CN106810937A - A kind of aqueous highlighted environment-friendly type tempering glass ink and preparation method thereof - Google Patents
A kind of aqueous highlighted environment-friendly type tempering glass ink and preparation method thereof Download PDFInfo
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- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
The invention belongs to aqueous highlighted environment-friendly type tempering glass ink of one kind and preparation method thereof, the safety glass ink is made up of the raw material of following portions by weight：8 30 parts of inorganic pigment, 30 78 parts of low melting point frit, 10 55 parts of varnish, 02 parts of wetting dispersing agent, 01 parts of defoamer, 02 parts of levelling agent, 02 parts of solid additive.The glass ink fusing point is low, good weatherability, and good brightness has appreciation very high.Wherein, low melting point frit glass melting temperature is relatively low, power saving, can effective extension device service life, and oxide volatilization is less.Wherein, low melting point frit does not contain Pb, Cr6+, Cd and Bi, this can effectively reduce the cost of ink and not contain harmful Pb, Cd and Cr6+.Te elements are introduced in low melting point frit, Te can reduce the glass melting temperature of frit, effectively reduce the low temperature viscosity of frit, and glass is had very strong covering power and anti-uv ability.
Description
Technical field
The invention belongs to chemical industry ink area, and in particular to a kind of aqueous highlighted environment-friendly type tempering glass ink and its preparation
Method.
Background technology
It is well known that glass tempering ink will have a sintering temperature and low, good weatherability, outstanding covering power and good
The performance such as visual effect.But traditional tempering ink contains lead and cadmium, or add great amount of cost bismuth oxide higher.
Oxide is founded needs and is carried out more than 1200 DEG C in traditional frit, and glass melting temperature high needs to expend more electric energy, to molten
System is also larger with equipment damage, and its service life is greatly reduced.Under high temperature, oxide larger, many oxide vapors of volatilization
Poisonous, this body to operator also has larger infringement.The present invention is founded using 800 DEG C -1000 DEG C, and the technique is more low
Carbocyclic ring is protected.
It is dimethylbenzene that traditional safety glass ink uses varnish, and cyclohexanone, isophorone dissolving resin is obtained, this tune
Black oil contains substantial amounts of toxic volatile solvent, and this is larger to people and surrounding environment infringement.The present invention is using environmentally friendly
Aqueous varnish.
The content of the invention
It is an object of the invention to provide a kind of fusing point is low, the aqueous highlighted environment-friendly type safety glass of good weatherability, good brightness
Ink and preparation method thereof.
To achieve the above object, the technical solution adopted by the present invention is, a kind of aqueous highlighted environment-friendly type tempering glass ink,
It is made up of the raw material of following portions by weight：Inorganic pigment 8-30 parts, 30-78 parts of low melting point frit, varnish 10-55 parts, wetting
Dispersant 0-2 parts, defoamer 0-1 parts, levelling agent 0-2 parts, solid additive 0-2 parts.
The inorganic pigment is copper-chrome black（Hunan Ju Fa Science and Technology Ltd.s, B2856, A2854）, siderochrome palm fibre（Hunan is huge
Hair Science and Technology Ltd., A2901）, titanium yellow（Fu Lu new materials company 10401）, titanium chrome yellow（Fu Lu new materials company V-
9118,10408,10415）, cobalt titanium is green（Fu Lu new materials company V-11633,21-4045PK）In any one or several.
The low melting point frit is by following weight percentage into being grouped into：SiO2 22%-50%、B2O3 0%-10%、TeO2
0.05%-15%、Al2O3 1%-8%、 (Na2O+K2O) 10%-19%、(CaO+MgO+BaO) 12%、Li2O 0.1%-5.1%、TiO2
0%-5%、F 0%-3%、P2O50%-5%, Sb2O30%-2%, ZrO20%-2%, NiO 0%-2%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：The watersoluble modified thermosetting acrylic resins of 10%-30%
Joncryl®678（BASF）, 15%-50% hydroxyethyl celluloses HBR250（Ya Shilan）, 10%-20% ethanol, 5%-20% butanol,
Balance of water.
Preferably, the solid additive is P2O5。
Preferably, the wetting dispersing agent is NUOSPERSE®FA182（This moral of hamming is modest）、NUOSPERSE®FA620
（This moral of hamming is modest）、Disponer W-920（This moral of hamming is modest）、NUOSPERSE®FX365（This moral of hamming is modest）、
Disponer W-18（This moral of hamming is modest）、KEPERDISP®-6090（Gold group chemicals）、KEPERDISP®-6091（Golden dough
Product）In any one or several.
Preferably, the defoamer is organic silicon emulsion Dow Corning®163 Additive（This moral of hamming is modest）、
Dow Corning®62 Additive（This moral of hamming is modest）, mineral oil and wax mixture DAPRO®AP7010（Hamming this moral
It is modest）, mineral oil amide polymer KEPERPOL®-367（Gold group chemicals）、KEPERPOL®-3134W（Gold group chemicals）In
Any one or several.
Preferably, the levelling agent is the moon/nonionic surfactant DAPRO®U-99（This moral of hamming is modest）, it is modified poly-
Siloxanes Levaslip W-461（This moral of hamming is modest）, acrylic copolymer KEPERSURF®-381（Gold group chemicals）, low point
The mixture KEPERSURF of sub- weight polymers®-388（Gold group chemicals）In one or more.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, in 100r/min-600r/min at 800 DEG C -1000 DEG C
Lower ball milling 1h-24h, dries 2h-24h at 50 DEG C -110 DEG C, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 1h-6h under 600r/min-1500r/min with mechanical agitator, must adjusted
Black oil；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer, three rollers of levelling agent and solid additive
Milling train is uniformly dispersed and obtains final product the aqueous highlighted environment-friendly type tempering glass ink.
When using, by aqueous highlighted environment-friendly type tempering glass ink silk-screen or glass surface is sprayed at（Electrical equipment glass, touches
Panel glass, engineering glass and family's glaze etc.）, 680 DEG C of -720 DEG C of sintering（Tempering）, sintering time determines by thickness of glass
(40s/mm)。
Environmentally friendly tempering ink fusing point of the present invention is low, and good weatherability, good brightness has appreciation very high.Its
In, low melting point frit glass melting temperature is relatively low, power saving, can effective extension device service life, and oxide volatilization is less.Wherein,
Low melting point frit does not contain Pb, Cr6+, Cd and Bi, this can effectively reduce the cost of ink and not contain harmful Pb, Cd and Cr6 +.Te elements are introduced in low melting point frit, Te can reduce the glass melting temperature of frit, effectively reduce the low temperature viscosity of frit, contained
The glass for having Te has very strong covering power and anti-uv ability.The frit that environment-friendly type tempering glass ink of the present invention is used for
Low bismuth, it is unleaded, without cadmium, environmental protection and cost is relatively low.Wherein, varnish is aqueous varnish, using only a small amount of environmentally friendly
Organic solvent ethanol and butanol, it is main using water as solvent, this substantially reduces toxic solvent during ink sintering and drying
Volatilization.
The present invention is aqueous highlighted safety glass ink, and selected resin is aqueous, can directly use water cleaning means, section
Can environmental protection.Solid additive is P in the present invention2O5, it plays fluxing action in ink.Frit and frit, frit and inorganic face
If there is gap between material, at high temperature sintering time section, their boundaries connection existing defects, this causes glass ink steel
Dumb light after change.Addition cosolvent P proposed by the invention2O5, this was also not involved with former patent.P2O5Addition can
Effectively to play facilitation to link between particle.Its mechanism of action is as follows：
.Na in glass is readily formed Na in atmosphere2CO3, this is to glass
The melting of glass frit is harmful, and the sodium phosphate for generating can be dissolved in glass frit, and this effectively improves frit boundary
Defect, so as to lift the glossiness of ink after tempering.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
Apply the content described by case and be merely to illustrate the present invention, without should also without limitation on described in detail in claims
The present invention.
Embodiment 1
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
25 parts of material, 50 parts of low melting point frit, 23 parts of varnish, 0.5 part of wetting dispersing agent, 0.5 part of defoamer, 1 part of solid additive.Institute
Solid additive is stated for P2O5。
The inorganic pigment is copper-chrome black（Hunan Ju Fa Science and Technology Ltd.s, B2856）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 35.2%、B2O3 3.2%、TeO2 3%、
Al2O3 1%、Na2O 14.2%、K2O 2.1%、CaO 3.8%、3.6%、Li2O 1.1%、TiO2 0.5%、F 3%、Sb2O3 1%、
ZrO2 0.3%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：25% watersoluble modified thermosetting acrylic resin
Joncryl®678（BASF）, 25% hydroxyethyl cellulose HBR250（Ya Shilan）, 14.6% ethanol, 8% butanol, balance of water.
The wetting dispersing agent is NUOSPERSE®FA182（This moral of hamming is modest）.
The defoamer is Dow Corning®62 Additive（This moral of hamming is modest）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting 0.5h, water quenching, with planetary ball mill in 400r/ at 950 DEG C
Ball milling 6h under min, dries 8h at 95 DEG C, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 4h under 1000r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer and solid additive three-high mill point
Dissipate and uniformly obtain final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 106（Gu）.
Embodiment 2
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
25 parts of material, 50 parts of low melting point frit, 23.2 parts of varnish, 0.5 part of wetting dispersing agent, 0.5 part of defoamer, levelling agent 0.05-2
Part, 0.8 part of solid additive.The solid additive is P2O5。
The inorganic pigment is siderochrome palm fibre（Hunan Ju Fa Science and Technology Ltd.s, A2901）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 42.3%、B2O3 6.2%、TeO2 1%、
Al2O3 1%、Na2O 10.2%、K2O 2.1%、CaO 3.8%、BaO 3.7%、Li2O 2.3%、TiO2 0.5%、F 1.8%、P2O5
0.2%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：10% watersoluble modified thermosetting acrylic resin
Joncryl®678（BASF）, 30% aqueous hydroxyethyl cellulose HBR250（Ya Shilan）, 10% ethanol, 5% butanol, it is balance of
Water.
The wetting dispersing agent is KEPERDISP®-6091（Gold group chemicals）.
The defoamer is mineral oil amide polymer KEPERPOL®-367（Gold group chemicals）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, the ball milling 12h under 400r/min, at 70 DEG C at 900 DEG C
Under dry 12h, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 2h under 900r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer and solid additive three-high mill point
Dissipate and uniformly obtain final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 113（Gu）.
Embodiment 3
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
25 parts of material, 50 parts of low melting point frit, 23 parts of varnish, 0.5 part of wetting dispersing agent, 0.5 part of defoamer, 1 part of solid additive.Institute
Solid additive is stated for P2O5。
The inorganic pigment is titanium yellow（Fu Lu new materials company 10401）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 32.2%、B2O3 8.2%、TeO2
0.08%、Al2O3 3.5%、Na2O 12.6%、K2O 2.1%、CaO 3.8%、BaO 7.2%、Li2O 2.3%、TiO2 0.8%、F 3%、
NiO 0.6%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：15% watersoluble modified thermosetting acrylic resin Joncryl®678（BASF）, 25% aqueous hydroxyethyl cellulose HBR250（Ya Shilan）, 15% ethanol, 10% butanol, balance of water.
The wetting dispersing agent is NUOSPERSE®FA182（This moral of hamming is modest）.
The defoamer is mineral oil amide polymer KEPERPOL®-367（Gold group chemicals）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, the ball milling 1h under 600r/min, at 50 DEG C at 800 DEG C
24h is dried, that is, obtains described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 6h under 600r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer and solid additive three-high mill point
Dissipate and uniformly obtain final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 115（Gu）.
Embodiment 4
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
25 parts of material, 50 parts of low melting point frit, 22.9 parts of varnish, 0.5 part of wetting dispersing agent, 0.5 part of defoamer are 0.5 part of levelling agent, solid
1.1 parts of body additives.The solid additive is P2O5。
The inorganic pigment is titanium chrome yellow（Fu Lu new materials company V-9118,10408,10415）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 48%、TeO2 3.2%、Al2O3 1%、
Na2O 17.2、K2O 1.4%、MgO 1.3%、Li2O 1.1%、TiO2 0.5%、F 2.7%、Sb2O3 0.8%, ZrO2 0.6%, surplus
It is ZnO.
The varnish is by following weight percentage into being grouped into：10% watersoluble modified thermosetting acrylic resin Joncryl®678（BASF）, 50% aqueous hydroxyethyl cellulose HBR250（Ya Shilan）, 10% ethanol, 5% butanol, balance of water.
The wetting dispersing agent is NUOSPERSE®FA620（This moral of hamming is modest）.
The defoamer is organic silicon emulsion Dow Corning®163 Additive（This moral of hamming is modest）.
The levelling agent is modified polyorganosiloxane Levaslip W-461（This moral of hamming is modest）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, the ball milling 1h under 600r/min, at 110 DEG C at 1000 DEG C
Under dry 2h, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 1h under 1500r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer, three rollers of levelling agent and solid additive
Milling train is uniformly dispersed and obtains final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 115（Gu）.
Embodiment 5
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
8 parts of material, 30 parts of low melting point frit, 10 parts of varnish, 0.5 part of wetting dispersing agent, 0.5 part of defoamer, 1 part of solid additive.Institute
Solid additive is stated for P2O5。
The inorganic pigment is that cobalt titanium is green（Fu Lu new materials company V-11633）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 32.2%、B2O3 3.2%、TeO2 5%、
Al2O3 1%、Na2O 15.2%、K2O 2.1%、CaO 3.8%、MgO 2%、BaO 2.6%、Li2O 5.1%、TiO2 0.5%、ZrO2
0.3%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：15% watersoluble modified thermosetting acrylic resin Joncryl®678（BASF）, 20% aqueous hydroxyethyl cellulose HBR250（Ya Shilan）, 15% ethanol, 10% butanol, balance of water.
The wetting dispersing agent is KEPERDISP®-6091（Gold group chemicals）.
The defoamer is mineral oil and wax mixture DAPRO®AP7010（This moral of hamming is modest）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, the ball milling 2h under 600r/min, at 80 DEG C at 1000 DEG C
Under dry 8h, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 3h under 900r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer and solid additive three-high mill point
Dissipate and uniformly obtain final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 113（Gu）.
Embodiment 6
A kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：Inorganic face
30 parts of material, 78 parts of low melting point frit, 55 parts of varnish, 2 parts of wetting dispersing agent, 0.05 part, solid additive 0-2 parts of defoamer.
The solid additive is P2O5。
The inorganic pigment is copper-chrome black（Hunan Ju Fa Science and Technology Ltd.s, B2856）.
The low melting point frit is by following weight percentage into being grouped into：SiO2 36.4%、B2O3 8.9%、TeO2
9.8%、Al2O3 1%、Na2O 14.2%、CaO 3.8%、BaO 1.9%、Li2O 5.1%、TiO2 0.5%、F 0.1%、Sb2O3
0.5%、ZrO2 0.3%, balance of ZnO.
The varnish is by following weight percentage into being grouped into：12% watersoluble modified thermosetting acrylic resin Joncryl®678（BASF）, 15% aqueous hydroxyethyl cellulose HBR250（Ya Shilan）, 18% ethanol, 10% butanol, balance of water.
The wetting dispersing agent is NUOSPERSE®FX365（This moral of hamming is modest）.
The defoamer is organic silicon emulsion Dow Corning®163 Additive（This moral of hamming is modest）.
The preparation method of described aqueous highlighted environment-friendly type tempering glass ink, comprises the following steps：
1）The raw material of low melting point frit is mixed, and in melting, water quenching, the ball milling 12h under 400r/min, at 70 DEG C at 900 DEG C
Under dry 8h, that is, obtain described low melting point frit；
2）The raw material of varnish is mixed, divides equally dispersion 3h under 800r/min with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer and solid additive three-high mill point
Dissipate and uniformly obtain final product the aqueous highlighted environment-friendly type tempering glass ink.
By aqueous highlighted environment-friendly type tempering glass ink silk-screen printing manufactured in the present embodiment into pattern, 690 DEG C of sintering
200 s, test gloss value is 108（Gu）.
Claims (9)
1. a kind of aqueous highlighted environment-friendly type tempering glass ink, it is characterised in that be made up of the raw material of following portions by weight：It is inorganic
Pigment 8-30 parts, 30-78 parts of low melting point frit, varnish 10-55 parts, wetting dispersing agent 0-2 parts, defoamer 0-1 parts, levelling agent
0-2 parts, solid additive 0-2 parts.
2. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the inorganic pigment is copper
Any one or several during chrome black, siderochrome palm fibre, titanium yellow, titanium chrome yellow, cobalt titanium are green.
3. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the low melting point frit
By following weight percentage into being grouped into：SiO2 22%-50%、B2O3 0%-10%、TeO2 0.05%-15%、Al2O3 1%-8%、
(Na2O+K2O) 10%-19%、(CaO+MgO+BaO) 0%-12%、Li2O 0.1%-5.1%、TiO2 0%-5%、F 0%-3%、P2O5
0%-5%, Sb2O30%-2%, ZrO20%-2%, NiO 0%-2%, balance of ZnO.
4. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the varnish is by following
Percentage by weight into being grouped into：The watersoluble modified thermosetting acrylic resin Joncryl of 10%-30%®678th, 15%-50% ethoxys
Cellulose, 10%-20% ethanol, 5%-20% butanol, balance of water.
5. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the solid additive is
P2O5。
6. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the wetting dispersing agent is
NUOSPERSE®FA182、NUOSPERSE®FA620、Disponer W-920、NUOSPERSE®FX365、Disponer W-18、
KEPERDISP®-6090、KEPERDISP®Any one or several in -6091.
7. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the defoamer is organic
Silicon emulsion Dow Corning®163 Additive、Dow Corning®62 Additive, mineral oil and wax mixture DAPRO®
AP7010, mineral oil amide polymer KEPERPOL®- 367, any one or several in KEPERPOL -3134W.
8. aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that the levelling agent is surface
Activating agent DAPRO®U-99, modified polyorganosiloxane Levaslip W-461, acrylic copolymer KEPERSURF®- 381, low molecule
The mixture KEPERSURF of weight polymers®In -388 any one or several.
9. the preparation method of aqueous highlighted environment-friendly type tempering glass ink as claimed in claim 1, it is characterised in that including with
Lower step：
1）The raw material of low melting point frit is mixed, and in being melted at 800 DEG C -1000 DEG C, water quenching, ball milling 1h-24h, 50 DEG C -
2h-24h is dried at 110 DEG C, that is, obtains described low melting point frit；
2）The raw material of varnish is mixed, dispersion is divided equally with mechanical agitator；
3）By inorganic pigment, low melting point frit, varnish, wetting dispersing agent, defoamer, three rollers of levelling agent and solid additive
Milling train is uniformly dispersed and obtains final product the aqueous highlighted environment-friendly type tempering glass ink.
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| CN201710024446.1A CN106810937B (en) | 2017-01-13 | 2017-01-13 | Water-based high-brightness environment-friendly tempered glass ink and preparation method thereof |
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| CN201710024446.1A CN106810937B (en) | 2017-01-13 | 2017-01-13 | Water-based high-brightness environment-friendly tempered glass ink and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964275A (en) * | 2017-12-19 | 2018-04-27 | 淄博欧泊陶瓷玻璃科技有限公司 | Tempered glass aqueous, environmental protective varnish |
| CN108467625A (en) * | 2018-01-31 | 2018-08-31 | 醴陵市精陶瓷业有限公司 | Marble paper inorganic pigment and preparation method thereof and marble paper and its preparation process |
| CN109651888A (en) * | 2018-12-25 | 2019-04-19 | 广东南亮艺术玻璃科技股份有限公司 | A kind of glass ink-jet printing ink and preparation method thereof |
| CN109817760A (en) * | 2018-12-27 | 2019-05-28 | 江苏林洋光伏科技有限公司 | A kind of preparation method and high reflection back-panel glass of high reflection back-panel glass |
| CN110283481A (en) * | 2019-07-19 | 2019-09-27 | 广州歌林尔新材料有限公司 | A kind of inorganic coating, substrate and preparation method thereof |
| CN110330836A (en) * | 2019-07-24 | 2019-10-15 | 芜湖职业技术学院 | A kind of ink and preparation method thereof for tempered glass |
| CN114014545A (en) * | 2021-12-15 | 2022-02-08 | 安徽工程大学 | Water-based glaze as well as preparation method and application thereof |
| CN116478571A (en) * | 2023-04-26 | 2023-07-25 | 佛山市高明绿色德化工有限公司 | High-temperature UV-LED imprinting ink for glass surface and preparation method thereof |
| CN118256113A (en) * | 2024-03-25 | 2024-06-28 | 江苏日御光伏新材料股份有限公司 | Marking slurry for solar cell and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104403419A (en) * | 2014-12-04 | 2015-03-11 | 河北省沙河玻璃技术研究院 | Glass ink for ink-jet printing and preparation method of glass ink |
| CN104973785A (en) * | 2014-04-03 | 2015-10-14 | 博思株式会社 | Glass Frit Using Glass Powder With Low Melting Point And Crystalline Ceramic Filler With Low Expansion And Paste Comprising The Same |
-
2017
- 2017-01-13 CN CN201710024446.1A patent/CN106810937B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104973785A (en) * | 2014-04-03 | 2015-10-14 | 博思株式会社 | Glass Frit Using Glass Powder With Low Melting Point And Crystalline Ceramic Filler With Low Expansion And Paste Comprising The Same |
| CN104403419A (en) * | 2014-12-04 | 2015-03-11 | 河北省沙河玻璃技术研究院 | Glass ink for ink-jet printing and preparation method of glass ink |
Non-Patent Citations (1)
| Title |
|---|
| 江伟辉等: "烧成制度与化学组成对分相-析晶乳浊釉的釉面性状的影响", 《中国陶瓷工业》 * |
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| CN107964275A (en) * | 2017-12-19 | 2018-04-27 | 淄博欧泊陶瓷玻璃科技有限公司 | Tempered glass aqueous, environmental protective varnish |
| CN108467625A (en) * | 2018-01-31 | 2018-08-31 | 醴陵市精陶瓷业有限公司 | Marble paper inorganic pigment and preparation method thereof and marble paper and its preparation process |
| CN109651888A (en) * | 2018-12-25 | 2019-04-19 | 广东南亮艺术玻璃科技股份有限公司 | A kind of glass ink-jet printing ink and preparation method thereof |
| CN109817760A (en) * | 2018-12-27 | 2019-05-28 | 江苏林洋光伏科技有限公司 | A kind of preparation method and high reflection back-panel glass of high reflection back-panel glass |
| CN110283481A (en) * | 2019-07-19 | 2019-09-27 | 广州歌林尔新材料有限公司 | A kind of inorganic coating, substrate and preparation method thereof |
| CN110330836A (en) * | 2019-07-24 | 2019-10-15 | 芜湖职业技术学院 | A kind of ink and preparation method thereof for tempered glass |
| CN114014545A (en) * | 2021-12-15 | 2022-02-08 | 安徽工程大学 | Water-based glaze as well as preparation method and application thereof |
| CN114014545B (en) * | 2021-12-15 | 2023-11-07 | 安徽工程大学 | Water-based glaze as well as preparation method and application thereof |
| CN116478571A (en) * | 2023-04-26 | 2023-07-25 | 佛山市高明绿色德化工有限公司 | High-temperature UV-LED imprinting ink for glass surface and preparation method thereof |
| CN118256113A (en) * | 2024-03-25 | 2024-06-28 | 江苏日御光伏新材料股份有限公司 | Marking slurry for solar cell and application thereof |
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