CN106835136B - A kind of technique that silver tire burns glaze - Google Patents

A kind of technique that silver tire burns glaze Download PDF

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Publication number
CN106835136B
CN106835136B CN201611168611.2A CN201611168611A CN106835136B CN 106835136 B CN106835136 B CN 106835136B CN 201611168611 A CN201611168611 A CN 201611168611A CN 106835136 B CN106835136 B CN 106835136B
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glaze
silver
coating
colored
colored tire
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CN106835136A (en
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汤作驰
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23DENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
    • C23D11/00Continuous processes; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions

Abstract

The invention discloses the techniques that a kind of silver-colored tire burns glaze, are related to the manufacturing process technology field of silverware.The technique is the following steps are included: S1: it is spare that glaze and water by weight the ratio of 1:1-2.5 are modulated into coating glaze;S2: the coating glaze of step S1 is coated in silver-colored tire surface;Be coated with glaze with a thickness of 0.1-2mm;S3: the coating glaze on silver-colored tire surface is dry, then silver-colored tire is placed in baking furnace and is fired to the melting of silver-colored tire surface glaze, then cooling down makes the glaze of melting form glaze layer on silver-colored tire surface.Silver tire of the invention burns the technique of glaze by being coated to silver-colored tire surface comprehensively, its surface is set to be coated with to form coat of colo(u)r, glaze layer is formed after firing, after through modes such as spraying, transfer, drawing or immersions glaze pattern is formed in glaze layer, then be fired into required gloss firing silverware.The process is simple, facilitates a variety of colored glazes on silverware to fire, solves the problems, such as traditional silverware monochrome and oxidizable blackening, have a vast market economic benefit and artistic value.

Description

A kind of technique that silver tire burns glaze
Technical field
The present invention relates to the manufacturing process technology field of silverware more particularly to a kind of techniques that silver-colored tire burns glaze.
Background technique
Silver is a kind of precious metal that comparison is active, easily reacts and generate in air the sulphur of black with sulphur or hydrogen sulfide Change silver.The silver jewellery of long-time service is since surface is little affected by friction, and it is more serious to become black phenomenon for this nigrescence after placement.Silverware Wear time is long to be cleared up, and when cleaning is time-consuming, easily precious metal is caused to be lost.Silverware is due to by certainly The limitation of body characteristic, either ornaments and articles for daily use will appear color reduction in use for some time, send out Wu Dengying Beautiful defect is rung, and the color that silverware is presented is more single, visual impact dynamics is not strong.
Based on the defect of above-mentioned silverware, the current fine work device for new silver-colored tire gloss firing occur few in the market, mainly The reason is that, silver-colored tire surface glazing material is fired, glaze melted, cool down after form cured glaze layer, due to silver-colored tire and glaze layer The coefficient of expansion, constriction coefficient are different, are easy cracking after the glaze layer on silver-colored tire surface is cooling;In addition, silver-colored tire surface smoother, especially It is burnishing surface, glaze is difficult to be adsorbed on silver-colored tire surface.
The method of existing silver tire surface application of glaze is generally referring to the technique of painted enamel, such as patent document CN104473392 B discloses a kind of manufacturing process of silver-colored painted enamel, after playing the silver-colored tire of wiping, accessory is welded on silver-colored tire, then to addition accessory Silver-colored tire painted, fired.Although the technique overcomes the single defect of silverware color, but to throw away that there are work consumings time-consuming, Higher cost and the problem of cause silverware to be lost.
Summary of the invention
In view of the above-mentioned problems, the present invention provides a kind of technique of silver-colored tire baked wheaten cake glaze, concrete scheme is as follows:
A kind of technique that silver tire burns glaze, comprising the following steps:
S1: it is spare that glaze and water by weight the ratio of 1:1-2.5 are modulated into coating glaze;
S2: the coating glaze that step S1 is modulated is coated in silver-colored tire surface;It is described coating glaze with a thickness of 0.1-2mm;
S3: the coating glaze on silver-colored tire surface is dry, then silver-colored tire is placed in baking furnace and is fired to silver-colored tire surface glaze Melting, then cooling down make the glaze of melting form glaze layer on silver-colored tire surface.
Further, further include step S0 before the step S1: by silver-colored tire removing surface it is clean after, be placed in 500- It over-fires and fires under conditions of 900 DEG C, make silver-colored tire roughing in surface.
Preferably, in the step S0, the time for the firing that over-fires is 3-10min.
Preferably, in the step S2, coating glaze overlays on silver-colored tire surface by spraying, impregnating, brushing or pouring showering.
Preferably, in the step S3, the maximum temperature in baking furnace is controlled within+50 DEG C of glaze melting temperature, And the maximum temperature in baking furnace controls within 850 DEG C.
Ceramic glaze, glass glaze, enamel glaze, cloisonne enamel glaze can be selected in glaze of the invention, due to different glaze Material has different fusing points, and therefore, the temperature in baking furnace is more than+50 DEG C of glaze melting temperature, glaze;More than 850 DEG C, silver-colored tire It is easily-deformable and easy to crack after glaze layer cooling.In general, firing temperature control is between 500-800 DEG C.
It further, further include step S4 after the step S3, coating thickness is the of 0.1-2mm in glaze layer Two coating glaze form pattern, then that the second coating glaze in glaze layer is dry, then are placed in baking furnace and are fired in glaze layer Second coating glaze melting, then cooling down make the second coating glaze of melting form the second glaze layer in glaze layer.
Preferably, in the step S4, the second coating glaze is coated in by spraying, transferring, paint, brush or impregnate In glaze layer.
Preferably, in the step S4, the maximum temperature control in baking furnace is coated with glaze melting temperature+50 second Within DEG C.
Further, it can carry out coating required glaze again in the second glaze layer surface according to the actual needs, repeat The technique of step S4, until completing the production.
Silver tire of the invention burns the technique of glaze by being coated with to silver-colored tire surface comprehensively, makes its surface formation glaze layer, Glaze layer is formed after firing, after through modes such as spraying, transfer, drawing, brushing, drawing or immersions glaze figure is formed in glaze layer Case, then it is fired into required gloss firing silverware.The process is simple, facilitates a variety of colored glazes on silverware to fire, is silverware The new process of industry solves the problems, such as traditional silverware monochrome and oxidizable blackening, have a vast market economic benefit and Artistic value.In addition, the technique that silver-colored tire of the invention burns glaze is fired using excessive fire makes silver-colored tire roughing in surface, coating glaze is promoted While silver-colored tire surface adhesion force, the polishing of silver-colored tire surface silver is avoided to be lost.
Specific embodiment
In order to more fully understand technology contents of the invention, combined with specific embodiments below to technical solution of the present invention into One step introduction and explanation.
Embodiment 1
Will silver-colored tire surface wash by water outwash after dry or naturally dry, under conditions of being subsequently placed in 500-900 DEG C over-fire fire 3-10min makes silver-colored tire roughing in surface.
It is spare that white powder glaze and water by weight the ratio of 1:1-2.5 are modulated into coating glaze.By the painting of modulation Cloth glaze is sprayed on silver-colored tire surface, is coated with the thickness control of glaze in 0.1-2mm.By the coating glaze natural air drying on silver-colored tire surface Or drying, form glaze layer;Then silver-colored tire is placed in baking furnace and is fired to the melting of silver-colored tire surface glaze layer, in baking furnace most High-temperature controls within+50 DEG C of glaze melting temperature, and cooling down makes the glaze of melting form white glaze layer on silver-colored tire surface.
It is spare that red powder glaze and water by weight the ratio of 1:1-2.5 are modulated into the second coating glaze.In white Pattern is formed by the second coating glaze that spraying, transfer, drawing or immersion coating thickness are 0.1-2mm in glaze layer, then will The second coating glaze natural air drying or drying in glaze layer, then be placed in baking furnace and be fired to the second coating glaze in white glaze layer Melting, cooling down make the second coating glaze of melting form red pattern glaze layer in glaze layer, obtain burning glaze silverware.
Embodiment 2
Will silver-colored tire surface wash by water outwash after dry or naturally dry, under conditions of being subsequently placed in 600-700 DEG C over-fire fire 6-8min makes silver-colored tire roughing in surface.
It is spare that white powder glaze and water by weight the ratio of 1:1.5-2 are modulated into coating glaze.By the painting of modulation Cloth glaze is sprayed on silver-colored tire surface, is coated with the thickness control of glaze in 0.5-1mm.By the coating glaze natural air drying on silver-colored tire surface Or drying, form glaze layer;Then silver-colored tire is placed in baking furnace and is fired to the melting of silver-colored tire surface glaze layer, in baking furnace most High-temperature controls within+30 DEG C of glaze melting temperature, and cooling down makes the glaze of melting form white glaze layer on silver-colored tire surface.
It is spare that red powder glaze and water by weight the ratio of 1:1.5-2 are modulated into the second coating glaze.In white Pattern is formed by the second coating glaze that spraying, transfer, drawing or immersion coating thickness are 0.5-1mm in glaze layer, then will The second coating glaze natural air drying or drying in glaze layer, then be placed in baking furnace and be fired to the second coating glaze in white glaze layer Melting, cooling down make the second coating glaze of melting form red pattern glaze layer in glaze layer.
It is spare that blue powder glaze and water by weight the ratio of 1:1.5-2 are modulated into third coating glaze.In red Glaze is coated with by the third that spraying, transfer, drawing or immersion coating thickness are 0.5-1mm on pattern glaze layer and forms pattern, so The third in glaze layer is coated with glaze natural air drying or drying afterwards, then is placed in baking furnace and is fired to third in red pattern glaze layer It is coated with glaze melting, cooling down makes the third coating glaze of melting form blue color patterns glaze layer in red pattern glaze layer, obtains To baked wheaten cake glaze silverware.
Embodiment 3
Will silver-colored bowl surface wash by water outwash after dry or naturally dry, under conditions of being subsequently placed in 600 DEG C excessive fire fire 7min, Make silver pot roughing in surface.
It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into coating glaze.The coating glaze of modulation is sprayed It is coated in silver-colored bowl surface, is coated with the thickness control of glaze in 0.2 ± 0.1mm.By the coating glaze natural air drying of silver-colored bowl surface, formed Glaze layer;Then silver-colored bowl is placed in baking furnace and is fired to silver-colored bowl surface glaze layer melting, the maximum temperature control in baking furnace The firing time of maximum temperature in 590-620 DEG C (590 DEG C of glaze melting temperature), baking furnace is 7min, and cooling down makes The glaze of melting forms transparent glaze layer in silver-colored bowl surface.
It is spare that red powder glaze and water by weight the ratio of 1:2 are modulated into the second coating glaze.In transparent glaze layer It is upper that pattern is formed by the second coating glaze that transfer coating thickness is 0.2 ± 0.1mm, then second in transparent glaze layer is applied Cloth glaze natural air drying, then be placed in baking furnace and be fired to the second coating glaze melting in transparent glaze layer, the highest in baking furnace The firing time of maximum temperature of the temperature control in 550-570 DEG C (second coating 550 DEG C of glaze melting temperature), baking furnace is 8min, cooling down make the second coating glaze of melting form red pattern glaze layer in glaze layer.
It is spare that blue powder glaze and water by weight the ratio of 1:2 are modulated into third coating glaze.In red pattern Glaze is coated with by the third that drawing coating thickness is 0.2 ± 0.1mm in glaze layer and forms pattern, it then will be in red pattern glaze layer Third be coated with glaze natural air drying, then be placed in baking furnace and be fired in red pattern glaze layer third coating glaze melting, burn Maximum temperature of the maximum temperature control in 520-550 DEG C (third is coated with 520 DEG C of glaze melting temperature), baking furnace in furnace processed Firing time be 6min, cooling down make melting third coating glaze blue color patterns glaze is formed in red pattern glaze layer Layer obtains burning glaze silver bowl product.
Embodiment 4
Will silver pot surface wash by water outwash after dry or naturally dry, under conditions of being subsequently placed in 600 DEG C excessive fire fire 5min, Make silver pot roughing in surface.
It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into coating glaze.The coating glaze of modulation is sprayed It is coated in silver pot surface, is coated with the thickness control of glaze in 0.3 ± 0.1mm.By the coating glaze natural air drying on silver pot surface, formed Glaze layer;Then silver pot is placed in baking furnace and is fired to the melting of silver pot surface glaze layer, the maximum temperature control in baking furnace The firing time of maximum temperature in 690-720 DEG C (690 DEG C of glaze melting temperature), baking furnace is 7min, and cooling down makes The glaze of melting forms transparent glaze layer on silver pot surface.
It is spare that red powder glaze and water by weight the ratio of 1:1 are modulated into the second coating glaze.By blue powder It is spare that glaze and water by weight the ratio of 1:1 are modulated into third coating glaze.By yellow powder glaze and water by weight 1:1 Ratio be modulated into the 4th coating glaze it is spare.
Pass through Freehandhand-drawing in transparent glaze layer using the second coating glaze, third coating glaze, the 4th coating glaze of modulation Draw required pattern, transparent glaze layer glazing material with a thickness of 0.3 ± 0.2mm, then by the glaze natural wind in transparent glaze layer It is dry, then be placed in baking furnace and be fired to transparent glaze layer glazing material melting, the maximum temperature in baking furnace is controlled at 630-650 DEG C (the second coating glaze, third coating glaze, the 4th coating glaze melting temperature are between 600-630 DEG C), in baking furnace Maximum temperature firing time be 5min, cooling down make melting glaze pattern glaze layer is formed in glaze layer, burnt Glaze silver pot product.
Embodiment 5
It will be dried after silver-colored bracelet surface bath outwash, excessive fire fires 5min under conditions of being subsequently placed in 550 DEG C, makes silver-colored bracelet surface Roughening.
It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into coating glaze.Silver-colored bracelet is immersed in modulation It is coated in glaze, natural air drying after taking-up, forms glaze layer, the thickness control of glaze layer is in 0.3 ± 0.1mm.Then by silver-colored bracelet It is placed in baking furnace and is fired to the melting of silver-colored bracelet surface glaze layer, (glaze is molten at 650-680 DEG C for the maximum temperature control in baking furnace Melt 650 DEG C of temperature), the firing time of the maximum temperature in baking furnace is 5min, and cooling down makes the glaze of melting in silver-colored bracelet table Face forms white glaze layer.
It is spare that red powder glaze and water by weight the ratio of 1:2 are modulated into red glaze, by blue powder glaze It is spare by weight the ratio modulation au bleu glaze of 1:2 with water, by yellow powder glaze and water by weight the ratio tune of 1:2 It is made that yellow glaze is spare, it is spare that cyan powder glaze and water by weight the ratio of 1:2 are modulated into cyan glaze, will be green It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into green glaze.Using the red glaze of modulation, blue glaze, Yellow glaze, cyan glaze and green glaze form required pattern, white glaze layer by way of transfer in white glaze layer The thickness control of upper glaze then by the pattern glaze natural air drying in white glaze layer, then is placed in baking furnace in 0.2 ± 0.1mm It is inside fired to glaze in white glaze layer to melt, the maximum temperature control in baking furnace is in 630-650 DEG C of (red glaze, blue glaze Material, yellow glaze, the melting temperature of cyan glaze and green glaze are between 600-630 DEG C), the highest temperature in baking furnace The firing time of degree is 5min, and cooling down makes the glaze of melting form pattern glaze layer in glaze layer.
It is spare that powder glaze and water by weight the ratio of 1:1 are modulated into surface layer coating glaze.On silver-colored bracelet silver bracelet surface The surface layer of 0.2 ± 0.1mm of brushing thickness is coated with glaze, and then natural air drying forms surface glaze layer.Then silver-colored bracelet is placed in burning Glaze layer melting in silver-colored bracelet surface is fired in furnace processed, (surface layer is coated with glaze to the maximum temperature control in baking furnace at 600-630 DEG C 600 DEG C of melting temperature), the firing time of the maximum temperature in baking furnace is 5min, and cooling down makes the surface layer coating glaze of melting Material forms transparent glaze layer on silver-colored bracelet surface, obtains burning glaze silver bracelet product.
Embodiment 6
It will be dried after silver-colored pot surface bath outwash, excessive fire fires 5min under conditions of being subsequently placed in 600 DEG C, makes silver-colored pot surface Roughening.
It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into coating glaze, then by the coating glaze of modulation Material is sprayed on silver-colored pot surface, is coated with the thickness control of glaze in 0.2 ± 0.1mm.Again by the coating glaze natural wind on silver-colored tire surface It is dry, glaze layer is formed, silver-colored tire is placed in baking furnace and is fired to the melting of silver-colored tire surface glaze layer, the maximum temperature control in baking furnace The firing time for making the maximum temperature in 590-620 DEG C (590 DEG C of glaze melting temperature), baking furnace is 6min, cooling down So that the glaze of melting is formed transparent glaze layer on silver-colored tire surface, obtains burning glaze silver pot product.
Comparative example 1
It will be dried after silver-colored pot surface bath outwash.
It is spare that powder glaze and water by weight the ratio of 1:2 are modulated into coating glaze, then by the coating glaze of modulation Material is sprayed on silver-colored pot surface, is coated with the thickness control of glaze in 0.2 ± 0.1mm.Again by the coating glaze natural wind on silver-colored pot surface It is dry, form glaze layer;Then silver-colored pot is placed in baking furnace and is fired to the melting of silver-colored pot surface glaze layer, the highest temperature in baking furnace The firing time of maximum temperature of the degree control in 590-620 DEG C (590 DEG C of glaze melting temperature), baking furnace is 6min, cooling The cooling glaze for making melting forms transparent glaze layer on silver-colored pot surface, obtains burning glaze silver pot product.
Embodiment 6
The baked wheaten cake glaze silver pot product surface glazed thickness of preparation is equal, flawless.Before 1 silver medal pot surface of comparative example sprays glaze It is made without burning, silver-colored pot surface glaze is unevenly distributed after spraying, the uneven thickness of glaze layer after firing, and the position thicker in glaze layer Set that there are crackles.
It is described above that technology contents of the invention are only further illustrated with embodiment, in order to which reader is easier to understand, But embodiments of the present invention are not represented and are only limitted to this, any technology done according to the present invention extends or recreation, is sent out by this Bright protection.

Claims (4)

1. it is a kind of silver tire burn glaze technique, which is characterized in that the technique successively the following steps are included:
S0: by silver-colored tire removing surface it is clean after, over-fire and fire under conditions of being placed in 500-900 DEG C, time of the firing that over-fires is 3- 10min;
S1: it is spare that glaze and water by weight the ratio of 1:1-2.5 are modulated into coating glaze;
S2: the coating glaze that step S1 is modulated is coated in the silver-colored tire surface after step S0 excessive fire is fired;The coating glaze With a thickness of 0.1-2mm;
S3: the coating glaze on silver-colored tire surface is dry, then silver-colored tire is placed in baking furnace and is fired to the melting of silver-colored tire surface glaze, Cooling down makes the glaze of melting form glaze layer on silver-colored tire surface again;Maximum temperature in the baking furnace is controlled in glaze fusing point Within+50 DEG C of temperature;
S4: the second coating glaze that coating thickness is 0.1-2mm in glaze layer forms pattern, then by the second coating in glaze layer Glaze is dry, then is placed in baking furnace and is fired to the second coating glaze melting in glaze layer, then cooling down makes the second of melting to apply Cloth glaze forms the second glaze layer in glaze layer;In the baking furnace maximum temperature control second be coated with glaze melting temperature+ Within 50 DEG C.
2. the technique that silver-colored tire burns glaze according to claim 1, which is characterized in that in the step S2, coating glaze is logical It crosses and sprays, impregnates, brushes or pour showering and overlay on silver-colored tire surface.
3. the technique that silver-colored tire burns glaze according to claim 2, which is characterized in that in the step S3, in baking furnace Maximum temperature controls within 850 DEG C.
4. the technique that silver-colored tire burns glaze according to claim 1, which is characterized in that in the step S4, the second coating glaze Material is by spraying, transferring, paint, brush or impregnate coated in glaze layer.
CN201611168611.2A 2016-12-16 2016-12-16 A kind of technique that silver tire burns glaze Active CN106835136B (en)

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Publication number Priority date Publication date Assignee Title
CN112355278A (en) * 2020-10-22 2021-02-12 江西桐青金属工艺品股份有限公司 Manufacturing process of thin-blank enamel sculpture product
CN114228377A (en) * 2021-12-07 2022-03-25 深圳市七彩珐琅科技有限公司 Metal product enamel process

Citations (6)

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Publication number Priority date Publication date Assignee Title
JPS57126970A (en) * 1981-01-31 1982-08-06 Kazuyoshi Fujimori Preparation of solder silver cloisonne ware
KR20040076622A (en) * 2003-02-26 2004-09-01 시리트베르케게엠바하운트콤파니카게 Use of a composite material in the case of a cooking vessel and a method for manufacturing a composite material
CN102173271A (en) * 2011-01-27 2011-09-07 山西银满楼景泰蓝银器制品有限公司 Process of manufacturing cloisonne silverware
CN104473392A (en) * 2014-11-19 2015-04-01 吕雪峰 Manufacturing process of silver-body painted enamel
CN105063409A (en) * 2015-08-17 2015-11-18 广州番禺职业技术学院 Silver alloy and method for preparing high-temperature transparent enamel decorating silver jewelry by using silver alloy
CN105082861A (en) * 2014-05-22 2015-11-25 过鹏儒 Novel silver blank enamel manufacturing process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57126970A (en) * 1981-01-31 1982-08-06 Kazuyoshi Fujimori Preparation of solder silver cloisonne ware
KR20040076622A (en) * 2003-02-26 2004-09-01 시리트베르케게엠바하운트콤파니카게 Use of a composite material in the case of a cooking vessel and a method for manufacturing a composite material
CN102173271A (en) * 2011-01-27 2011-09-07 山西银满楼景泰蓝银器制品有限公司 Process of manufacturing cloisonne silverware
CN105082861A (en) * 2014-05-22 2015-11-25 过鹏儒 Novel silver blank enamel manufacturing process
CN104473392A (en) * 2014-11-19 2015-04-01 吕雪峰 Manufacturing process of silver-body painted enamel
CN105063409A (en) * 2015-08-17 2015-11-18 广州番禺职业技术学院 Silver alloy and method for preparing high-temperature transparent enamel decorating silver jewelry by using silver alloy

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