CN106832781A - 新型纳米高阻燃固性树脂基复合材料 - Google Patents

新型纳米高阻燃固性树脂基复合材料 Download PDF

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Publication number
CN106832781A
CN106832781A CN201710086682.6A CN201710086682A CN106832781A CN 106832781 A CN106832781 A CN 106832781A CN 201710086682 A CN201710086682 A CN 201710086682A CN 106832781 A CN106832781 A CN 106832781A
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Prior art keywords
fire
thermosetting resin
retardance
based composites
resin based
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CN201710086682.6A
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朱爱民
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Nantong Su Chemical Fiber Co Ltd
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Nantong Su Chemical Fiber Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

本发明提供了一种新型纳米高阻燃固性树脂基复合材料，所述的复合材料通过如下方法制成：将原料依配比，按顺序混合，加热回流，搅拌使其混合充分制得，所述的原料包括环氧树脂、阻燃剂、固化剂、固化促进剂和溶剂，所述的阻燃剂选自纳米氢氧化铝和纳米蒙脱土；所述的固化剂选自双氰胺；所述的促进剂选自2‑甲基咪唑或甲基甲酰胺；所述的溶剂选自丙酮。本发明的新型纳米高阻燃固性树脂基复合材料是一种性能优良的阻燃固性树脂材料，具有良好的阻燃性能。

Description

新型纳米高阻燃固性树脂基复合材料
技术领域
本发明涉及一种新型纳米高阻燃固性树脂基复合材料，属于化工材料技术领域。
背景技术
阻燃固性树脂是指经过技术处理后能阻止或减缓燃烧速度的树脂。多数聚合物树脂都是遇火易燃物质，阻燃树脂可大大降低其易燃性，并使其着火后可自行熄灭，从而抑制火焰蔓延、减轻燃烧产生的烟或有毒气体的危害。阻燃技术处理常添加阻燃剂或添加无机填料，如碳酸钙、硅酸盐、云母等，也可与阻燃性好的单体(如氯乙烯)进行共聚、接枝，与高难燃树脂共混等。以难燃树脂制备的塑料制品、涂料、胶粘剂等在建筑、交通工具、电子电器、日用家具等领域的应用日趋广泛。
国内在阻燃固性树脂研究方面历史较短, 材料研究基本上处于探索阶段。
发明内容
本发明的目的是克服现有技术的不足之处，提供一种新型纳米高阻燃固性树脂基复合材料。
本发明的新型纳米高阻燃固性树脂基复合材料，所述的复合材料通过如下方法制成：将原料依配比，按顺序混合，加热回流，搅拌使其混合充分制得，
所述的原料包括环氧树脂、阻燃剂、固化剂、固化促进剂和溶剂，
所述的阻燃剂选自纳米氢氧化铝和纳米蒙脱土；
所述的固化剂选自双氰胺；
所述的促进剂选自2-甲基咪唑或甲基甲酰胺；
所述的溶剂选自丙酮。
本发明的新型纳米高阻燃固性树脂基复合材料是一种性能优良的阻燃固性树脂材料，具有良好的阻燃性能。
具体实施方式
实施例1
本发明的新型纳米高阻燃固性树脂基复合材料，所述的复合材料通过如下方法制成：将原料依配比，按顺序混合，加热回流，搅拌使其混合充分制得，
所述的原料包括环氧树脂、阻燃剂、固化剂、固化促进剂和溶剂，
所述的阻燃剂选自纳米氢氧化铝和纳米蒙脱土；
所述的固化剂选自双氰胺；
所述的促进剂选自2-甲基咪唑或甲基甲酰胺；
所述的溶剂选自丙酮。

Claims (1)

1.新型纳米高阻燃固性树脂基复合材料，其特征在于，所述的复合材料通过如下方法制成：将原料依配比，按顺序混合，加热回流，搅拌使其混合充分制得，
所述的原料包括环氧树脂、阻燃剂、固化剂、固化促进剂和溶剂，
所述的阻燃剂选自纳米氢氧化铝和纳米蒙脱土；
所述的固化剂选自双氰胺；
所述的促进剂选自2-甲基咪唑或甲基甲酰胺；
所述的溶剂选自丙酮。
CN201710086682.6A 2017-02-17 2017-02-17 新型纳米高阻燃固性树脂基复合材料 Pending CN106832781A (zh)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1548473A (zh) * 2003-05-09 2004-11-24 广州宏仁电子工业有限公司 一种胶液、使用该胶液的无卤阻燃覆铜箔基板及其制作方法
CN102731969A (zh) * 2012-06-18 2012-10-17 航天材料及工艺研究所 一种阻燃环氧预浸料复合材料及其制备方法和用途
CN103435973A (zh) * 2013-09-06 2013-12-11 苏州生益科技有限公司 一种无卤环氧树脂组合物及使用其制作的半固化片及层压板
CN105504694A (zh) * 2015-12-30 2016-04-20 青岛宇星智能科技开发有限公司 一种高强度阻燃纳米复合材料
CN105754295A (zh) * 2016-03-21 2016-07-13 北京中新泰合电子材料科技有限公司 一种绿色环保型环氧树脂组合物及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1548473A (zh) * 2003-05-09 2004-11-24 广州宏仁电子工业有限公司 一种胶液、使用该胶液的无卤阻燃覆铜箔基板及其制作方法
CN102731969A (zh) * 2012-06-18 2012-10-17 航天材料及工艺研究所 一种阻燃环氧预浸料复合材料及其制备方法和用途
CN103435973A (zh) * 2013-09-06 2013-12-11 苏州生益科技有限公司 一种无卤环氧树脂组合物及使用其制作的半固化片及层压板
CN105504694A (zh) * 2015-12-30 2016-04-20 青岛宇星智能科技开发有限公司 一种高强度阻燃纳米复合材料
CN105754295A (zh) * 2016-03-21 2016-07-13 北京中新泰合电子材料科技有限公司 一种绿色环保型环氧树脂组合物及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中华人民共和国公安部消防局编: "《中国消防手册》", 30 December 2017 *

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Application publication date: 20170613