CN107459868A - A kind of automobile glass printing ink of acid and alkali-resistance and preparation method thereof - Google Patents

A kind of automobile glass printing ink of acid and alkali-resistance and preparation method thereof Download PDF

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Publication number
CN107459868A
CN107459868A CN201710882596.6A CN201710882596A CN107459868A CN 107459868 A CN107459868 A CN 107459868A CN 201710882596 A CN201710882596 A CN 201710882596A CN 107459868 A CN107459868 A CN 107459868A
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Prior art keywords
parts
acid
printing ink
alkali
glass
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CN201710882596.6A
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Chinese (zh)
Inventor
王斌
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JURONG CITY HOUBAI TOWN YINGRUI PRINT WORKS
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JURONG CITY HOUBAI TOWN YINGRUI PRINT WORKS
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Priority to CN201710882596.6A priority Critical patent/CN107459868A/en
Publication of CN107459868A publication Critical patent/CN107459868A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Glass Compositions (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention provides a kind of automobile glass printing ink of acid and alkali-resistance, raw material includes：Epoxy resin, acrylic resin, amino resins, Ludox, glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent, thickener.Its preparation method is first to take to be placed in high temperature furnace after glass dust raw material mixed grinding to heat, and by the glass metal cast molding of melting and is annealed after insulation, i.e., the grinding of gained both bulk glasses is obtained into glass dust；Epoxy resin, acrylic resin, amino resins and Ludox are added in solvent again, obtain varnish；Finally gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added in gained varnish, grinding, produced.The present invention coordinates epoxy resin, acrylic resin and amino resins that automobile glass printing ink is made using glass powder with low melting point, has good acid-proof alkaline.

Description

A kind of automobile glass printing ink of acid and alkali-resistance and preparation method thereof
Technical field
The present invention relates to automobile glass printing ink technical field, and in particular to the automobile glass printing ink and its system of a kind of acid and alkali-resistance Preparation Method.
Background technology
Automobile glass printing ink is a kind of black glass for being printed on windshield edge or whole windscreen surface Slurry, scattered mill mainly is mixed by the auxiliary agent such as glass powder with low melting point, inorganic pigment, varnish and dispersant, levelling agent and formed. Ink is printed on printing glass substrate by silk-screen printing, by drying and sintering, the other compositions in ink are waved substantially Hair decomposition finishes, and glass powder with low melting point and inorganic pigment melt and covered the glass layer of ink for forming black on the windshield, rise Chemical change, masking conductive silver paste, decoration automobile appearance occurs to the glue for preventing from bonding windshield and car body and absorbs purple The effect of outside line.
With the fast development of automobile industry, there is the very big demand to automobile glass printing ink, driven vehicle glass The research and innovation of ink.However, the preparation and its performance to automobile glass printing ink domestic at present lacks systematic research data, The problem of automobile glass printing ink of production exposes resistance to acids and bases deficiency mostly, and resistance to bond is bad.
The content of the invention
It is an object of the invention to provide a kind of automobile glass printing ink of acid and alkali-resistance and preparation method thereof.
A kind of automobile glass printing ink of acid and alkali-resistance, raw material include in parts by weight：Epoxy resin 20-30 parts, acrylic acid tree Fat 10-20 parts, amino resins 3-7 parts, Ludox 1-3 parts, glass dust 30-40 parts, pigment 10-20 parts, emulsifying agent 1-3 parts are molten Agent 100-120 parts, dispersant 1-2 parts, levelling agent 1-2 parts, thickener 0.5-1 parts.
The glass dust is by Bi by percentage to the quality2O3 10-35%、B2O3 4-8%、SiO2 20-40%、ZnO 2- 8%、K2O 5-12%、Na2O 3-10%、MgO 3-5%、TiO2 1-4%、Al2O33-4%, BaO 6-9% raw material composition, Suo Youyuan The mass percent of material amounts to 100%.
The emulsifying agent is the mixing of lecithin, oleic acid diethyl amide, diisooctyl sodium sulfosuccinate and aliphatic acid Thing, lecithin, oleic acid diethyl amide, the mass ratio of diisooctyl sodium sulfosuccinate and aliphatic acid are 1：1：1：0.3.
The aliphatic acid is hard fatty acids.
The solvent be terpinol, diglycol and organic silicone oil mixture, terpinol, diglycol and The mass ratio of organic silicone oil is 1：1：0.1.
The thickener is Macrogol 4000.
The preparation method of the automobile glass printing ink of above-mentioned acid and alkali-resistance, comprises the following steps：
Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
The present invention coordinates epoxy resin, acrylic resin and amino resins that vehicle glass oil is made using glass powder with low melting point Ink, there is good acid-proof alkaline.
Embodiment
Embodiment 1
A kind of automobile glass printing ink of acid and alkali-resistance, raw material include in parts by weight：20 parts of epoxy resin, 10 parts of acrylic resin, 3 parts of amino resins, 1 part of Ludox, 30 parts of glass dust, 10 parts of pigment, 1 part of emulsifying agent, 100 parts of solvent, 1 part of dispersant, levelling 1 part of agent, 0.5 part of thickener.
Wherein, the glass dust is by Bi by percentage to the quality2O3 30%、B2O3 5%、SiO2 27%、ZnO 4%、K2O 7%、Na2O 8%、MgO 3%、TiO2 4%、Al2O34%th, BaO 8% raw material composition；The emulsifying agent is lecithin, oleic acid two The mixture of glycollic amide, diisooctyl sodium sulfosuccinate and aliphatic acid, lecithin, oleic acid diethyl amide, diisooctyl The mass ratio of sodium sulfosuccinate and aliphatic acid is 1：1：1：0.3；The aliphatic acid is hard fatty acids；The solvent is pine tar The mixture of alcohol, diglycol and organic silicone oil, the mass ratio of terpinol, diglycol and organic silicone oil is 1：1： 0.1；The thickener is Macrogol 4000.
The preparation method of the automobile glass printing ink of above-mentioned acid and alkali-resistance, comprises the following steps：
Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
Embodiment 2
A kind of automobile glass printing ink of acid and alkali-resistance, raw material include in parts by weight：23 parts of epoxy resin, 12 parts of acrylic resin, 4 parts of amino resins, 2 parts of Ludox, 35 parts of glass dust, 13 parts of pigment, 2 parts of emulsifying agent, 106 parts of solvent, 1.5 parts of dispersant, stream Flat 1.3 parts of agent, 0.8 part of thickener.
Wherein, the glass dust is by Bi by percentage to the quality2O3 25%、B2O3 7%、SiO2 35%、ZnO 8%、K2O 5%、Na2O 5%、MgO 3%、TiO2 2%、Al2O34%th, BaO 9% raw material composition；The emulsifying agent is lecithin, oleic acid two The mixture of glycollic amide, diisooctyl sodium sulfosuccinate and aliphatic acid, lecithin, oleic acid diethyl amide, diisooctyl The mass ratio of sodium sulfosuccinate and aliphatic acid is 1：1：1：0.3；The aliphatic acid is hard fatty acids；The solvent is pine tar The mixture of alcohol, diglycol and organic silicone oil, the mass ratio of terpinol, diglycol and organic silicone oil is 1：1： 0.1；The thickener is Macrogol 4000.
The preparation method of the automobile glass printing ink of above-mentioned acid and alkali-resistance, comprises the following steps：
Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
Embodiment 3
A kind of automobile glass printing ink of acid and alkali-resistance, raw material include in parts by weight：28 parts of epoxy resin, 17 parts of acrylic resin, 5 parts of amino resins, 2 parts of Ludox, 37 parts of glass dust, 16 parts of pigment, 1 part of emulsifying agent, 110 parts of solvent, 2 parts of dispersant, levelling 1 part of agent, 0.8 part of thickener.
Wherein, the glass dust is by Bi by percentage to the quality2O3 18%、B2O3 8%、SiO2 40%、ZnO 5%、K2O 8%、Na2O 4%、MgO 5%、TiO2 3%、Al2O33%th, BaO 6% raw material composition；The emulsifying agent is lecithin, oleic acid two The mixture of glycollic amide, diisooctyl sodium sulfosuccinate and aliphatic acid, lecithin, oleic acid diethyl amide, diisooctyl The mass ratio of sodium sulfosuccinate and aliphatic acid is 1：1：1：0.3；The aliphatic acid is hard fatty acids；The solvent is pine tar The mixture of alcohol, diglycol and organic silicone oil, the mass ratio of terpinol, diglycol and organic silicone oil is 1：1： 0.1；The thickener is Macrogol 4000.
The preparation method of the automobile glass printing ink of above-mentioned acid and alkali-resistance, comprises the following steps：
Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
Embodiment 4
A kind of automobile glass printing ink of acid and alkali-resistance, raw material include in parts by weight：30 parts of epoxy resin, 20 parts of acrylic resin, 7 parts of amino resins, 3 parts of Ludox, 40 parts of glass dust, 20 parts of pigment, 3 parts of emulsifying agent, 120 parts of solvent, 2 parts of dispersant, levelling 2 parts of agent, 1 part of thickener.
Wherein, the glass dust is by Bi by percentage to the quality2O3 35%、B2O3 4%、SiO2 25%、ZnO 2%、K2O 8%、Na2O 6%、MgO 3%、TiO2 4%、Al2O34%th, BaO 9% raw material composition, the mass percent of all raw materials amount to 100%；The emulsifying agent is the mixture of lecithin, oleic acid diethyl amide, diisooctyl sodium sulfosuccinate and aliphatic acid, Lecithin, oleic acid diethyl amide, the mass ratio of diisooctyl sodium sulfosuccinate and aliphatic acid are 1：1：1：0.3；The fat Fat acid is hard fatty acids；The solvent be terpinol, diglycol and organic silicone oil mixture, terpinol, one contracting two The mass ratio of ethylene glycol and organic silicone oil is 1：1：0.1；The thickener is Macrogol 4000.
The preparation method of the automobile glass printing ink of above-mentioned acid and alkali-resistance, comprises the following steps：
Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
By the correlated performance of ink sample test ink sintered products after printing, dry, sinter obtained by embodiment.After sintering Layer of ink surface is smooth, and ink has good resistance to bond, blackness and glossiness；It is put into 0.1mol/L 80 DEG C of sulfuric acid solution Water-bath immersion 72h, it is put into 0.5% sodium hydroxide solution after soak at room temperature 80h, ink pellet surface does not have aberration before and after immersion, through super Depth-of-field microscope observation layer of ink surface is not ftractureed, obscission.

Claims (7)

  1. A kind of 1. automobile glass printing ink of acid and alkali-resistance, it is characterised in that：Raw material includes in parts by weight：Epoxy resin 20-30 parts, Acrylic resin 10-20 parts, amino resins 3-7 parts, Ludox 1-3 parts, glass dust 30-40 parts, pigment 10-20 parts, emulsifying agent 1-3 parts, solvent 100-120 parts, dispersant 1-2 parts, levelling agent 1-2 parts, thickener 0.5-1 parts.
  2. 2. the automobile glass printing ink of acid and alkali-resistance according to claim 1, it is characterised in that：The glass dust is by with quality Percentages Bi2O3 10-35%、B2O3 4-8%、SiO2 20-40%、ZnO 2-8%、K2O 5-12%、Na2O 3-10%、MgO 3- 5%、TiO2 1-4%、Al2O33-4%, BaO 6-9% raw material composition, the mass percent of all raw materials amount to 100%.
  3. 3. the automobile glass printing ink of acid and alkali-resistance according to claim 1, it is characterised in that：The emulsifying agent be lecithin, The mixture of oleic acid diethyl amide, diisooctyl sodium sulfosuccinate and aliphatic acid, lecithin, oleic acid diethyl amide, two The mass ratio of iso-octyl sodium sulfosuccinate and aliphatic acid is 1：1：1：0.3.
  4. 4. the automobile glass printing ink of acid and alkali-resistance according to claim 1, it is characterised in that：The aliphatic acid is tallow Acid.
  5. 5. the automobile glass printing ink of acid and alkali-resistance according to claim 1, it is characterised in that：The solvent is terpinol, one The mixture of diglycol ethylene and organic silicone oil, the mass ratio of terpinol, diglycol and organic silicone oil is 1：1：0.1.
  6. 6. the automobile glass printing ink of acid and alkali-resistance according to claim 1, it is characterised in that：The thickener is polyethylene glycol 4000。
  7. 7. the preparation method of the automobile glass printing ink of the acid and alkali-resistance described in claim 1, it is characterised in that：Comprise the following steps：
    Step 1, take to be placed in high temperature furnace after glass dust raw material mixed grinding and be heated to 1200 DEG C, be incubated the glass of melting after 2h Liquid cast molding is simultaneously annealed at 440 DEG C, i.e., the grinding of gained both bulk glasses is obtained into glass dust；
    Step 2, epoxy resin, acrylic resin, amino resins and Ludox are added in solvent, is warming up to 40-50 DEG C, insulation 0.5~1h, obtain varnish；
    Step 3, step 1 gained glass dust, pigment, emulsifying agent, solvent, dispersant, levelling agent and thickener are added into step 2 institute Obtain in varnish, grinding, produce.
CN201710882596.6A 2017-09-26 2017-09-26 A kind of automobile glass printing ink of acid and alkali-resistance and preparation method thereof Pending CN107459868A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329862A (en) * 2018-02-11 2018-07-27 江苏斯迪克新材料科技股份有限公司 Minute surface rupture pressure disc
CN109913028A (en) * 2019-03-01 2019-06-21 雷飞 A kind of preparation method of wear-resisting scratch resistant type plate glass ink material
CN110028831A (en) * 2019-04-23 2019-07-19 郑州知淘信息科技有限责任公司 A kind of tempered glass of automobile crown glass ink and preparation method thereof
CN111378318A (en) * 2020-04-30 2020-07-07 广州亦盛环保科技有限公司 Alkali-resistant protective printing ink and application thereof
CN112551910A (en) * 2020-12-18 2021-03-26 江苏秀强玻璃工艺股份有限公司 Acid-resistant high-temperature ink for glass and preparation method thereof
CN113174151A (en) * 2021-05-07 2021-07-27 珠海市力众实业有限公司 Slurry and preparation method and application thereof
CN113636756A (en) * 2021-06-25 2021-11-12 吴江南玻玻璃有限公司 Water-based environment-friendly white glaze for high-reflection anti-PID photovoltaic back plate glass and preparation method thereof
CN114381165A (en) * 2022-01-25 2022-04-22 武汉理工大学 White microcrystalline glass ink for digital ink jet and preparation method and application thereof

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108329862A (en) * 2018-02-11 2018-07-27 江苏斯迪克新材料科技股份有限公司 Minute surface rupture pressure disc
CN109913028A (en) * 2019-03-01 2019-06-21 雷飞 A kind of preparation method of wear-resisting scratch resistant type plate glass ink material
CN110028831A (en) * 2019-04-23 2019-07-19 郑州知淘信息科技有限责任公司 A kind of tempered glass of automobile crown glass ink and preparation method thereof
CN111378318A (en) * 2020-04-30 2020-07-07 广州亦盛环保科技有限公司 Alkali-resistant protective printing ink and application thereof
CN112551910A (en) * 2020-12-18 2021-03-26 江苏秀强玻璃工艺股份有限公司 Acid-resistant high-temperature ink for glass and preparation method thereof
CN112551910B (en) * 2020-12-18 2022-05-13 江苏秀强玻璃工艺股份有限公司 Acid-resistant high-temperature ink for glass and preparation method thereof
CN113174151A (en) * 2021-05-07 2021-07-27 珠海市力众实业有限公司 Slurry and preparation method and application thereof
CN113174151B (en) * 2021-05-07 2022-06-03 珠海市力众实业有限公司 Slurry and preparation method and application thereof
CN113636756A (en) * 2021-06-25 2021-11-12 吴江南玻玻璃有限公司 Water-based environment-friendly white glaze for high-reflection anti-PID photovoltaic back plate glass and preparation method thereof
CN114381165A (en) * 2022-01-25 2022-04-22 武汉理工大学 White microcrystalline glass ink for digital ink jet and preparation method and application thereof
CN114381165B (en) * 2022-01-25 2022-12-09 武汉理工大学 White microcrystalline glass ink for digital ink jet and preparation method and application thereof

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