CN106810083A - 一种除雾玻璃及其制造方法 - Google Patents
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- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
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- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
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- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
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- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
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Abstract
本发明提供一种除雾玻璃及其制造方法，该产品主要通过提升玻璃温度达到除雾目的，应用于湿度较大，易产生水雾的环境中。其主体结构包括：该除雾玻璃包括玻璃基板(1)，在玻璃基板(1)上设有镀膜层(2)，在镀膜层(2)上设有绝缘保护层(3)，在内绝缘保护层(3)上设有制热碳浆层(4)，在制热碳浆层(4)上设有导电银浆线圈(5)，在导电银浆线圈(5)上设有外绝缘保护层(6)，在外绝缘保护层(5)上设有封底层(7)；电源接口(8)位于封底层(7)上。在玻璃基板(1)上顺序印上以上材料，烘干固化后完成制作。本发明制备的产品具有特点是镜面除雾效果明显，使用时间长久，适宜在湿度较大、易产生水雾的环境中使用。
Description
技术领域
本发明涉及一种除雾玻璃的制造方法，采用化学镀银法和丝网印刷法结合，在玻璃表面制成一种发热涂层，用于玻璃表面除雾，属于玻璃深加工及卫浴用品领域。
背景技术
在日常生活中，卫浴间是每个家庭必备空间，而卫浴间缺不了梳妆镜，但在洗浴过程中，产生的水雾很容易附着到梳妆镜表面，使镜面模糊朦胧，失去成像能力，反复擦拭后方可使用，但短时间内还会重新附着一层水雾，影响使用，在浴室等湿度较大的地方尤其明显。现在市面上有两种产品意在解决此问题。其一，是在玻璃表面镀上一层特殊膜层，通过此膜层的亲水或憎水特点达到防雾目的，但所镀膜层不耐擦拭，长时间使用，会慢慢失去防雾能力；其二，是在玻璃背面粘贴一层电致发热膜，但发热膜热膨胀系数与玻璃的热膨胀系数不一样，长时间使用容易从四周向中心起皮、脱落，此外此类发热膜价格较高。
因此需要找到一种新技术解决上述问题，且制造成本低，生产工艺简单，各项性能指标符合要求的新产品及制造方法。
发明内容
技术问题：本发明的目的是针对上述问题提供一种除雾玻璃及其制造方法，在玻璃背面直接通过丝网印刷电致发热涂层，起到除雾目的，一是印刷的各个涂层之间与玻璃热膨胀系数的一致性；二是在绝缘涂层上印刷制热碳浆；三是在制热碳浆上印刷导电银浆线圈，用于提供电源；四是在制热碳浆及导电银浆上印刷绝缘涂层，且预留电源接口；五是印刷最后的高抗耐保护涂层。
技术方案：本发明是提供一种除雾玻璃及其制造方法，其一是制热碳浆的配比是高阻碳浆比低阻碳浆为9:1；其二是印刷的制热碳浆厚度要保持在100μ—150μ之间，且并列均匀排布；其三是印刷导电银浆线圈厚度要保持在80μ—120μ之间，且要完全连接并列均匀排布的制热碳浆，并预留出电源接口；其四是最后印刷的高抗耐保护涂层须印刷两遍，且套印预留出的电源接口。
本发明的一种除雾玻璃包括玻璃基板，在玻璃基板上设有镀膜层，在镀膜层上设有绝缘保护层，在内绝缘保护层上设有制热碳浆层，在制热碳浆层上设有导电银浆层，在导电银浆上设有外绝缘保护层，在外绝缘保护层上设有封底层；电源接口位于封底层上。
所述的玻璃基板是钢化的平板玻璃，
所述的镀膜层为通过磁控溅射技术镀上的一层铝金属薄层；
所述的封底层为环氧树脂加防腐助剂。
本发明的除雾玻璃的制造方法包括：
步骤一：选取2-6mm厚的超白或普通浮法透明玻璃，进行切裁、磨边、钢化，形成钢化的平板玻璃作为玻璃基板；
步骤二：在玻璃基板的一面，通过磁控溅射技术覆盖铝膜层；
步骤三：在铝膜层上通过丝网印刷满面内绝缘保护层，然后加热烘干固化；
步骤四：在烘干固化后的内绝缘保护层上通过丝网印刷并排均匀的制热碳浆层，然后加热烘干固化；
步骤五：在烘干后的并排均匀制热碳浆层上通过丝网印刷导电银浆层，使导电银浆层与制热碳浆层形成并联电路，然后加热烘干固化；
步骤六：在烘干固化后的并联电路上通过丝网印刷满面外绝缘保护层，并预留出电源接口，然后加热烘干固化；
步骤七：在烘干固化后的外绝缘保护层上通过丝网印刷封底层，并预留出电源接口，然后加热烘干固化。
其中：
步骤三中内绝缘保护层与步骤六中的外绝缘保护层，使用100目—150目网板进行印刷后，170℃-200℃烘干7-8分钟固化形成。
步骤四中制热碳浆层与步骤五中的导电银浆层使用100目—200目网板进行印刷后，190℃-210℃烘干18-22分钟固化形成；制热碳浆是由按质量比为高阻碳浆:低阻碳浆为9:1组成；印刷的制热碳浆厚度要保持在100μ—150μ之间。
所述的导电银浆线圈厚度要保持在80μ—120μ之间，
步骤七中，封底层采用高耐抗屏蔽封底油墨，使用100目-150目网板进行两次刮印后160℃-180℃烘干8-10分钟固化制成。
在步骤六、步骤七预留电源接口过程中，必须保证外绝缘保护层与封底保护层印刷的一致性。
有益效果：通过直接在钢化后的平板玻璃上通过磁控溅射镀膜技术覆盖铝膜层，在铝膜层上丝网印刷绝缘层，而后在绝缘层上直接丝网印刷并排均匀的制热碳浆，通过印刷导电银浆把制热碳浆并联起来，形成电致发热涂层，然后印刷绝缘层及高抗耐保护层。在保证各涂层附着力、耐抗性和耐老化性能达标前提下，又具有发热除雾效力，克服了现今市面上通过在镜面镀上特殊的亲水或憎水膜层达到除雾效果技术的不耐擦拭弊端，此外完全可替代在玻璃背面粘贴一层电致发热膜达到除雾效果的技术。且制造成本低，生产工艺简单，克服了电致发热膜容易发黄、老化、脱落的问题。
附图说明
图1是本发明的结构示意图。
其中有：玻璃基板1、镀膜层2、绝缘保护层3、制热碳浆层4、导电银浆线圈5、外绝缘保护层6、封底层7、电源接口8。
具体实施方式
如附图1所示，本发明的除雾玻璃包括玻璃基板1，在玻璃基板1上设有镀膜层2，在镀膜层2上设有绝缘保护层3，在内绝缘保护层3上设有制热碳浆层4，在制热碳浆层4上设有导电银浆线圈5，在导电银浆线圈5上设有外绝缘保护层6，在外绝缘保护层5上设有封底层7；电源接口8位于封底层7上。
本发明制造的具体步骤为：
步骤一：选取2-6mm厚的超白或普通浮法透明玻璃，进行切裁、磨边、钢化，形成钢化的平板玻璃作为玻璃基板1；
步骤二：在玻璃基板1的一面，通过磁控溅射技术覆盖镀膜层2；
步骤三：在镀膜层2上通过丝网印刷满面内绝缘保护层3，然后加热烘干固化；内绝缘保护层3使用100目—150目网板进行印刷后，170℃-200℃烘干7-8分钟固化形成；
步骤四：在烘干固化后的内绝缘保护层3上通过丝网印刷并排均匀的制热碳浆层4，然后加热烘干固化；使用100目—200目网板进行印刷后，190℃-210℃烘干18-22分钟固化形成；制热碳浆是由按质量比为高阻碳浆:低阻碳浆为9:1组成；印刷的制热碳浆厚度要保持在100μ—150μ之间；
步骤五：在烘干后的并排均匀制热碳浆层4上通过丝网印刷导电银浆线圈5，使导电银浆线圈5与制热碳浆层4形成并联电路，然后加热烘干固化；导电银浆线圈5使用100目—200目网板进行印刷后，190℃-210℃烘干18-22分钟固化形成；导电银浆线圈厚度要保持在80μ—120μ之间；
步骤六：在烘干固化后的并联电路上通过丝网印刷满面外绝缘保护层6，并预留出电源接口8，然后加热烘干固化；外绝缘保护层6使用100目—150目网板进行印刷后，170℃-200℃烘干7-8分钟固化形成；
步骤七：在烘干固化后的外绝缘保护层6上通过丝网印刷封底层7，并预留出电源接口8，然后加热烘干固化，用于保护镀膜层2、绝缘保护层3、制热碳浆层4、导电银浆线圈5、外绝缘保护层6印刷层；封底层7采用高耐抗屏蔽封底油墨，使用100目-150目网板进行两次刮印后160℃-180℃烘干8-10分钟固化制成；预留电源接口8过程中，必须保证外绝缘保护层6与封底保护层7印刷的一致性。
以上是对本发明所提供的一种除雾玻璃及其制造方法，进行了详细的介绍，上述实施例只为说明本发明的技术构思及特点，其目的在于让本领域技术人员能够理解本发明的内容并实施，并不能以此来限制本发明的保护范围。凡根据本发明的技术方案所做的变换或改动，都在本发明的保护范围之内。
Claims (10)
1.一种除雾玻璃，其特征在于该除雾玻璃包括玻璃基板(1)，在玻璃基板(1)上设有镀膜层(2)，在镀膜层(2)上设有绝缘保护层(3)，在内绝缘保护层(3)上设有制热碳浆层(4)，在制热碳浆层(4)上设有导电银浆线圈(5)，在导电银浆线圈(5)上设有外绝缘保护层(6)，在外绝缘保护层(5)上设有封底层(7)；电源接口(8)位于封底层(7)上。
2.根据权利要求1所述的一种除雾玻璃，其特征在于所述的玻璃基板(1)是钢化的平板玻璃。
3.根据权利要求1所述的一种除雾玻璃，其特征在于所述的镀膜层(2)是通过磁控溅射技术镀上的一层铝金属薄层。
4.根据权利要求1所述的一种除雾玻璃，其特征在于所述的封底层(7)为环氧树脂加防腐助剂。
5.一种如权利要求1所述的除雾玻璃的制造方法，其特征在于该制造方法包括：
步骤一：选取2-6mm厚的超白或普通浮法透明玻璃，进行切裁、磨边、钢化，形成钢化的平板玻璃作为玻璃基板(1)；
步骤二：在玻璃基板(1)的一面，通过磁控溅射技术覆盖镀膜层(2)；
步骤三：在镀膜层(2)上通过丝网印刷满面内绝缘保护层(3)，然后加热烘干固化；
步骤四：在烘干固化后的内绝缘保护层(3)上通过丝网印刷并排均匀的制热碳浆层(4)，然后加热烘干固化；
步骤五：在烘干后的并排均匀制热碳浆层(4)上通过丝网印刷导电银浆线圈(5)，使导电银浆线圈(5)与制热碳浆层(4)形成并联电路，然后加热烘干固化；
步骤六：在烘干固化后的并联电路上通过丝网印刷满面外绝缘保护层(6)，并预留出电源接口(8)，然后加热烘干固化；
步骤七：在烘干固化后的外绝缘保护层(6)上通过丝网印刷封底层(7)，并预留出电源接口(8)，然后加热烘干固化。
6.如权利要求5所述的一种除雾玻璃制造方法，其特征在于步骤三中内绝缘保护层(3)与步骤六中的外绝缘保护层(6)，使用100目—150目网板进行印刷后，170℃-200℃烘干7-8分钟固化形成。
7.如权利要求5所述的一种除雾玻璃制造方法，其特征在于步骤四中制热碳浆层(4)与步骤五中的导电银浆线圈(5)使用100目—200目网板进行印刷后，190℃-210℃烘干18-22分钟固化形成；制热碳浆是由按质量比为高阻碳浆:低阻碳浆为9:1组成；印刷的制热碳浆厚度要保持在100μ—150μ之间。
8.如权利要求5所述的一种除雾玻璃制造方法，其特征在于所述的导电银浆线圈厚度要保持在80μ—120μ之间。
9.如权利要求5所述的一种除雾玻璃制造方法，其特征在于步骤七中，封底层(7)采用高耐抗屏蔽封底油墨，使用100目-150目网板进行两次刮印后160℃-180℃烘干8-10分钟固化制成。
10.如权利要求5所述的一种除雾玻璃制造方法，其特征在于在步骤六、步骤七预留电源接口(8)过程中，必须保证外绝缘保护层(6)与封底保护层(7)印刷的一致性。
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| CN108724857A (zh) * | 2018-05-16 | 2018-11-02 | 浙江西溪玻璃有限公司 | 一种控温防雾玻璃的制备方法 |
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| CN103304153A (zh) * | 2013-06-26 | 2013-09-18 | 江苏秀强玻璃工艺股份有限公司 | 一种多层彩色玻璃板的制造方法 |
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| CN107311470A (zh) * | 2017-06-22 | 2017-11-03 | 江苏秀强玻璃工艺股份有限公司 | 一种多功能直印式涂层制热玻璃及其制造方法 |
| CN108724857A (zh) * | 2018-05-16 | 2018-11-02 | 浙江西溪玻璃有限公司 | 一种控温防雾玻璃的制备方法 |
| CN108724857B (zh) * | 2018-05-16 | 2020-09-04 | 浙江西溪玻璃有限公司 | 一种控温防雾玻璃的制备方法 |
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