CN106480724A - Anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric - Google Patents
Anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric Download PDFInfo
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- CN106480724A CN106480724A CN201611006421.0A CN201611006421A CN106480724A CN 106480724 A CN106480724 A CN 106480724A CN 201611006421 A CN201611006421 A CN 201611006421A CN 106480724 A CN106480724 A CN 106480724A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
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- D—TEXTILES; PAPER
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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Abstract
The present invention is anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric, A, with Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 5 10, hydroxyl-terminated injecting two methyl siloxane emulsion 58, poly- methyl carbamide resin 35, suitable quantity of water are obtained primer coating glue；B, with the micropore ligno-cellulose 58 of 100,15 μm≤d≤30 μm of aqueous polyurethane adhesive, anti-bacteium deodorization finishing agent 68, isocyanate crosslinking 13, suitable quantity of water are obtained surface layer coating adhesive；Coating treatment is carried out to terylene, polyamide fibre, polyester polyamide blended yarn weaved fabric, prepared raincoat fabric, process is simple, easy to operate, the product feature of environmental protection is good.
Description
Technical field
The present invention relates to fabric coating field, and in particular to be anti-aging, cold-resistant, antibacterial, high moisture-inhibiting terylene, polyamide fibre
And the processing method of polyester polyamide blending raincoat fabric.
Background technology
At present, the existing function in market is more, better performances raincoat fabrics are substantially by solvent-borne type waterproof moisture-penetrating urethane
Processing is obtained.Due to containing the organic solvent such as a large amount of toluene, dimethylformamide, not environmentally, serious prestige is constituted to human health
The side of body.
In addition, the moisture permeability raincoat product that prepared by most of waterproof moisture-penetrating urethane coating agents, it may appear that product is met
Water moisture absorption, swelling problem, so as to cause fabric weight to increase, take uncomfortable.Meanwhile, the dress of summer raincoat fabric directly connects
Tactile skin, and the existing raincoat fabric in market does not often possess antibacterial functions.
Had no while having anti-aging, cold-resistant, antibacterial, the technology of high moisture-inhibiting raincoat fabric at present and disclose.
Chinese patent CN103628322B《The processing method of rain coat fabric with high peel strength》, which discloses a kind of coating process
The processing method of the rain coat fabric with high peel strength of preparation, its primary coat coating adhesive is by toluene, micropore ligno-cellulose, nano-silica
Change titanium, Waterproof Breathable primer, butanone, isocyanate crosslinking to be obtained；Surface layer coating adhesive is by micropore ligno-cellulose, Waterproof Breathable
Face gluing, dimethylformamide, toluene, solvent-borne type dispersant are obtained.Above coating adhesive is used for arranging polyester fabric, collated
Afterwards, fabric possesses moisture-inhibiting, water repellent, high-peeling strength performance, in addition, nothing other functions, while which uses toluene butanone
Deng organic solvent, not environmentally.
10481580 B of Chinese patent CN《A kind of waterproof, low-temperature resistant soft, moisture permeable coating glue and preparation method thereof》, its
It is made up of coating agent, three kinds of components of crosslinking agent and crosslinking accelerator and organic solvent.Wherein coating agent is by diisocyanate, hydrocarbon hydroxyl
Base dimethyl silicone polymer, the polyethers moisture-inhibiting factor and modified wood fibre element powder is obtained through the synthesis of primary, secondary reaction；Crosslinking agent
For polyisocyanates or melmac, accelerator is dibutyltindilaurylmercaptide cinnamic acid, stannous octoate, triethylenediamine, to toluene
One kind in sulfonic acid；Solvent be ethyl acetate, dimethylformamide, toluene, butanone, cyclohexanone, acetone, methyl pyrrolidone,
One or two or three kinds in dimethyl sulfoxide (DMSO)；After its arrangement base fabric possess that waterproof, minus 20 degrees are low temperature resistant, moisture-inhibiting, anti-
Ageing properties.In addition, no other performances, while which uses the organic solvents such as toluene, dimethylformamide, not environmentally.
Chinese patent CN201010205336.3《A kind of waterproof moisture permeation polyurethane paint used for textiles and preparation method》, its
Using methyl diphenylene diisocyanate, toluene di-isocyanate(TDI), polyether Glycols, Linear Double hydroxyalkyl siloxanes, polyester two
First alcohol, trimethylolpropane, chain extender, sealer, dibutyltin dilaurate, solvent are through prepolymerization reaction, chain extending reaction, envelope
Close reaction to be obtained.Wherein solvent is ethyl acetate, butyl acetate, dimethylbenzene, cyclohexanone, toluene, butanone, N, N- dimethyl formyl
In amine one or its two or its three.After its arrangement, product is soft, subzero 30 degree cold resistance is good, moisture-inhibiting is high, hydraulic pressure is high, removes
Outside this, other performances of product nothing；While product contains the organic solvents such as toluene, N,N-dimethylformamide not environmentally.
Content of the invention
It is an object of the invention to provide the processing method of a kind of anti-aging, cold-resistant, antibacterial, high moisture-inhibiting raincoat fabric.Increasing
Plus while raincoat fabric wearing comfort, health, also avoid the fabric through the coating of waterproof moisture-penetrating urethane glue from meeting water moisture absorption
Swelling problem.Suitable for terylene, polyamide fibre and polyester polyamide blending raincoat fabric.
Raincoat fabric after coating adhesive of the present invention processing has anti-aging, cold-resistant, antibacterial, high moisture-inhibiting performance, while face
Material environmental protection.
The present invention is anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric：
1）The preparation of coating adhesive
A, the preparation of primer coating glue, raw material is by weight ratio：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 5-10, terminal hydroxy group poly dimethyl
Siloxane emulsified thing 5-8, poly- methyl carbamide resin 3-5 mixing and stirring, be subsequently adding appropriate water viscosity is adjusted in 10000-
15000mPa.s, obtains primer coating glue.
B, the preparation of surface layer coating adhesive, raw material is by weight ratio：
Aqueous polyurethane adhesive 100, the micropore ligno-cellulose 5-8 of 15 μm≤d≤30 μm, anti-bacteium deodorization finishing agent 6-8 are mixed
Conjunction stirs, and is subsequently adding isocyanate crosslinking 1-3, adds appropriate water to adjust viscosity in 7000-8000mPa.s, obtains
To surface layer coating adhesive.
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric；Or using through waterproof
The terylene of process, polyamide fibre and polyester polyamide blended yarn weaved fabric.
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2.
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C of roasting
2.5-3 minute is dried, does weightening 15-20g/m2.
Waterproof high moisture-inhibiting polyurethane binder：Selected from Liaoning fixed star fine chemistry industry FS-760 product；
Aqueous polyurethane adhesive, selected from Liaoning Sunichem Co., Ltd.'s FS-701R product；
Poly- methyl carbamide resin：Selected from Beijing skill Development Co., Ltd of Tian Heng Rehabilitation PERGOPAK product；
Hydroxyl-terminated injecting two methyl siloxane emulsion：Selected from the soft gorgeous sliding product of Liaoning Sunichem Co., Ltd.；
Anti-bacteium deodorization finishing agent：Selected from Beijing Jie Ershuan High Seience Technology Co., Ltd. SCJ-990 product；
Anion or non-ion fluorin system waterproofing agent：Optional great Jin fluorination Gong Zhong Co., Ltd TG-580 product；
Isocyanate crosslinking：Optional Liaoning fixed star fine chemistry industry DF-897 product.
Simple production process of the present invention, easy to operate, invention raw material environmental protection, product is prepared without volatile organic compound
Thing, belongs to environment-friendly products.
Primer coating glue main component of the present invention is Waterproof high moisture-inhibiting polyurethane binder, contains in its synthesis material
A large amount of ethylene glycol polyethers；Ethylene glycol polyethers is the polyethers containing a large amount of ethyoxyl hydrophilic radicals, containing big in polymerisation molecule
- the OCH2CH2- of amount ,-OH ,-NH- ,-NHCOO- group, above group can capture, in the form of hydrogen bond, the vapor that human body is distributed
Molecule, and by the warm-up movement of polyurethane macromolecular segment and ectonexine relative humidity differential, make water vapour molecule from humidity high one
Side is delivered to the low side of humidity, reaches the effect of fabric high moisture-inhibiting.
Meanwhile, Waterproof high moisture-inhibiting polyurethane binder is the heat reactivity polyurethane containing active group-NCO, can be with which
Anion or non-ion fluorin system waterproofing agent are effectively adhered in fabric for medium；Under the conditions of 120-140 DEG C of coating fabric is baked, water
Property the release of waterproof high moisture-inhibiting polyurethane binder activity-NCO group can with hydroxyl-terminated injecting two methyl siloxane emulsion in
The hydroxyl isoreactivity radical reaction contained in terminal hydroxy group, poly- methyl carbamide resin, also can be with the active group in fabric（Hydroxyl, ammonia
Base etc.）React.Each component raw material and fabric effectively can be combined by Waterproof high moisture-inhibiting polyurethane binder, it is ensured that bottom
Layer coating adhesive and fabric binding strength and washing fastness.
The present invention selects poly- methyl carbamide resin, and great amount of hydroxy group active group is contained on its surface can be poly- with Waterproof high moisture-inhibiting
Active group-NCO in urethane adhesive is chemically bonded, and builds the skeleton structure of primer coating glue, and waterproofing agent is sticked to
The enrichment of skeleton surface, i.e. fluorine atom is arranged in coating surface, makes primer coating glue hydrophobic, and is prevented effectively from saturating by fabric gap
The swelling problem of glued membrane that the water that crosses is caused.
Contain hydroxyl-terminated injecting two methyl siloxane emulsion in primer coating glue of the present invention, which contains siloxanes, siloxanes
Softness, its rheological flow activation performance very little, when temperature drops to -136 DEG C, also there is sub-chain motion in siloxanes, and therefore which is low temperature resistant, resistance to
Cold good, fabric still has preferable feel at subzero 40 DEG C, and web surface is smooth.In addition, the poly- diformazan of terminal hydroxy group
Without unsaturated bond on radical siloxane emulsion main chain, and-Si-O-Si- key is sufficiently stable to oxygen and ozone and ultraviolet etc., because
This fabric ageing resistace is good.
Waterproof high moisture-inhibiting polyurethane binder, anion or non-ion fluorin system waterproofing agent, terminal hydroxy group poly dimethyl silicon
Oxygen alkane emulsion, poly- methyl carbamide resin, above mixed raw material obtain hydrophobic underlayer coating adhesive of the present invention.Fabric is coated through which,
Web surface can form hydrophobic polyurethane cured film.
Surface layer coating adhesive main component of the present invention be aqueous polyurethane adhesive, its be containing hydrophilic radicals such as a large amount of carboxyls
Soft bullet polyurethane.
In surface layer coating adhesive of the present invention add micropore ligno-cellulose, its contain a large amount of lignin effectively can adsorb ultraviolet
Line, so as to slow down the ageing properties of polyurethane；Meanwhile, the phenolic hydroxyl structure that micropore ligno-cellulose contains can prevent free radical
Reaction, therefore, makes polyurethane have good ageing resistace.The microcellular structure of micropore ligno-cellulose can increase face further
The moisture-inhibiting passage of the water vapour molecule of layer coating adhesive, increases fabric moisture transmission performance.
The realization of antibacterial functions of the present invention is to adopt anti-bacteium deodorization finishing agent, and which is a kind of phenylamide cationic antibacterial
Agent deodorization finishing agent.
Contain isocyanate crosslinking, when 165-170 DEG C of coating fabric is baked, isocyanates in surface layer coating adhesive of the present invention
Releasable active group-the NCO of crosslinking agent also can be bonded with aqueous polyurethane with the hydroxyl reaction on micropore ligno-cellulose surface
Carboxyl isoreactivity radical reaction in agent, while can react with the amino in phenylamide cationic antibacterial deodorization finishing agent,
Which plays function served as bridge, and each raw material in surface layer coating adhesive is effectively bonded together, and lifts the binding strength, resistance to of surface layer coating adhesive
Wash fastness.In addition, when 165-170 DEG C of high temperature of coating fabric is baked, isocyanate crosslinking also can with primer coating glue in
Completely active group reacts unreacted further；While surface layer coating adhesive fastness is guaranteed, primary coat coating adhesive has also been ensured
Binding strength with surface layer coating adhesive.
The raincoat fabric of present invention processing, coating adhesive face are that cloth cover is outer layer near skin surface.During use, human body goes out
After sweat, water vapour molecule is first entered in surface layer coating adhesive glued membrane by " chemical ladder stone " effect, then enters primer coating glue
In glued membrane.As water vapour molecule is different from moisture sub-volume, water vapour molecule can spontaneous forward movement under pressure, and
Quick diffusive evaporation, the micro channel for easily passing through hydrophobic polyurethane cured film reach and lead wet purpose, and moisture sub-volume is larger,
By cut-off outside passage, therefore, after arrangement, fabric has water resistance but does not affect the water vapour permeability of fabric, while also effective
Avoid the problem that waterproof moisture-penetrating urethane coating glued membrane hygroscopic swelling causes fabric to increase weight.
Specific embodiment
Embodiment 1
1）The preparation of coating adhesive
A, the preparation of primer coating glue：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 5, terminal hydroxy group poly dimethyl silicon
Oxygen alkane emulsion 5, poly- 3 mixing and stirring of methyl carbamide resin, be subsequently adding appropriate water and viscosity adjusted in 10000mPa.s, obtain
To bottom coating adhesive.
B, the preparation of surface layer coating adhesive：
Aqueous polyurethane adhesive 100, d=30 μm of micropore ligno-cellulose 5,6 mixing and stirring of anti-bacteium deodorization finishing agent,
Isocyanate crosslinking 1 is subsequently adding, and is added appropriate water viscosity to be adjusted in 7000mPa.s, is obtained surface layer coating adhesive.
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric.
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2.
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C of roasting
2.5-3 minute is dried, does weightening 15-20g/m2.
Embodiment 2
1）The preparation of coating adhesive
A, the preparation of primer coating glue：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 7, terminal hydroxy group poly dimethyl silicon
Oxygen alkane emulsion 6, poly- 4 mixing and stirring of methyl carbamide resin, be subsequently adding appropriate water and viscosity adjusted in 12000mPa.s, obtain
To bottom coating adhesive.
B, the preparation of surface layer coating adhesive：
Aqueous polyurethane adhesive 100, d=30 μm of micropore ligno-cellulose 6,7 mixing and stirring of anti-bacteium deodorization finishing agent,
Isocyanate crosslinking 2 is subsequently adding, and is added appropriate water viscosity to be adjusted in 7300mPa.s, is obtained surface layer coating adhesive.
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric.
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2.
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C of roasting
2.5-3 minute is dried, does weightening 15-20g/m2.
Embodiment 3
1）The preparation of coating adhesive
A, the preparation of primer coating glue：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 8, terminal hydroxy group poly dimethyl silicon
Oxygen alkane emulsion 7, poly- 3 mixing and stirring of methyl carbamide resin, be subsequently adding appropriate water and viscosity adjusted in 13000mPa.s, obtain
To bottom coating adhesive.
B, the preparation of surface layer coating adhesive：
Aqueous polyurethane adhesive 100, d=15 μm of micropore ligno-cellulose 8,7 mixing and stirring of anti-bacteium deodorization finishing agent,
Isocyanate crosslinking 2.5 is subsequently adding, and is added appropriate water viscosity to be adjusted in 7500mPa.s, is obtained surface layer coating adhesive.
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric.
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2.
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C of roasting
2.5-3 minute is dried, does weightening 15-20g/m2.
Embodiment 4
1）The preparation of coating adhesive
A, the preparation of primer coating glue：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 10, terminal hydroxy group poly dimethyl silicon
Oxygen alkane emulsion 8, poly- 5 mixing and stirring of methyl carbamide resin, be subsequently adding appropriate water and viscosity adjusted in 15000mPa.s, obtain
To bottom coating adhesive.
B, the preparation of surface layer coating adhesive：
Aqueous polyurethane adhesive 100, d=20 μm of micropore ligno-cellulose 8,8 mixing and stirring of anti-bacteium deodorization finishing agent,
Isocyanate crosslinking 3 is subsequently adding, and is added appropriate water viscosity to be adjusted in 8000mPa.s, is obtained surface layer coating adhesive.
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric.
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2.
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C of roasting
2.5-3 minute is dried, does weightening 15-20g/m2.
The raw material proportioning of above-described embodiment 1-4 is weight ratio.
In above-described embodiment 1-4：
Waterproof high moisture-inhibiting polyurethane binder：Selected from Liaoning fixed star fine chemistry industry FS-760 product；
Aqueous polyurethane adhesive, selected from Liaoning Sunichem Co., Ltd.'s FS-701R product；
Poly- methyl carbamide resin：Selected from Beijing skill Development Co., Ltd of Tian Heng Rehabilitation PERGOPAK product；
Hydroxyl-terminated injecting two methyl siloxane emulsion：Selected from the soft gorgeous sliding product of Liaoning Sunichem Co., Ltd.；
Anti-bacteium deodorization finishing agent：Selected from Beijing Jie Ershuan High Seience Technology Co., Ltd. SCJ-990 product；
Anion or non-ion fluorin system waterproofing agent：Selected from great Jin fluorination Gong Zhong Co., Ltd TG-580 product；
Isocyanate crosslinking：Selected from Liaoning fixed star fine chemistry industry DF-897 product.
Testing inspection：
Experimental example 1
1. base fabric is selected：The 70D*160D Tynex woven fabric of water-proofing treatment；
2. carry out primary coat with 4 bottom of embodiment 1-, surface layer coating adhesive respectively to base fabric and face painting is processed：
（2-1）4 primer coating glue of embodiment 1- is coated in base fabric with floating blade coating machine, 120 DEG C -120 DEG C -130 DEG C -
140 DEG C bake 1.5 minutes, do weightening 20g/m2；
（2-2）4 surface layer coating adhesive of embodiment 1- is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165
DEG C -165 DEG C -170 DEG C -170 DEG C bake 2.5 minutes, do weightening 15g/m2.
Concrete Testing index such as following table：
10 product performance indexs of washing：
Experimental example 2
1. base fabric is selected：The 150D*150D terylene oxford of water-proofing treatment
2. carry out primary coat with 4 bottom of embodiment 1-, surface layer coating adhesive respectively to base fabric and face painting is processed；
（2-1）4 primer coating glue of embodiment 1- embodiment is coated in base fabric with floating blade coating machine, 120 DEG C -120 DEG C -
130 DEG C -140 DEG C bake 2 minutes, do weightening 25g/m2；
（2-2）4 surface layer coating adhesive of embodiment 1- is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165
DEG C -165 DEG C -170 DEG C -170 DEG C bake 3 minutes, do weightening 18g/m2.
Concrete Testing index such as following table：
10 product performance indexs of washing：
Experimental example 3
1. base fabric is selected：Water-proofing treatment（75D terylene+70D nylon）* (40s+100D) washs short fibre/147*102/ inch brocade
Wash interwoven
2. carry out primary coat with 4 bottom of embodiment 1-, surface layer coating adhesive respectively to base fabric and face painting is processed；
（2-1）4 primer coating glue of embodiment 1- embodiment is coated in base fabric with floating blade coating machine, 120 DEG C -120 DEG C -
130 DEG C -140 DEG C bake 2 minutes, do weightening 30g/m2；
（2-2）4 surface layer coating adhesive of embodiment 1- embodiment is coated on above-mentioned base fabric primer coating glue with floating blade coating machine,
165 DEG C -165 DEG C -170 DEG C -170 DEG C bake 3 minutes, do weightening 20g/m2.
Concrete Testing index such as following table：
10 product performance indexs of washing：
Detection method：
Wet and heat ageing resistant：By FZ/T75007-1995 standard testing；
Lower temperature resistance：By FZ/T 01007-2008 standard testing；
Surface moisture resistance：By GB/T4745-2012 standard testing；
Vapor transfer rate：According to ASTM E96-1995 standard testing
Washing fastness：By GB/T 8629-2001《Textile Test home washings and drying program》, 5A program washes 10 times；
Water permeability resistance energy（Hydrostatic pressing）：By GB/T4744-2013 standard testing.
Anti-microbial property：By GB/T 20944-2007 standard testing.
Compare terylene, polyamide fibre and polyester polyamide blending raincoat product nothing as can be seen that being obtained by the present invention by upper table
Smell, VOC free discharge, the feature of environmental protection are good；Product has several functions：Good surface moisture resistance, water permeability resistance energy, subzero 40
DEG C low-temperature impact free from flaw, soft；Product wearing comfort is good, with higher vapor transfer rate and anti-microbial property, and simultaneously
Waterproof Breathable coating product glued membrane is avoided to meet water hygroscopic swelling problem；Additionally, durability of product is good, and wet and heat ageing resistant, water-fastness；
To sum up, product good combination property.
Claims (2)
1. anti-aging, cold-resistant, antibacterial, the processing method of high moisture-inhibiting raincoat fabric, is characterized in that：
1）The preparation of coating adhesive
A, the preparation of primer coating glue, raw material is by weight ratio：
Waterproof high moisture-inhibiting polyurethane binder 100, anion or non-ion fluorin system waterproofing agent 5-10, terminal hydroxy group poly dimethyl
Siloxane emulsified thing 5-8, poly- methyl carbamide resin 3-5 mixing and stirring, be subsequently adding appropriate water viscosity is adjusted in 10000-
15000mPa.s, obtains primer coating glue；
B, the preparation of surface layer coating adhesive, raw material is by weight ratio：
Aqueous polyurethane adhesive 100, the micropore ligno-cellulose 5-8 of 15 μm≤d≤30 μm, anti-bacteium deodorization finishing agent 6-8 are mixed
Conjunction stirs, and is subsequently adding isocyanate crosslinking 1-3, adds appropriate water to adjust viscosity in 7000-8000mPa.s, obtains
To surface layer coating adhesive；
2）Base fabric pre-treatment：Water-proofing treatment is carried out to terylene, polyamide fibre and polyester polyamide blended yarn weaved fabric；
3) fabric working process
(3-1) primer coating glue is coated in base fabric with floating blade coating machine, 120-140 DEG C bakes 1.5-2 minute, does weightening
20-30g/m2；
（3-2）Surface layer coating adhesive is coated on above-mentioned base fabric primer coating glue with floating blade coating machine, 165-170 DEG C bakes
2.5-3 minute, do weightening 15-20g/m2；
Waterproof high moisture-inhibiting polyurethane binder：Selected from Liaoning fixed star fine chemistry industry FS-760 product；
Aqueous polyurethane adhesive：Selected from Liaoning Sunichem Co., Ltd.'s FS-701R product；
Poly- methyl carbamide resin：Selected from Beijing skill Development Co., Ltd of Tian Heng Rehabilitation PERGOPAK product；
Hydroxyl-terminated injecting two methyl siloxane emulsion：Selected from the soft gorgeous sliding product of Liaoning Sunichem Co., Ltd.；
Anti-bacteium deodorization finishing agent：Selected from Beijing Jie Ershuan High Seience Technology Co., Ltd. SCJ-990 product.
2. as claim 1 processing method, the raincoat fabric for obtaining.
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| CN108977021A (en) * | 2018-06-08 | 2018-12-11 | 浙江安吉朝辉新材料有限公司 | A kind of aqueous woodware paint |
| CN109610193A (en) * | 2018-11-06 | 2019-04-12 | 辽宁恒星精细化工有限公司 | Textile fabric is windproof, cold-resistant, fixation aqueous coating glue and preparation method |
| CN115613368A (en) * | 2022-09-05 | 2023-01-17 | 合肥冠怡涂层织物有限公司 | Flame-retardant high-cold-resistance PU raincoat leather and preparation method thereof |
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| CN109610193A (en) * | 2018-11-06 | 2019-04-12 | 辽宁恒星精细化工有限公司 | Textile fabric is windproof, cold-resistant, fixation aqueous coating glue and preparation method |
| CN109610193B (en) * | 2018-11-06 | 2021-03-23 | 辽宁恒星精细化工有限公司 | Windproof, cold-resistant and color-fixing water-based coating adhesive for textile fabric and preparation method thereof |
| CN115613368A (en) * | 2022-09-05 | 2023-01-17 | 合肥冠怡涂层织物有限公司 | Flame-retardant high-cold-resistance PU raincoat leather and preparation method thereof |
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