CN106795052B - Core of preventing fires is rolled up and its manufacturing method - Google Patents
Core of preventing fires is rolled up and its manufacturing method Download PDFInfo
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- CN106795052B CN106795052B CN201680001046.2A CN201680001046A CN106795052B CN 106795052 B CN106795052 B CN 106795052B CN 201680001046 A CN201680001046 A CN 201680001046A CN 106795052 B CN106795052 B CN 106795052B
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- fire prevention
- core volume
- prevention core
- sheet material
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Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 58
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 185
- 230000002265 prevention Effects 0.000 claims abstract description 178
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 88
- 239000000839 emulsion Substances 0.000 claims abstract description 76
- 239000003365 glass fiber Substances 0.000 claims abstract description 45
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 44
- 239000006004 Quartz sand Substances 0.000 claims abstract description 43
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 42
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 42
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 42
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 41
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 41
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011256 inorganic filler Substances 0.000 claims abstract description 21
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 21
- 230000002708 enhancing effect Effects 0.000 claims abstract description 20
- 238000002485 combustion reaction Methods 0.000 claims abstract description 13
- 239000003112 inhibitor Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims description 164
- 239000000377 silicon dioxide Substances 0.000 claims description 70
- 239000002002 slurry Substances 0.000 claims description 60
- 235000013312 flour Nutrition 0.000 claims description 42
- 238000004804 winding Methods 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 30
- 238000001125 extrusion Methods 0.000 claims description 30
- 235000019362 perlite Nutrition 0.000 claims description 19
- 239000010451 perlite Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000010453 quartz Substances 0.000 claims 1
- 239000004576 sand Substances 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000011162 core material Substances 0.000 abstract description 185
- 239000006210 lotion Substances 0.000 abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 8
- 238000003306 harvesting Methods 0.000 abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 4
- 239000002174 Styrene-butadiene Substances 0.000 abstract description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011115 styrene butadiene Substances 0.000 abstract description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract description 4
- 238000010924 continuous production Methods 0.000 abstract description 2
- 239000011435 rock Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- VAJVDSVGBWFCLW-UHFFFAOYSA-N 3-Phenyl-1-propanol Chemical compound OCCCC1=CC=CC=C1 VAJVDSVGBWFCLW-UHFFFAOYSA-N 0.000 description 4
- DYUQAZSOFZSPHD-UHFFFAOYSA-N Phenylpropyl alcohol Natural products CCC(O)C1=CC=CC=C1 DYUQAZSOFZSPHD-UHFFFAOYSA-N 0.000 description 4
- 210000000481 breast Anatomy 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/02—Inorganic materials
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C8/00—Hand tools or accessories specially adapted for fire-fighting, e.g. tool boxes
- A62C8/06—Fire-blankets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Laminated Bodies (AREA)
- Building Environments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
This case discloses a kind of fire prevention core volume and its manufacturing method, and fire prevention core volume includes water-based emulsion, inorganic combustion inhibitor, inorganic filler and enhancing aggregate;Wherein, the water-based emulsion is one or more in styrene-acrylic emulsion, styrene-butadiene emulsion, acrylic emulsion, acrylate and vinyl acetate emulsion and VAE lotions;The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;The inorganic filler is selected from calcium carbonate, quartz sand or combination;The enhancing aggregate is glass fibre.This case is improved and is optimized by the component to existing fire prevention core material and manufacturing process so that the core material prepared has excellent flexibility and intensity, at low temperature also can harvest coil structure, suitable for continuous production operation;Flexible sandwich layer performance also provides more wide shape-designing space for the production board after processing, greatly expands the application range of the product.
Description
Technical field
The present invention relates to fire prevention board core material field, more particularly to a kind of A2 grades of fire prevention core volume and its manufacturing method.
Background technology
The international at present and domestic precedent that A2 grades of fire prevention sandwich layers are not made to web-like.Existing technology is that sandwich layer is straight
It connects and A2 grades of fireproof metal composite plates is made, manufacture sandwich layer is connected as a single entity with the process of manufacture composite plate.And the manufacture of core volume
It is then separately to carry out two processes.Integration production underaction is convenient, and production line occupied ground is larger.Entire production process
For the more demanding of operating personnel, it is unfavorable for the popularization and application of product and equipment.
Fire-proof plate core plate of the prior art mostly based on calcium carbonate, polypropylene short fiber, zinc molybdate and acrylic emulsion,
And due to the restriction of respective content ratio, cause core plate toughness that this scheme obtains and intensity poor, it can not harvest web-like.And
And in production technology of the prior art by the way of heated at constant temperature so that the solidification effect of glue and additive is poor, makes
The peel strength for the core plate that must be obtained is relatively low.
Invention content
For the shortcomings of the prior art, the present invention provides a kind of A2 grades of fire prevention core volume and its manufacturing method.
Technical scheme of the present invention is summarized as follows:
A kind of fire prevention core volume, in parts by weight, including at least having 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers and 1-5 parts of enhancing aggregates.
Preferably, fire prevention core volume, wherein, the water-based emulsion is selected from styrene-acrylic emulsion, styrene-butadiene emulsion, acrylic acid
It is one or more in lotion, acrylate and vinyl acetate emulsion and VAE lotions;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
Preferably, fire prevention core volume, wherein, in parts by weight, 114-123 parts of water-based emulsion, inorganic combustion inhibitor
200-350 parts, 250-350 parts of inorganic filler, enhancing 2-4 parts of aggregate.
Preferably, fire prevention core volume, wherein, in parts by weight, 120 parts of water-based emulsion, inorganic combustion inhibitor 260
3 parts part, 300 parts of inorganic filler, enhancing of aggregate.
Preferably, fire prevention core volume, wherein, the solid content of the water-based emulsion is 50-55wt%, and viscosity is
600-5000cps, pH value 4-8.
Preferably, fire prevention core volume, wherein, further include 15-25 parts of silica flours in the fire prevention core volume.
Preferably, fire prevention core volume, wherein, the silica flour is 18-21 parts.
Preferably, fire prevention core volume, wherein, the silica flour is 20 parts.
Preferably, fire prevention core volume, wherein, further include 1-10 parts of perlites in the fire prevention core volume.
Preferably, fire prevention core volume, wherein, the perlite is 2-7 parts.
Preferably, fire prevention core volume, wherein, the perlite is 5 parts.
Preferably, fire prevention core volume, wherein, further include 5-10 parts of cenospheres in the fire prevention core volume.
Preferably, fire prevention core volume, wherein, the cenosphere is 6-8 parts.
Preferably, fire prevention core volume, wherein, the cenosphere is 7 parts.
Preferably, fire prevention core volume, wherein, further include 15-25 parts of silica in the fire prevention core volume.
Preferably, fire prevention core volume, wherein, the silica is 19-23 parts.
Preferably, fire prevention core volume, wherein, the silica is 20 parts.
Preferably, fire prevention core volume, wherein, in parts by weight, include:120-280 parts of calcium carbonate, silica flour
15-25 parts, 60-120 parts of quartz sand, 1-10 parts of perlite, 5-10 parts of cenosphere, 5-25 parts of silica 1, aluminium hydroxide
100-300 parts, 50-150 parts of magnesium hydroxide, 1-5 parts of glass fibre, 110-130 parts of styrene-acrylic emulsion.
Preferably, fire prevention core volume, wherein, in parts by weight, include:228-275 parts of calcium carbonate, silica flour
17-21 parts, 60-118 parts of quartz sand, 3-9 parts of perlite, 7-9 parts of cenosphere, 7-22 parts of silica 1, aluminium hydroxide 155-
195 parts, 65-95 parts of magnesium hydroxide, 2-4 parts of glass fibre, 117-123 parts of styrene-acrylic emulsion.
Preferably, fire prevention core volume, wherein, in parts by weight, 240 parts of calcium carbonate, 20 parts of silica flour, quartz sand 60
Part, 5 parts of perlite, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre,
120 parts of styrene-acrylic emulsion.
A kind of manufacturing method of as above any one of them fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Preferably, the manufacturing method of the fire prevention core volume, wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 10-20 minutes at 80-130 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 10-20 minutes at 120-150 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 10-15 minutes at 150-180 DEG C.
Preferably, the manufacturing method of the fire prevention core volume, wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 13-18 minutes at 87-122 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 11-17 minutes at 126-143 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 11-14 minutes at 154-172 DEG C.
Preferably, the manufacturing method of the fire prevention core volume, wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 115 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The beneficial effects of the invention are as follows:It is rolled using core and makes the method separated with composite manufacturing, then can solve above-mentioned ask
Topic.The fire prevention core that producer need to only use the equipment complex of back segment and prepare is rolled up, you can produces finished product composite plate, so both
Reduce place occupancy, the occupation of capital, while reduce technical threshold again, it is easy to operation, convenient for promoting.It but will script one
The sandwich layer of body metaplasia production is prepared into core volume, needs to overcome many technology barriers, such as flexibility, combustion heat value, peel strength
Deng.
This case is improved and is optimized by the component to existing fire prevention core material and manufacturing process so that the core prepared
Material has excellent flexibility and intensity, at low temperature also can harvest coil structure, suitable for continuous production operation;It is making
When making fire-proof board, it is only necessary to release core material by unreeling, reuse equipment complex and core material is manufactured fireproof metal
Composite plate both saves transportation cost in this way, decreases fund input of the manufacturer in production line;Since Compound Machining only needs
Want an equipment complex, therefore do not limited by place, technical operation is greatly simplified, to worker's skills involved in the labour rely on compared with
It is small, it is easy to be extended and applied;It is empty that flexible sandwich layer performance also provides more wide shape-designing for the production board after processing
Between, greatly expand the application range of the product.
Description of the drawings
Fig. 1 is the process flow chart of manufacturing method that core is rolled up of preventing fires.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, to enable those skilled in the art with reference to specification
Word can be implemented according to this.
The fire prevention core volume of an embodiment is listed in this case, includes water-based emulsion, inorganic combustion inhibitor, inorganic filler and enhancing
Aggregate;
Wherein, water-based emulsion in styrene-acrylic emulsion, styrene-butadiene emulsion, acrylic emulsion, acrylate and vinyl acetate emulsion and VAE lotions one
Kind is a variety of;Water-based emulsion plays cementation, while provides core material with certain flexibility.
Inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
Inorganic filler is selected from calcium carbonate, quartz sand or combination;Inorganic filler plays filling effect.
Enhancing aggregate is glass fibre.The effect of glass fibre is to increase the intensity of core material.
Wherein, the solid content of water-based emulsion is preferably 50-55wt%, and viscosity is preferably 600-5000cps, and pH value is preferably
4-8.If beyond preferred range, the flexibility for leading to core material is affected, surface is cracked, under the peel strength of core material
Drop.
Wherein, silica flour has been further included in fire prevention core volume.Silica flour is a kind of for improving the packing material of core material toughness, its energy
Enough improve the bending fatigue resistance of core volume.
Wherein, perlite has been further included in fire prevention core volume.The effect of perlite is the proportion of lightening core volume.
Wherein, cenosphere has been further included in fire prevention core volume.The effect of cenosphere is before core volume toughness is not influenced
It puts, the proportion of lightening core volume, meanwhile, it also can help to improve the peel strength of core volume.
Wherein, silica has been further included in fire prevention core volume.The effect of silica is that collaboration water-based emulsion improves core volume
Whole intensity promotes the cohesive force of core volume, and core volume is made to take into account toughness and certain mechanical strength.
Wherein, there are a preferred proportional region between each component, so that the core volume obtained has more preferably performance.With
Parts by weight meter, 120-280 parts of calcium carbonate, 15-25 parts of silica flour, 60-120 parts of quartz sand, 1-10 parts of perlite, cenosphere 5-10
Part, 5-25 parts of silica 1,100-300 parts of aluminium hydroxide, 50-150 parts of magnesium hydroxide, 1-5 parts of glass fibre, styrene-acrylic emulsion
110-130 parts.Above-mentioned formula is an organic whole, from the point of view of the globality, if the content deviation of some component therein is excellent
The range of choosing, then by cause the core prepared roll up performance be affected, and it is this influence not only with corresponding function
Ingredient is related, such as:If only reducing the content of aluminium hydroxide, not only flame retardant property declines, toughness and peel strength
It is similarly subjected to influence;If improving the content of water-based emulsion, the bending property for equally also resulting in core volume declines.Come with water-based emulsion
It says, the effect outline of styrene-acrylic emulsion is better than styrene-butadiene emulsion, acrylic emulsion, acrylate and vinyl acetate emulsion and VAE lotions.
Wherein, in parts by weight, include also there are a more preferably ratio in above-mentioned preferred proportional region:Carbon
Sour calcium 228-275 parts, 17-21 parts of silica flour, 60-118 parts of quartz sand, 3-9 parts of perlite, 7-9 parts of cenosphere, silica
17-22 parts, 155-195 parts of aluminium hydroxide, 65-95 parts of magnesium hydroxide, 2-4 parts of glass fibre, 117-123 parts of styrene-acrylic emulsion.
Wherein, also there are an optimal ratios, in parts by weight, calcium carbonate 240 in above-mentioned preferred proportional region
Part, 20 parts of silica flour, 60 parts of quartz sand, 5 parts of perlite, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, hydrogen-oxygen
Change 80 parts of magnesium, 3 parts of glass fibre, 120 parts of styrene-acrylic emulsion.
A kind of manufacturing method of as above any one of them fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 10-20 minutes at 80-130 DEG C, starts primary solidification;
S2:The actual temperature of sheet material is controlled to be toasted 10-20 minutes, at 120-150 DEG C to slough moisture;
S3:The actual temperature of sheet material is controlled to toast 10-15 minutes at 150-180 DEG C, water is further sloughed by high temperature
Point, to form intensity.
It can be by sheet sandwich layer harvest web-like by this case technique.The sandwich layer of the prior art be all do not have it is flexible,
It can not harvest coil structure.This case formula and technique have taken into account the flexibility and intensity of sandwich layer, can be continuously produced operation.
The sandwich layer of conventional 3mm thickness can core volume of the harvest length for 500m.The smooth flawless of plate face, core volume are internal close
It is real, intensity and toughness are had both, can be arbitrarily bent, core two side edges of volume are neat, both artistic and practical.
In use, only needing to release core plate by unreeling, reuse equipment complex and core plate is manufactured into fire prevention gold
Belong to composite plate.Transportation cost is both greatly saved in this way, decreases the fund input of production line.Since Compound Machining only needs
One equipment complex, therefore do not limited by place.Technical operation is greatly simplified, smaller to the dependence of worker's skills involved in the labour,
It is easy to be extended and applied.Flexible sandwich layer performance also provides more wide shape-designing space for the production board after processing,
Greatly expand the application range of the product.
Embodiment 1
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 60 parts of quartz sand, aluminium hydroxide 100
Part, 50 parts of magnesium hydroxide, 1 part of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 10 minutes at 80 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 10 minutes at 120 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 10 minutes at 150 DEG C.
The density of fire prevention core volume obtained is 1.70g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.5N/mm, the smooth flawless of rear surface is wound.
Embodiment 2
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 120 parts of quartz sand, aluminium hydroxide 300
Part, 150 parts of magnesium hydroxide, 5 parts of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 20 minutes at 130 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 20 minutes at 150 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 15 minutes at 180 DEG C.
The density of fire prevention core volume obtained is 1.73g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.6N/mm, the smooth flawless of rear surface is wound.
Embodiment 3
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 60 parts of quartz sand, aluminium hydroxide 300
Part, 50 parts of magnesium hydroxide, 1 part of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 10 minutes at 130 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 10 minutes at 130 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 10 minutes at 150 DEG C.
The density of fire prevention core volume obtained is 1.71g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.6N/mm, the smooth flawless of rear surface is wound.
Embodiment 4
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 120 parts of quartz sand, aluminium hydroxide 100
Part, 150 parts of magnesium hydroxide, 5 parts of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 10 minutes at 80 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 10 minutes at 150 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 10 minutes at 180 DEG C.
The density of fire prevention core volume obtained is 1.69g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.3N/mm, the smooth flawless of rear surface is wound.
Embodiment 5
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 15 parts of silica flour, 60 parts of quartz sand, hydrogen-oxygen
Change 100 parts of aluminium, 50 parts of magnesium hydroxide, 1 part of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.76g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.3N/mm, the smooth flawless of rear surface is wound.
Embodiment 6
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 25 parts of silica flour, 120 parts of quartz sand, hydrogen
300 parts of aluminium oxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.77g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.3N/mm, the smooth flawless of rear surface is wound.
Embodiment 7
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 15 parts of silica flour, 120 parts of quartz sand, hydrogen
100 parts of aluminium oxide, 150 parts of magnesium hydroxide, 1 part of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 12 minutes at 120 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 13 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 11 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.77g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.2N/mm, the smooth flawless of rear surface is wound.
Embodiment 8
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 25 parts of silica flour, 60 parts of quartz sand, hydrogen-oxygen
Change 300 parts of aluminium, 50 parts of magnesium hydroxide, 5 parts of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 14 minutes at 80 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 13 minutes at 130 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 160 DEG C.
The density of fire prevention core volume obtained is 1.75g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.4N/mm, the smooth flawless of rear surface is wound.
Embodiment 9
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 15 parts of silica flour, 60 parts of quartz sand, pearl
1 part of rock, 100 parts of aluminium hydroxide, 50 parts of magnesium hydroxide, 1 part of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.75g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.9N/mm, the smooth flawless of rear surface is wound.
Embodiment 10
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 25 parts of silica flour, 120 parts of quartz sand are precious
10 parts of pearl rock, 300 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.75g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 8.0N/mm, the smooth flawless of rear surface is wound.
Embodiment 11
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 15 parts of silica flour, 120 parts of quartz sand are precious
1 part of pearl rock, 300 parts of aluminium hydroxide, 50 parts of magnesium hydroxide, 5 parts of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 14 minutes at 110 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 14 minutes at 125 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 13 minutes at 155 DEG C.
The density of fire prevention core volume obtained is 1.76g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.8N/mm, the smooth flawless of rear surface is wound.
Embodiment 12
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 25 parts of silica flour, 60 parts of quartz sand, pearl
10 parts of rock, 100 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 1 part of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 110 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 145 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 175 DEG C.
The density of fire prevention core volume obtained is 1.74g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 7.7N/mm, the smooth flawless of rear surface is wound.
Embodiment 13
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 15 parts of silica flour, 60 parts of quartz sand, pearl
1 part of rock, 5 parts of cenosphere, 100 parts of aluminium hydroxide, 50 parts of magnesium hydroxide, 1 part of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.79g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 9.1N/mm, the smooth flawless of rear surface is wound.
Embodiment 14
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 25 parts of silica flour, 120 parts of quartz sand are precious
10 parts of pearl rock, 10 parts of cenosphere, 300 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.80g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 9.2N/mm, the smooth flawless of rear surface is wound.
Embodiment 15
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 15 parts of silica flour, 120 parts of quartz sand are precious
1 part of pearl rock, 5 parts of cenosphere, 300 parts of aluminium hydroxide, 50 parts of magnesium hydroxide, 5 parts of glass fibre, 110 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.78g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 9.0N/mm, the smooth flawless of rear surface is wound.
Embodiment 16
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 25 parts of silica flour, 60 parts of quartz sand, pearl
10 parts of rock, 5 parts of cenosphere, 100 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 1 part of glass fibre, 130 parts of styrene-acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 13 minutes at 110 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 13 minutes at 145 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 13 minutes at 170 DEG C.
The density of fire prevention core volume obtained is 1.77g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 8.9N/mm, the smooth flawless of rear surface is wound.
Embodiment 17
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 15 parts of silica flour, 60 parts of quartz sand, pearl
1 part of rock, 5 parts of cenosphere, 5 parts of silica 1,100 parts of aluminium hydroxide, 50 parts of magnesium hydroxide, 1 part of glass fibre, phenylpropyl alcohol breast
110 parts of liquid.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.89g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 10.1N/mm, the smooth flawless of rear surface is wound.
Embodiment 18
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 25 parts of silica flour, 120 parts of quartz sand are precious
10 parts of pearl rock, 10 parts of cenosphere, 25 parts of silica, 300 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, benzene
130 parts of acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.90g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 10.0N/mm, the smooth flawless of rear surface is wound.
Embodiment 19
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 15 parts of silica flour, 120 parts of quartz sand are precious
1 part of pearl rock, 5 parts of cenosphere, 25 parts of silica, 100 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 1 part of glass fibre, phenylpropyl alcohol
130 parts of lotion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.90g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 10.3N/mm, the smooth flawless of rear surface is wound.
Embodiment 20
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 25 parts of silica flour, 60 parts of quartz sand, pearl
10 parts of rock, 5 parts of cenosphere, 25 parts of silica, 100 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, phenylpropyl alcohol
110 parts of lotion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.90g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 10.0N/mm, the smooth flawless of rear surface is wound.
Embodiment 21
A kind of fire prevention core volume, in parts by weight, includes:240 parts of calcium carbonate, 20 parts of silica flour, 60 parts of quartz sand, pearl
5 parts of rock, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre, phenylpropyl alcohol breast
120 parts of liquid.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.84g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 11.0N/mm, the smooth flawless of rear surface is wound.
Embodiment 22
A kind of fire prevention core volume, in parts by weight, includes:240 parts of calcium carbonate, 20 parts of silica flour, 60 parts of quartz sand, pearl
5 parts of rock, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre, butylbenzene breast
120 parts of liquid.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.77g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.8N/mm, the smooth flawless of rear surface is wound.
Embodiment 23
A kind of fire prevention core volume, in parts by weight, includes:240 parts of calcium carbonate, 20 parts of silica flour, 60 parts of quartz sand, pearl
5 parts of rock, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre, acrylic acid
120 parts of lotion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.71g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.6N/mm, the smooth flawless of rear surface is wound.
Embodiment 24
A kind of fire prevention core volume, in parts by weight, includes:240 parts of calcium carbonate, 20 parts of silica flour, 60 parts of quartz sand, pearl
5 parts of rock, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre, the third breast of vinegar
120 parts of liquid.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.72g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.7N/mm, the smooth flawless of rear surface is wound.
Embodiment 25
A kind of fire prevention core volume, in parts by weight, includes:240 parts of calcium carbonate, 20 parts of silica flour, 60 parts of quartz sand, pearl
5 parts of rock, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide, 3 parts of glass fibre, VAE lotions
120 parts.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.74g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 6.5N/mm, the smooth flawless of rear surface is wound.
Comparative example 1
A kind of fire prevention core volume, in parts by weight, includes:280 parts of calcium carbonate, 25 parts of silica flour, 120 parts of quartz sand are precious
10 parts of pearl rock, 10 parts of cenosphere, 25 parts of silica, 300 parts of aluminium hydroxide, 150 parts of magnesium hydroxide, 5 parts of glass fibre, benzene
131 parts of acrylic emulsion.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.65g/cm3, calorific value≤3.0MJ/kg reaches A2 grades of standards;Peel strength
For 5.9N/mm, winding rear surface has fine crack.
Comparative example 2
A kind of fire prevention core volume, in parts by weight, includes:120 parts of calcium carbonate, 15 parts of silica flour, 60 parts of quartz sand, pearl
1 part of rock, 5 parts of cenosphere, 5 parts of silica 1,99 parts of aluminium hydroxide, 49 parts of magnesium hydroxide, 1 part of glass fibre, styrene-acrylic emulsion
110 parts.
The manufacturing method of fire prevention core volume, including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
Wherein, in step 3), baking includes the following steps:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 100 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
The density of fire prevention core volume obtained is 1.62g/cm3, calorific value=3.1MJ/kg, not up to A2 grade standard;Stripping is strong
It spends for 6.1N/mm, winding rear surface has fine crack.
Although the embodiments of the present invention have been disclosed as above, but its be not restricted in specification and embodiment it is listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, it is of the invention and unlimited
In specific details.
Claims (23)
1. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers and 1-5 parts of enhancing aggregate compositions;
The water-based emulsion is styrene-acrylic emulsion;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
2. fire prevention core volume according to claim 1, which is characterized in that in parts by weight, 114-123 parts of water-based emulsion, nothing
2-4 parts 200-350 parts of machine fire retardant, 250-350 parts of inorganic filler, enhancing of aggregate.
3. fire prevention core volume according to claim 1, which is characterized in that in parts by weight, 120 parts of water-based emulsion, inorganic resistance
Fire 3 parts 260 parts of agent, 300 parts of inorganic filler, enhancing of aggregate.
4. fire prevention core volume according to claim 1, which is characterized in that the solid content of the water-based emulsion is 50-55wt%,
Viscosity is 600-5000cps, pH value 4-8.
5. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers, 1-5 parts of enhancing aggregates and 15-25 parts of silica flour compositions;
The water-based emulsion is styrene-acrylic emulsion;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
6. fire prevention core volume according to claim 5, which is characterized in that the silica flour is 18-21 parts.
7. fire prevention core volume according to claim 6, which is characterized in that the silica flour is 20 parts.
8. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers, 1-5 parts of enhancing aggregates, 15-25 parts of silica flours and 1-10 parts of perlite compositions;
The water-based emulsion is styrene-acrylic emulsion;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
9. fire prevention core volume according to claim 8, which is characterized in that the perlite is 2-7 parts.
10. fire prevention core volume according to claim 9, which is characterized in that the perlite is 5 parts.
11. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers, 1-5 parts of enhancing aggregates, 15-25 parts of silica flours, 1-10 parts of perlites and 5-10 parts of cenospheres
Composition;
The water-based emulsion is styrene-acrylic emulsion;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
12. fire prevention core volume according to claim 11, which is characterized in that the cenosphere is 6-8 parts.
13. fire prevention core volume according to claim 12, which is characterized in that the cenosphere is 7 parts.
14. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 110-130 parts of water-based emulsions, 150-450 parts of inorganic resistances
Fire agent, 180-400 parts of inorganic fillers, 1-5 parts of enhancing aggregates, 15-25 parts of silica flours, 1-10 parts of perlites, 5-10 parts of cenospheres
It is formed with 15-25 parts of silica;
The water-based emulsion is styrene-acrylic emulsion;
The inorganic combustion inhibitor is selected from aluminium hydroxide, magnesium hydroxide or combination;
The inorganic filler is selected from calcium carbonate, quartz sand or combination;
The enhancing aggregate is glass fibre.
15. fire prevention core volume according to claim 14, which is characterized in that the silica is 19-23 parts.
16. fire prevention core volume according to claim 15, which is characterized in that the silica is 20 parts.
17. a kind of fire prevention core volume, which is characterized in that in parts by weight, by 120-280 parts of calcium carbonate, 15-25 parts of silica flour, quartz
60-120 parts of sand, 1-10 parts of perlite, 5-10 parts of cenosphere, 5-25 parts of silica 1,100-300 parts of aluminium hydroxide, hydrogen-oxygen
Change 50-150 parts of magnesium, 110-130 parts of compositions of 1-5 parts of glass fibre and styrene-acrylic emulsion.
18. fire prevention core volume according to claim 17, which is characterized in that in parts by weight, 228-275 parts of calcium carbonate, silicon
17-21 parts of powder, 60-118 parts of quartz sand, 3-9 parts of perlite, 7-9 parts of cenosphere, 7-22 parts of silica 1, aluminium hydroxide
155-195 parts, 65-95 parts of magnesium hydroxide, 2-4 parts of glass fibre, 117-123 parts of styrene-acrylic emulsion.
19. fire prevention core volume according to claim 18, which is characterized in that in parts by weight, 240 parts of calcium carbonate, silica flour 20
Part, 60 parts of quartz sand, 5 parts of perlite, 8 parts of cenosphere, 20 parts of silica, 180 parts of aluminium hydroxide, 80 parts of magnesium hydroxide,
3 parts of glass fibre, 120 parts of styrene-acrylic emulsion.
20. a kind of manufacturing method of fire prevention core volume as described in any one of claim 1-19, which is characterized in that including:
Step 1):Each component is weighed in proportion, is stirred under vacuum, and slurry is made;
Step 2):Slurry is put into extrusion equipment, sheet material is made;
Step 3):Sheet material feeding oven is toasted;
Step 4):Overlay film is carried out to sheet surface;
Step 5):Fire prevention core volume is made in cooling, winding.
21. it is according to claim 20 fire prevention core volume manufacturing method, which is characterized in that in step 3), baking include with
Lower step:
S1:The actual temperature of sheet material is controlled to be toasted 10-20 minutes at 80-130 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 10-20 minutes at 120-150 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 10-15 minutes at 150-180 DEG C.
22. it is according to claim 21 fire prevention core volume manufacturing method, which is characterized in that in step 3), baking include with
Lower step:
S1:The actual temperature of sheet material is controlled to be toasted 13-18 minutes at 87-122 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 11-17 minutes at 126-143 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 11-14 minutes at 154-172 DEG C.
23. it is according to claim 22 fire prevention core volume manufacturing method, which is characterized in that in step 3), baking include with
Lower step:
S1:The actual temperature of sheet material is controlled to be toasted 15 minutes at 115 DEG C;
S2:The actual temperature of sheet material is controlled to be toasted 15 minutes at 135 DEG C;
S3:The actual temperature of sheet material is controlled to be toasted 12 minutes at 165 DEG C.
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PCT/CN2016/098013 WO2018040079A1 (en) | 2016-09-05 | 2016-09-05 | Fireproof core coil and manufacturing method therefor |
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CN106795052B true CN106795052B (en) | 2018-06-12 |
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CN108395200A (en) * | 2018-03-30 | 2018-08-14 | 江苏阿路美格新材料股份有限公司 | Fire-resistant composite panel core material and preparation method thereof |
WO2019203812A1 (en) * | 2018-04-18 | 2019-10-24 | Arconic Inc. | Flame retardant composition and composite panel |
CN108859302B (en) * | 2018-06-22 | 2020-11-13 | 浙江阿路佑邦新材料科技有限公司 | A2-grade fireproof copper composite board and production method thereof |
CN113635622A (en) * | 2021-08-12 | 2021-11-12 | 北京赛博思工程技术研究院 | Mineral core fireproof refrigeration inorganic heat-insulation composite board |
CN113530117A (en) * | 2021-08-12 | 2021-10-22 | 北京赛博思工程技术研究院 | Mineral core fireproof refrigeration organic heat insulation composite board |
CN113968693A (en) * | 2021-10-28 | 2022-01-25 | 江苏阿路美格新材料股份有限公司 | Fireproof core material and manufacturing method thereof |
CN113802791A (en) * | 2021-10-28 | 2021-12-17 | 江苏阿路美格新材料股份有限公司 | Fire prevention heat preservation decorative structure |
CN113818583A (en) * | 2021-10-28 | 2021-12-21 | 江苏阿路美格新材料股份有限公司 | Fireproof structure with single-layer metal layer |
CN113913072B (en) * | 2021-11-02 | 2022-10-14 | 雨中情防水技术集团股份有限公司 | Flame-retardant isolation sand for asphalt-based pre-laid waterproof coiled material and preparation method thereof |
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CN116119982A (en) * | 2022-11-03 | 2023-05-16 | 凌岫(福建)装配式建筑有限公司 | Fireproof plate of composite floating beads and magnesium crystalline silicon and processing technology thereof |
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- 2016-09-05 RU RU2017123079A patent/RU2669839C1/en active
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