resistant plastic material |
| CN103614922A (en) * | 2013-11-22 | 2014-03-05 | 丹东优耐特纺织品有限公司 | Down coat fabric treatment method for preventing down feather from escaping from needle holes |
| CN106049049A (en) * | 2016-08-02 | 2016-10-26 | 丹东优耐特纺织品有限公司 | Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108528059A (en) * | 2018-03-08 | 2018-09-14 | 海宁天福经编涂层有限公司 | A kind of preparation method of fire-retardant banner fabric |
| CN109778545A (en) * | 2019-01-22 | 2019-05-21 | 乐清市雅格狮丹服饰有限公司 | A kind of finishing technique of waterproof casings |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106867380B (en) | 2019-07-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106049049B (en) | Dacron permanent seal cooling is fire-retardant, water repellent, Waterproof Breathable method for sorting | |
| CN104527190B (en) | A kind of oil storage bag TPU composite | |
| CN103687989B (en) | Utilize the manufacture method of the synthetic leather of mutually different fluid silicone rubber coating fluids | |
| CN101538800B (en) | Thermoplastic resin coating film material and preparation method thereof | |
| CN105002748B (en) | It is a kind of it is crease-resistant, without folding line footwear nonwoven polyurethane synthetic leather and preparation method thereof | |
| CN101247949B (en) | Treated textile fabric | |
| CN103255640B (en) | Environmentally-friendly flame retardant polyurethane synthetic leather, preparation method and product thereof | |
| CN105821670A (en) | Novel textile downproof technology | |
| CN103082533B (en) | Composite preparation method for functionality protective clothing fabric | |
| CN103407215B (en) | Electrostatic flocking fabric made of alginate fiber and preparation method of electrostatic flocking fabric | |
| CN107558231A (en) | A kind of umbrella cloth and its manufacture method | |
| CN106480724B (en) | The processing method of anti-aging, cold-resistant, antibacterial, high moisture-inhibiting raincoat fabric | |
| CN106867380B (en) | Breathable flame-retardant anti-immersion fabric and preparation method thereof | |
| CN109322158A (en) | A kind of single side waterproof fabric and preparation method thereof | |
| CN112522962A (en) | Crease-free low-elasticity calendering coating composite finishing polyester printed fabric | |
| CN101962915B (en) | Method for preparing windproof moisture-penetrable wool polyester viscose gabardine | |
| CN108193506A (en) | A kind of automotive trim graphene superfine fiber chemical leather | |
| CN103628322B (en) | The processing method of rain coat fabric with high peel strength | |
| CN102851973A (en) | Waterproof moisture-permeable fabric and manufacturing method thereof | |
| CN106087454A (en) | A kind of high water-fastness waterproof moisture-penetrating urethane fabric and preparation method | |
| CN107722856A (en) | A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof | |
| CA2685505C (en) | Covering fabric for aircraft in general aviation | |
| CN112709077B (en) | Finishing method of durable flame-retardant, moisture-permeable, single-absorption and single-prevention fabric | |
| CN109454942A (en) | A kind of high density height removing deer fibre suede synthetic leather | |
| CN111764170B (en) | Waterproof moisture-permeable film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |