CN109913028A - A kind of preparation method of wear-resisting scratch resistant type plate glass ink material - Google Patents
A kind of preparation method of wear-resisting scratch resistant type plate glass ink material Download PDFInfo
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Abstract
The present invention relates to a kind of preparation methods of wear-resisting scratch resistant type plate glass ink material, belong to engraving technology field.Technical solution of the present invention prepares SiO using sol-gel technique2‑TiO2‑ZrO2Collosol-gelatum system, organic group of the gel surface due to being grafted long-chain, increase interparticle repulsive interaction, the aggregation for reducing particle, increases the stability of colloidal sol, while introducing photocuring system and effectively photocuring modification, it is modified by material photocuring, it is added to gel rubber material in varnish, forms effective cladding and filling, effective modified material wear-resisting property and scraping and wiping resistance performance through photocuring；Technical solution of the present invention carries out coating modification using sol-gel system, it is allowed to form the three-dimensional netted cross-linked structure of complete densification, and it is securely bonded to together with substrate, this spacial framework can be formed effectively in surface of plate glass and be loaded, further improve the bond strength between material and substrate, to effectively improve the wear-resisting property of material.
Description
Technical field
The present invention relates to a kind of preparation methods of wear-resisting scratch resistant type plate glass ink material, belong to engraving technology neck
Domain.
Background technique
Glass ink be it is a kind of in glass, ceramic surface can print and can firm attachment ink.High temperature tempered glass
Glass ink, sintering temperature is at 720-850 DEG C, and after High temperature tempered, ink is together with the secured clinkering of glass.Medium temperature glass is roasting
Caul-fat ink, sintering temperature is at 500 DEG C ~ 600 DEG C.Glass powder is as the important component in high temperature glass ink, property
Energy superiority and inferiority directly affects ink performance.Traditional high temp glass ink is mostly with leaded glass powder with low melting point for main fluxing film forming
Substance with preferable chemical stability, adhesive force and can maintain the preferable color characteristics of ink and be used widely.
Plate glass ink is exactly the ink that can carry out printing simultaneously energy firm attachment on glass.It can by processing temperature
It is divided into high temp glass ink, glass decoration firing ink, low temperature glass ink and simple glass ink etc..Oil can be divided by tune membrane solvent
Property glass ink, waterborne glass ink.Flint glass ink and crown glass ink etc. can be divided by environmental protection standard.
The theoretical strength of ordinary plate glass is very high, but actual strength is lower, 2~3 orders of magnitude lower than theoretical strength.For
Acquisition high strength glass original piece, at present countries in the world are all strong to improve glass using the method for the secondary deep processing of plate glass
Degree, the method for secondary deep processing can be summarized as following three aspects: first is that causing compression prestress in glass surface；Second is that changing
Kind glass surface quality；Third is that the synthesis enhancing technology that the two combines.
Polydiphenyl ether resin is thermosetting polymer.It has high temperature resistant, radiation hardness and excellent mechanical electric performance.
But since its solidification temperature is high, moulded manufacturability is poor, generally using the modified diphenyl ether of biphenol as composite wood
The matrix resin of material.Diphenyl ether after phenol-modified has the characteristics that at low cost, solidification temperature is low, in recent years by widely
Applied to the preparation of glass cloth laminated board, but at present it is some manufacture in a rough and slipshod way, the phenol-modified diphenyl ether laminate of low price is in city
It is on sale throughout on field for the moment, the normal market order of very disruptive, and certain content is added in high strength glass domestic at present
Fe2O3 so that the diathermancy and color of glass all defects.
Glass is the stable inorganic material of chemical property, and surface is smooth hard, with the common organic printing ink of synthetic resin
Binding force is not strong, and most is transparent article, cannot there is the spot of printing ink on surface.Therefore, the printing of halftone is suitble to the most.
Can carry out the mode of screen painting by the silicate glass product surface of screen painting is mainly pattern decorative, scale text
Deng, silicate glass product (generally glass sheet and bottle glass) surface carry out screen painting used in ink be known as
Glass ink.
It will be carved with the glass of text or pattern, decorative pattern, it is beautiful and generous as ornament.Reaching this purpose method is to adopt
With decorations lithography, i.e., corrode the method for scribing glass using chemical agent-etchant.As etchant, use for a long time
It is hydrofluoric acid.It is then that glass to be etched is cleaned and dries horizontal as engraving method, the stone that coating is dissolved with gasoline thereon
Wax liquor is as protective layer, text required for carving out on the paraffin layer after solidification or pattern.When engraving, it is necessary to carve paraffin
Layer, exposes glass.Then, hydrofluoric acid is dripped on the text or pattern for exposing glass.According to the depth of required decorative pattern, control
Etching time washes away paraffin and hydrofluoric acid after a predetermined time, with warm water, can be prepared by the glass with beautiful decorative pattern.
Due to having various texts or pattern etc. on engraved glass, it is accordingly used in the plate glass ink of artistic carving just
It needs that ink is made to reach requirement in terms of adhesive force, scratch resistance and wearability simultaneously, and existing plate glass ink is difficult to
It is up to standard simultaneously.
Summary of the invention
The technical problems to be solved by the invention: it is difficult to simultaneously for existing plate glass ink in scratch resistance and resistance to
The problem of mill property aspect reaches requirement, provide a kind of preparation method of wear-resisting scratch resistant type plate glass ink material.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
(1) according to parts by weight, 45~50 parts of deionized waters, 10~15 parts of dehydrated alcohols and 1~2 part of zirconium oxychloride are weighed respectively
It is placed in a beaker and is stirred to obtain reaction solution, according to parts by weight, weigh 45~50 parts of reaction solutions, 2~3 parts of positive silicic acid second respectively
Ester and 6~8 parts of dehydrated alcohols are placed in a beaker, and are stirred and are adjusted pH to 1.5, be stirred juxtaposition and stand at room temperature,
Hydrolyzate and 1:10 in mass ratio are collected to obtain, butyl titanate ethanol solution is added dropwise in hydrolyzate, after being added dropwise to complete, stirring
Mixing, obtains sol solutions；
(2) flyash is taken to be placed in grinder, grinding distribution simultaneously crosses 200 meshes, collect to obtain abrasive grains and in mass ratio 1:
15, abrasive grains are added in 5% hydrochloric acid solution of mass fraction, stirs mixed rear and filters, obtain filtrate and filter residue, filtrate is taken to revolve
Turn evaporation, collect dry particle and roast, powders calcined, then 1:10 in mass ratio is ground to obtain, by filter residue and mass fraction 15%
Sodium hydroxide solution is stirred and is centrifugated, and collects supernatant liquor, powders calcined and supernatant liquor are stirred,
Dry 2~3h, obtains composite particles and ground 200 mesh, obtains matrix modification particle at 110~120 DEG C；
(3) according to parts by weight, respectively weigh 45~50 parts of sol solutions, 3~5 parts of matrix modification particles, 1~2 part of photoinitiator,
3~5 parts of 5% poly-vinyl alcohol solutions of mass fraction meter, 1~2 part of sodium carboxymethylcellulose, 1~2 part of glycerol, 0.5~1.0 part three
Pears acid sodium and 45~50 parts of deionized waters are placed in blender, are stirred and collect mixed liquor, then according to parts by weight, respectively
Weigh 45~50 portions of mixed liquors, 10~15 parts of pigment, 1~2 part of dispersing agent 5040,1~2 parts of thixotropic agent 6500 and levelling agents
BYK346 is placed in mortar, grinding distribution, is collected dispersion slurries and is again placed in three-roll grinder and grind, the screen to filtrate is simultaneously received
Collection filtering slurries, can be prepared into the wear-resisting scratch resistant type plate glass ink material.
Adjusting pH to 1.5 described in step (1) is using dropwise addition 15% hydrochloric acid of mass fraction.
Butyl titanate ethanol solution mass fraction described in step (1) is 15%.
Butyl titanate ethanol solution drop rate described in step (1) is 1~2mL/min.
Rotary evaporation described in step (2) is the rotary evaporated to dryness at 85~90 DEG C.
Dry particle maturing temperature described in step (2) is 250~300 DEG C.
Ratio is 1:1 between powders calcined and supernatant liquor described in step (2).
Photoinitiator described in step (3) is any one in photoinitiator 1173 and photoinitiator 819.
Thixotropic agent described in step (3) is any one in thixotropic agent 6500 and BYK-R605 thixotropic agent.
Mesh size described in step (3) is 6~8 μm.
The present invention is compared with other methods, and advantageous effects are:
(1) technical solution of the present invention prepares SiO using sol-gel technique2-TiO2-ZrO2Collosol-gelatum system, gel surface
Due to being grafted the organic group of long-chain, interparticle repulsive interaction is increased, the aggregation of particle is reduced, increases the steady of colloidal sol
It is qualitative, while photocuring system and effectively photocuring modification are introduced, it is modified by material photocuring, so that gel rubber material is added to tune
In black oil, effective cladding and filling, effective modified material wear-resisting property and scraping and wiping resistance performance are formed through photocuring；
(2) technical solution of the present invention carries out coating modification using sol-gel system, due to the SiO of formation2-TiO2-ZrO2Friendship
The coating for being coupled structure plate glass structure is coated, and by improving the degree of cross linking of adhesive, is allowed to form the three of complete densification
Cross-linked network is tieed up, and is securely bonded to together with substrate, this spacial framework can be effectively in flat glass table
Face forms load, further improves the bond strength between material and substrate, to effectively improve the wear-resisting property of material；
(3) technical solution of the present invention is modified using coal ash for manufacturing for nano silicon oxide composite alumina, due to nano oxidized
Silicon materials are insoluble in the abrasion-proof materiel of water-based ink, and in the drying process, silicon oxide particle and ink particle are or not water-based ink
It can mix and cohere completely, but generate many fine crack when fretting wear machine in the intersection of ink and nano silicon oxide
Emery wheel when water-based ink glass pane surface is acted on, nano silicon oxide water-based ink surface fall off consume it is certain
Energy, while the crackle of interface also consumes portion of energy prevents crackle to continue to extend, hinders the de- of sample overlay film
It falls, meanwhile, aluminium oxide is as packing material, and the increased friction of nano aluminium oxide, abrasion is more, has reached relative equilibrium, effectively
The abrasion resistance properties and scraping and wiping resistance performance for improving material are effectively improved the impaired and variation of material in use.
Specific embodiment
According to parts by weight, 45~50 parts of deionized waters, 10~15 parts of dehydrated alcohols and 1~2 part of oxychlorination are weighed respectively
Zirconium, which is placed in a beaker, is stirred to obtain reaction solution, according to parts by weight, weighs 45~50 parts of reaction solutions, 2~3 parts of positive silicic acid respectively
Ethyl ester and 6~8 parts of dehydrated alcohols are placed in a beaker, and are stirred and 15% hydrochloric acid of mass fraction is added dropwise to pH to 1.5, stirring is mixed
Merging is placed in 2~3h of standing at room temperature, hydrolyzate and 1:10 in mass ratio is collected to obtain, by 10% butyl titanate ethyl alcohol of mass-dispersion
Solution is added dropwise in hydrolyzate, and control drop rate is 1~2mL/min, after being added dropwise to complete, then mixing 10 is stirred at room temperature
~12h, obtains sol solutions；Flyash is taken to be placed in grinder, grinding distribution simultaneously crosses 200 meshes, collects abrasive grains and to press
Abrasive grains are added in 5% hydrochloric acid solution of mass fraction by mass ratio 1:15, are stirred mixed rear and are filtered, obtain filtrate and filter residue,
It takes filtrate to be placed in rotary evaporated to dryness at 85~90 DEG C, collects dry particle and be placed in 1~2h of roasting at 250~300 DEG C, grind
Powders calcined, then 1:10 in mass ratio are ground to obtain, filter residue and 15% sodium hydroxide solution of mass fraction are stirred and is centrifuged point
From, supernatant liquor and 1:1 in mass ratio are collected, powders calcined and supernatant liquor are stirred, the drying 2 at 110~120 DEG C
~3h obtains composite particles and ground 200 mesh, obtains matrix modification particle；According to parts by weight, 45~50 parts of weighing is molten respectively
Glue, 3~5 parts of matrix modification particles, 1~2 part of photoinitiator, 1173,3~5 parts of 5% poly-vinyl alcohol solutions of mass fraction meter, 1
~2 parts of sodium carboxymethylcelluloses, 1~2 part of glycerol, 0.5~1.0 part of three pears acid sodium and 45~50 parts of deionized waters are placed in blender
In, it is stirred and is collected mixed liquor, then according to parts by weight, weighs 45~50 portions of mixed liquors, 10~15 parts of pigment, 1 respectively
5040,1~2 parts of thixotropic agent 6500 of~2 parts of dispersing agents and levelling agent BYK346 are placed in mortar, are placed under 400~500r/min
Grinding distribution, collection dispersion slurries, which are placed in three-roll grinder, to be ground 2~3 times, with 6~8 μm of the screen to filtrates and collects filtering
Slurries can be prepared into the wear-resisting scratch resistant type plate glass ink material.
According to parts by weight, 45 parts of deionized waters, 10 parts of dehydrated alcohols and 1 part of zirconium oxychloride is weighed respectively to be placed in a beaker
It is stirred to obtain reaction solution, according to parts by weight, 45 parts of reaction solutions, 2 parts of ethyl orthosilicates and 6 parts of dehydrated alcohols is weighed respectively and sets
In beaker, it is stirred and 15% hydrochloric acid of mass fraction is added dropwise to pH to 1.5, be stirred juxtaposition and stand 2h at room temperature,
Hydrolyzate and 1:10 in mass ratio are collected to obtain, 10% butyl titanate ethanol solution of mass-dispersion is added dropwise in hydrolyzate, is controlled
Drop rate is 1mL/min, after being added dropwise to complete, then mixing 10h is stirred at room temperature, obtains sol solutions；Flyash is taken to be placed in
In grinder, grinding distribution simultaneously crosses 200 meshes, collects to obtain abrasive grains and 1:15 in mass ratio, abrasive grains are added to matter
It measures in 5% hydrochloric acid solution of score, stir mixed rear and filters, obtain filtrate and filter residue, take filtrate to be placed in rotation at 85 DEG C and be evaporated to
Dry, collection dry particle, which is placed at 250 DEG C, roasts 1h, powders calcined, then 1:10 in mass ratio is ground to obtain, by filter residue and quality
15% sodium hydroxide solution of score is stirred and is centrifugated, and collects supernatant liquor and 1:1 in mass ratio, by powders calcined and
Supernatant liquor is stirred, and dry 2h, obtains composite particles and ground 200 mesh, obtain matrix modification particle at 110 DEG C；It presses
Parts by weight meter weighs 45 parts of sol solutions, 3 parts of matrix modification particles, 1 part of photoinitiator, 1173,3 parts of mass fraction meters respectively
5% poly-vinyl alcohol solution, 1 part of sodium carboxymethylcellulose, 1 part of glycerol, 0.5 part of three pears acid sodium and 45 parts of deionized waters are placed in stirring
In machine, it is stirred and is collected mixed liquor, then according to parts by weight, weighs 45 portions of mixed liquors, 10 parts of pigment, 1 part of dispersion respectively
5040,1 parts of thixotropic agent 6500 of agent and levelling agent BYK346 are placed in mortar, are placed in grinding distribution under 400r/min, collect dispersion
Slurries are placed in three-roll grinder and grind 2 times, with 6 μm of the screen to filtrates and collect filtering slurries, can be prepared into described resistance to
Grind scratch resistant type plate glass ink material.
According to parts by weight, 47 parts of deionized waters, 13 parts of dehydrated alcohols and 1.5 parts of zirconium oxychlorides are weighed respectively be placed in beaker
In be stirred to obtain reaction solution, according to parts by weight, weigh 47 parts of reaction solutions, 2.5 parts of ethyl orthosilicates and 7 parts of anhydrous second respectively
Alcohol is placed in a beaker, and is stirred and 15% hydrochloric acid of mass fraction is added dropwise to pH to 1.5, be stirred juxtaposition and stand at room temperature
2.5h collects to obtain hydrolyzate and 1:10 in mass ratio, and 10% butyl titanate ethanol solution of mass-dispersion is added dropwise in hydrolyzate,
Control drop rate is 1.5mL/min, after being added dropwise to complete, then mixing 11h is stirred at room temperature, obtains sol solutions；Take flyash
It is placed in grinder, grinding distribution simultaneously crosses 200 meshes, collects to obtain abrasive grains and 1:15 in mass ratio, abrasive grains are added
It adds in 5% hydrochloric acid solution of mass fraction, stir mixed rear and filters, obtain filtrate and filter residue, take filtrate to be placed at 87 DEG C and rotate
It is evaporated to dryness, collection dry particle, which is placed at 275 DEG C, roasts 1.5h, grinds to obtain powders calcined, then 1:10 in mass ratio, will filter
Slag is stirred and is centrifugated with 15% sodium hydroxide solution of mass fraction, collects supernatant liquor and 1:1 in mass ratio, will roast
It burns powder to be stirred with supernatant liquor, dry 2.5h, obtains composite particles and ground 200 mesh, obtain matrix and change at 115 DEG C
Property particle；According to parts by weight, 47 parts of sol solutions, 4 parts of matrix modification particles, 1.5 parts 1173,4 parts of photoinitiator are weighed respectively
5% poly-vinyl alcohol solution of mass fraction meter, 1.5 parts of sodium carboxymethylcelluloses, 1.5 parts of glycerol, 0.7 part of three pears acid sodium and 47 parts are gone
Ionized water is placed in blender, is stirred and collects mixed liquor, then according to parts by weight, weighs 47 parts of mixed liquors, 13 respectively
Part pigment, 1.5 parts of dispersing agents, 5040,1.5 parts of thixotropic agent 6500 and levelling agent BYK346 are placed in mortar, are placed under 450r/min
Grinding distribution, collection dispersion slurries, which are placed in three-roll grinder, to be ground 2 times, with 7 μm of the screen to filtrates and collects filtering slurries, i.e.,
The wear-resisting scratch resistant type plate glass ink material can be prepared into.
According to parts by weight, 48 parts of deionized waters, 14 parts of dehydrated alcohols and 2 parts of zirconium oxychlorides are weighed respectively to be placed in a beaker
It is stirred to obtain reaction solution, according to parts by weight, 48 parts of reaction solutions, 3 parts of ethyl orthosilicates and 8 parts of dehydrated alcohols is weighed respectively and sets
In beaker, it is stirred and 15% hydrochloric acid of mass fraction is added dropwise to pH to 1.5, be stirred juxtaposition and stand 3h at room temperature,
Hydrolyzate and 1:10 in mass ratio are collected to obtain, 10% butyl titanate ethanol solution of mass-dispersion is added dropwise in hydrolyzate, is controlled
Drop rate is 2mL/min, after being added dropwise to complete, then mixing 11h is stirred at room temperature, obtains sol solutions；Flyash is taken to be placed in
In grinder, grinding distribution simultaneously crosses 200 meshes, collects to obtain abrasive grains and 1:15 in mass ratio, abrasive grains are added to matter
It measures in 5% hydrochloric acid solution of score, stir mixed rear and filters, obtain filtrate and filter residue, take filtrate to be placed in rotation at 85~90 DEG C and steam
It is sent to dry, collects dry particle and be placed at 285 DEG C and roast 1.5h, powders calcined, then 1:10 in mass ratio are ground to obtain, by filter residue
It is stirred and is centrifugated with 15% sodium hydroxide solution of mass fraction, collect supernatant liquor and 1:1 in mass ratio, will roast
Powder is stirred with supernatant liquor, and dry 3h, obtains composite particles and ground 200 mesh, obtain matrix modification at 117 DEG C
Grain；According to parts by weight, 48 parts of sol solutions, 4 parts of matrix modification particles, 2 parts of photoinitiators, 1173,5 parts of quality point are weighed respectively
Number 5% poly-vinyl alcohol solution of meter, 2 parts of sodium carboxymethylcelluloses, 1 part of glycerol, 0.8 part of three pears acid sodium and 48 parts of deionized waters are placed in
In blender, it is stirred and is collected mixed liquor, then according to parts by weight, weighs 48 portions of mixed liquors, 14 parts of pigment, 2 parts respectively
5040,2 parts of thixotropic agent 6500 of dispersing agent and levelling agent BYK346 are placed in mortar, are placed in grinding distribution under 480r/min, are collected
Dispersion slurries, which are placed in three-roll grinder, to be ground 3 times, with 8 μm of the screen to filtrates and collects filtering slurries, can be prepared into described
Wear-resisting scratch resistant type plate glass ink material.
According to parts by weight, 50 parts of deionized waters, 15 parts of dehydrated alcohols and 2 parts of zirconium oxychlorides are weighed respectively to be placed in a beaker
It is stirred to obtain reaction solution, according to parts by weight, 50 parts of reaction solutions, 3 parts of ethyl orthosilicates and 8 parts of dehydrated alcohols is weighed respectively and sets
In beaker, it is stirred and 15% hydrochloric acid of mass fraction is added dropwise to pH to 1.5, be stirred juxtaposition and stand 3h at room temperature,
Hydrolyzate and 1:10 in mass ratio are collected to obtain, 10% butyl titanate ethanol solution of mass-dispersion is added dropwise in hydrolyzate, is controlled
Drop rate is 2mL/min, after being added dropwise to complete, then mixing 12h is stirred at room temperature, obtains sol solutions；Flyash is taken to be placed in
In grinder, grinding distribution simultaneously crosses 200 meshes, collects to obtain abrasive grains and 1:15 in mass ratio, abrasive grains are added to matter
It measures in 5% hydrochloric acid solution of score, stir mixed rear and filters, obtain filtrate and filter residue, take filtrate to be placed in rotation at 90 DEG C and be evaporated to
Dry, collection dry particle, which is placed at 300 DEG C, roasts 2h, powders calcined, then 1:10 in mass ratio is ground to obtain, by filter residue and quality
15% sodium hydroxide solution of score is stirred and is centrifugated, and collects supernatant liquor and 1:1 in mass ratio, by powders calcined and
Supernatant liquor is stirred, and dry 3h, obtains composite particles and ground 200 mesh, obtain matrix modification particle at 120 DEG C；It presses
Parts by weight meter weighs 50 parts of sol solutions, 5 parts of matrix modification particles, 2 parts of photoinitiators, 1173,5 parts of mass fraction meters respectively
5% poly-vinyl alcohol solution, 2 parts of sodium carboxymethylcelluloses, 2 parts of glycerol, 1.0 part of three pears acid sodium and 50 parts of deionized waters are placed in stirring
In machine, it is stirred and is collected mixed liquor, then according to parts by weight, weighs 50 portions of mixed liquors, 15 parts of pigment, 2 parts of dispersions respectively
5040,2 parts of thixotropic agent 6500 of agent and levelling agent BYK346 are placed in mortar, are placed in grinding distribution under 500r/min, collect dispersion
Slurries are placed in three-roll grinder and grind 3 times, with 8 μm of the screen to filtrates and collect filtering slurries, can be prepared into described resistance to
Grind scratch resistant type plate glass ink material.
Wear-resisting scratch resistant type plate glass ink material prepared by the present invention and commercially available plate glass ink are examined
It surveys, specific testing result such as following table table 1:
Test method:
Adhesive force: 3M adhesive tape, the test of hundred lattice, GB/T9286-1998；
Scratch resistance: ink is printed on glass slide and abundant curing and drying, uses QHQ shaking pencil hardometer, hardness
For the pencil of H, load 175g power, the scratch resistance of test ink coating surface；
Wearability: ink is printed on glass slide and abundant curing and drying, uses multifunctional alcohol rubber friction testing machine (type
Number: LX-5600, Dongguan Li Xin instrument and equipment factory) test, load 500g；
Adhesive force, scratch resistance, wearability representation method: 1 is worst, and 5 be optimal；
The wear-resisting scratch resistant type plate glass ink material performance characterization of table 1
| Performance characterization | Example 1 | Example 2 | Example 3 | Comparative example |
| Adhesive force | 4 | 5 | 4 | 3 |
| Scratch resistance | 5 | 5 | 5 | 3 |
| Wearability | 5 | 5 | 5 | 3 |
Wear-resisting scratch resistant type plate glass ink material prepared by the present invention as shown in Table 1, adhesive force is good, wear-resisting property and scratch resistance
Wiping is had excellent performance, and has a vast market value and application prospect.
Claims (10)
1. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material, it is characterised in that specific preparation step are as follows:
(1) according to parts by weight, 45~50 parts of deionized waters, 10~15 parts of dehydrated alcohols and 1~2 part of zirconium oxychloride are weighed respectively
It is placed in a beaker and is stirred to obtain reaction solution, according to parts by weight, weigh 45~50 parts of reaction solutions, 2~3 parts of positive silicic acid second respectively
Ester and 6~8 parts of dehydrated alcohols are placed in a beaker, and are stirred and are adjusted pH to 1.5, be stirred juxtaposition and stand at room temperature,
Hydrolyzate and 1:10 in mass ratio are collected to obtain, butyl titanate ethanol solution is added dropwise in hydrolyzate, after being added dropwise to complete, stirring
Mixing, obtains sol solutions；
(2) flyash is taken to be placed in grinder, grinding distribution simultaneously crosses 200 meshes, collect to obtain abrasive grains and in mass ratio 1:
15, abrasive grains are added in 5% hydrochloric acid solution of mass fraction, stirs mixed rear and filters, obtain filtrate and filter residue, filtrate is taken to revolve
Turn evaporation, collect dry particle and roast, powders calcined, then 1:10 in mass ratio is ground to obtain, by filter residue and mass fraction 15%
Sodium hydroxide solution is stirred and is centrifugated, and collects supernatant liquor, powders calcined and supernatant liquor are stirred,
Dry 2~3h, obtains composite particles and ground 200 mesh, obtains matrix modification particle at 110~120 DEG C；
(3) according to parts by weight, respectively weigh 45~50 parts of sol solutions, 3~5 parts of matrix modification particles, 1~2 part of photoinitiator,
3~5 parts of 5% poly-vinyl alcohol solutions of mass fraction meter, 1~2 part of sodium carboxymethylcellulose, 1~2 part of glycerol, 0.5~1.0 part three
Pears acid sodium and 45~50 parts of deionized waters are placed in blender, are stirred and collect mixed liquor, then according to parts by weight, respectively
Weigh 45~50 portions of mixed liquors, 10~15 parts of pigment, 1~2 part of dispersing agent 5040,1~2 parts of thixotropic agent 6500 and levelling agents
BYK346 is placed in mortar, grinding distribution, is collected dispersion slurries and is again placed in three-roll grinder and grind, the screen to filtrate is simultaneously received
Collection filtering slurries, can be prepared into the wear-resisting scratch resistant type plate glass ink material.
2. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: adjusting pH to 1.5 described in step (1) is using dropwise addition 15% hydrochloric acid of mass fraction.
3. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: butyl titanate ethanol solution mass fraction described in step (1) is 15%.
4. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: butyl titanate ethanol solution drop rate described in step (1) is 1~2mL/min.
5. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: rotary evaporation described in step (2) is the rotary evaporated to dryness at 85~90 DEG C.
6. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: dry particle maturing temperature described in step (2) is 250~300 DEG C.
7. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: ratio is 1:1 between powders calcined and supernatant liquor described in step (2).
8. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: photoinitiator described in step (3) is any one in photoinitiator 1173 and photoinitiator 819.
9. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: thixotropic agent described in step (3) is any one in thixotropic agent 6500 and BYK-R605 thixotropic agent.
10. a kind of preparation method of wear-resisting scratch resistant type plate glass ink material according to claim 1, feature exist
In: mesh size described in step (3) is 6~8 μm.
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| CN113234347A (en) * | 2021-04-28 | 2021-08-10 | 厦门欧化实业有限公司 | Water-based wear-resistant ink and preparation method thereof |
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| CN113234347A (en) * | 2021-04-28 | 2021-08-10 | 厦门欧化实业有限公司 | Water-based wear-resistant ink and preparation method thereof |
| CN113234347B (en) * | 2021-04-28 | 2023-01-10 | 厦门欧化实业有限公司 | Water-based wear-resistant ink and preparation method thereof |
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