CN106867380B - Breathable flame-retardant anti-immersion fabric and preparation method thereof - Google Patents
Breathable flame-retardant anti-immersion fabric and preparation method thereof Download PDFInfo
- Publication number
- CN106867380B CN106867380B CN201710096259.4A CN201710096259A CN106867380B CN 106867380 B CN106867380 B CN 106867380B CN 201710096259 A CN201710096259 A CN 201710096259A CN 106867380 B CN106867380 B CN 106867380B
- Authority
- CN
- China
- Prior art keywords
- parts
- fabric
- butanone
- toluene
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 135
- 239000003063 flame retardant Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 7
- 238000007654 immersion Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title description 2
- 238000000576 coating method Methods 0.000 claims abstract description 71
- 239000011248 coating agent Substances 0.000 claims abstract description 70
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 49
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 48
- 230000001070 adhesive effect Effects 0.000 claims abstract description 44
- 229920002635 polyurethane Polymers 0.000 claims abstract description 44
- 239000004814 polyurethane Substances 0.000 claims abstract description 44
- 239000000853 adhesive Substances 0.000 claims abstract description 43
- 239000002131 composite material Substances 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000012528 membrane Substances 0.000 claims abstract description 30
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003292 glue Substances 0.000 claims abstract description 27
- 230000002940 repellent Effects 0.000 claims abstract description 20
- 239000005871 repellent Substances 0.000 claims abstract description 20
- 238000003490 calendering Methods 0.000 claims abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 120
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 80
- 238000004132 cross linking Methods 0.000 claims description 57
- 150000001875 compounds Chemical class 0.000 claims description 34
- 239000004971 Cross linker Substances 0.000 claims description 32
- 229920000877 Melamine resin Polymers 0.000 claims description 32
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 32
- 229920005749 polyurethane resin Polymers 0.000 claims description 31
- 239000012948 isocyanate Substances 0.000 claims description 25
- 150000002513 isocyanates Chemical class 0.000 claims description 25
- 229920006231 aramid fiber Polymers 0.000 claims description 24
- 239000004831 Hot glue Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 14
- 230000004584 weight gain Effects 0.000 claims description 13
- 235000019786 weight gain Nutrition 0.000 claims description 13
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 17
- 238000013329 compounding Methods 0.000 abstract description 14
- 230000002706 hydrostatic effect Effects 0.000 abstract description 6
- 230000032683 aging Effects 0.000 abstract description 5
- 230000035699 permeability Effects 0.000 abstract description 5
- 239000011229 interlayer Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000006757 chemical reactions by type Methods 0.000 description 10
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 7
- 238000009940 knitting Methods 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 6
- 239000011527 polyurethane coating Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 235000014347 soups Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000003712 anti-aging effect Effects 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010008190 Cerebrovascular accident Diseases 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 208000006011 Stroke Diseases 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The invention discloses a breathable flame-retardant anti-immersion fabric and a preparation method thereof. The preparation method of the breathable flame-retardant immersion-resistant fabric comprises the following steps: 1) coating the coating adhesive on the outer-layer fabric which is subjected to water repellent finishing and calendering in sequence to obtain a windproof finished fabric; 2) carrying out glue point compounding on the surface of the windproof finished fabric coated with the coating glue and the polytetrafluoroethylene/polyurethane composite film; 3) and (3) carrying out glue point compounding on the surface of the composite polytetrafluoroethylene/polyurethane composite film of the fabric obtained in the step 2) and the lining fabric. The invention solves the problem that the interlayer peeling of the middle two-component PTFE membrane material occurs due to wind action in the use environment of the water-resistant fabric. And simultaneously, the comprehensive indexes of hydrostatic pressure, moisture permeability, flame retardance, ageing resistance and the like of the fabric are ensured, and the requirements of the fabric of the clothing for special industry operation are met.
Description
Technical field
The present invention relates to fire-retardant anti-dip facing materials of a kind of vapor-permeable type and preparation method thereof, belong to textile processing field.
Background technique
With the raising of living standards of the people and the progress of society, functional fabric is increasingly used in people
Daily life and work, especially special trade tooling fabric and outdoor sport fabric functionality are more and more stronger, and overall target is got over
Come higher.The garment material of simple function is easier to realize, but the comprehensive one of many indexes, due to the mutual system between index
About, difficulty of processing is larger, is often difficult all to reach expected requirement simultaneously.
It in order to meet indexs, the existing method such as fire-retardant, moisture-inhibiting, anti-aging, water resistant leaching is existed by the way of coating
The mode that a kind of flame-retardant coatings glue coating is taken on a kind of fibr tissue fabric realizes that index, but this are soaked in fire-retardant, moisture-inhibiting, water resistant
Fabric after kind arranging due to the influence of flame-retardant additive, often after hydrothermal aging, soda boiling aging and washing hydrostatic drops compared with
Greatly, it is difficult to meet anti-aging index request.
Summary of the invention
The object of the present invention is to provide fire-retardant anti-dip facing materials of a kind of vapor-permeable type and preparation method thereof, by substrate outer facing material
Coating arrangement is carried out, makes fabric that there is fabulous wind-proof performance to be made due to the windproof barrier action of outer facing material in operating environment
Wind-force can not be applied directly in intermediate membrane material, will not therefore be caused the interlayer slip of membrane material and be influenced product and take effect,
And this coating to outer facing material is arranged except having the conditions such as low weight gain, feel be soft, should not influence product penetrability, anti-flammability,
Water permeability resistance and ageing properties index request.
Present invention firstly provides a kind of coating adhesives, are made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2~3 parts of isocyanate crosslinking；
0.2~0.5 part of melamine crosslinkers；
1.2~1.8 parts of crosslinking accelerator；
15~35 parts of organic solvent.
In above-mentioned coating adhesive, the organic solvent can be butanone and toluene；
The viscosity of the coating adhesive can be 10000~12000mPa.s, concretely 10500mPa.s, 11000mPa.s,
11500mPa.s or 12000mPa.s, the viscosity can ensure that coating starching amount is small, low weight gain, and the fabric hand feel after making coating is soft
It is soft, vapor transfer rate is high, and reduce influence to flame retardant property, water vapour permeability index.
It is the quality of the butanone in terms of 100 parts by the mass parts of the reactive polyurethane resin in above-mentioned coating adhesive
Additive amount can be 5~15 parts, and the quality additive amount of the toluene can be 10~20 parts.
The coating adhesive concretely following 1) -7) in it is any:
1) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2~2.5 parts of isocyanate crosslinking；
0.2~0.3 part of melamine crosslinkers；
1.2~1.5 parts of crosslinking accelerator；
5~10 parts of butanone；
15~20 parts of toluene；
2) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.3~0.5 part of melamine crosslinkers；
1.5~1.8 parts of crosslinking accelerator；
5~8 parts of butanone；
17~20 parts of toluene；
3) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.4~0.5 part of melamine crosslinkers；
1.6~1.8 parts of crosslinking accelerator；
8~10 parts of butanone；
10~17 parts of toluene；
4) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2 parts of isocyanate crosslinking；
0.2 part of melamine crosslinkers；
1.2 parts of crosslinking accelerator；
10 parts of butanone；
15 parts of toluene；
5) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.3 part of melamine crosslinkers；
1.5 parts of crosslinking accelerator；
5 parts of butanone；
20 parts of toluene；
6) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
3 parts of isocyanate crosslinking；
0.5 part of melamine crosslinkers；
1.8 parts of crosslinking accelerator；
8 parts of butanone；
17 parts of toluene；
7) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.4 part of melamine crosslinkers；
1.6 parts of crosslinking accelerator；
10 parts of butanone；
10 parts of toluene.
The reactive polyurethane resin refers to the polyurethane resin there are also hydroxyl reactive group, and hydroxyl therein can be with
Cross-linking reaction is carried out with the isocyanate crosslinking and melamine crosslinkers, forms cross-linked structure, improves binding strength.
It is D-ACE 2345 that new east station of Guangzhou, which can be used, into the code that Chemical Co., Ltd. produces in the reactive polyurethane resin
Product；
The product that new east station of Guangzhou is D-ACE 555 at the code that Chemical Co., Ltd. produces can be used in the isocyanate crosslinking；
The product that new east station of Guangzhou is D-ACE 557 at the code that Chemical Co., Ltd. produces can be used in the melamine crosslinkers；
The product that new east station of Guangzhou is D-ACE 900 at the code that Chemical Co., Ltd. produces can be used in the crosslinking accelerator.
The coating adhesive can be prepared according to the method included the following steps:
The reactive polyurethane resin and the solvent are mixed to get mixed liquor；Described in being added into the mixed liquor
Isocyanate crosslinking, the crosslinking accelerator and the melamine crosslinkers, stir evenly to obtain the final product.
Using butanone or toluene by the viscosity-adjusting agent of the coating adhesive to 10000~12000mPa.s.
Invention further provides a kind of preparation methods of the fire-retardant anti-dip facing material of vapor-permeable type, include the following steps:
1) coating adhesive is coated on the outer shell fabric successively through water repellent finish and calendering, obtains radix saposhnikoviae and arranges fabric；
2) radix saposhnikoviae is arranged the coating coating adhesive of fabric surface and polytetrafluoroethylene (PTFE)/polyurethane composite membrane into
Row glue point is compound；
3) surface of the compound polytetrafluoroethylene (PTFE)/polyurethane composite membrane for the fabric for obtaining step 2) and inner layer fabric
It is compound to get the fire-retardant anti-dip facing material of the vapor-permeable type to carry out glue point.
In above-mentioned preparation method, the outer shell fabric can be aramid fiber plain cloth；
The inner layer fabric can be knitted screen cloth for aramid fiber；
The aramid fiber plain cloth and aramid fiber knitting screen cloth all have good flame retardant property, and without molten drop problem；
The polytetrafluoroethylene (PTFE)/polyurethane composite membrane refers to coating a strata urethane in PolytetrafluoroethylFilm Film
The composite membrane that film obtains, thickness can be 15~50 μm, and grammes per square metre can be 15~55g/m2, specifically can be used with a thickness of 30 μm, grams
Weight is 35g/m2Polytetrafluoroethylene (PTFE)/polyurethane composite membrane.
It is removed using the polytetrafluoroethylene (PTFE)/polyurethane composite membrane and has certain hydrostatic pressing index because of it while being also to ensure that whole
The fire-retardant index of body reaches standard requirements.
In above-mentioned preparation method, in step 1), method conventional in the art is can be used in the step of water repellent finish
It carries out；
The spray rating of the outer shell fabric is not less than 3 grades after the water repellent finish；
In step 1), the condition of the calendering is as follows:
Pressure can be 10~11Mpa, and concretely 10Mpa or 11Mpa, temperature can be 100~120 DEG C, concretely 110
DEG C or 120 DEG C, speed can be 20~30m/min, concretely 20m/min, 25m/min or 30m/min；
In step 1), the radix saposhnikoviae arranges fabric and dries 1~1.5 minute under conditions of 160~170 DEG C；
After the coating step, the dry weight gain of the outer shell fabric can be 7~10g/m2, concretely 7g/m2、8g/
m2、9g/m2Or 10g/m2。
By carrying out water repellent finish and calendering pretreatment to the outer shell fabric, web surface is made to reach water repellent, smooth cause
Close effect keeps coating adhesive film forming continuity good and soft to reduce slurry penetration in coating procedure, for windproof coating
Finishing effect creates primary condition.
In above-mentioned preparation method, the compound condition of glue point described in step 2) is as follows:
Compound binding agent can (through inquiring, this statement should be more acurrate for mono-component polyurethane Reactive hot melt adhesive
's！), the code that the production of Fuller (China) adhesive Co., Ltd specifically can be used is the product of TL-5201；
Spread can be 8~12g/m2, concretely 10g/m2；
Solidification temperature can be 25~35 DEG C, and solidification humidity can be 50~70%, and curing time can be 1~7 day；
The compound condition of glue point described in step 3) is as follows:
Compound binding agent can be the mono-component polyurethane Reactive hot melt adhesive；
Spread can be 8~10g/m2, concretely 8g/m2；
Solidification temperature can be 25~35 DEG C, and solidification humidity can be 50~70%, and curing time can be 1~7 day；
The fire-retardant anti-dip facing material of the vapor-permeable type that the above method is prepared also belongs to protection scope of the present invention.
It is anti-well to guarantee that the fabric after arranging has by coating using the coating adhesive to fabric by the present invention
Wind performance, while there is preferable water vapour permeability again, and ensure that (reaction type polyurethane heats for coat side and compound binding agent
Glue) there is good binding strength.Reaction type polyurethane hot-melt adhesive is selected, can use hydrophilic non-porous reactive polyurethane resin
In moisture and other active hydrogen compounds react with-NCO group, chain extension, generate the cross-linked network with stronger cohesive force
Shape structural polymer, it is ensured that the binding strength of reaction type polyurethane hot-melt adhesive and coating adhesive；Meanwhile the isocyanic acid in coating glue formula
Ester crosslinking agent contain-NCO group can further ensure that the binding strength of coating adhesive and fabric with the active hydrogen reaction in fabric.
The present invention, which passes through, is coated on a certain amount of hydrophilic non-porous type polyurethane resin on outer facing material, reaches good radix saposhnikoviae
Effect (air penetrability norm controlling is under certain standard), makes wind-force that can not penetrate the two-component that fabric acts on composite material inner layer
On fire-retardant PTFE film material, solve because wind-force oscillation makes two-component PTFE generate interlayer stripping problem, and improve cloth and film it
Between binding strength, while the laminating technology of three kinds of materials realizes fabric water permeability resistance, penetrability, anti-flammability, ageing resistance etc.
Overall target meets the functional requirement of job that requires special skills environmental suits fabric.
The present invention solves water resistant dip facing material because intermediate two-component PTFE film material occurs in the effect of use environment apoplexy power
Splitting problem.And the overall targets such as hydrostatic pressing, vapor transfer rate, anti-flammability, anti-ageing property for guaranteeing fabric simultaneously, meet special type
Industry operation garment material needs.
Detailed description of the invention
Fig. 1 is the schematic diagram of the fire-retardant anti-dip facing material of vapor-permeable type of the present invention.
It is respectively marked in figure as follows:
1. outer shell fabric；2. coating glue surface；3. polytetrafluoroethylene (PTFE)/polyurethane composite membrane；4. inner layer fabric (screen cloth)；
5. reaction type polyurethane hot-melt adhesive point.
Specific embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
The materials, reagents and the like used in the following examples is commercially available unless otherwise specified.
The present invention by outer fabric carry out coating way solve composite material among bilayer film because of wind oscillation action
Slippage between generation film.
Embodiment 1,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish being carried out to outer shell fabric: uses fluorine system waterproofing agent (TX-15) padding finishing, temperature is 160 DEG C,
Time 1min, drying, spray rating >=4 grade；
(4) calendering, pressure 10Mpa, temperature 110 are carried out with calender to the outer shell fabric after progress water repellent finish
DEG C, speed 20m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 10 parts
Toluene: 15 parts
555:2.0 parts of isocyanate crosslinking D-ACE
900:1.2 parts of crosslinking accelerator D-ACE
557:0.2 parts of melamine crosslinkers D-ACE
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers obtain coating adhesive with toluene tune viscosity to 10500mPa.s；
The toluene dosage of viscosity is adjusted to be not included in the toluene proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, staged temperature, which is 140 DEG C -140 DEG C -150 DEG C -160 DEG C, is dried 1 minute, does weight gain 7g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane on compounding machine with glue
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature,
Solidify 3 days (72h) in 50% environment of humidity.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2.In 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 1#.
Embodiment 2,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering, pressure 11Mpa, temperature 110 are carried out with calender to the outer shell fabric after progress water repellent finish
DEG C, speed 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 5 parts
Toluene: 20 parts
555:2.5 parts of isocyanate crosslinking D-ACE
900:1.5 parts of crosslinking accelerator D-ACE
D-ACE557:0.3 parts of melamine crosslinkers
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers obtain coating adhesive with butanone tune viscosity to 11500mPa.s；
The butanone dosage of viscosity is adjusted to be not included in the butanone proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, 140 DEG C -140 DEG C -150 DEG C -160 DEG C of staged temperature are dried 1 minute, do weight gain 8g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane on compounding machine with glue
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature,
Solidify 3 days (72h) in 50% environment of humidity.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2.In 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 2#.
Embodiment 3,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering, pressure 11Mpa, temperature 120 are carried out with calender to the outer shell fabric after progress water repellent finish
DEG C, speed 30m/min；
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 8 parts
Toluene: 17 parts
555:3.0 parts of isocyanate crosslinking D-ACE
900:1.8 parts of crosslinking accelerator D-ACE
D-ACE557:0.5 parts of melamine crosslinkers
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers obtain coating adhesive with butanone tune viscosity to 11000mPa.s；
The butanone dosage of viscosity is adjusted to be not included in the butanone proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, 140 DEG C -140 DEG C -150 DEG C -160 DEG C of staged temperature are dried 1 minute, do weight gain 9g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane on compounding machine with glue
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature,
Solidify 3 days (72h) in 50% environment of humidity.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2.In 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 3#.
Embodiment 4,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering, pressure 11Mpa, temperature 110 are carried out with calender to the outer shell fabric after progress water repellent finish
DEG C, speed 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 10 parts
Toluene: 10 parts
555:2.5 parts of isocyanate crosslinking D-ACE
900:1.6 parts of crosslinking accelerator D-ACE
557:0.4 parts of melamine crosslinkers D-ACE
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers obtain coating adhesive with toluene tune viscosity number 12000mPa.s；
The toluene dosage of viscosity is adjusted to be not included in the toluene proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, 140 DEG C -140 DEG C -150 DEG C -160 DEG C of staged temperature are dried 1 minute, do weight gain 10g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane on compounding machine with glue
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature,
Solidify 3 days (72h) in 50% environment of humidity.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2, in 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 4#.
Comparative example 1,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure 11Mpa, 110 DEG C of temperature, vehicle
Fast 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 5 parts
Toluene: 10 parts
555:2.5 parts of isocyanate crosslinking D-ACE
900:1.6 parts of crosslinking accelerator D-ACE
D-ACE557:0.4 parts of melamine crosslinkers
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator, melamine crosslinkers obtain coating adhesive with toluene tune viscosity 13000mPa.s；
The toluene dosage of viscosity is adjusted to be not included in the toluene proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, 140 DEG C -140 DEG C -150 DEG C -160 DEG C of step temperature are dried 1 minute, do weight gain 12g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and the fire-retardant PTFE film of (2) two-component is compound with glue point on compounding machine,
Composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature, humidity
Solidify 3 days (72h) in 50% environment.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2, in 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 5#.
Comparative example 2,
(1) fabric selects: outer shell fabric is aramid fiber plain cloth 40S/2*40S/ 2/248*216, inner layer fabric are aramid fiber needle
Knitmesh cloth (yarn count 40S, grammes per square metre 30g/m2)。
(2) intermediate membrane material be polytetrafluoroethylene (PTFE)/polyurethane composite membrane (30 μm of thickness, grammes per square metre 35g/m2)。
(3) water repellent finish, spray rating >=4 grade are carried out to outer shell fabric.
(4) calendering is carried out with calender to carrying out the outer shell fabric after water repellent finish, pressure 11Mpa, 110 DEG C of temperature, vehicle
Fast 25m/min.
(5) prepared by coating adhesive, raw material weight proportioning of soup processed:
2345:100 parts of reactive polyurethane resin D-ACE
Butanone: 10 parts
Toluene: 20 parts
555:2.5 parts of isocyanate crosslinking D-ACE
900:1.5 parts of crosslinking accelerator D-ACE
D-ACE557:0.3 parts of melamine crosslinkers
Butanone and toluene are added sequentially in reaction type polyurethane coating adhesive, stirred evenly, then be separately added into isocyanic acid
Ester crosslinking agent, crosslinking accelerator and melamine crosslinkers obtain coating adhesive with butanone tune viscosity 9000mPa.s；
The butanone dosage of viscosity is adjusted to be not included in the butanone proportional quantity of ingredient in the above method.
(6) coating: coating adhesive made from above-mentioned steps (4) is handled with floating blade coating machine coated in above-mentioned steps (4)
On fabric afterwards, 140 DEG C -140 DEG C -150 DEG C -160 DEG C of step temperature are dried 1 minute, do weight gain 6g/m2。
(7) radix saposhnikoviae made from (6) is arranged into fabric and (2) polytetrafluoroethylene (PTFE)/polyurethane composite membrane on compounding machine with glue
Point is compound, and composite caking agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 10g/m2, at 25 DEG C of temperature,
Solidify 3 days (72h) in 50% environment of humidity.
(8) fabric film surface is made in (7) and inner layer fabric aramid fiber knitting screen cloth is compound with glue point on compounding machine, it is compound viscous
Connecing agent is mono-component polyurethane Reactive hot melt adhesive TL-5201, spread 8g/m2.In 25 DEG C of temperature, 50% environment of humidity
Solidify 3 days (72h) finished product 6#.
When the dry weight gain of fabric radix saposhnikoviae top finish is respectively in 7,8,9,10,12 and 6g/m2When, finished product obtained after compound
1#-6# product all technical test result is as shown in table 1.
With the increase of windproof top finish spread it can be seen from the data in table 1, air penetrability (windproof index) by
It gradually improves, when windproof coating does weight gain >=7g/m2, air penetrability index do not measure, it is ensured that wind-force can not penetrate fabric be applied to it is poly-
On tetrafluoroethene/polyurethane compound film material, polytetrafluoroethylene (PTFE)/polyurethane composite film material interlayer slip problem is avoided.And with
Spread increase it is fire-retardant be gradually reduced with moisture-inhibiting index, (weight gain is more than 10g/m when reaching certain amount2), it is fire-retardant with it is saturating
Wet index is unable to satisfy standard requirements, and hydrostatic pressing increases with the increase of spread, and hydrostatic pressing refers to after wash resistant and aging
Mark is more preferable.
Verifying is when glue-spread is in 7~10g/m through the foregoing embodiment2When, that is, can guarantee outer facing material to the resilience of wind,
Also ensuring that does not influence vapor transfer rate, anti-flammability, resistance to ag(e)ing index.Fabric prepared by the present invention meets fire-retardant, moisture-inhibiting, anti-ageing
Change, the requirement of waterproof high-performance apparel fabric product standard.
The index test result of the 1#-6# fabric of table 1 1-4 of the embodiment of the present invention and comparative example 1-2 preparation
Claims (8)
1. a kind of preparation method of the fire-retardant anti-dip facing material of vapor-permeable type, includes the following steps:
1) coating adhesive is coated on the outer shell fabric successively through water repellent finish and calendering, obtains radix saposhnikoviae and arranges fabric；It is described outer
Shell fabric is aramid fiber plain cloth；
The coating adhesive is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2~3 parts of isocyanate crosslinking；
0.2~0.5 part of melamine crosslinkers；
1.2~1.8 parts of crosslinking accelerator；
15~35 parts of organic solvent；
The solvent is butanone and toluene；
The viscosity of the coating adhesive is 10000~12000mPas；
2) surface and polytetrafluoroethylene (PTFE)/polyurethane composite membrane that the radix saposhnikoviae is arranged to the coating coating adhesive of fabric carry out glue
Point is compound；
3) surface of the compound polytetrafluoroethylene (PTFE)/polyurethane composite membrane for the fabric for obtaining step 2) and inner layer fabric carry out
Glue point is compound to get the fire-retardant anti-dip facing material of the vapor-permeable type；
The inner layer fabric is that aramid fiber is knitted screen cloth.
2. preparation method according to claim 1, it is characterised in that: the polytetrafluoroethylene (PTFE)/polyurethane composite membrane thickness
Degree is 15~50 μm, and grammes per square metre is 15~55g/m2。
3. preparation method according to claim 1 or 2, it is characterised in that: described after the water repellent finish in step 1)
The spray rating of outer shell fabric is not less than 3 grades；
In step 1), the condition of the calendering is as follows:
Pressure is 10~11MPa, and temperature is 100~120 DEG C, and speed is 20~30m/min；
In step 1), the radix saposhnikoviae arranges fabric and dries 1~1.5 minute under conditions of 160~170 DEG C；
After the coating step, the dry weight gain of the outer shell fabric is 7~10g/m2。
4. preparation method according to claim 1 or 2, it is characterised in that: the compound condition of glue point described in step 2) is such as
Under:
Compound binding agent is mono-component polyurethane Reactive hot melt adhesive；
Spread is 8~12g/m2；
Solidification temperature is 25~35 DEG C, and solidification humidity is 50~70%, and curing time is 1~7 day；
The compound condition of glue point described in step 3) is as follows:
Compound binding agent is mono-component polyurethane Reactive hot melt adhesive；
Spread is 8~10g/m2；
Solidification temperature is 25~35 DEG C, and solidification humidity is 50~70%, and curing time is 1~7 day.
5. preparation method according to claim 1, it is characterised in that: the mass parts with the reactive polyurethane resin are
100 parts of meters, the quality additive amount of the butanone are 5~15 parts, and the quality additive amount of the toluene is 10~20 parts.
6. preparation method according to claim 1, it is characterised in that: the coating adhesive is following 1) -7) in it is any:
1) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2~2.5 parts of isocyanate crosslinking；
0.2~0.3 part of melamine crosslinkers；
1.2~1.5 parts of crosslinking accelerator；
5~10 parts of butanone；
15~20 parts of toluene；
2) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.3~0.5 part of melamine crosslinkers；
1.5~1.8 parts of crosslinking accelerator；
5~8 parts of butanone；
17~20 parts of toluene；
3) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5~3 parts of isocyanate crosslinking；
0.4~0.5 part of melamine crosslinkers；
1.6~1.8 parts of crosslinking accelerator；
8~10 parts of butanone；
10~17 parts of toluene；
4) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2 parts of isocyanate crosslinking；
0.2 part of melamine crosslinkers；
1.2 parts of crosslinking accelerator；
10 parts of butanone；
15 parts of toluene；
5) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.3 part of melamine crosslinkers；
1.5 parts of crosslinking accelerator；
5 parts of butanone；
20 parts of toluene；
6) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
3 parts of isocyanate crosslinking；
0.5 part of melamine crosslinkers；
1.8 parts of crosslinking accelerator；
8 parts of butanone；
17 parts of toluene；
7) it is made of the component of following mass parts:
100 parts of reactive polyurethane resin；
2.5 parts of isocyanate crosslinking；
0.4 part of melamine crosslinkers；
1.6 parts of crosslinking accelerator；
10 parts of butanone；
10 parts of toluene.
7. preparation method according to claim 1, it is characterised in that: method system of the coating adhesive by including the following steps
It is standby: the reactive polyurethane resin and the solvent are mixed to get mixed liquor；The isocyanide is added into the mixed liquor
Acid esters crosslinking agent, the crosslinking accelerator and the melamine crosslinkers, stir evenly to obtain the final product.
8. the fire-retardant anti-dip facing material of vapor-permeable type of any one of claim 1-7 the method preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096259.4A CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096259.4A CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106867380A CN106867380A (en) | 2017-06-20 |
| CN106867380B true CN106867380B (en) | 2019-07-19 |
Family
ID=59168954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710096259.4A Active CN106867380B (en) | 2017-02-22 | 2017-02-22 | Breathable flame-retardant anti-immersion fabric and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106867380B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108528059A (en) * | 2018-03-08 | 2018-09-14 | 海宁天福经编涂层有限公司 | A kind of preparation method of fire-retardant banner fabric |
| CN109778545A (en) * | 2019-01-22 | 2019-05-21 | 乐清市雅格狮丹服饰有限公司 | A kind of finishing technique of waterproof casings |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201104309Y (en) * | 2007-08-29 | 2008-08-20 | 中国人民解放军总后勤部军需装备研究所 | Active nucleus ash protection facing material |
| WO2010057593A1 (en) * | 2008-11-21 | 2010-05-27 | Bayer Materialscience Ag | Multi-layered fire-resistant plastic material |
| CN103614922A (en) * | 2013-11-22 | 2014-03-05 | 丹东优耐特纺织品有限公司 | Down coat fabric treatment method for preventing down feather from escaping from needle holes |
| CN106049049A (en) * | 2016-08-02 | 2016-10-26 | 丹东优耐特纺织品有限公司 | Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric |
-
2017
- 2017-02-22 CN CN201710096259.4A patent/CN106867380B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201104309Y (en) * | 2007-08-29 | 2008-08-20 | 中国人民解放军总后勤部军需装备研究所 | Active nucleus ash protection facing material |
| WO2010057593A1 (en) * | 2008-11-21 | 2010-05-27 | Bayer Materialscience Ag | Multi-layered fire-resistant plastic material |
| CN103614922A (en) * | 2013-11-22 | 2014-03-05 | 丹东优耐特纺织品有限公司 | Down coat fabric treatment method for preventing down feather from escaping from needle holes |
| CN106049049A (en) * | 2016-08-02 | 2016-10-26 | 丹东优耐特纺织品有限公司 | Durable flame-retardant, water-repellent, waterproof and moisture permeable finishing method of polyester fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106867380A (en) | 2017-06-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104527190B (en) | A kind of oil storage bag TPU composite | |
| CN106049049B (en) | Dacron permanent seal cooling is fire-retardant, water repellent, Waterproof Breathable method for sorting | |
| CN101538800B (en) | Thermoplastic resin coating film material and preparation method thereof | |
| CN101736595B (en) | Method for preparing waterproof moisture-permeable coated fabric | |
| KR100822641B1 (en) | Textile coating method with water urethane emulsion | |
| CN103255640B (en) | Environmentally-friendly flame retardant polyurethane synthetic leather, preparation method and product thereof | |
| CN101247949B (en) | Treated textile fabric | |
| CN105002748B (en) | It is a kind of it is crease-resistant, without folding line footwear nonwoven polyurethane synthetic leather and preparation method thereof | |
| CN105821670A (en) | Novel textile downproof technology | |
| CN103082533B (en) | Composite preparation method for functionality protective clothing fabric | |
| CN106867380B (en) | Breathable flame-retardant anti-immersion fabric and preparation method thereof | |
| CN107558231A (en) | A kind of umbrella cloth and its manufacture method | |
| CN110273302B (en) | Preparation method of multifunctional superfine fiber synthetic leather | |
| CN109322158A (en) | A kind of single side waterproof fabric and preparation method thereof | |
| CN107476077A (en) | A kind of preparation technology of ultra-fine velvet surface synthetic leather | |
| CN106480724A (en) | Anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric | |
| CN108842469A (en) | A kind of preparation method of the anti-drilling pile fabric of waterproof and breathable | |
| DE69927185T2 (en) | WATER VAPOR PERMEABLE, WATERPROOF MATERIAL AND METHOD FOR THE PRODUCTION THEREOF | |
| CN107829307A (en) | A kind of level membrane structure acid-proof moisture permeable fabricses and preparation method thereof | |
| CN108193506A (en) | A kind of automotive trim graphene superfine fiber chemical leather | |
| CN106103837A (en) | The delay differentiation of the composite strengthened | |
| CN102851973A (en) | Waterproof moisture-permeable fabric and manufacturing method thereof | |
| CN106087454A (en) | A kind of high water-fastness waterproof moisture-penetrating urethane fabric and preparation method | |
| CN107722856A (en) | A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof | |
| CN112709077B (en) | Finishing method of durable flame-retardant, moisture-permeable, single-absorption and single-prevention fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |